Page 1/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 26.12.2012 Revision: 26.12.2012
1 Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
·
Trade name: TRACE
·
Article number:
·
1.2 Relevant identified uses of the substance or mixture and uses advised against
·
No further relevant information available.
Application of the substance / the preparation
·
Oil Additive, Internal Refrigerant, and Lubricant Leak Detector.
1.3 Details of the supplier of the Safety Data Sheet
·
Manufacturer/Supplier:
·
Highside Chemicals, Inc.
11114 Reichold Road
Gulfport, MS 39503 USA
Phone: (228) 896-9220
1.4 Emergency telephone number:
·
ChemTel Inc.
(800)255-3924, +1 (813)248-0585
20004, 20016, 20128
2 Hazards identification
2.1 Classification of the substance or mixture
·
Classification according to Regulation (EC) No 1272/2008
·
GHS07
Acute Tox. 4 H332 Harmful if inhaled.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
·
Xn; Harmful
R20: Harmful by inhalation.
Information concerning particular hazards for human and environment:
·
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
Classification system:
·
The classification is according to the latest editions of the EU-lists, and extended by company and
literature data.
The classification is in accordance with the latest editions of international substances lists, and is
supplemented by information from technical literature and by information provided by the company.
2.2 Label elements
·
Labelling according to Regulation (EC) No 1272/2008
·
The product is classified and labelled according to the CLP regulation.
(Contd. on page 2)
Page 2/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 26.12.2012 Revision: 26.12.2012
Trade name: TRACE
(Contd. of page 1)
Hazard pictograms
·
GHS07
Signal word
·
Hazard-determining components of labelling:
·
1-(2-methyl-4-(2-methylphenylazo)phenylazo)-2-naphthol
Hazard statements
·
H332 Harmful if inhaled.
Precautionary statements
·
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
Hazard description:
·
WHMIS-symbols:
·
NFPA ratings (scale 0 - 4)
·
Warning
breathing.
Not hazardous under WHMIS.
Health = 1
110
HMIS-ratings (scale 0 - 4)
·
HEALTH
FIRE
REACTIVITY
HMIS Long Term Health Hazard Substances
·
Fire = 1
Reactivity = 0
1
Health = 1
1
Fire = 1
0
Reactivity = 0
None of the ingredients is listed.
2.3 Other hazards
·
Results of PBT and vPvB assessment
·
PBT:
·
·
Not applicable.
vPvB:
Not applicable.
3 Composition/information on ingredients
3.2 Mixtures
·
Description:
·
Mixture of substances listed below with nonhazardous additions.
(Contd. on page 3)
Page 3/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 26.12.2012 Revision: 26.12.2012
Trade name: TRACE
(Contd. of page 2)
Dangerous components:
·
CAS: 85-83-6
EINECS: 201-635-8
CAS: 91-44-1
EINECS: 202-068-9
CAS: 64742-44-5
EINECS: 265-146-1
Index number: 649-463-00-6
Additional information:
·
1-(2-methyl-4-(2-methylphenylazo)phenylazo)-2-naphthol
Xn R20/21; Xi R36/38
Acute Tox. 4, H312; Acute Tox. 4, H332; Skin Irrit. 2, H315;
Eye Irrit. 2, H319
7-(diethylamino)-4-methyl-2-benzopyrone
Xn R22; Xi R36; N R51/53
Aquatic Chronic 2, H411
Acute Tox. 4, H302; Eye Irrit. 2, H319
Distillates (petroleum), clay-treated heavy naphthenic
For the wording of the listed risk phrases refer to section 16.
< 10%
< 10%
>80%
4 First aid measures
4.1 Description of first aid measures
·
General information:
·
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
hours after the accident.
Take affected persons out into the fresh air.
After inhalation:
·
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms
persist.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:
·
Clean with water and soap.
If skin irritation continues, consult a doctor.
After eye contact:
·
Protect unharmed eye.
Rinse opened eye for several minutes under running water.
Remove contact lenses if worn.
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:
·
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
4.2 Most important symptoms and effects, both acute and delayed
·
Dizziness
Headache
Gastric or intestinal disorders
Hazards
·
4.3 Indication of any immediate medical attention and special treatment needed
·
If swallowed, gastric irrigation with added, activated carbon.
If necessary oxygen respiration treatment.
No further relevant information available.
(Contd. on page 4)
Page 4/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 26.12.2012 Revision: 26.12.2012
Trade name: TRACE
(Contd. of page 3)
5 Firefighting measures
5.1 Extinguishing media
·
Suitable extinguishing agents:
·
Alcohol resistant foam
Gaseous extinguishing agents
ABC powder
Carbon dioxide
Fire-extinguishing powder
For safety reasons unsuitable extinguishing agents:
·
5.2 Special hazards arising from the substance or mixture
·
In case of fire, the following can be released:
Carbon monoxide (CO)
Under certain fire conditions, traces of other toxic gases cannot be excluded.
5.3 Advice for firefighters
·
Protective equipment:
·
Wear self-contained respiratory protective device.
Wear fully protective suit.
Additional information
·
Cool endangered receptacles with water fog or haze.
Water with full jet
6 Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
·
Use respiratory protective device against the effects of fumes/dust/aerosol.
Wear protective equipment. Keep unprotected persons away.
Particular danger of slipping on leaked/spilled product.
Ensure adequate ventilation
6.2 Environmental precautions:
·
6.3 Methods and material for containment and cleaning up:
·
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
6.4 Reference to other sections
·
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Do not allow to enter sewers/ surface or ground water.
7 Handling and storage
7.1 Precautions for safe handling
·
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about fire - and explosion protection:
·
No special measures required.
(Contd. on page 5)
Page 5/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 26.12.2012 Revision: 26.12.2012
Trade name: TRACE
(Contd. of page 4)
7.2 Conditions for safe storage, including any incompatibilities
·
Storage:
·
Requirements to be met by storerooms and receptacles:
·
Avoid storage near extreme heat, ignition sources or open flame.
Information about storage in one common storage facility:
·
Store away from foodstuffs.
Store away from oxidizing agents.
Further information about storage conditions:
·
Store in cool, dry conditions in well sealed receptacles.
Keep container tightly sealed.
7.3 Specific end use(s)
·
8 Exposure controls/personal protection
No further relevant information available.
Additional information about design of technical facilities:
·
8.1 Control parameters
·
Ingredients with limit values that require monitoring at the workplace:
·
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
DNELs
·
PNECs
·
Additional information:
·
8.2 Exposure controls
·
Personal protective equipment:
·
General protective and hygienic measures:
·
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes and skin.
Respiratory protection:
·
Not necessary if room is well-ventilated.
Use suitable respiratory protective device in case of insufficient ventilation.
Use suitable respiratory protective device when aerosol or mist is formed.
Protection of hands:
·
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the produc t/ the
preparation/ the chemical mixture.
Selection of the glove m aterial on consideration of the penetration times, rates of diffusion and the
degradation
Material of gloves
·
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
No further relevant information available.
No further relevant information available.
The lists valid during the making were used as basis.
Protective gloves
No further data; see item 7.
(Contd. on page 6)
Page 6/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 26.12.2012 Revision: 26.12.2012
Trade name: TRACE
(Contd. of page 5)
checked prior to the application.
Penetration time of glove material
·
The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
For the permanent contact gloves made of the following materials are suitable:
·
Not suitable are gloves made of the following materials:
·
Eye protection:
·
Safety glasses
Body protection:
·
Limitation and supervision of exposure into the environment
·
No further relevant information available.
Risk management measures
·
See Section 7 for additional information.
No further relevant information available.
Protective work clothing
Leather gloves
Rubber gloves
9 Physical and chemical properties
9.1 Information on basic physical and chemical properties
·
General Information
·
Appearance:
·
Form:
Colour:
Odour:
·
Odour threshold:
·
pH-value:
·
Change in condition
·
Melting point/Melting range:
Boiling point/Boiling range:
Flash point:
·
Flammability (solid, gaseous):
·
Ignition temperature:
·
Decomposition temperature:
·
Self-igniting:
·
Danger of explosion:
·
Explosion limits:
·
Lower:
Upper:
Liquid
Red
Solvent-like
Not determined.
Not determined.
Undetermined.
Undetermined.
Not applicable.
Not applicable.
Not determined.
Not determined.
Product is not self-igniting.
Product does not present an explosion hazard.
Not determined.
Not determined.
(Contd. on page 7)
Page 7/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 26.12.2012 Revision: 26.12.2012
Trade name: TRACE
(Contd. of page 6)
Vapour pressure:
·
Density:
·
Relative density
·
Vapour density
·
Evaporation rate
·
Solubility in / Miscibility with
·
water:
Partition coefficient (n-octanol/water):
·
Viscosity:
·
Dynamic:
Kinematic:
Solvent content:
·
Organic solvents:
Solids content:
9.2 Other information
·
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Not miscible or difficult to mix.
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
No further relevant information available.
10 Stability and reactivity
10.1 Reactivity
·
10.2 Chemical stability
·
Thermal decomposition / conditions to be avoided:
·
No decomposition if used and stored according to specifications.
10.3 Possibility of hazardous reactions
·
10.4 Conditions to avoid
·
10.5 Incompatible materials:
·
10.6 Hazardous decomposition products:
·
Hydrocarbons
Carbon monoxide and carbon dioxide
No further relevant information available.
No further relevant information available.
Reacts with strong acids and oxidizing agents.
11 Toxicological information
11.1 Information on toxicological effects
·
Acute toxicity:
·
Primary irritant effect:
·
on the skin:
·
on the eye:
·
Sensitization:
·
Additional toxicological information:
·
The product shows the following dangers according to the calculation m ethod of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Slight irritant effect on skin and mucous membranes.
Slight irritant effect on eyes.
No sensitizing effects known.
(Contd. on page 8)
Page 8/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 26.12.2012 Revision: 26.12.2012
Trade name: TRACE
(Contd. of page 7)
Harmful
12 Ecological information
12.1 Toxicity
·
Aquatic toxicity:
·
12.2 Persistence and degradability
·
12.3 Bioaccumulative potential
·
Due to the distribution coefficient n-octanol/water an accumulation in organisms is not expected.
12.4 Mobility in soil
·
Ecotoxical effects:
·
Remark:
·
Additional ecological information:
·
General notes:
·
This statement was deduced from products with a similar structure or composition.
Avoid transfer into the environment.
Due to the consistence and the low watersolubility of the product a bioavailability is not probable.
Due to available data on eliminability/decomposition and bioaccum ulation potential prolonged term
damage of the environment can not be excluded.
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
12.5 Results of PBT and vPvB assessment
·
PBT:
·
vPvB:
·
12.6 Other adverse effects
·
Due to mechanical actions of the product (e.g. agglutinations) damages may occur.
Not applicable.
Not applicable.
The material is harmful to the environment.
The product is partly biodegradale. Significant residuals remain.
No further relevant information available.
No further relevant information available.
13 Disposal considerations
13.1 Waste treatment methods
·
Recommendation
·
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Product is recyclable as a waste oil. Deliver unused and/or contaminated product to waste oil collectors.
Can be burned with household garbage after consulting with the waste disposal facility operator and the
pertinent authorities and adhering to the necessary technical regulations.
Uncleaned packaging:
·
Recommendation:
·
Disposal must be made according to official regulations.
14 Transport information
14.1 UN-Number
·
DOT, ADR, ADN, IMDG, IATA
·
N/A
(Contd. on page 9)
Page 9/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 26.12.2012 Revision: 26.12.2012
Trade name: TRACE
(Contd. of page 8)
14.2 UN proper shipping name
·
DOT, ADR, ADN, IMDG, IATA
·
14.3 Transport hazard class(es)
·
DOT, ADR, ADN, IMDG, IATA
·
Class
·
14.4 Packing group
·
DOT, ADR, IMDG, IATA
·
14.5 Environmental hazards:
·
Marine pollutant:
·
14.6 Special precautions for user
·
14.7 Transport in bulk according to Annex II of
·
MARPOL73/78 and the IBC Code
UN "Model Regulation":
·
N/A
N/A
N/A
No
Not applicable.
Not applicable.
-
15 Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
·
United States (USA)
·
SARA
·
Section 355 (extremely hazardous substances):
·
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
·
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
·
All ingredients are listed.
Proposition 65 (California):
·
Chemicals known to cause cancer:
·
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
·
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
·
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
·
None of the ingredients is listed.
Carcinogenic Categories
·
EPA (Environmental Protection Agency)
·
None of the ingredients is listed.
(Contd. on page 10)
Page 10/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 26.12.2012 Revision: 26.12.2012
Trade name: TRACE
(Contd. of page 9)
IARC (International Agency for Research on Cancer)
·
85-83-6 1-(2-methyl-4-(2-methylphenylazo)phenylazo)-2-naphthol 3
TLV (Threshold Limit Value established by ACGIH)
·
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
·
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
·
None of the ingredients is listed.
Canada
·
Canadian Domestic Substances List (DSL)
·
All ingredients are listed.
Canadian Ingredient Disclosure list (limit 0.1%)
·
None of the ingredients is listed.
Canadian Ingredient Disclosure list (limit 1%)
·
None of the ingredients is listed.
15.2 Chemical safety assessment:
·
A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Relevant phrases
·
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H411 Toxic to aquatic life with long lasting effects.
R20/21 Harmful by inhalation and in contact with skin.
R22 Harmful if swallowed.
R36 Irritating to eyes.
R36/38 Irritating to eyes and skin.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Abbreviations and acronyms:
·
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
DNEL: Derived No-Effect Level (REACH)
(Contd. on page 11)
Page 11/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 26.12.2012 Revision: 26.12.2012
Trade name: TRACE
PNEC: Predicted No-Effect Concentration (REACH)
Sources
·
SDS Prepared by:
ChemTel Inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtelinc.com
(Contd. of page 10)
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