Highside Chemicals Inc. 22008, 22032, 22128 User Manual

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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 09.04.2013 Revision: 09.04.2013
1 Identification of the substance/mixture and of the company/undertaking
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Trade name: GAS LEAK DETECTOR - LOW TEMP
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Article number:
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1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
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Application of the substance / the preparation
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1.3 Details of the supplier of the Safety Data Sheet
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Manufacturer/Supplier:
Highside Chemicals, Inc. 11114 Reichold Road Gulfport, MS 39503 USA Phone: (228) 896-9220
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1.4 Emergency telephone number:
ChemTel Inc. (800)255-3924, +1 (813)248-0585
22008, 22032, 22128
Leak detection fluid
2 Hazards identification
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2.1 Classification of the substance or mixture
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Classification according to Regulation (EC) No 1272/2008
GHS07
Eye Irrit. 2 H319 Causes serious eye irritation.
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Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Xi; Irritant
R36: Irritating to eyes.
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Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version.
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Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature data. The classification is in accordance with the latest editions of international substances lists, and is supplemented by information from technical literature and by information provided by the company.
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2.2 Label elements
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Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
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Hazard pictograms
GHS07
(Contd. on page 2)
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Page 2
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 09.04.2013 Revision: 09.04.2013
Trade name: GAS LEAK DETECTOR - LOW TEMP
(Contd. of page 1)
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Signal word
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Hazard statements
H319 Causes serious eye irritation.
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Precautionary statements
P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read label before use. P280 Wear protective gloves/protective clothing/eye protection/face protection. P264 Wash thoroughly after handling. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
P337+P313 If eye irritation persists: Get medical advice/attention.
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Hazard description:
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WHMIS-symbols:
D2B - Toxic material causing other toxic effects
Warning
present and easy to do. Continue rinsing.
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NFPA ratings (scale 0 - 4)
Health = 2
200
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HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
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HMIS Long Term Health Hazard Substances
Fire = 0 Reactivity = 0
*2
Health = *2
0
Fire = 0
0
Reactivity = 0
None of the ingredients is listed.
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2.3 Other hazards
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Results of PBT and vPvB assessment
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PBT:
Not applicable.
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vPvB:
Not applicable.
3 Composition/information on ingredients
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3.2 Mixtures
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Description:
Mixture of substances listed below with nonhazardous additions.
(Contd. on page 3)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 09.04.2013 Revision: 09.04.2013
Trade name: GAS LEAK DETECTOR - LOW TEMP
(Contd. of page 2)
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Dangerous components:
CAS: 57-55-6 EINECS: 200-338-0
CAS: 9016-45-9 4-nonylphenyl-polyethylene glycol
CAS: 68603-42-9 EINECS: 271-657-0
CAS: 111-42-2 EINECS: 203-868-0 Index number: 603-071-00-1
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Additional information:
Propylene Glycol substance with a Community workplace exposure limit
Xi R41; N R50 Eye Dam. 1, H318
Aquatic Acute 1, H400
Coconut diethanolamide
Xi R36/38 Skin Irrit. 2, H315; Eye Irrit. 2, H319
Proprietary Anionic/Nonionic Detergent Blend
Xn R22; Xi R36/38; N R51/53 Aquatic Chronic 2, H411
Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2, H319
2,2'-iminodiethanol
Xn R22-48/22; Xi R38-41 STOT RE 2, H373
Eye Dam. 1, H318 Acute Tox. 4, H302; Skin Irrit. 2, H315
For the wording of the listed risk phrases refer to section 16.
25-50%
<10%
<10%
<10%
<1,0%
4 First aid measures
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4.1 Description of first aid measures
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General information:
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After inhalation:
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After skin contact:
Immediately rinse with water. If skin irritation continues, consult a doctor.
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After eye contact:
Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
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After swallowing:
Rinse out mouth and then drink plenty of water. Do not induce vomiting; call for medical help immediately.
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4.2 Most important symptoms and effects, both acute and delayed
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Hazards
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4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
If swallowed, gastric irrigation with added, activated carbon. Medical supervision for at least 48 hours. Treat skin and mucous membrane with antihistamine and corticoid preparations. In cases of irritation to the lungs, initial treatment with cortical steroid inhalants. If necessary oxygen respiration treatment.
No special measures required.
Supply fresh air; consult doctor in case of complaints.
Gastric or intestinal disorders
(Contd. on page 4)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 09.04.2013 Revision: 09.04.2013
Trade name: GAS LEAK DETECTOR - LOW TEMP
(Contd. of page 3)
5 Firefighting measures
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5.1 Extinguishing media
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Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
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For safety reasons unsuitable extinguishing agents:
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5.2 Special hazards arising from the substance or mixture
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5.3 Advice for firefighters
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Protective equipment:
Wear self-contained respiratory protective device. Wear fully protective suit.
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Additional information
No further relevant information available.
6 Accidental release measures
None.
No further relevant information available.
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6.1 Personal precautions, protective equipment and emergency procedures
Particular danger of slipping on leaked/spilled product. Wear protective clothing. Ensure adequate ventilation
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6.2 Environmental precautions:
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6.3 Methods and material for containment and cleaning up:
No special measures required.
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Clean the affected area carefully; suitable cleaners are: Warm water and cleansing agent
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6.4 Reference to other sections
See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.
7 Handling and storage
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7.1 Precautions for safe handling
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Information about fire - and explosion protection:
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7.2 Conditions for safe storage, including any incompatibilities
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Storage:
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Requirements to be met by storerooms and receptacles:
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Information about storage in one common storage facility:
Store away from foodstuffs. Store away from oxidizing agents.
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Further information about storage conditions:
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7.3 Specific end use(s)
No further relevant information available.
No special precautions are necessary if used correctly.
No special measures required.
No special requirements.
Store in cool, dry conditions in well sealed receptacles.
(Contd. on page 5)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 09.04.2013 Revision: 09.04.2013
Trade name: GAS LEAK DETECTOR - LOW TEMP
(Contd. of page 4)
8 Exposure controls/personal protection
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Additional information about design of technical facilities:
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8.1 Control parameters
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Ingredients with limit values that require monitoring at the workplace: 57-55-6 Propylene Glycol
WEEL (USA) 10 mg/m³ EV (Canada) 155* 10** mg/m³, 50* ppm
*vapour and aerosol;**aerosol only
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DNELs
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PNECs
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Additional information:
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8.2 Exposure controls
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Personal protective equipment:
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General protective and hygienic measures:
No further relevant information available.
No further relevant information available.
The lists valid during the making were used as basis.
Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Avoid contact with the eyes. Avoid contact with the eyes and skin.
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Respiratory protection:
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Protection of hands:
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Eye protection:
Not required under normal conditions of use.
Rubber gloves
No further data; see item 7.
Safety glasses
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Body protection:
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Limitation and supervision of exposure into the environment
Not required under normal conditions of use.
No further relevant information available.
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Risk management measures
See Section 7 for additional information. No further relevant information available.
9 Physical and chemical properties
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9.1 Information on basic physical and chemical properties
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General Information
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Appearance:
Form: Colour:
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Odour:
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Odour threshold:
Liquid Greenish-Yellow. Mild Not determined.
(Contd. on page 6)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 09.04.2013 Revision: 09.04.2013
Trade name: GAS LEAK DETECTOR - LOW TEMP
(Contd. of page 5)
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pH-value:
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Change in condition
Melting point/Melting range: Boiling point/Boiling range:
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Flash point:
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Flammability (solid, gaseous):
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Ignition temperature:
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Decomposition temperature:
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Self-igniting:
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Danger of explosion:
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Explosion limits:
Lower: Upper:
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Vapour pressure at 20 °C:
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Density at 20 °C:
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Relative density
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Vapour density
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Evaporation rate
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Solubility in / Miscibility with
water:
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Partition coefficient (n-octanol/water):
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Viscosity:
Dynamic: Kinematic:
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Solvent content:
Organic solvents:
Solids content:
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9.2 Other information
Not determined.
Undetermined. 212 °F / 100 °C
Not applicable.
Not applicable.
>500 °F / >260 °C
Not determined.
Product is not self-igniting.
Product does not present an explosion hazard.
2,6 Vol % 12,6 Vol %
23 hPa
1,02 g/cm³ Not determined. Not determined. Not determined.
Fully miscible.
Not determined.
Not determined. Not determined.
Not determined.
Not determined. No further relevant information available.
10 Stability and reactivity
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10.1 Reactivity
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10.2 Chemical stability
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Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
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10.3 Possibility of hazardous reactions
Reacts with strong acids and alkali. Reacts with strong oxidizing agents.
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(Contd. on page 7)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 09.04.2013 Revision: 09.04.2013
Trade name: GAS LEAK DETECTOR - LOW TEMP
(Contd. of page 6)
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10.4 Conditions to avoid
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10.5 Incompatible materials:
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10.6 Hazardous decomposition products:
11 Toxicological information
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11.1 Information on toxicological effects
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Acute toxicity:
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Primary irritant effect:
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on the skin:
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on the eye:
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Sensitization:
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Additional toxicological information:
The product shows the following dangers according to the calculation m ethod of the General EU Classification Guidelines for Preparations as issued in the latest version: Irritant At long or repeated contact with skin it may cause dermatitis due to the degreasing effect of the solvent.
Slight irritant effect on skin and mucous membranes.
Irritating effect.
No sensitizing effects known.
No further relevant information available.
No further relevant information available.
Possible in traces.
12 Ecological information
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12.1 Toxicity
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Aquatic toxicity:
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12.2 Persistence and degradability
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12.3 Bioaccumulative potential
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12.4 Mobility in soil
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Ecotoxical effects:
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Remark:
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Additional ecological information:
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General notes:
Due to mechanical actions of the product (e.g. agglutinations) damages may occur.
This statement was deduced from products with a similar structure or composition. Due to available data on eliminability/decomposition and bioaccumulation potential a prolonged damage of the environment is unlikely. Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
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12.5 Results of PBT and vPvB assessment
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PBT:
Not applicable.
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vPvB:
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12.6 Other adverse effects
Not applicable.
The product contains materials that are harmful to the environment.
biodegradable
Does not accumulate in organisms
No further relevant information available.
No further relevant information available.
(Contd. on page 8)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 09.04.2013 Revision: 09.04.2013
Trade name: GAS LEAK DETECTOR - LOW TEMP
(Contd. of page 7)
13 Disposal considerations
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13.1 Waste treatment methods
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Recommendation
Small amounts may be diluted with plenty of water and washed away. Dispose of bigger amounts in accordance with Local Authority requirements.
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Uncleaned packaging:
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Recommendation:
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Recommended cleansing agents:
14 Transport information
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14.1 UN-Number
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DOT, ADR, ADN, IMDG, IATA
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14.2 UN proper shipping name
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DOT, ADR, ADN, IMDG, IATA
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14.3 Transport hazard class(es)
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DOT, ADR, ADN, IMDG, IATA
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Class
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14.4 Packing group
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DOT, ADR, IMDG, IATA
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14.5 Environmental hazards:
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Marine pollutant:
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14.6 Special precautions for user
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14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
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UN "Model Regulation":
Disposal must be made according to official regulations.
Water only.
N/A
N/A
N/A
N/A
No
Not applicable.
Not applicable.
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15 Regulatory information
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
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United States (USA)
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SARA
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Section 355 (extremely hazardous substances):
None of the ingredients is listed.
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Section 313 (Specific toxic chemical listings):
111-42-2 2,2'-iminodiethanol
(Contd. on page 9)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 09.04.2013 Revision: 09.04.2013
Trade name: GAS LEAK DETECTOR - LOW TEMP
(Contd. of page 8)
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TSCA (Toxic Substances Control Act):
All ingredients are listed.
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Proposition 65 (California):
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Chemicals known to cause cancer:
68603-42-9 Coconut diethanolamide
111-42-2 2,2'-iminodiethanol
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Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
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Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
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Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
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Carcinogenic Categories
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EPA (Environmental Protection Agency)
None of the ingredients is listed.
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IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
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TLV (Threshold Limit Value established by ACGIH)
111-42-2 2,2'-iminodiethanol A3
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NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
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OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
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Canada
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Canadian Domestic Substances List (DSL)
All ingredients are listed.
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Canadian Ingredient Disclosure list (limit 0.1%)
None of the ingredients is listed.
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Canadian Ingredient Disclosure list (limit 1%)
57-55-6 Propylene Glycol
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15.2 Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.
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Relevant phrases
H302 Harmful if swallowed. H315 Causes skin irritation. H318 Causes serious eye damage.
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(Contd. on page 10)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 09.04.2013 Revision: 09.04.2013
Trade name: GAS LEAK DETECTOR - LOW TEMP
(Contd. of page 9)
H319 Causes serious eye irritation. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H411 Toxic to aquatic life with long lasting effects.
R22 Harmful if swallowed. R36/38 Irritating to eyes and skin. R38 Irritating to skin. R41 Risk of serious damage to eyes. R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed. R50 Very toxic to aquatic organisms. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
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Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals ACGIH: American Conference of Governmental Industrial Hygienists NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) WHMIS: Workplace Hazardous Materials Information System (Canada) DNEL: Derived No-Effect Level (REACH) PNEC: Predicted No-Effect Concentration (REACH)
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Sources
SDS Prepared by: ChemTel Inc. 1305 North Florida Avenue Tampa, Florida USA 33602-2902 Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573 Website: www.chemtelinc.com
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