HCC Holdings, Inc. an Oatey Affiliate
4700 West 160th Street
Cleveland, OH 44135
216-267-7100
info@oatey.com
Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)
1-877-740-5015
MSDS Coordinator
Category 2Flammable liquids
Health hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Category 4Acute toxicity, oral
Category 2Skin corrosion/irritation
Category 2ASerious eye damage/eye irritation
Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 1Aspiration hazard
Not classified.
Danger
Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters
airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May
cause drowsiness or dizziness.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly
closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after
handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a
well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Immediately call a poison center/doctor. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and
keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if
you feel unwell. Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical
advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated
clothing and wash before reuse. In case of fire: Use appropriate media to extinguish.
Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.
HERCULES CLEAR, PURPLE, AND UNPURPLE PRIMERSDS US
924272 Version #: 01 Revision date: - Issue date: 17-Dec ember-2014
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Disposal
Hazard(s) not otherwise
classified (HNOC)
Supplemental information
Not applicable.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.
May form explosive peroxides. Contains a chemical classified by the US EPA as a suspected
possible carcinogen.
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin
irritation occurs: Get medical advice/attention.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs,
keep head low so that stomach content doesn't get into the lungs. Aspiration may cause
pulmonary edema and pneumonitis.
Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye
irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May
cause respiratory irritation. Vapors have a narcotic effect and may cause headache, fatigue,
dizziness and nausea. Skin irritation. May cause redness and pain.
Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give
oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.
Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the
material(s) involved, and take precautions to protect themselves. Wash contaminated clothing
before reuse.
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire fighting
equipment/instructions
Specific methods
General fire hazards
HERCULES CLEAR, PURPLE, AND UNPURPLE PRIMERSDS US
924272 Version #: 01 Revision date: - Issue date: 17-Dec ember-2014
Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire.
Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
of ignition and flash back. During fire, gases hazardous to health may be formed.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk.
Use standard firefighting procedures and consider the hazards of other involved materials.
Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive
organic peroxide when exposed to air or light or with age.
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6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Environmental precautions
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or
vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective
clothing. Ventilate closed spaces before entering them. Local authorities should be advised if
significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take
precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles
(wood, paper, oil, etc.) away from spilled material. This product is miscible in water.
Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or
divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to
prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the
product and place into a container for later disposal. Prevent entry into waterways, sewer,
basements or confined areas. Following product recovery, flush area with water.
Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers
for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame,
sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof
general and local exhaust ventilation. Take precautionary measures against static discharges. All
equipment used when handling the product must be grounded. Use non-sparking tools and
explosion-proof equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and
clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or
smoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling.
Observe good industrial hygiene practices.
Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge
build-up by using common bonding and grounding techniques. Store in a cool, dry place out of
direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Store
away from incompatible materials (see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin.
Furan, Tetrahydro- (CAS 109-99-9)Can be absorbed through the skin.
US. NIOSH: Pocket Guide to Chemical Hazards
Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin.
Appropriate engineering
controls
Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air
changes per hour) should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency
shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Eye/face protection
Face shield is recommended. Wear safety glasses with side shields (or goggles).
Urine
Urine
Urine
Sampling TimeDeterminantSpecimenComponents
*
*
*
*
*
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Skin protection
Hand protection
Other
Respiratory protection
Thermal hazards
General hygiene
considerations
Wear appropriate chemical resistant gloves.
Wear appropriate chemical resistant clothing.
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn.
Wear appropriate thermal protective clothing, when necessary.
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such
as washing after handling the material and before eating, drinking, and/or smoking. Routinely
wash work clothing and protective equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
SARA 313 (TRI reporting)
Not regulated.
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
No
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Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
US. New Jersey Worker and Community Right-to-Know Act
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. Pennsylvania Worker and Community Right-to-Know Law
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. Rhode Island RTK
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or regionInventory nameOn inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS)YesAustralia
Domestic Substances List (DSL)YesCanada
Non-Domestic Substances List (NDSL)NoCanada
Inventory of Existing Chemical Substances in China (IECSC)YesChina
European Inventory of Existing Commercial Chemical
Substances (EINECS)
European List of Notified Chemical Substances (ELINCS)NoEurope
Inventory of Existing and New Chemical Substances (ENCS)YesJapan
Existing Chemicals List (ECL)YesKorea
New Zealand InventoryYesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
YesEurope
YesPhilippines
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Country(s) or regionInventory nameOn inventory (yes/no)*
A
Toxic Substances Control Act (TSCA) InventoryYesUnited States & Puerto Rico
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
"No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date
Revision date
Version #
HMIS® ratings
Disclaimer
17-December-2014
01
Health: 2
Flammability: 3
Physical hazard: 0
The information in the sheet was written based on the best knowledge and experience currently
available. HCC Holdings Inc. an Oatey Affiliate cannot anticipate all conditions under which this
information and its product, or the products of other manufacturers in combination with its product,
may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and
disposal of the product, and to assume liability for loss, injury, damage or expense due to improper
use.
HERCULES CLEAR, PURPLE, AND UNPURPLE PRIMERSDS US
924272 Version #: 01 Revision date: - Issue date: 17-Dec ember-2014
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