HCC Holdings, Inc. an Oatey Affiliate
4700 West 160th Street
Cleveland, OH 44135
Telephone
E-mail
Transport Emergency
Emergency First Aid
Contact person
216-267-7100
info@oatey.com
Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)
1-877-740-5015
MSDS Coordinator
2. Hazard(s) identification
Physical hazards
Health hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
HERCULES Below Zero PVC Cement Clear Regul ar Body, Fast SetSDS US
927340 Version #: 01 Revision date: - Issue date: 27-May-2015
Not classified.
Danger
Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters
airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May
cause drowsiness or dizziness.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly
closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after
handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a
well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Immediately call a poison center/doctor. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and
keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if
you feel unwell. Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical
advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated
clothing and wash before reuse. In case of fire: Use appropriate media to extinguish.
Category 2Skin corrosion/irritation
Category 2ASerious eye damage/eye irritation
Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 1Aspiration hazard
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Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Supplemental information
Not applicable.
Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.
May form explosive peroxides. Contains a chemical classified by the US EPA as a suspected
possible carcinogen.
3. Composition/information on ingredients
Mixtures
CAS number%Chemical name
109-99-940-60Furan, Tetrahydro-
78-93-310-25Methyl ethyl ketone
9002-86-212-20Polyvinyl chloride
67-64-17-15Acetone
108-94-15-15Cyclohexanone
112945-52-51-5Silica, amorphous, fumed
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin
irritation occurs: Get medical advice/attention.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs,
keep head low so that stomach content doesn't get into the lungs. Aspiration may cause
pulmonary edema and pneumonitis.
Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye
irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May
cause respiratory irritation. Vapors have a narcotic effect and may cause headache, fatigue,
dizziness and nausea. Skin irritation. May cause redness and pain.
Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give
oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.
Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the
material(s) involved, and take precautions to protect themselves. Wash contaminated clothing
before reuse.
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire fighting
equipment/instructions
Specific methods
General fire hazards
HERCULES Below Zero PVC Cement Clear Regul ar Body, Fast SetSDS US
927340 Version #: 01 Revision date: - Issue date: 27-May-2015
Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire.
Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
of ignition and flash back. During fire, gases hazardous to health may be formed.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk.
Use standard firefighting procedures and consider the hazards of other involved materials.
Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive
organic peroxide when exposed to air or light or with age.
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6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Environmental precautions
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or
vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective
clothing. Ventilate closed spaces before entering them. Local authorities should be advised if
significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take
precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles
(wood, paper, oil, etc.) away from spilled material. This product is miscible in water.
Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or
divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to
prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the
product and place into a container for later disposal. Prevent entry into waterways, sewer,
basements or confined areas. Following product recovery, flush area with water.
Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers
for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame,
sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof
general and local exhaust ventilation. Take precautionary measures against static discharges. All
equipment used when handling the product must be grounded. Use non-sparking tools and
explosion-proof equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and
clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or
smoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling.
Observe good industrial hygiene practices.
Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge
build-up by using common bonding and grounding techniques. Store in a cool, dry place out of
direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Store
away from incompatible materials (see Section 10 of the SDS).
Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin.
Furan, Tetrahydro- (CAS 109-99-9)Can be absorbed through the skin.
US. NIOSH: Pocket Guide to Chemical Hazards
Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin protection
Hand protection
Other
Respiratory protection
Thermal hazards
General hygiene
considerations
Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air
changes per hour) should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency
shower must be available when handling this product.
Face shield is recommended. Wear safety glasses with side shields (or goggles).
Wear appropriate chemical resistant gloves.
Wear appropriate chemical resistant clothing.
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn.
Wear appropriate thermal protective clothing, when necessary.
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such
as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash
work clothing and protective equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Symptoms related to the
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicit
Acetone (CAS 67-64-1)
Acute
Dermal
LD50Rabbit
Inhalation
LC50Rat
Oral
LD50Rat
Cyclohexanone (CAS 108-94-1)
Acute
Dermal
LD50Rabbit
Inhalation
LC50Rat
May be fatal if swallowed and enters airways. Headache. Nausea, vomiting. May cause irritation
to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue,
dizziness and nausea. Prolonged inhalation may be harmful.
Causes skin irritation.
Causes serious eye irritation.
May be fatal if swallowed and enters airways. Harmful if swallowed. Harmful if swallowed. Droplets
of the product aspirated into the lungs through ingestion or vomiting may cause a serious
chemical pneumonia.
Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe
eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May
cause respiratory irritation. Skin irritation. May cause redness and pain. Symptoms of
overex
May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation.
osure may be headache, dizziness, tiredness, nausea and vomiting.
Test ResultsComponentsSpecies
20 ml/kg
50 mg/l, 8 Hours
5800 mg/kg
948 mg/kg
8000 ppm, 4 hours
HERCULES Below Zero PVC Cement Clear Regul ar Body, Fast SetSDS US
927340 Version #: 01 Revision date: - Issue date: 27-May-2015
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Oral
LD50Rat
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Carcinogenicity
IARC Monographs. Overall Evaluation of Carcinogenicity
Cyclohexanone (CAS 108-94-1)3 Not classifiable as to carcinogenicity to humans.
Polyvinyl chloride (CAS 9002-86-2)3 Not classifiable as to carcinogenicity to humans.
Silica, amorphous, fumed (CAS 112945-52-5)3 Not classifiable as to carcinogenicity to humans.
No data is available on the degradability of this product.
No data available.
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
7 / 10
13. Disposal considerations
Disposal instructions
Local disposal regulations
Hazardous waste code
Waste from residues / unused
products
Contaminated packaging
14. Transport information
DOT
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
Special precautions for user
Special provisions
Packaging exceptions
Packaging non bulk
Packaging bulk
IATA
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Packing group
Environmental hazards
ERG Code
Special precautions for user
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Packing group
Environmental hazards
Marine pollutant
EmS
Special precautions for user
Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material
and its container must be disposed of as hazardous waste. Do not allow this material to drain into
sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used
container. Dispose of contents/container in accordance with local/regional/national/international
regulations.
Dispose in accordance with all applicable regulations.
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
No.
F-E, S-E
Read safety instructions, SDS and emergency procedures before handling.
Not available.
15. Regulatory information
US federal regulations
HERCULES Below Zero PVC Cement Clear Regul ar Body, Fast SetSDS US
927340 Version #: 01 Revision date: - Issue date: 27-May-2015
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
US. New Jersey Worker and Community Right-to-Know Act
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
Polyvinyl chloride (CAS 9002-86-2)
US. Pennsylvania Worker and Community Right-to-Know Law
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
HERCULES Below Zero PVC Cement Clear Regul ar Body, Fast SetSDS US
927340 Version #: 01 Revision date: - Issue date: 27-May-2015
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Methyl ethyl ketone (CAS 78-93-3)
A
Silica, amorphous, fumed (CAS 112945-52-5)
US. Rhode Island RTK
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or regionInventory nameOn inventory (yes/no)*
Domestic Substances List (DSL)YesCanada
Toxic Substances Control Act (TSCA) InventoryNoUnited States & Puerto Rico
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
"No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date
Revision date
Version #
HMIS® ratings
NFPA ratings
27-May-2015
01
Health: 2
Flammability: 3
Physical hazard: 0
3
02
Disclaimer
The information in the sheet was written based on the best knowledge and experience currently
available. HCC Holdings Inc. an Oatey Affiliate cannot anticipate all conditions under which this
information and its product, or the products of other manufacturers in combination with its product,
may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and
disposal of the product, and to assume liability for loss, injury, damage or expense due to improper
use.
HERCULES Below Zero PVC Cement Clear Regul ar Body, Fast SetSDS US
927340 Version #: 01 Revision date: - Issue date: 27-May-2015
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