SAFETY DATA SHEET
1. Identification
Product identifier
Other means of identification
Product code
Synonyms
Recommended use
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Company Name
Address
Hercules High Heat Furnace Cement
7330E
Part Numbers: Regular- 35503, 35504, 35509, 35515, 35610, Heavy- 35521, 35526
Furnace Cement
Workers (and your customers or users in the case of resale) should be informed of the potential
presence of respirable dust and respirable crystalline silica as well as their potential hazards.
Appropriate training in the proper use and handling of this material should be provided as required
under applicable regulations.
HCC Holdings, Inc. an Oatey Affiliate
4700 West 160th Street
Cleveland, OH 44135
Telephone
E-mail
Transport Emergency
Emergency First Aid
Contact person
2. Hazard(s) identification
Physical hazards
Health hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
216-267-7100
info@oatey.com
Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)
1-877-740-5015
MSDS Coordinator
Not classified.
Category 1Skin corrosion/irritation
Category 1Serious eye damage/eye irritation
Not classified.
Danger
Causes severe skin burns and eye damage.
Do not breathe mist or vapor. Wash thoroughly after handling. Wear protective gloves/protective
clothing/eye protection/face protection.
If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and
keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison
center/doctor. Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.
3. Composition/information on ingredients
Mixtures
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CAS number %Chemical name
1332-58-7 10-30Kaolin
37244-96-5 10-30Nepheline Syenite
1344-09-8 10-30Sodium silicate
12001-26-2 5-10Mica
13983-17-0 5-10Wollastonite
14808-60-7 1-5Crystalline silica (Quartz)
68131-74-8 0-3Microspheres
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
Move to fresh air.
Take off immediately all contaminated clothing. Wash off with soap and water. Call a physician or
poison control center immediately. Chemical burns must be treated by a physician. Wash
contaminated clothing before reuse.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Call a physician or poison control center immediately.
Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs,
keep head low so that stomach content doesn't get into the lungs.
Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may
include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including
blindness could result.
Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. Keep victim under observation.
Symptoms may be delayed.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
24.12Other components below reportable levels
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire fighting
equipment/instructions
Specific methods
General fire hazards
Powder. Foam. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire.
During fire, gases hazardous to health may be formed.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Move containers from fire area if you can do so without risk.
Use standard firefighting procedures and consider the hazards of other involved materials.
No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do
not touch damaged containers or spilled material unless wearing appropriate protective clothing.
Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be
contained. For personal protection, see section 8 of the SDS.
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Methods and materials for
containment and cleaning up
Environmental precautions
Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or
divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to
prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following
product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Do not breathe mist or vapor. Do not get in eyes, on skin, or on clothing. Avoid prolonged
exposure. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe
good industrial hygiene practices.
Store locked up. Store in original tightly closed container. Store away from incompatible materials
(see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
US. OSHA Table Z-3 (29 CFR 1910.1000)
Components
(CAS 14808-60-7)
US. ACGIH Threshold Limit Values
Components
(CAS 14808-60-7)
US. NIOSH: Pocket Guide to Chemical Hazards
Components
(CAS 14808-60-7)
Biological limit values
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin protection
Hand protection
Other
Respiratory protection
Thermal hazards
No biological exposure limits noted for the ingredient(s).
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Eye
wash facilities and emergency shower must be available when handling this product.
Wear safety glasses with side shields (or goggles) and a face shield.
Wear appropriate chemical resistant gloves.
Wear appropriate chemical resistant clothing.
In case of insufficient ventilation, wear suitable respiratory equipment.
Wear appropriate thermal protective clothing, when necessary.
Type
PEL 5 mg/m3 Respirable fraction.Kaolin (CAS 1332-58-7)
Type
TWA 0.3 mg/m3 Total dust.Crystalline silica (Quartz)
TWA 20 mppcfMica (CAS 12001-26-2)
Type
TWA 0.025 mg/m3 Respirable fraction.Crystalline silica (Quartz)
TWA 2 mg/m3 Respirable fraction.Kaolin (CAS 1332-58-7)
TWA 3 mg/m3 Respirable fraction.Mica (CAS 12001-26-2)
Type
TWA 0.05 mg/m3 Respirable dust.Crystalline silica (Quartz)
TWA 5 mg/m3 Respirable.Kaolin (CAS 1332-58-7)
TWA 3 mg/m3 Respirable.Mica (CAS 12001-26-2)
Value
15 mg/m3 Total dust.
Value
0.1 mg/m3 Respirable.
Value
Value
10 mg/m3 Total
Form
Form
Form
Form
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General hygiene
t
considerations
Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Flammability limit - upper
(%)
Explosive limit - lower (%)
Explosive limit - upper (%)
Vapor pressure
Vapor density
Relative density
Solubility(ies)
Solubility (water)
Partition coefficient
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity
Other information
VOC (Weight %)
Liquid.
Paste.
Tan. or Black.
Odorless.
Not available.
11 - 13
Not available.
212 °F (100 °C)
> 212.0 °F (> 100.0 °C)
Not available.
Not applicable.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
1.95 +/- 0.03
Not available.
Not available.
Not available.
Not available.
Not available.
0 g/l
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Contact with incompatible materials.
Strong oxidizing agents.
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Inhalation
Skin contact
Eye contac
925123 Version #: 01 Revision date: - Issue date: 22-April-2015
May cause irritation to the respiratory system. Prolonged inhalation may be harmful.
Causes severe skin burns.
Causes serious eye damage.
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Ingestion
y
Symptoms related to the
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicit
Skin corrosion/irritation
Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Carcinogenicity
IARC Monographs. Overall Evaluation of Carcinogenicity
Crystalline silica (Quartz) (CAS 14808-60-7) 1 Carcinogenic to humans.
Wollastonite (CAS 13983-17-0) 3 Not classifiable as to carcinogenicity to humans.
NTP Report on Carcinogens
Crystalline silica (Quartz) (CAS 14808-60-7) Known To Be Human Carcinogen.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity
Specific target organ toxicity -
single exposure
Specific target organ toxicity -
repeated exposure
Aspiration hazard
Chronic effects
Causes digestive tract burns.
Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may
include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including
blindness could result.
Not available.
Causes severe skin burns and eye damage.
Causes serious eye damage.
Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
In 1997, IARC (the International Agency for Research on Cancer) concluded that crystalline silica
inhaled from occupational sources can cause lung cancer in humans. However in making the
overall evaluation, IARC noted that "carcinogenicity was not detected in all industrial
circumstances studied. Carcinogenicity may be dependent on inherent characteristics of the
crystalline silica or on external factors affecting its biological activity or distribution of its
polymorphs." (IARC Monographs on the evaluation of the carcinogenic risks of chemicals to
humans, Silica, silicates dust and organic fibres, 1997, Vol. 68, IARC, Lyon, France.) Risk of
cancer cannot be excluded with prolonged exposure.
This product is not expected to cause reproductive or developmental effects.
Not classified.
Not classified.
Not an aspiration hazard.
Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.
12. Ecological information
Ecotoxicity
Persistence and degradability
Bioaccumulative potential
Mobility in soil
Other adverse effects
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
No data is available on the degradability of this product.
No data available.
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions
Local disposal regulations
Hazardous waste code
Waste from residues / unused
products
Contaminated packaging
925123 Version #: 01 Revision date: - Issue date: 22-April-2015
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Dispose in accordance with all applicable regulations.
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
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14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
Not established.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
SARA 313 (TRI reporting)
Not regulated.
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
One or more components are not listed on TSCA.
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
No
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Crystalline silica (Quartz) (CAS 14808-60-7)
Kaolin (CAS 1332-58-7)
Mica (CAS 12001-26-2)
US. New Jersey Worker and Community Right-to-Know Act
Crystalline silica (Quartz) (CAS 14808-60-7)
Kaolin (CAS 1332-58-7)
Mica (CAS 12001-26-2)
US. Pennsylvania Worker and Community Right-to-Know Law
Crystalline silica (Quartz) (CAS 14808-60-7)
Kaolin (CAS 1332-58-7)
Mica (CAS 12001-26-2)
US. Rhode Island RTK
Not regulated.
Not regulated.
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US. California Proposition 65
A
WARNING: This product contains a chemical known to the State of California to cause cancer.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Crystalline silica (Quartz) (CAS 14808-60-7)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) NoAustralia
Domestic Substances List (DSL) YesCanada
Inventory of Existing and New Chemical Substances (ENCS) NoJapan
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
"No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date
Revision date
Version #
HMIS® ratings
NFPA ratings
22-April-2015
-
01
Health: 3
Flammability: 0
Physical hazard: 0
0
03
NoPhilippines
Disclaimer
HCC Holdings Inc. an Oatey Affiliate cannot anticipate all conditions under which this information
and its product, or the products of other manufacturers in combination with its product, may be
used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of
the product, and to assume liability for loss, injury, damage or expense due to improper use. The
information in the sheet was written based on the best knowledge and experience currently
available.
SDS USHercules High Heat Furnace Cement
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