Page 1
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 25.03.2014 Revision: 25.03.2014
1 Identification of the substance/mixture and of the company/undertaking
·
1.1 Product identifier
·
Trade name: ICE BLOCK
·
Article number:
·
1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
·
Application of the substance / the mixture
·
1.3 Details of the supplier of the Safety Data Sheet
·
Manufacturer/Supplier:
Highside Chemicals, Inc.
11114 Reichold Road
Gulfport, MS 39503 USA
Phone: (228) 896-9220
·
1.4 Emergency telephone number:
ChemTel Inc.
(800)255-3924, +1 (813)248-0585
15128, 15640, 15550
Coolant / Anti-freeze.
2 Hazards identification
·
2.1 Classification of the substance or mixture
·
Classification according to Regulation (EC) No 1272/2008
The product is not classified as hazardous according to GHS regulations.
The product is not classified as hazardous according to the CLP regulation.
·
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
·
Information concerning particular hazards for human and environment:
The product does not have to be labelled due to the calculation procedure of the "General Classification
guideline for preparations of the EU" in the latest valid version.
·
Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and
literature data.
The classification is in accordance with the latest editions of international substances lists, and is
supplemented by information from technical literature and by information provided by the company.
·
2.2 Label elements
·
Labelling according to Regulation (EC) No 1272/2008
·
Hazard pictograms
·
Signal word
·
Hazard-determining components of labelling:
·
Hazard statements
·
Hazard description:
·
WHMIS-symbols:
Not Regulated
Not Regulated
None.
Not Regulated
Not hazardous under WHMIS.
Not Regulated
Not applicable.
(Contd. on page 2)
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Page 2
Page 2/9
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 25.03.2014 Revision: 25.03.2014
Trade name: ICE BLOCK
(Contd. of page 1)
·
NFPA ratings (scale 0 - 4)
Health = 0
010
·
HMIS-ratings (scale 0 - 4)
Fire = 1
Reactivity = 0
HEALTH
FIRE
REACTIVITY
·
HMIS Long Term Health Hazard Substances
0
Health = 0
1
Fire = 1
0
Reactivity = 0
None of the ingredients is listed.
·
2.3 Other hazards
·
Results of PBT and vPvB assessment
·
PBT:
Not applicable.
·
vPvB:
Not applicable.
3 Composition/information on ingredients
·
3.2 Mixtures
·
Description:
·
Dangerous components:
CAS: 57-55-6
Mixture of substances listed below with nonhazardous additions.
Propylene Glycol substance with a Community workplace exposure limit 50-100%
EINECS: 200-338-0
·
Additional information:
For the wording of the listed risk phrases refer to section 16.
4 First aid measures
·
4.1 Description of first aid measures
·
General information:
·
After inhalation:
·
After skin contact:
Immediately rinse with water.
If skin irritation continues, consult a doctor.
·
After eye contact:
Remove contact lenses if worn.
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
·
After swallowing:
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
·
4.2 Most important symptoms and effects, both acute and delayed
Cramp
Gastric or intestinal disorders.
Nausea
Immediately remove any clothing soiled by the product.
Supply fresh air; consult doctor in case of complaints.
(Contd. on page 3)
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Page 3
Page 3/9
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 25.03.2014 Revision: 25.03.2014
Trade name: ICE BLOCK
(Contd. of page 2)
·
Hazards
·
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Firefighting measures
·
5.1 Extinguishing media
·
Suitable extinguishing agents:
·
For safety reasons unsuitable extinguishing agents:
·
5.2 Special hazards arising from the substance or mixture
·
5.3 Advice for firefighters
·
Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
·
Additional information
No further relevant information available.
Use fire extinguishing methods suitable to surrounding conditions.
None.
No further relevant information available.
No further relevant information available.
6 Accidental release measures
·
6.1 Personal precautions, protective equipment and emergency procedures
Use respiratory protective device against the effects of fumes/dust/aerosol.
Ensure adequate ventilation
Particular danger of slipping on leaked/spilled product.
Wear protective equipment. Keep unprotected persons away.
·
6.2 Environmental precautions:
·
6.3 Methods and material for containment and cleaning up:
No special measures required.
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Pick up mechanically.
Dispose contaminated material as waste according to item 13.
·
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
·
7.1 Precautions for safe handling
·
Information about fire - and explosion protection:
·
7.2 Conditions for safe storage, including any incompatibilities
·
Storage:
·
Requirements to be met by storerooms and receptacles:
Avoid storage near extreme heat, ignition sources or open flame.
No special requirements.
·
Information about storage in one common storage facility:
Store away from foodstuffs.
Store away from oxidizing agents.
Store in cool, dry place in tightly closed receptacles.
No special measures required.
(Contd. on page 4)
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Page 4
Page 4/9
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 25.03.2014 Revision: 25.03.2014
Trade name: ICE BLOCK
(Contd. of page 3)
·
Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
This product is hygroscopic.
Protect from humidity and water.
·
7.3 Specific end use(s)
8 Exposure controls/personal protection
·
Additional information about design of technical facilities:
·
8.1 Control parameters
·
Ingredients with limit values that require monitoring at the workplace:
57-55-6 Propylene Glycol
WEEL (USA) Long-term value: 10 mg/m³
EV (Canada) Long-term value: 155* 10** mg/m³, 50* ppm
*vapour and aerosol;**aerosol only
·
DNELs
·
PNECs
·
Additional information:
·
8.2 Exposure controls
·
Personal protective equipment:
·
General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Avoid contact with the eyes.
Avoid close or long term contact with the skin.
·
Respiratory protection:
Not required under normal conditions of use.
For spills, respiratory protection may be advisable.
Use suitable respiratory protective device when aerosol or mist is formed.
·
Protection of hands:
Not required under normal conditions of use.
Wear protective gloves to handle contents of damaged or leaking units.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation.
·
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.
·
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
No further relevant information available.
No further relevant information available.
No further relevant information available.
No further data; see item 7.
The lists valid during the making were used as basis.
(Contd. on page 5)
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Page 5
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 25.03.2014 Revision: 25.03.2014
Trade name: ICE BLOCK
(Contd. of page 4)
·
Eye protection:
Safety glasses
·
Body protection:
Not required under normal conditions of use.
Protection may be required for spills.
·
Limitation and supervision of exposure into the environment
·
Risk management measures
No special requirements.
9 Physical and chemical properties
·
9.1 Information on basic physical and chemical properties
·
General Information
·
Appearance:
Form:
Colour:
·
Odour:
·
Odour threshold:
·
pH-value at 20 °C:
·
Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
·
Flash point:
·
Flammability (solid, gaseous):
·
Auto/Self-ignition temperature:
·
Decomposition temperature:
·
Self-igniting:
·
Danger of explosion:
·
Explosion limits:
Lower:
Upper:
·
Vapour pressure at 20 °C:
·
Density at 20 °C:
·
Relative density
·
Vapour density
·
Evaporation rate
·
Solubility in / Miscibility with
water:
Liquid
Colourless
Mild
Not determined.
9,0 - 9,5
Not Determined.
>212 °F / >100 °C
Not determined.
Not applicable.
700 ° F / 371 °C
Not determined.
Product is not self-igniting.
Product does not present an explosion hazard.
2,6 Vol %
12,6 Vol %
23 hPa
1,035 - 1,045 g/cm³
Not determined.
Not determined.
Not determined.
Fully miscible.
No special requirements.
(Contd. on page 6)
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Page 6
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 25.03.2014 Revision: 25.03.2014
Trade name: ICE BLOCK
(Contd. of page 5)
·
Partition coefficient (n-octanol/water):
·
Viscosity:
Dynamic at 24 °C:
Kinematic:
·
9.2 Other information
10 Stability and reactivity
·
10.1 Reactivity
·
10.2 Chemical stability
·
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
·
10.3 Possibility of hazardous reactions
Reacts with strong oxidizing agents.
Reacts with strong acids.
Reacts with strong alkali.
·
10.4 Conditions to avoid
·
10.5 Incompatible materials:
·
10.6 Hazardous decomposition products:
Store away from oxidizing agents.
No further relevant information available.
Not determined.
8 mPas
Not determined.
No further relevant information available.
Carbon monoxide and carbon dioxide
11 Toxicological information
·
11.1 Information on toxicological effects
·
Acute toxicity:
·
Primary irritant effect:
·
on the skin:
·
on the eye:
·
Sensitization:
·
Additional toxicological information:
No irritant effect.
Slight irritant effect on eyes.
No sensitizing effects known.
The product is not subject to classification according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version.
When used and handled according to specifications, the product does not have any harmful effects to our
experience and the information provided to us.
12 Ecological information
·
12.1 Toxicity
·
Aquatic toxicity:
·
12.2 Persistence and degradability
·
12.3 Bioaccumulative potential
·
12.4 Mobility in soil
No further relevant information available.
No further relevant information available.
No further relevant information available.
No further relevant information available.
(Contd. on page 7)
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Page 7
Page 7/9
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 25.03.2014 Revision: 25.03.2014
Trade name: ICE BLOCK
(Contd. of page 6)
·
Additional ecological information:
·
General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
·
12.5 Results of PBT and vPvB assessment
·
PBT:
Not applicable.
·
vPvB:
·
12.6 Other adverse effects
13 Disposal considerations
·
13.1 Waste treatment methods
·
Recommendation
Smaller quantities can be disposed of with household waste.
Can be burned with household garbage after consulting with the waste disposal facility operator and the
pertinent authorities and adhering to the necessary technical regulations.
·
Uncleaned packaging:
·
Recommendation:
·
Recommended cleansing agents:
Not applicable.
No further relevant information available.
Disposal must be made according to official regulations.
Water, if necessary together with cleansing agents.
14 Transport information
·
14.1 UN-Number
·
DOT, ADR, ADN, IMDG, IATA
·
14.2 UN proper shipping name
·
DOT, ADR, ADN, IMDG, IATA
·
14.3 Transport hazard class(es)
·
DOT, ADR, ADN, IMDG, IATA
·
Class
·
14.4 Packing group
·
DOT, ADR, IMDG, IATA
·
14.5 Environmental hazards:
·
Marine pollutant:
·
14.6 Special precautions for user
·
14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code
·
UN "Model Regulation":
Not Regulated
Not Regulated
Not Regulated
Not Regulated
No
Not applicable.
Not applicable.
-
(Contd. on page 8)
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Page 8
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 25.03.2014 Revision: 25.03.2014
Trade name: ICE BLOCK
(Contd. of page 7)
15 Regulatory information
·
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
·
United States (USA)
·
SARA
·
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
·
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
·
TSCA (Toxic Substances Control Act):
All ingredients are listed.
·
Proposition 65 (California):
·
Chemicals known to cause cancer:
None of the ingredients is listed.
·
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
·
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
·
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
·
Carcinogenic Categories
·
EPA (Environmental Protection Agency)
None of the ingredients is listed.
·
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
·
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
·
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
·
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
·
Canada
·
Canadian Domestic Substances List (DSL)
All ingredients are listed.
·
Canadian Ingredient Disclosure list (limit 0.1%)
None of the ingredients is listed.
·
Canadian Ingredient Disclosure list (limit 1%)
57-55-6 Propylene Glycol
(Contd. on page 9)
38.0.16
Page 9
Page 9/9
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 25.03.2014 Revision: 25.03.2014
Trade name: ICE BLOCK
(Contd. of page 8)
·
Other regulations, limitations and prohibitive regulations
This product has been classified in accordance with hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.
·
Substances of very high concern (SVHC) according to REACH, Article 57
None of the ingredients is listed.
·
15.2 Chemical safety assessment:
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
·
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
·
Sources
SDS Prepared by:
ChemTel Inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtelinc.com
A Chemical Safety Assessment has not been carried out.
38.0.16
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