Hi-Genic FRK F270012 User Manual

SAFETY DATA SHEET
1. Identification
Product identifier Hi-Genic
Other means of identification
Product code
Product registration number
Recommended use
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Company name Address
Telephone E-mail
Emergency phone number
F2700
47371-97-1124
Non-Acid Bowl and Bathroom Cleaner
None known.
Franklin Cleaning Technology One Fuller Way Great Bend, KS 67530 United States Customer Service (800) 810-4829 Not available.
CHEMTREC (800) 424-9300 Emergency (620) 792-1711 24 hour Emergency (800) 424-9300
2. Hazard(s) identification
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
Label elements
Hazard symbol
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise classified (HNOC)
Supplemental information
Not classified.
Not classified.
Category 3Hazardous to the aquatic environment, acute
hazard
Category 3Hazardous to the aquatic environment,
long-term hazard
Not classified.
None.
Warning
Harmful in contact with skin. Harmful to aquatic life. Harmful to aquatic life with long lasting effects.
Avoid release to the environment.
Wash hands after handling.
Store away from incompatible materials.
Dispose of contents/container in accordance with local/regional/national/international regulations.
None known.
0.94% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment. 1.03% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment.
3. Composition/information on ingredients
Mixtures
Material name: Hi-Genic
1463 Version #: 01 Issue date: 03-19-2015
SDS US
1 / 6
CAS number %Chemical name Common name and synonyms
68131-39-5ALCOHOLS, C12-15,
ETHOXYLATED
Other components below reportable levels 90 - 100
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed
General information
Move to fresh air. Call a physician if symptoms develop or persist.
Wash off with soap and water. Get medical attention if irritation develops and persists.
Rinse with water. Get medical attention if irritation develops and persists.
Rinse mouth. Get medical attention if symptoms occur.
Direct contact with eyes may cause temporary irritation.
Provide general supportive measures and treat symptomatically.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing media
Specific hazards arising from the chemical
Special protective equipment and precautions for firefighters
Fire-fighting equipment/instructions
Specific methods
General fire hazards
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire.
During fire, gases hazardous to health may be formed.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Move containers from fire area if you can do so without risk.
Use standard firefighting procedures and consider the hazards of other involved materials.
No unusual fire or explosion hazards noted.
< 1
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Methods and materials for containment and cleaning up
Environmental precautions
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent product from entering drains. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Conditions for safe storage, including any incompatibilities
Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Avoid release to the environment. Do not empty into drains.
Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
Biological limit values
Material name: Hi-Genic
1463 Version #: 01 Issue date: 03-19-2015
No exposure limits noted for ingredient(s).
No biological exposure limits noted for the ingredient(s).
SDS US
2 / 6
Appropriate engineering controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection
Other
Respiratory protection
Thermal hazards
General hygiene considerations
Wear appropriate chemical resistant gloves.
Wear suitable protective clothing.
In case of insufficient ventilation, wear suitable respiratory equipment.
Wear appropriate thermal protective clothing, when necessary.
Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower (%)
Flammability limit - upper (%)
Explosive limit - lower (%)
Explosive limit - upper (%)
Vapor pressure
Vapor density
Relative density
Solubility(ies)
Solubility (water)
Partition coefficient (n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity
Other information
Density
Percent volatile
Pounds per gallon
Specific gravity
VOC (Weight %)
Viscous Liquid
Liquid.
Liquid.
Slightly viscous blue
Matches to Standard
Not available.
10.8 - 11.8
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
0.00001 hPa estimated
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
8.34 lbs/gal estimated
98.01 % estimated
8.34
1 estimated
0.02 % estimated
Material name: Hi-Genic
1463 Version #: 01 Issue date: 03-19-2015
SDS US
3 / 6
10. Stability and reactivity
Ingestion
Inhalation
Skin contact
Eye contact
Acute toxicity
Respiratory sensitization
Carcinogenicity
Aspiration hazard
Reactivity
Chemical stability
Possibility of hazardous reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition products
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Contact with incompatible materials.
Strong oxidizing agents.
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Expected to be a low ingestion hazard.
No adverse effects due to inhalation are expected.
No adverse effects due to skin contact are expected.
Direct contact with eyes may cause temporary irritation.
Symptoms related to the physical, chemical and toxicological characteristics
Information on toxicological effects
Hi-Genic (CAS Mixture)
Acute
Inhalation
LC50 Mouse
Oral
LD50 Rat
Other
LD50 Mouse
Direct contact with eyes may cause temporary irritation.
Not available.
Rat 1150 mg/l, 2 Hours estimated
Rat 15407.2637 mg/kg estimated
Test ResultsProduct Species
600 mg/l, 2 Hours estimated
27555.5547 g/kg estimated
57491.6953 mg/kg, 30 Days estimated
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Serious eye damage/eye
Prolonged skin contact may cause temporary irritation.
Direct contact with eyes may cause temporary irritation.
irritation
Respiratory or skin sensitization
Not available.
Skin sensitization
Germ cell mutagenicity
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity
Specific target organ toxicity -
This product is not expected to cause reproductive or developmental effects.
Not classified.
single exposure
Specific target organ toxicity -
Not classified.
repeated exposure
Not available.
Material name: Hi-Genic
1463 Version #: 01 Issue date: 03-19-2015
SDS US
4 / 6
12. Ecological information
with chemical or used container. Dispose of contents/container in accordance with
Ecotoxicity
Product Test ResultsSpecies
Hi-Genic (CAS Mixture)
* Estimates for product may be based on additional component data not shown.
Persistence and degradability
Bioaccumulative potential
Mobility in soil
Other adverse effects
Harmful to aquatic life with long lasting effects. Accumulation in aquatic organisms is expected.
EC50Crustacea 120.9181 mg/l, 48 hours estimatedDaphnia
LC50Fish 227.4786 mg/l, 96 hours estimatedFish
No data is available on the degradability of this product.
No data available.
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions
Local disposal regulations
Hazardous waste code
Waste from residues / unused products
Contaminated packaging
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches
local/regional/national/international regulations.
Dispose in accordance with all applicable regulations.
The waste code should be assigned in discussion between the user, the producer and the waste disposal company.
Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).
Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied.
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
This substance/mixture is not intended to be transported in bulk.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
Material name: Hi-Genic
1463 Version #: 01 Issue date: 03-19-2015
SDS US
5 / 6
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
No
chemical
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
Not regulated.
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Not regulated.
US. New Jersey Worker and Community Right-to-Know Act
Not listed.
US. Pennsylvania Worker and Community Right-to-Know Law
Not listed.
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins.
16. Other information, including date of preparation or last revision
Issue date
Version #
Disclaimer
03-19-2015
01
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
Material name: Hi-Genic
1463 Version #: 01 Issue date: 03-19-2015
SDS US
6 / 6
Loading...