Hercules 252034 User Manual

SAFETY DATA SHEET
1. Identification
Cloroben Aid-Ox®Product identifier
Other means of identification
SDS number
Synonyms Recommended use Recommended restrictions Manufacturer/Importer/Supplier/Distributor information
Company Name
Address
252034 Part Numbers: 252034 Septic System Restorer None known.
HCC Holdings, Inc. an Oatey Affiliate 4700 West 160th Street Cleveland, OH 44135
Telephone
E-mail
Transport Emergency
Emergency First Aid
Contact person
216-267-7100 info@oatey.com Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887) 1-877-740-5015 MSDS Coordinator
2. Hazard(s) identification
Physical hazards Health hazards
Environmental hazards
OSHA defined hazards Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage Disposal
Hazard(s) not otherwise classified (HNOC)
Cloroben Aid-Ox® SDS US 925574 Version #: 01 Revision date: - Issue date: 23-April-2015
hazard Not classified.
Warning May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation. May cause
respiratory irritation. Harmful to aquatic life.
Keep away from heat. Keep/Store away from clothing and other combustible materials. Take any precaution to avoid mixing with combustibles. Avoid breathing dust. Use only outdoors or in a well-ventilated area. Wear protective gloves/eye protection/face protection. Wash thoroughly after handling. Avoid release to the environment.
In case of fire: Use media appropriate for surrounding materials for extinction. If on skin: Wash with plenty of water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell.
Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. None known.
Category 2Oxidizing solids Category 2Skin corrosion/irritation
Category 2ASerious eye damage/eye irritation Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure
Category 3Hazardous to the aquatic environment, acute
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3. Composition/information on ingredients
Mixtures
CAS number %Chemical name
15630-89-4 60-100Sodium percarbonate
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed
General information
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
Remove contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse.
Do not rub eyes. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Rinse mouth. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Get medical advice/attention if you feel unwell.
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Dusts may irritate the respiratory tract, skin and eyes. Skin irritation. May cause redness and pain.
Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim under observation. Symptoms may be delayed.
If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance.
5. Fire-fighting measures
Suitable extinguishing media Unsuitable extinguishing
media Specific hazards arising from
the chemical Special protective equipment
and precautions for firefighters Fire fighting
equipment/instructions Specific methods General fire hazards
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire.
During fire, gases hazardous to health may be formed.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Use water spray to cool unopened containers.
Use standard firefighting procedures and consider the hazards of other involved materials. No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Methods and materials for containment and cleaning up
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation of dust. Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at levels exceeding the exposure limits. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air). Stop the flow of material, if this is without risk. Absorb in vermiculite, dry sand or earth and place into containers. Collect dust using a vacuum cleaner equipped with HEPA filter.
Large Spills: Wet down with water and dike for later disposal. Shovel the material into waste container. Prevent product from entering drains. Following product recovery, flush area with water.
Small Spills: Sweep up or vacuum up spillage and collect in suitable container for disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Cloroben Aid-Ox® SDS US 925574 Version #: 01 Revision date: - Issue date: 23-April-2015
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Environmental precautions
Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases.
7. Handling and storage
Precautions for safe handling
Conditions for safe storage, including any incompatibilities
Minimize dust generation and accumulation. Provide appropriate exhaust ventilation at places where dust is formed. Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Do not taste or swallow. When using, do not eat, drink or smoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices.
Store locked up. Store in original tightly closed container. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits Biological limit values Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin protection
Hand protection Other
Respiratory protection
Thermal hazards General hygiene
considerations
No exposure limits noted for ingredient(s). No biological exposure limits noted for the ingredient(s). Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. If material is ground, cut, or used in any operation which may generate dusts, use appropriate local exhaust ventilation to keep exposures below the recommended exposure limits. Eye wash facilities and emergency shower must be available when handling this product.
Face shield is recommended. Wear safety glasses with side shields (or goggles).
Wear appropriate chemical resistant gloves. Wear appropriate chemical resistant clothing. Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at levels
exceeding the exposure limits. Dust & vapor respirator. Wear appropriate thermal protective clothing, when necessary. Keep away from food and drink. Always observe good personal hygiene measures, such as
washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Physical state
Form
Color Odor Odor threshold pH Melting point/freezing point Initial boiling point and boiling
range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Flammability limit - upper
(%)
Explosive limit - lower (%)
Explosive limit - upper (%) Vapor pressure
Solid. Powder. White.
Odorless. Not available. 10 (1% by weight) Not available. None
None Not available.
Not available.
Not available.
Not available.
Not available. Not available. Not available.
Cloroben Aid-Ox® SDS US 925574 Version #: 01 Revision date: - Issue date: 23-April-2015
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Vapor density
t
y
y
Relative density Solubility(ies)
Solubility (water)
Partition coefficient (n-octanol/water)
Auto-ignition temperature Decomposition temperature Viscosity Other information
VOC (Weight %)
Not available.
0.95 - 1.08
Not available.
Not available.
Not available. Not available. Not available.
0 g/l
10. Stability and reactivity
Reactivity Chemical stability Possibility of hazardous
reactions Conditions to avoid Incompatible materials Hazardous decomposition
products
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Contact with incompatible materials.
Strong oxidizing agents.
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Inhalation Skin contact Eye contac Ingestion
Symptoms related to the physical, chemical and toxicological characteristics
Information on toxicological effects Acute toxicit
Cloroben Aid-Ox® (CAS Mixture)
Dermal
LD50 Rabbit
Inhalation
LC50
Oral
LD50 Rat
May cause irritation to the respiratory system. Dust may irritate respiratory system.
Causes skin irritation.
Causes serious eye irritation.
Expected to be a low ingestion hazard.
Severe eye irritation. Dusts may irritate the respiratory tract, skin and eyes. Symptoms may
include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness
and pain.
Test ResultsProduct Species
2000 mg/kg
4580 mg/l
2400 mg/kg
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Serious eye damage/eye
irritation Respiratory or skin sensitization
Respiratory sensitization Skin sensitization
Germ cell mutagenicity
Carcinogenicit
Cloroben Aid-Ox® SDS US 925574 Version #: 01 Revision date: - Issue date: 23-April-2015
Causes skin irritation.
Causes serious eye irritation.
Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
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OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity Specific target organ toxicity -
single exposure Specific target organ toxicity -
repeated exposure Aspiration hazard
This product is not expected to cause reproductive or developmental effects.
May cause respiratory irritation.
Not classified.
Not an aspiration hazard.
12. Ecological information
Ecotoxicity
Components Test ResultsSpecies
Sodium percarbonate (CAS 15630-89-4)
Aquatic
* Estimates for product may be based on additional component data not shown.
Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects
Toxic to aquatic life. Harmful to aquatic life with long lasting effects.
LC50Fish 70.7 mg/l, 96 hoursPimephales promelas
No data is available on the degradability of this product.
No data available.
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions
Local disposal regulations Hazardous waste code
Waste from residues / unused products
Contaminated packaging
14. Transport information
DOT
UN number UN proper shipping name Transport hazard class(es)
Class Subsidiary risk
Label(s) Packing group Special precautions for user Special provisions Packaging exceptions Packaging non bulk Packaging bulk
IATA
UN number UN proper shipping name Transport hazard class(es)
Class
Subsidiary risk
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations.
Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste
disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).
Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied.
UN1479 Oxidizing solid, n.o.s. (Sodium percarbonate, Sodium carbonate)
5.1
-
5.1 II Read safety instructions, SDS and emergency procedures before handling. 62, IB8, IP2, IP4, T3, TP33 152 212 240
UN1479 Oxidizing solid, n.o.s. (Sodium percarbonate, Sodium carbonate)
5.1
-
Cloroben Aid-Ox® SDS US 925574 Version #: 01 Revision date: - Issue date: 23-April-2015
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Packing group Environmental hazards ERG Code Special precautions for user
IMDG
UN number UN proper shipping name Transport hazard class(es)
Class
Subsidiary risk Packing group Environmental hazards
Marine pollutant EmS Special precautions for user
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
II No. 5L Read safety instructions, SDS and emergency procedures before handling.
UN1479 OXIDIZING SOLID, N.O.S. (Sodium percarbonate, Sodium carbonate)
5.1
­II
No. F-A, S-Q Read safety instructions, SDS and emergency procedures before handling. Not applicable.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous chemical
SARA 313 (TRI reporting)
Not regulated.
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No
No
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act (SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Not regulated.
US. New Jersey Worker and Community Right-to-Know Act
Not listed.
US. Pennsylvania Worker and Community Right-to-Know Law
Not listed.
US. Rhode Island RTK
Not regulated.
Cloroben Aid-Ox® SDS US 925574 Version #: 01 Revision date: - Issue date: 23-April-2015
Not regulated.
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US. California Proposition 65
A
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia Domestic Substances List (DSL) YesCanada Non-Domestic Substances List (NDSL) NoCanada Inventory of Existing Chemical Substances in China (IECSC) YesChina European Inventory of Existing Commercial Chemical
Substances (EINECS) European List of Notified Chemical Substances (ELINCS) NoEurope Inventory of Existing and New Chemical Substances (ENCS) YesJapan Existing Chemicals List (ECL) YesKorea New Zealand Inventory YesNew Zealand Philippine Inventory of Chemicals and Chemical Substances
(PICCS) Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
"No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date Revision date Version # HMIS® ratings
NFPA ratings
23-April-2015
­01
Health: 2 Flammability: 2 Physical hazard: 2
2
22
YesEurope
YesPhilippines
Disclaimer
HCC Holdings Inc. an Oatey Affiliate cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available.
Cloroben Aid-Ox® SDS US 925574 Version #: 01 Revision date: - Issue date: 23-April-2015
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