Page 1/12
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 30.10.2012 Revision: 30.10.2012
1 Identification of the substance/mixture and of the company/undertaking
·
1.1 Product identifier
·
Trade name: LEAK LOCK
·
Article number:
·
1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
·
Application of the substance / the preparation
·
1.3 Details of the supplier of the Safety Data Sheet
·
Manufacturer/Supplier:
Highside Chemicals, Inc.
11114 Reichold Road
Gulfport, MS 39503
Phone: (228) 896-9220
·
Further information obtainable from:
·
1.4 Emergency telephone number:
ChemTel Inc.
(800)255-3924, +1 (813)248-0585
10001, 10004, 10016, 10128
Pipe joint sealant, Gasket seal, Threadlocker
Product Safety Department
2 Hazards identification
·
2.1 Classification of the substance or mixture
·
Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 2 H225 Highly flammable liquid and vapour.
·
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
F; Highly flammable
R11: Highly flammable.
·
Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline
for preparations of the EU" in the latest valid version.
·
Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and
literature data.
The classification is in accordance with the latest editions of international su bstances lists, and is
supplemented by information from technical literature and by information provided by the company.
·
2.2 Label elements
·
Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
(Contd. on page 2)
35.0.37
Page 2/12
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 30.10.2012 Revision: 30.10.2012
Trade name: LEAK LOCK
(Contd. of page 1)
·
Hazard pictograms
GHS02
·
Signal word
·
Hazard-determining components of labelling:
Danger
titanium dioxide
·
Hazard statements
H225 Highly flammable liquid and vapour.
·
Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P240 Ground/bond container and receiving equipment.
P233 Keep container tightly closed.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P303+P361+P353 IF ON SKIN (or ha ir) : Re mo ve/T ake off imm edi ate ly al l c ont amin at ed c lot hing . R ins e
skin with water/shower.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P370+P378 In case of fire: Use for extinction: CO2, powder or water spray.
P405 Store locked up.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container in acc ordan ce with loca l/regional/national/inter national
regulations.
·
Hazard description:
·
WHMIS-symbols:
B2 - Flammable liquid
D2B - Toxic material causing other toxic effects
·
NFPA ratings (scale 0 - 4)
Health = 2
230
35.0.37
Fire = 3
Reactivity = 0
(Contd. on page 3)
Page 3/12
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 30.10.2012 Revision: 30.10.2012
Trade name: LEAK LOCK
(Contd. of page 2)
·
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
*2
Health = *2
3
Fire = 3
0
Reactivity = 0
* - Indicates a long term health hazard from repeated or prolonged exposures.
·
HMIS Long Term Health Hazard Substances
64-17-5 ethanol
13463-67-7 titanium dioxide
·
2.3 Other hazards
·
Results of PBT and vPvB assessment
·
·
Not applicable.
PBT:
vPvB:
Not applicable.
3 Composition/information on ingredients
·
3.2 Mixtures
·
Description:
·
Dangerous components:
CAS: 64-17-5
EINECS: 200-578-6
Index number: 603-002-00-5
CAS: 13463-67-7
EINECS: 236-675-5
CAS: 57-55-6
EINECS: 200-338-0
·
Additional information:
Mixture of substances listed below with nonhazardous additions.
ethanol
F R11
Flam. Liq. 2, H225
titanium dioxide
Xn R20-40
Carc. Cat. 3
Carc. 2, H351
Acute Tox. 4, H332
Propylene Glycol
substance with a Community workplace exposure limit
For the wording of the listed risk phrases refer to section 16.
25-50%
< 10%
< 10%
4 First aid measures
·
4.1 Description of first aid measures
·
General information:
·
After inhalation:
·
After skin contact:
Clean with water and soap.
If skin irritation continues, consult a doctor.
·
After eye contact:
Rinse opened eye for several minutes under running water.
Remove contact lenses if worn.
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
35.0.37
No special measures required.
Supply fresh air; consult doctor in case of complaints.
(Contd. on page 4)
Page 4/12
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 30.10.2012 Revision: 30.10.2012
Trade name: LEAK LOCK
(Contd. of page 3)
·
After swallowing:
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
·
4.2 Most important symptoms and effects, both acute and delayed
Dizziness
Gastric or intestinal disorders
·
Hazards
·
4.3 Indication of any immediate medical attention and special treatment needed
If swallowed, gastric irrigation with added, activated carbon.
Monitor circulation, possible shock treatment.
Medical supervision for at least 48 hours.
5 Firefighting measures
·
5.1 Extinguishing media
·
Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
·
For safety reasons unsuitable extinguishing agents:
·
5.2 Special hazards arising from the substance or mixture
In case of fire, the following can be released:
Carbon monoxide (CO)
Under certain fire conditions, traces of other toxic gases cannot be excluded.
·
5.3 Advice for firefighters
·
Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
·
Additional information
No further relevant information available.
None.
Cool endangered receptacles with water spray.
6 Accidental release measures
·
6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources.
Protect from heat.
·
6.2 Environmental precautions:
·
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
·
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
35.0.37
Dilute with plenty of water.
(Contd. on page 5)
Page 5/12
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 30.10.2012 Revision: 30.10.2012
Trade name: LEAK LOCK
(Contd. of page 4)
7 Handling and storage
·
7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
·
Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Flammable gas-air mixtures may form in empty receptacles.
·
7.2 Conditions for safe storage, including any incompatibilities
·
Storage:
·
Requirements to be met by storerooms and receptacles:
Store in a cool location.
Provide ventilation for receptacles.
·
Information about storage in one common storage facility:
Store away from foodstuffs.
Store away from oxidizing agents.
·
Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
Keep container tightly sealed.
Store receptacle in a well ventilated area.
·
7.3 Specific end use(s)
No further relevant information available.
8 Exposure controls/personal protection
·
Additional information about design of technical facilities:
·
8.1 Control parameters
·
Ingredients with limit values that require monitoring at the workplace:
64-17-5 ethanol
PEL (USA) 1900 mg/m³, 1000 ppm
REL (USA) 1900 mg/m³, 1000 ppm
TLV (USA) Short-term value: 1880 mg/m³, 1000 ppm
EL (Canada) Short-term value: 1000 ppm
EV (Canada) 1,900 mg/m³, 1,000 ppm
57-55-6 Propylene Glycol
WEEL (USA) 10 mg/m³
EV (Canada) 155* 10** mg/m³, 50* ppm
*vapour and aerosol;**aerosol only
·
DNELs
·
PNECs
·
Additional information:
No further relevant information available.
No further relevant information available.
The lists valid during the making were used as basis.
No further data; see item 7.
(Contd. on page 6)
35.0.37
Page 6/12
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 30.10.2012 Revision: 30.10.2012
Trade name: LEAK LOCK
(Contd. of page 5)
·
8.2 Exposure controls
·
Personal protective equipment:
·
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Do not inhale dust / smoke / mist.
·
Respiratory protection:
Use suitable respiratory protective device in case of insufficient ventilation.
Use suitable respiratory protective device when aerosol or mist is formed.
·
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the g love material can be given for the product/ the
preparation/ the chemical mixture.
Selection of the glove material on consideratio n of the penetration times, rates of diffusion and the
degradation
·
Material of gloves
Sensibilization by the components in the glove materials is possible.
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has there fore to be
checked prior to the application.
·
Penetration time of glove material
The exact break through time has to be found out by the manufactur er of the pr otective gloves and has to
be observed.
·
For the permanent contact gloves made of the following materials are suitable:
Butyl rubber, BR
Nitrile rubber, NBR
Neoprene gloves
·
Eye protection:
Contact lenses should not be worn.
Safety glasses with side shields or face shield strongly suggested.
·
Body protection:
·
Limitation and supervision of exposure into the environment
·
Risk management measures
Protective work clothing
No special requirements.
See Section 7 for additional information.
No special requirements.
(Contd. on page 7)
35.0.37
Page 7/12
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 30.10.2012 Revision: 30.10.2012
Trade name: LEAK LOCK
(Contd. of page 6)
9 Physical and chemical properties
·
9.1 Information on basic physical and chemical properties
·
General Information
·
Appearance:
Form:
Colour:
·
Odour:
·
Odour threshold:
·
pH-value:
·
Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
·
Flash point:
·
Flammability (solid, gaseous):
·
Ignition temperature:
·
Decomposition temperature:
·
Self-igniting:
·
Danger of explosion:
·
Explosion limits:
Lower:
Upper:
·
Vapour pressure at 20 °C:
·
Density at 20 °C:
·
Relative density
·
Vapour density
·
Evaporation rate
·
Solubility in / Miscibility with
water:
·
Partition coefficient (n-octanol/water):
·
Viscosity:
Dynamic:
Kinematic:
·
9.2 Other information
Pourable paste
Blue or Gray
Alcohol-like
Not determined.
Not determined.
Undetermined.
172 °F / 78 °C
61 °F / 16 °C
Not applicable.
797 °F / 425 °C
Not determined.
Product is not self-igniting.
Product is not explosive. However, formation of explosive air/
vapour mixtures are possible.
3,5 Vol %
15,0 Vol %
59 hPa
1,3 g/cm³
Not determined.
Not determined.
Not determined.
Fully miscible.
Not determined.
Not determined.
Not determined.
No further relevant information available.
(Contd. on page 8)
35.0.37
Page 8/12
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 30.10.2012 Revision: 30.10.2012
Trade name: LEAK LOCK
(Contd. of page 7)
10 Stability and reactivity
·
10.1 Reactivity
·
10.2 Chemical stability
·
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
·
10.3 Possibility of hazardous reactions
Flammable.
Reacts with oxidizing agents.
Can form explosive mixtures in air if heated above flash point and/or when sprayed or atomised.
Used empty containers may contain product gases which form explosive mixtures with air.
Reacts with peroxides and other radical forming substances.
·
10.4 Conditions to avoid
Keep ignition sources away - Do not smoke.
Store away from oxidizing agents.
·
10.5 Incompatible materials:
·
10.6 Hazardous decomposition products:
Toxic metal oxide smoke
Hydrocarbons
Carbon monoxide and carbon dioxide
No further relevant information available.
11 Toxicological information
·
11.1 Information on toxicological effects
·
Acute toxicity:
·
LD/LC50 values relevant for classification:
13463-67-7 titanium dioxide
Oral LD50 >20000 mg/kg (rat)
Dermal LD50 >10000 mg/kg (rabbit)
Inhalative LC50/4 h >6,82 mg/l (rat)
57-55-6 Propylene Glycol
Oral LD50 20000 mg/kg (rat)
Dermal LD50 20800 mg/kg (rabbit)
64-17-5 ethanol
Oral LD50 7060 mg/kg (rat)
Inhalative LC50/4 h 20000 mg/l (rat)
·
Primary irritant effect:
·
on the skin:
·
on the eye:
·
Sensitization:
·
Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Slight irritant effect on skin and mucous membranes.
Irritating effect.
Sensitizing effect by skin contact is possible by prolonged exposure.
(Contd. on page 9)
35.0.37
Page 9/12
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 30.10.2012 Revision: 30.10.2012
Trade name: LEAK LOCK
(Contd. of page 8)
Inhalation of concentrated vapour s as well as oral intake w ill lead to anaesthesia-like con ditions and
headache, dizziness, etc.
·
Repeated dose toxicity
12 Ecological information
·
12.1 Toxicity
·
Aquatic toxicity:
·
12.2 Persistence and degradability
·
12.3 Bioaccumulative potential
·
12.4 Mobility in soil
·
Additional ecological information:
·
General notes:
This statement was deduced from the properties of the single components.
Avoid transfer into the environment.
Due to available data on eliminability/decomposition and bioaccumulation potential prolonged term
damage of the environment can not be excluded.
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reac h ground water, water cou rse or sewage
system.
·
12.5 Results of PBT and vPvB assessment
·
·
·
Not applicable.
PBT:
vPvB:
Not applicable.
12.6 Other adverse effects
The product contains materials that are harmful to the environment.
Repeated exposures may result in skin and/or respiratory sensitivity.
The product is partly biodegradale. Significant residuals remain.
May be accumulated in organism
No further relevant information available.
No further relevant information available.
13 Disposal considerations
·
13.1 Waste treatment methods
·
Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Can be burned with household garbage after consulting with the waste disposal facility operator and the
pertinent authorities and adhering to the necessary technical regulations.
Can be disposed of with household garbage with prior chemical-physical or biological treatment following
consultation with the waste disposal facility operator and the pertinent authorities and adhering to the
necessary technical regulations.
·
Uncleaned packaging:
·
Recommendation:
·
Recommended cleansing agents:
Disposal must be made according to official regulations.
Water, if necessary together with cleansing agents.
14 Transport information
·
14.1 UN-Number
·
DOT, ADR, IMDG, IATA
UN1133
(Contd. on page 10)
35.0.37
Page 10/12
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 30.10.2012 Revision: 30.10.2012
Trade name: LEAK LOCK
(Contd. of page 9)
·
14.2 UN proper shipping name
·
DOT, ADR, IMDG, IATA
·
14.3 Transport hazard class(es)
·
DOT
Adhesives
·
Class
·
Label
·
ADR
·
Class
·
Label
·
IMDG, IATA
·
Class
·
Label
·
14.4 Packing group
·
DOT, ADR, IMDG, IATA
·
14.5 Environmental hazards:
·
Marine pollutant:
·
14.6 Special precautions for user
·
Danger code (Kemler):
·
EMS Number:
·
14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code
·
Transport/Additional information:
·
ADR
·
Limited quantities (LQ)
·
Transport category
·
Tunnel restriction code
·
UN "Model Regulation":
3 Flammable liquids.
3
3 (F1) Flammable liquids.
3
3 Flammable liquids.
3
II
No
Warning: Flammable liquids.
33
F-E,S-D
Not applicable.
5L
2
D/E
UN1133, ADHESIVES, 3, II
(Contd. on page 11)
35.0.37
Page 11/12
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 30.10.2012 Revision: 30.10.2012
Trade name: LEAK LOCK
(Contd. of page 10)
15 Regulatory information
·
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
·
United States (USA)
·
SARA
·
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
·
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
·
TSCA (Toxic Substances Control Act):
All ingredients are listed.
·
Proposition 65 (California):
·
Chemicals known to cause cancer:
Reference to Titanium Dioxide is based on unbound respirable pa rticles and is not generally applicable to
product as supplied.
13463-67-7 titanium dioxide
·
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
·
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
·
Chemicals known to cause developmental toxicity:
Ethanol - listing refers specifically to alcoholic beverage consumption and is not applicable for product.
64-17-5 ethanol
·
Carcinogenic Categories
·
EPA (Environmental Protection Agency)
None of the ingredients is listed.
·
IARC (International Agency for Research on Cancer)
13463-67-7 titanium dioxide
·
TLV (Threshold Limit Value established by ACGIH)
13463-67-7 titanium dioxide A4
64-17-5 ethanol A3
·
NIOSH-Ca (National Institute for Occupational Safety and Health)
13463-67-7 titanium dioxide
·
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
·
Canada
·
Canadian Domestic Substances List (DSL)
All ingredients are listed.
(Contd. on page 12)
35.0.37
Page 12/12
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 30.10.2012 Revision: 30.10.2012
Trade name: LEAK LOCK
(Contd. of page 11)
·
Canadian Ingredient Disclosure list (limit 0.1%)
64-17-5 ethanol
·
Canadian Ingredient Disclosure list (limit 1%)
57-55-6 Propylene Glycol
·
15.2 Chemical safety assessment:
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
·
Relevant phrases
H225 Highly flammable liquid and vapour.
H332 Harmful if inhaled.
H351 Suspected of causing cancer.
R11 Highly flammable.
R20 Harmful by inhalation.
R40 Limited evidence of a carcinogenic effect.
·
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuse s par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
·
Sources
SDS Prepared by:
ChemTel Inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtelinc.com
A Chemical Safety Assessment has not been carried out.
35.0.37
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