Hercules 35253, 35260, 35267, 35284, 35286 User Manual

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SAFETY DATA SHEET
1. Identification
Product identifier Cryo- Tek Original and Cryo- Tek - 100 Antifreeze Other means of identification
Product code
Synonyms Recommended use Recommended restrictions Manufacturer/Importer/Supplier/Distributor information
Company Name
Address
Telephone
E-mail
Transport Emergency
Emergency First Aid
Contact person
2. Hazard(s) identification
Physical hazards
7301E Part Numbers: 35253, 35260, 35267, 35284, 35286, 35287, 35281 Propylene Glycol Based Antifreeze None known.
HCC Holdings, Inc. an Oatey Affiliate 4700 West 160th Street Cleveland, OH 44135 216-267-7100 info@oatey.com Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887) 1-877-740-5015 MSDS Coordinator
Not classified.
Health hazards OSHA defined hazards Label elements
Hazard symbol
Signal word
Hazard statement
Precautionary statement
Prevention Response Storage Disposal
Hazard(s) not otherwise classified (HNOC)
Not classified. Not classified.
None. None.
The mixture does not meet the criteria for classification.
Observe good industrial hygiene practices. Wash hands after handling. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. None known.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name
57-55-6 40-60Propylene glycol
7732-18-5 40-60Water
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact Eye contact Ingestion
Cryo- Tek Original and Cryo- Tek - 100 Antifreeze SDS US 924648 Version #: 01 Revision date: - Issue date: 05-February-2015
If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a physician if symptoms develop or persist.
Rinse skin with water/shower. Get medical attention if irritation develops and persists. Rinse with water. Get medical attention if irritation develops and persists. Rinse mouth. If ingestion of a large amount does occur, call a poison control center immediately.
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Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed
General information
Direct contact with eyes may cause temporary irritation.
Treat symptomatically.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.
5. Fire-fighting measures
Suitable extinguishing media Unsuitable extinguishing
media Specific hazards arising from
the chemical Special protective equipment
and precautions for firefighters Fire fighting
equipment/instructions Specific methods General fire hazards
Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire.
During fire, gases hazardous to health may be formed.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Move containers from fire area if you can do so without risk.
Use standard firefighting procedures and consider the hazards of other involved materials. No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Methods and materials for containment and cleaning up
Keep unnecessary personnel away. For personal protection, see section 8 of the SDS.
Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions
Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling Conditions for safe storage,
including any incompatibilities
Avoid prolonged exposure. Use care in handling/storage. Store in original tightly closed container. Store away from incompatible materials (see Section 10
of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
US. Workplace Environmental Exposure Level (WEEL) Guides
Components
57-55-6)
Biological limit values Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin protection
Hand protection Other
Respiratory protection
Cryo- Tek Original and Cryo- Tek - 100 Antifreeze SDS US 924648 Version #: 01 Revision date: - Issue date: 05-February-2015
No biological exposure limits noted for the ingredient(s). Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.
Wear safety glasses with side shields (or goggles).
Wear appropriate chemical resistant gloves. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Type
TWA 10 mg/m3 Aerosol.Propylene glycol (CAS
Value
Form
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Thermal hazards General hygiene
considerations
Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Physical state
Form
Color Odor Odor threshold pH Melting point/freezing point Initial boiling point and boiling
range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Flammability limit - upper
(%)
Explosive limit - lower (%)
Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies)
Solubility (water) Partition coefficient
(n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information
VOC (Weight %)
Liquid. Liquid. Blue or Pink. Odorless.
Not available.
8.5 - 10 Not available. 212 °F (100 °C)
> 212.0 °F (> 100.0 °C) Not available.
Not available.
Not available.
Not available.
Not available. Not available. Not available. Not available.
1.05
Not available.
Not available.
Not available. Not available. 10 cP
575 g/l 55% by weight
10. Stability and reactivity
Reactivity Chemical stability Possibility of hazardous
reactions Conditions to avoid Incompatible materials Hazardous decomposition
products
The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. No dangerous reaction known under conditions of normal use.
Contact with incompatible materials. Strong oxidizing agents. No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Inhalation
Skin contact
Cryo- Tek Original and Cryo- Tek - 100 Antifreeze SDS US 924648 Version #: 01 Revision date: - Issue date: 05-February-2015
Prolonged inhalation may be harmful. No adverse effects due to skin contact are expected.
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Eye contac
t
y
y
Ingestion Symptoms related to the
physical, chemical and toxicological characteristics
Information on toxicological effects Acute toxicit
Propylene glycol (CAS 57-55-6)
Acute
Oral
LD50 Rat
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Serious eye damage/eye
irritation Respiratory or skin sensitization
Respiratory sensitization
Skin sensitization Germ cell mutagenicity
Carcinogenicit
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity Specific target organ toxicity -
single exposure Specific target organ toxicity -
repeated exposure Aspiration hazard Chronic effects Further information
Direct contact with eyes may cause temporary irritation. Expected to be a low ingestion hazard. Direct contact with eyes may cause temporary irritation.
Prolonged skin contact may cause temporary irritation. Direct contact with eyes may cause temporary irritation.
Not a respiratory sensitizer. This product is not expected to cause skin sensitization. No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
This product is not expected to cause reproductive or developmental effects. Not classified.
Not classified.
Not an aspiration hazard. Prolonged inhalation may be harmful. This product has no known adverse effect on human health.
Test ResultsComponents Species
30 g/kg
12. Ecological information
Ecotoxicity
Components Test ResultsSpecies
Propylene glycol (CAS 57-55-6)
Aquatic
* Estimates for product may be based on additional component data not shown.
Persistence and degradability Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Propylene glycol (CAS 57-55-6) -0.92
Mobility in soil Other adverse effects
The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.
LC50Crustacea 18340 mg/l, 48 hoursCeriodaphnia dubia LC50Fish 46500 mg/l, 96 hoursPimephales promelas
No data is available on the degradability of this product.
No data available. No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions
Cryo- Tek Original and Cryo- Tek - 100 Antifreeze SDS US 924648 Version #: 01 Revision date: - Issue date: 05-February-2015
Collect and reclaim or dispose in sealed containers at licensed waste disposal site.
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Local disposal regulations Hazardous waste code
Waste from residues / unused products
Contaminated packaging
Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste
disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).
Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied.
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not established.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
SARA 313 (TRI reporting)
Not regulated.
This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List.
Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No
No
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
(SDWA) US state regulations
US. Massachusetts RTK - Substance List
Not regulated.
US. New Jersey Worker and Community Right-to-Know Act
Propylene glycol (CAS 57-55-6)
US. Pennsylvania Worker and Community Right-to-Know Law
Propylene glycol (CAS 57-55-6)
Cryo- Tek Original and Cryo- Tek - 100 Antifreeze SDS US 924648 Version #: 01 Revision date: - Issue date: 05-February-2015
Not regulated.
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US. Rhode Island RTK
A
Not regulated.
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia Domestic Substances List (DSL) YesCanada Non-Domestic Substances List (NDSL) NoCanada Inventory of Existing Chemical Substances in China (IECSC) YesChina European Inventory of Existing Commercial Chemical
Substances (EINECS) European List of Notified Chemical Substances (ELINCS) NoEurope Inventory of Existing and New Chemical Substances (ENCS) YesJapan Existing Chemicals List (ECL) YesKorea New Zealand Inventory YesNew Zealand Philippine Inventory of Chemicals and Chemical Substances
(PICCS) Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
"No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
YesEurope
YesPhilippines
16. Other information, including date of preparation or last revision
Issue date Revision date Version # HMIS® ratings
NFPA ratings
Disclaimer
05-February-2015
­01
Health: 0 Flammability: 0 Physical hazard: 0
0
00
HCC Holdings Inc. an Oatey Affiliate cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available.
Cryo- Tek Original and Cryo- Tek - 100 Antifreeze SDS US 924648 Version #: 01 Revision date: - Issue date: 05-February-2015
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