Category 2Skin corrosion/irritation
Category 2ASerious eye damage/eye irritation
Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 1Aspiration hazard
Not classified.
Danger
Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters
airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May
cause drowsiness or dizziness.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly
closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after
handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a
well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection.
HERCULES PVC Cement Cl ear Medium Body, Medium SetSDS US
927387 Version #: 01 Revision date: - Issue date: 27-May-2015
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Response
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Supplemental information
Not applicable.
If swallowed: Immediately call a poison center/doctor. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and
keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if
you feel unwell. Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical
advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated
clothing and wash before reuse. In case of fire: Use appropriate media to extinguish.
Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.
May form explosive peroxides. Contains a chemical classified by the US EPA as a suspected
possible carcinogen.
3. Composition/information on ingredients
Mixtures
CAS number%Chemical name
109-99-940-60Furan, Tetrahydro-
78-93-310-25Methyl ethyl ketone
9002-86-210-20Polyvinyl chloride
67-64-17-15Acetone
108-94-15-15Cyclohexanone
112945-52-51-5Silica, amorphous, fumed
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin
irritation occurs: Get medical advice/attention.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs,
keep head low so that stomach content doesn't get into the lungs. Aspiration may cause
pulmonary edema and pneumonitis.
Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye
irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May
cause respiratory irritation. Vapors have a narcotic effect and may cause headache, fatigue,
dizziness and nausea. Skin irritation. May cause redness and pain.
Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give
oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.
Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the
material(s) involved, and take precautions to protect themselves. Wash contaminated clothing
before reuse.
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
HERCULES PVC Cement Cl ear Medium Body, Medium SetSDS US
927387 Version #: 01 Revision date: - Issue date: 27-May-2015
Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire.
Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
of ignition and flash back. During fire, gases hazardous to health may be formed.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
2 / 10
Fire fighting
equipment/instructions
Specific methods
General fire hazards
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk.
Use standard firefighting procedures and consider the hazards of other involved materials.
Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive
organic peroxide when exposed to air or light or with age.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or
vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective
clothing. Ventilate closed spaces before entering them. Local authorities should be advised if
significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take
precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles
(wood, paper, oil, etc.) away from spilled material. This product is miscible in water.
Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or
divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to
prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the
product and place into a container for later disposal. Prevent entry into waterways, sewer,
basements or confined areas. Following product recovery, flush area with water.
Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers
for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions
Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame,
sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof
general and local exhaust ventilation. Take precautionary measures against static discharges. All
equipment used when handling the product must be grounded. Use non-sparking tools and
explosion-proof equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and
clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or
smoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling.
Observe good industrial hygiene practices.
Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge
build-up by using common bonding and grounding techniques. Store in a cool, dry place out of
direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Store
away from incompatible materials (see Section 10 of the SDS).
Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin.
Furan, Tetrahydro- (CAS 109-99-9)Can be absorbed through the skin.
US. NIOSH: Pocket Guide to Chemical Hazards
Cyclohexanone (CAS 108-94-1)Can be absorbed through the skin.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin protection
Hand protection
Other
Respiratory protection
Thermal hazards
General hygiene
considerations
2 mg/lTetrahydrofura
n
2 mg/lMEKUrine
Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air
changes per hour) should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency
shower must be available when handling this product.
Face shield is recommended. Wear safety glasses with side shields (or goggles).
Wear appropriate chemical resistant gloves.
Wear appropriate chemical resistant clothing.
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn.
Wear appropriate thermal protective clothing, when necessary.
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such
as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash
work clothing and protective equipment to remove contaminants.
Urine
Sampling TimeDeterminantSpecimenComponents
*
*
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
HERCULES PVC Cement Cl ear Medium Body, Medium SetSDS US
927387 Version #: 01 Revision date: - Issue date: 27-May-2015
Liquid.
Transparent liquid.
Clear.
Solvent.
Not available.
Not available.
Not available.
151 °F (66.11 °C)
6.0 °F (-14.4 °C) Based on THF
7 - 11
Not available.
1.8
5 / 10
Flammability limit - upper
t
p
y
(%)
Explosive limit - lower (%)
Explosive limit - upper (%)
Vapor pressure
Vapor density
Relative density
Solubility(ies)
Solubility (water)
Partition coefficient
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity
Other information
Bulk density
VOC (Weight %)
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
11.8
Not available.
Not available.
143 mm Hg @ 20 C
2 - 2.5
0.91 +/- 0.02
Negligible
Not available.
Not available.
Not available.
80 - 500 cP
7.6 lb/gal
484 g/l SCAQMD 1168/M316A
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the
flash point. Contact with incompatible materials.
Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics.
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Inhalation
Skin contact
Eye contac
Ingestion
Symptoms related to the
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicit
Acetone (CAS 67-64-1)
Acute
Dermal
LD50Rabbit
Inhalation
LC50Rat
Oral
LD50Rat
May be fatal if swallowed and enters airways. Headache. Nausea, vomiting. May cause irritation
to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue,
dizziness and nausea. Prolonged inhalation may be harmful.
Causes skin irritation.
Causes serious eye irritation.
May be fatal if swallowed and enters airways. Harmful if swallowed. Harmful if swallowed. Droplets
of the product aspirated into the lungs through ingestion or vomiting may cause a serious
chemical pneumonia.
Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe
eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May
cause respiratory irritation. Skin irritation. May cause redness and pain. Symptoms of
overex
May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation.
osure may be headache, dizziness, tiredness, nausea and vomiting.
Test ResultsComponentsSpecies
20 ml/kg
50 mg/l, 8 Hours
5800 mg/kg
HERCULES PVC Cement Cl ear Medium Body, Medium SetSDS US
927387 Version #: 01 Revision date: - Issue date: 27-May-2015
6 / 10
Cyclohexanone (CAS 108-94-1)
Acute
Dermal
LD50Rabbit
Inhalation
LC50Rat
Oral
LD50Rat
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Carcinogenicity
IARC Monographs. Overall Evaluation of Carcinogenicity
Cyclohexanone (CAS 108-94-1)3 Not classifiable as to carcinogenicity to humans.
Polyvinyl chloride (CAS 9002-86-2)3 Not classifiable as to carcinogenicity to humans.
Silica, amorphous, fumed (CAS 112945-52-5)3 Not classifiable as to carcinogenicity to humans.
Not available.
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalation
lifetime study on THF conducted by NTP (1998). Male rats developed renal tumors and female
mice developed liver tumors while neither the female rats nor the male mice showed similar
results. Because the carcinogenic mechanisms could not be identified clearly in either species for
either tumor, the EPA determined that the male rat and female mouse findings are relevant to the
assessment of carcinogenic potential in humans. Therefore, the IRIS review concludes that these
data in aggregate indicate that there is "suggestive evidence of carcinogenic potential" following
exposure to THF by all routes of exposure.
This product is not expected to cause reproductive or developmental effects.
Narcotic effects. May cause drowsiness and dizziness. Respiratory tract irritation.
Not classified.
May be fatal if swallowed and enters airways.
Prolonged inhalation may be harmful.
Test ResultsComponentsSpecies
948 mg/kg
8000 ppm, 4 hours
1540 mg/kg
12. Ecological information
Ecotoxicity
ComponentsTest ResultsSpecies
Acetone (CAS 67-64-1)
Aquatic
Cyclohexanone (CAS 108-94-1)
Aquatic
* Estimates for product may be based on additional component data not shown.
Persistence and degradability
Bioaccumulative potential
HERCULES PVC Cement Cl ear Medium Body, Medium SetSDS US
927387 Version #: 01 Revision date: - Issue date: 27-May-2015
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
No data is available on the degradability of this product.
No data available.
7 / 10
Partition coefficient n-octanol / water (log Kow)
Acetone (CAS 67-64-1)-0.24
Cyclohexanone (CAS 108-94-1)0.81
Furan, Tetrahydro- (CAS 109-99-9)0.46
Methyl ethyl ketone (CAS 78-93-3)0.29
Mobility in soil
Other adverse effects
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions
Local disposal regulations
Hazardous waste code
Waste from residues / unused
products
Contaminated packaging
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material
and its container must be disposed of as hazardous waste. Do not allow this material to drain into
sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used
container. Dispose of contents/container in accordance with local/regional/national/international
regulations.
Dispose in accordance with all applicable regulations.
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
14. Transport information
DOT
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
Special precautions for user
Special provisions
Packaging exceptions
Packaging non bulk
Packaging bulk
IATA
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Packing group
Environmental hazards
ERG Code
Special precautions for user
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Packing group
Environmental hazards
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
SARA 313 (TRI reporting)
Not regulated.
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
Central nervous system
Liver
Blood
Flammability
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
No
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
HERCULES PVC Cement Cl ear Medium Body, Medium SetSDS US
927387 Version #: 01 Revision date: - Issue date: 27-May-2015
9 / 10
US. New Jersey Worker and Community Right-to-Know Act
A
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
Polyvinyl chloride (CAS 9002-86-2)
US. Pennsylvania Worker and Community Right-to-Know Law
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
Silica, amorphous, fumed (CAS 112945-52-5)
US. Rhode Island RTK
Acetone (CAS 67-64-1)
Cyclohexanone (CAS 108-94-1)
Furan, Tetrahydro- (CAS 109-99-9)
Methyl ethyl ketone (CAS 78-93-3)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or regionInventory nameOn inventory (yes/no)*
Domestic Substances List (DSL)YesCanada
Toxic Substances Control Act (TSCA) InventoryNoUnited States & Puerto Rico
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
"No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date
Revision date
Version #
HMIS® ratings
NFPA ratings
Disclaimer
27-May-2015
01
Health: 2
Flammability: 3
Physical hazard: 0
3
02
The information in the sheet was written based on the best knowledge and experience currently
available. HCC Holdings Inc. an Oatey Affiliate cannot anticipate all conditions under which this
information and its product, or the products of other manufacturers in combination with its product,
may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and
disposal of the product, and to assume liability for loss, injury, damage or expense due to improper
use.
HERCULES PVC Cement Cl ear Medium Body, Medium SetSDS US
927387 Version #: 01 Revision date: - Issue date: 27-May-2015
10 / 10
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