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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 09.04.2013 Revision: 04.04.2013
1 Identification of the substance/mixture and of the company/undertaking
·
1.1 Product identifier
·
Trade name: LEAK LOCK GOLD
·
Article number:
·
1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
·
Application of the substance / the preparation
·
1.3 Details of the supplier of the Safety Data Sheet
·
Manufacturer/Supplier:
Highside Chemicals, Inc.
11114 Reichold Road
Gulfport, MS 39503 USA
Phone: (228) 896-9220
·
1.4 Emergency telephone number:
ChemTel Inc.
(800)255-3924, +1 (813)248-0585
11001,11004,11016,11128,11550
Sealant
2 Hazards identification
·
2.1 Classification of the substance or mixture
·
Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 2 H225 Highly flammable liquid and vapour.
GHS07
STOT SE 3 H336 May cause drowsiness or dizziness.
·
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
F; Highly flammable
R11: Highly flammable.
R67: Vapours may cause drowsiness and dizziness.
·
Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
·
Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and
literature data.
The classification is in accordance with the latest editions of international substances lists, and is
supplemented by information from technical literature and by information provided by the company.
·
2.2 Label elements
·
Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
(Contd. on page 2)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 09.04.2013 Revision: 04.04.2013
Trade name: LEAK LOCK GOLD
(Contd. of page 1)
·
Hazard pictograms
GHS02 GHS07
·
Signal word
·
Hazard statements
H225 Highly flammable liquid and vapour.
H336 May cause drowsiness or dizziness.
·
Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P280 Wear protective gloves and eye protection.
P233 Keep container tightly closed.
P261 Avoid breathing mist/vapours/spray.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse
P370+P378 In case of fire: Use for extinction: CO2, powder or water spray.
P403+P235 Store in a well-ventilated place. Keep cool.
·
Hazard description:
·
WHMIS-symbols:
B2 - Flammable liquid
D2B - Toxic material causing other toxic effects
Danger
skin with water/shower.
·
NFPA ratings (scale 0 - 4)
Health = 1
130
·
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
·
HMIS Long Term Health Hazard Substances
Fire = 3
Reactivity = 0
1
Health = 1
3
Fire = 3
0
Reactivity = 0
64-17-5 ethanol
·
2.3 Other hazards
·
Results of PBT and vPvB assessment
·
PBT:
Not applicable.
(Contd. on page 3)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 09.04.2013 Revision: 04.04.2013
Trade name: LEAK LOCK GOLD
(Contd. of page 2)
·
vPvB:
3 Composition/information on ingredients
·
3.2 Mixtures
·
Description:
·
Dangerous components:
CAS: 64-17-5
EINECS: 200-578-6
Index number: 603-002-00-5
CAS: 14807-96-6
EINECS: 238-877-9
CAS: 67-63-0
EINECS: 200-661-7
Index number: 603-117-00-0
·
Additional information:
For the wording of the listed risk phrases refer to section 16.
Dried product contains substances which are considered nuisance dusts which require a NIOSH Breathing
airborne particles or dust from mixing, spraying, sanding, grinding, etc. may cause irritation to respiratory
tract.
Not applicable.
Mixture of substances listed below with nonhazardous additions.
ethanol
F R11
Flam. Liq. 2, H225
Talc (Mg3H2(SiO3)4) 25-50%
propan-2-ol
Xi R36; F R11
R67
Flam. Liq. 2, H225
Eye Irrit. 2, H319; STOT SE 3, H336
25-50%
<10%
4 First aid measures
·
4.1 Description of first aid measures
·
General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
hours after the accident.
Take affected persons out into the fresh air.
·
After inhalation:
Supply fresh air.
Seek medical treatment in case of complaints.
·
After skin contact:
Immediately rinse with water.
Clean with water and soap.
If skin irritation continues, consult a doctor.
·
After eye contact:
Remove contact lenses if worn.
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
·
After swallowing:
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
·
4.2 Most important symptoms and effects, both acute and delayed
Dizziness
(Contd. on page 4)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 09.04.2013 Revision: 04.04.2013
Trade name: LEAK LOCK GOLD
(Contd. of page 3)
Headache
Nausea
Thirst
Disorientation
·
Hazards
·
4.3 Indication of any immediate medical attention and special treatment needed
Monitor circulation.
If necessary oxygen respiration treatment.
Medical supervision for at least 48 hours.
Contains ethanol and isopropanol.
5 Firefighting measures
·
5.1 Extinguishing media
·
Suitable extinguishing agents:
·
For safety reasons unsuitable extinguishing agents:
·
5.2 Special hazards arising from the substance or mixture
In case of fire, the following can be released:
Carbon monoxide (CO)
·
5.3 Advice for firefighters
·
Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
·
Additional information
Eliminate all ignition sources if safe to do so.
Cool endangered receptacles with water spray.
Condition may deteriorate with alcohol consumption.
Use fire extinguishing methods suitable to surrounding conditions.
None.
6 Accidental release measures
·
6.1 Personal precautions, protective equipment and emergency procedures
Use respiratory protective device against the effects of fumes/dust/aerosol.
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources.
Protect from heat.
·
6.2 Environmental precautions:
Dilute with plenty of water.
Suppress gases/fumes/haze with water haze or fog.
·
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dilute with plenty of water.
Dispose contaminated material as waste according to item 13.
·
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
(Contd. on page 5)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 09.04.2013 Revision: 04.04.2013
Trade name: LEAK LOCK GOLD
(Contd. of page 4)
See Section 13 for disposal information.
7 Handling and storage
·
7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Keep away from heat and direct sunlight.
·
Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Flammable gas-air mixtures may form in empty receptacles.
Fumes can combine with air to form an explosive mixture.
·
7.2 Conditions for safe storage, including any incompatibilities
·
Storage:
·
Requirements to be met by storerooms and receptacles:
Store in a cool location.
Provide ventilation for receptacles.
Avoid storage near extreme heat, ignition sources or open flame.
·
Information about storage in one common storage facility:
Store away from foodstuffs.
Store away from oxidizing agents.
Do not store together with acids.
·
Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
Keep container tightly sealed.
Protect from heat and direct sunlight.
Store receptacle in a well ventilated area.
·
7.3 Specific end use(s)
No further relevant information available.
8 Exposure controls/personal protection
·
Additional information about design of technical facilities:
·
8.1 Control parameters
·
Ingredients with limit values that require monitoring at the workplace:
64-17-5 ethanol
PEL (USA) 1900 mg/m³, 1000 ppm
REL (USA) 1900 mg/m³, 1000 ppm
TLV (USA) Short-term value: 1880 mg/m³, 1000 ppm
EL (Canada) Short-term value: 1000 ppm
EV (Canada) 1,900 mg/m³, 1,000 ppm
67-63-0 propan-2-ol
PEL (USA) 980 mg/m³, 400 ppm
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No further data; see item 7.
(Contd. on page 6)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 09.04.2013 Revision: 04.04.2013
Trade name: LEAK LOCK GOLD
(Contd. of page 5)
REL (USA) Short-term value: 1225 mg/m³, 500 ppm
Long-term value: 980 mg/m³, 400 ppm
TLV (USA) Short-term value: 984 mg/m³, 400 ppm
Long-term value: 492 mg/m³, 200 ppm
BEI
EL (Canada) Short-term value: 400 ppm
Long-term value: 200 ppm
EV (Canada) Short-term value: 400 ppm
Long-term value: 200 ppm
·
DNELs
·
PNECs
·
Additional information:
·
8.2 Exposure controls
·
Personal protective equipment:
·
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes and skin.
·
Respiratory protection:
Use suitable respiratory protective device in case of insufficient ventilation.
Use suitable respiratory protective device when high concentrations are present.
For spills, respiratory protection may be advisable.
·
Protection of hands:
No further relevant information available.
No further relevant information available.
The lists valid during the making were used as basis.
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the produc t/ the
preparation/ the chemical mixture.
Selection of the glove m aterial on consideration of the penetration times, rates of diffusion and the
degradation
·
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.
·
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
·
Eye protection:
Tightly sealed goggles
(Contd. on page 7)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 09.04.2013 Revision: 04.04.2013
Trade name: LEAK LOCK GOLD
(Contd. of page 6)
·
Body protection:
·
Limitation and supervision of exposure into the environment
No further relevant information available.
·
Risk management measures
See Section 7 for additional information.
No further relevant information available.
9 Physical and chemical properties
·
9.1 Information on basic physical and chemical properties
·
General Information
·
Appearance:
Form:
Colour:
·
Odour:
·
Odour threshold:
·
pH-value:
·
Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
·
Flash point:
·
Flammability (solid, gaseous):
·
Ignition temperature:
·
Decomposition temperature:
·
Self-igniting:
·
Danger of explosion:
·
Explosion limits:
Lower:
Upper:
·
Vapour pressure at 20 °C:
·
Density at 20 °C:
·
Relative density
·
Vapour density
·
Evaporation rate
·
Solubility in / Miscibility with
water:
·
Partition coefficient (n-octanol/water):
Protective work clothing
Pasty
Gold coloured
Alcohol-like
Not determined.
Not determined.
Undetermined.
172 °F / 78 °C
59 °F / 15 °C
Not applicable.
>500 °F / 260 °C
Not determined.
Product is not self-igniting.
Product is not explosive. However, formation of explosive air/
vapour mixtures are possible.
3,5 Vol %
15,0 Vol %
59 hPa
1,2 g/cm³
Not determined.
Not determined.
Not determined.
Not miscible or difficult to mix.
Not determined.
(Contd. on page 8)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 09.04.2013 Revision: 04.04.2013
Trade name: LEAK LOCK GOLD
(Contd. of page 7)
·
Viscosity:
Dynamic:
Kinematic:
·
Solvent content:
Organic solvents:
VOC (US EPA Method 24)
·
9.2 Other information
10 Stability and reactivity
·
10.1 Reactivity
·
10.2 Chemical stability
·
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
·
10.3 Possibility of hazardous reactions
Flammable.
Used empty containers may contain product gases which form explosive mixtures with air.
Can react violently with oxygen rich (oxidizing) material. Danger of Explosion.
Strong exothermic reaction with acids.
Develops readily flammable gases/fumes.
·
10.4 Conditions to avoid
Keep ignition sources away - Do not smoke.
Store away from oxidizing agents.
·
10.5 Incompatible materials:
·
10.6 Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Danger of forming toxic pyrolysis products.
No further relevant information available.
Not determined.
Not determined.
Not determined.
35 %
No further relevant information available.
11 Toxicological information
·
11.1 Information on toxicological effects
·
Acute toxicity:
·
Primary irritant effect:
·
on the skin:
·
on the eye:
·
Sensitization:
·
Subacute to chronic toxicity:
·
Additional toxicological information:
The product shows the following dangers according to the calculation m ethod of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Harmful
Irritant
36.0.22
Slight irritant effect on skin and mucous membranes.
Slight irritant effect on eyes.
No sensitizing effects known.
Vapours have narcotic effect.
(Contd. on page 9)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 09.04.2013 Revision: 04.04.2013
Trade name: LEAK LOCK GOLD
(Contd. of page 8)
Inhalation of concentrated vapours as well as oral intake will lead to anaesthesia-like conditions and
headache, dizziness, etc.
12 Ecological information
·
12.1 Toxicity
·
Aquatic toxicity:
·
12.2 Persistence and degradability
·
12.3 Bioaccumulative potential
·
12.4 Mobility in soil
·
Additional ecological information:
·
General notes:
This statement was deduced from the properties of the single components.
Due to available data on eliminability/decomposition and bioaccumulation potential a prolonged damage of
the environment is unlikely.
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
·
12.5 Results of PBT and vPvB assessment
·
PBT:
Not applicable.
·
vPvB:
·
12.6 Other adverse effects
Not applicable.
No further relevant information available.
The product is partially biodegradable. Significant residuals remain.
No further relevant information available.
No further relevant information available.
No further relevant information available.
13 Disposal considerations
·
13.1 Waste treatment methods
·
Recommendation
Can be burned with household garbage after consulting with the waste disposal facility operator and the
pertinent authorities and adhering to the necessary technical regulations.
Small amounts may be diluted with plenty of water and washed away. Dispose of bigger amounts in
accordance with Local Authority requirements.
·
Uncleaned packaging:
·
Recommendation:
·
Recommended cleansing agents:
Disposal must be made according to official regulations.
Water only.
14 Transport information
·
14.1 UN-Number
·
DOT, ADR, IMDG, IATA
·
14.2 UN proper shipping name
·
DOT, ADR, IMDG, IATA
UN1133
Adhesives
(Contd. on page 10)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 09.04.2013 Revision: 04.04.2013
Trade name: LEAK LOCK GOLD
(Contd. of page 9)
·
14.3 Transport hazard class(es)
·
DOT
·
Class
·
Label
·
ADR
·
Class
·
Label
·
IMDG, IATA
3 Flammable liquids.
3
3 (F1) Flammable liquids.
3
·
Class
·
Label
·
14.4 Packing group
·
DOT, ADR, IMDG, IATA
·
14.5 Environmental hazards:
·
Marine pollutant:
·
14.6 Special precautions for user
·
Danger code (Kemler):
·
EMS Number:
·
14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code
·
Transport/Additional information:
·
ADR
·
Limited quantities (LQ)
·
Transport category
·
Tunnel restriction code
·
UN "Model Regulation":
3 Flammable liquids.
3
II
No
Warning: Flammable liquids.
33
F-E,S-E
Not applicable.
5L
2
D/E
UN1133, ADHESIVES, 3, II
(Contd. on page 11)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 09.04.2013 Revision: 04.04.2013
Trade name: LEAK LOCK GOLD
(Contd. of page 10)
15 Regulatory information
·
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
·
United States (USA)
·
SARA
·
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
·
Section 313 (Specific toxic chemical listings):
67-63-0 propan-2-ol
·
TSCA (Toxic Substances Control Act):
All ingredients are listed.
·
Proposition 65 (California):
·
Chemicals known to cause cancer:
None of the ingredients is listed.
·
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
·
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
·
Chemicals known to cause developmental toxicity:
Ethanol - listing refers specifically to alcoholic beverage consumption and is not applicable for product.
64-17-5 ethanol
·
Carcinogenic Categories
·
EPA (Environmental Protection Agency)
None of the ingredients is listed.
·
IARC (International Agency for Research on Cancer)
64-17-5 ethanol 1
14807-96-6 Talc (Mg3H2(SiO3)4) 2B
·
TLV (Threshold Limit Value established by ACGIH)
64-17-5 ethanol A3
14807-96-6 Talc (Mg3H2(SiO3)4) A4
67-63-0 propan-2-ol A4
·
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
·
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
·
Canada
·
Canadian Domestic Substances List (DSL)
All ingredients are listed.
(Contd. on page 12)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 09.04.2013 Revision: 04.04.2013
Trade name: LEAK LOCK GOLD
(Contd. of page 11)
·
Canadian Ingredient Disclosure list (limit 0.1%)
64-17-5 ethanol
·
Canadian Ingredient Disclosure list (limit 1%)
67-63-0 propan-2-ol
·
15.2 Chemical safety assessment:
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
·
Relevant phrases
H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
R11 Highly flammable.
R36 Irritating to eyes.
R67 Vapours may cause drowsiness and dizziness.
·
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
·
Sources
SDS Prepared by:
ChemTel Inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtelinc.com
A Chemical Safety Assessment has not been carried out.
36.0.22
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