HERNON HER WK800-D-25ML Datasheet

SAFETY DATA SHEET

This safety data sheet complies with the requirements of:

Regulation (EC) No. 1907/2006 and Regulation (EC) No. 1272/2008

Issue Date 04-May-2015

Revision Date 26-Dec-2017

Version 1

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Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1. Product identifier

Product Code

MS-746

Product Name

Dissipator 746

Contains Cumene Hydroperoxide, TETRAHYDROFURFURYL METHACRYLATE, Hydroxypropyl Methacrylate

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended Use

Adhesives

Uses advised against

None known

1.3. Details of the supplier of the safety data sheet

Manufacturer

Hernon Manufacturing Inc. 121 Tech Drive Sanford, FL 32771 800-527-0004

For further information, please contact

Contact Point

[email protected]

1.4. Emergency telephone number

Emergency Telephone

Chemtel 800-255-3924

Emergency Telephone - §45 - (EC)1272/2008

Europe

112

Section 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Regulation (EC) No 1272/2008

Acute toxicity - Inhalation (Dusts/Mists)

Category 3 - (H331)

Serious eye damage/eye irritation

Category 2 - (H319)

Skin sensitization

Category 1 - (H317)

Reproductive Toxicity

Category 1B - (H360D)

Specific target organ toxicity (single exposure)

Category 3 - (H335)

Chronic aquatic toxicity

Category 3 - (H412)

2.2. Label elements

Product identifier

Contains Cumene Hydroperoxide, TETRAHYDROFURFURYL METHACRYLATE, Hydroxypropyl Methacrylate

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Signal word

Danger

Hazard statements

H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H331 - Toxic if inhaled H335 - May cause respiratory irritation H412 - Harmful to aquatic life with long lasting effects H360D - May damage the unborn child

Precautionary Statements - EU (§28, 1272/2008)

P201 - Obtain special instructions before use P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P273 - Avoid release to the environment P280 - Wear protective gloves and eye/face protection P312 - Call a POISON CENTER or doctor/physician if you feel unwell P362 - Take off contaminated clothing and wash before reuse P403 + P233 - Store in a well-ventilated place. Keep container tightly closed P501 - Dispose of contents/ container to an approved waste disposal plant

2.3. Other hazards

No information available

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances

Chemical Name

EC No.

CAS No.

Weight-%

Classification according to

Regulation (EC) No.

1272/2008 [CLP]

REACH

Registration

Number

OFF-WHITE HYDRATED ALUMINA

244-492-7

21645-51-2

40 - 70

No data available

TETRAHYDROFURFURYL

METHACRYLATE

219-529-5

2455-24-5

10 - 30

Skin Sens. 1 (H317)

Repr. 1B(H360D)

Aquatic Chronic 3 (H412)

No data available

Hydroxypropyl Methacrylate

248-666-3

27813-02-1

3 - 7

Eye Irrit. 2 (H319)

Skin Sens. 1 (H317)

No data available

Cumene Hydroperoxide

201-254-7

80-15-9

1 - 5

Acute Tox. 4 (H302) Acute Tox. 4 (H312) Acute Tox. 3 (H331)

Skin Corr. 1B (H314)

STOT SE 3 (H335)

STOT RE 2 (H373)

Aquatic Chronic 2 (H411)

Org. Perox. E (H242)

No data available

Full text of H- and EUH-phrases: see section 16

Section 4: FIRST AID MEASURES

4.1. Description of first aid measures

Inhalation

Remove to fresh air. If breathing is difficult, give oxygen. If breathing has stopped, give artificial respiration. Get medical attention immediately.

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Skin contact

Wash with soap and water. Flush skin with water for several minutes. Remove contaminated clothing and shoes. If irritation develops, seek medical attention. Wash clothing before reuse.

Eye contact

Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician.

Ingestion

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a POISON CENTER or doctor/physician if you feel unwell.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms

Avoid prolonged contact with eyes, skin, and clothing.

4.3. Indication of any immediate medical attention and special treatment needed

Note to physicians

Treat symptomatically.

Section 5: FIRE FIGHTING MEASURES

5.1. Extinguishing media

Suitable extinguishing media

Use CO2, dry chemical, or foam.

Unsuitable extinguishing media

None

5.2. Special hazards arising from the substance or mixture

No information available

Hazardous combustion products

Carbon oxides. Nitrogen oxides (NOx). Irritating organic vapors.

5.3. Advice for firefighters

Wear self-contained breathing apparatus and protective suit. Use personal protective equipment as required.

Section 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions

Use personal protective equipment as required. Ensure adequate ventilation, especially in confined areas.

For emergency responders

Use personal protection recommended in Section 8.

6.2. Environmental precautions

Do not allow into any sewer, on the ground or into any body of water. See Section 12 for additional ecological information.

6.3. Methods and material for containment and cleaning up

Methods for containment

Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal.

Methods for cleaning up

Soak up with inert absorbent material. Take up mechanically, placing in appropriate

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containers for disposal.

6.4. Reference to other sections

See section 8 for more information. See section 13 for more information.

Section 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Advice on safe handling

Avoid contact with skin, eyes or clothing. Avoid breathing vapors or mists. Wash thoroughly after handling. Ensure adequate ventilation, especially in confined areas.

General Hygiene Considerations

Handle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions

Keep at temperatures between 7 and 29 °C.

Incompatible materials

Strong oxidizers.

7.3. Specific end use(s)

Specific use(s)

Adhesives and/or sealants.

Risk Management Methods (RMM)

The information required is contained in this Material Safety Data Sheet.

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Chemical Name

European Union

United Kingdom

France

Spain

Germany

OFF-WHITE HYDRATED

ALUMINA

21645-51-2

-

TWA: 10 mg/m3

TWA: 4 mg/m3

-

Chemical Name

Austria

Switzerland

Poland

Norway

Ireland

OFF-WHITE HYDRATED

ALUMINA

21645-51-2

TWA: 5 mg/m3

STEL 10 mg/m3

-

TWA: 2.5 mg/m3 TWA: 1.2 mg/m3

-

TWA: 10 mg/m3

TWA: 4 mg/m3 STEL: 30 mg/m3 STEL: 12 mg/m3

Derived No Effect Level (DNEL)

No information available.

Predicted No Effect Concentration (PNEC)

No information available.

8.2. Exposure controls

Engineering Controls

Ensure adequate ventilation, especially in confined areas.

Personal protective equipment

Eye/face protection

Wear safety glasses with side shields (or goggles).

Hand Protection

Wear protective gloves. Wear protective nitrile rubber gloves.

Skin and body protection

Suitable protective clothing.

Respiratory protection

In case of insufficient ventilation, wear suitable respiratory equipment.

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Environmental exposure controls

No information available.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Physical state

Paste

Appearance

No information available

Odor

Mild

Color

White

Odor threshold

No information available

Property

Values

Remarks • Method

pH

Does not apply

Melting point / freezing point

No information available

Boiling point / boiling range

> 149 °C / 300 °F

Flash point

> 93 °C / 200 °F

Evaporation rate

No information available

Flammability (solid, gas)

No information available

Flammability Limit in Air

Upper flammability limit:

No information available

Lower flammability limit:

No information available

Vapor pressure

< 5mm @ 80° F

Vapor density

No information available

Relative density

1.62

Water solubility

Slightly soluble

Solubility(ies)

No information available

Partition coefficient

No information available

Autoignition temperature

No information available

Decomposition temperature

No information available

Kinematic viscosity

No information available

Dynamic viscosity

No information available

Explosive properties

No information available

Oxidizing properties

No information available

9.2. Other information

Softening point

No information available

Molecular weight

No information available

VOC Content (%)

No information available

Density

No information available

Bulk density

No information available

Section 10: STABILITY AND REACTIVITY

10.1. Reactivity

No data available.

10.2. Chemical stability

Stable under normal conditions.

Explosion data

Sensitivity to Mechanical Impact

None.

Sensitivity to Static Discharge

None.

10.3. Possibility of hazardous reactions

Possibility of Hazardous Reactions

None under normal processing.

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10.4. Conditions to avoid

Incompatible materials.

10.5. Incompatible materials

Strong oxidizers.

10.6. Hazardous decomposition products

Carbon oxides. Nitrogen oxides (NOx). Irritating organic vapors.

Section 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Acute toxicity

Product Information Inhalation

No data available.

Eye contact

No data available.

Skin contact

No data available.

Ingestion

No data available.

The following values are calculated based on chapter 3.1 of the GHS document

ATEmix (oral)

3,984.00 mg/kg

ATEmix (dermal)

2,254.00 mg/kg

ATEmix (inhalation-dust/mist)

0.79 mg/l

Chemical Name

Oral LD50

Dermal LD50

Inhalation LC50

OFF-WHITE HYDRATED ALUMINA

> 5000 mg/kg ( Rat )

Hydroxypropyl Methacrylate

= 11200 mg/kg ( Rat )

> 3000 mg/kg ( Rabbit )

Cumene Hydroperoxide

= 382 mg/kg ( Rat )

= 0.126 mL/kg ( Rabbit )

= 220 ppm ( Rat ) 4 h

METHANOL

= 6200 mg/kg ( Rat )

= 15800 mg/kg ( Rabbit )

= 22500 ppm ( Rat ) 8 h = 64000

ppm ( Rat ) 4 h

Skin corrosion/irritation

No information available.

Serious eye damage/eye irritation

No information available.

Sensitization

No information available.

Germ cell mutagenicity

No information available.

Carcinogenicity

No information available.

Reproductive toxicity

No information available.

STOT - single exposure

No information available.

STOT - repeated exposure

No information available.

Aspiration hazard

No information available.

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Section 12: ECOLOGICAL INFORMATION

12.1. Toxicity

Chemical Name

Algae/aquatic plants

Fish

Crustacea

TETRAHYDROFURFURYL

METHACRYLATE

-

31.1 - 38.8: 96 h Pimephales

promelas mg/L LC50 flow-through

-

Hydroxypropyl Methacrylate

-

493: 48 h Leuciscus idus melanotus

mg/L LC50 static

-

Cumene Hydroperoxide

-

3.9: 96 h Oncorhynchus mykiss mg/L LC50 static

7: 24 h Daphnia magna mg/L EC50

12.2. Persistence and degradability

No information available.

12.3. Bioaccumulative potential

No information available.

12.4. Mobility in soil

Mobility in soil

No information available.

12.5. Results of PBT and vPvB assessment

No information available.

12.6. Other adverse effects

No information available

Section 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Waste from residues/unused products

Dispose of in accordance with federal, state and local regulations.

Contaminated packaging

Improper disposal or reuse of this container may be dangerous and illegal.

Section 14: TRANSPORT INFORMATION

IMDG

14.1 UN/ID no.

None

14.2 Proper shipping name

Not regulated

14.3 Hazard Class

None

14.4 Packing Group

None

14.5 Marine pollutant

Not applicable

14.6 Special Provisions

None

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

No information available

IATA

14.1 UN/ID no.

None

14.2 Proper shipping name

Not regulated

14.3 Hazard Class

None

14.4 Packing Group

None

14.5 Environmental hazard

Not applicable

14.6 Special Provisions

None

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DOT

Not regulated

UN/ID no.

None

Proper shipping name

Not regulated

Hazard Class

None

Packing Group

None

Special Provisions

None

Section 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

France

Occupational Illnesses (R-463-3, France)

Chemical Name

French RG number

Title

Hydroxypropyl Methacrylate

27813-02-1

RG 65

-

European Union

Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work

Authorizations and/or restrictions on use:

This product does not contain substances subject to authorization (Regulation (EC) No. 1907/2006 (REACH), Annex XIV) This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII)

Persistent Organic Pollutants

Not applicable

Named dangerous substances per Seveso Directive (2012/18/EU)

Ozone-depleting substances (ODS) regulation (EC) 1005/2009 Not applicable

International Inventories

TSCA

Complies

DSL/NDSL

Complies

EINECS/ELINCS

Complies

ENCS

Complies

IECSC

Complies

KECL

Complies

PICCS

Complies

AICS

Complies

All ingredients are on the inventory or are exempt from listing.

Legend:

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory

DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List

EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances

ENCS - Japan Existing and New Chemical Substances

IECSC - China Inventory of Existing Chemical Substances

KECL - Korean Existing and Evaluated Chemical Substances

PICCS - Philippines Inventory of Chemicals and Chemical Substances

AICS - Australian Inventory of Chemical Substances

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US State Regulations

California Proposition 65

This product contains the following Proposition 65 chemicals

Chemical Name

California Proposition 65

METHANOL - 67-56-1 (<1%)

Developmental

15.2. Chemical safety assessment

No information available

Section 16: OTHER INFORMATION

Key or legend to abbreviations and acronyms used in the safety data sheet

Full text of H-Statements referred to under section 3

H335 - May cause respiratory irritation H319 - Causes serious eye irritation H317 - May cause an allergic skin reaction H360D - May damage the unborn child H412 - Harmful to aquatic life with long lasting effects H302 - Harmful if swallowed H312 - Harmful in contact with skin H331 - Toxic if inhaled H314 - Causes severe skin burns and eye damage H373 - May cause damage to organs through prolonged or repeated exposure if inhaled H411 - Toxic to aquatic life with long lasting effects H242 - Heating may cause a fire

Legend

SVHC: Substances of Very High Concern for Authorization:

Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

TWA

TWA (time-weighted average)

STEL

STEL (Short Term Exposure Limit)

Ceiling

Maximum limit value

*

Skin designation

Prepared By

SDS coordinator

Issue Date

04-May-2015

Revision Date

26-Dec-2017

Revision Note

Not applicable.

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet