SAFETY DATA SHEET
1. Identification
Hercules StaputProduct identifier
Other means of identification
Product code
Synonyms
Recommended use
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Company Name
Address
1618E
Part Numbers: 25101, 25103, 25105, 25110, 25120, 25122
Plumbing Mastic
Workers (and your customers or users in the case of resale) should be informed of the potential
presence of respirable dust and respirable crystalline silica as well as their potential hazards.
Appropriate training in the proper use and handling of this material should be provided as required
under applicable regulations.
HCC Holdings, Inc. an Oatey Affiliate
4700 West 160th Street
Cleveland, OH 44135
Telephone
E-mail
Transport Emergency
Emergency First Aid
Contact person
2. Hazard(s) identification
Physical hazards
Health hazards
OSHA defined hazards
Label elements
Hazard symbol
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
216-267-7100
info@oatey.com
Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)
1-877-740-5015
MSDS Coordinator
Not classified.
Not classified.
Not classified.
None.
None.
The mixture does not meet the criteria for classification.
Observe good industrial hygiene practices.
Wash hands after handling.
Store away from incompatible materials.
Dispose of waste and residues in accordance with local authority requirements.
Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name
1317-65-3 60-100Calcium carbonate
1332-58-7 5-10Kaolin
65997-17-3 1-5Mineral Wool
64741-88-4 1-5Petroleum-based Lubricating
Oil
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925326 Version #: 01 Revision date: - Issue date: 22-April-2015
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14808-60-7 <1Crystalline silica (Quartz)
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
Move to fresh air. Call a physician if symptoms develop or persist.
Wash off with soap and water. Get medical attention if irritation develops and persists.
Rinse with water. Get medical attention if irritation develops and persists.
Rinse mouth. Get medical attention if symptoms occur.
Coughing.
Treat symptomatically.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire fighting
equipment/instructions
Specific methods
General fire hazards
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire.
During fire, gases hazardous to health may be formed.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Move containers from fire area if you can do so without risk.
Use standard firefighting procedures and consider the hazards of other involved materials.
No unusual fire or explosion hazards noted.
16.5Other components below reportable levels
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Environmental precautions
Keep unnecessary personnel away. For personal protection, see section 8 of the SDS.
Stop the flow of material, if this is without risk. Following product recovery, flush area with water.
For waste disposal, see section 13 of the SDS.
Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Keep formation of airborne dusts to a minimum. Provide appropriate exhaust ventilation at places
where dust is formed. Do not breathe dust. Avoid prolonged exposure.
Store in original tightly closed container. Store away from incompatible materials (see Section 10
of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
1317-65-3)
Type
PEL 5 mg/m3 Respirable fraction.Calcium carbonate (CAS
PEL 5 mg/m3 Respirable fraction.Kaolin (CAS 1332-58-7)
Value
15 mg/m3 Total dust.
15 mg/m3 Total dust.
Form
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US. OSHA Table Z-3 (29 CFR 1910.1000)
Components
Type
TWA 0.3 mg/m3 Total dust.Crystalline silica (Quartz)
(CAS 14808-60-7)
US. ACGIH Threshold Limit Values
Components
Type
TWA 0.025 mg/m3 Respirable fraction.Crystalline silica (Quartz)
(CAS 14808-60-7)
TWA 2 mg/m3 Respirable fraction.Kaolin (CAS 1332-58-7)
TWA 5 mg/m3 Inhalable fraction.Petroleum-based
Lubricating Oil (CAS
64741-88-4)
US. NIOSH: Pocket Guide to Chemical Hazards
Components
Type
TWA 5 mg/m3 Respirable.Calcium carbonate (CAS
1317-65-3)
TWA 0.05 mg/m3 Respirable dust.Crystalline silica (Quartz)
(CAS 14808-60-7)
TWA 5 mg/m3 Respirable.Kaolin (CAS 1332-58-7)
TWA 3 fibers/cm3 Dust.Mineral Wool (CAS
65997-17-3)
Ceiling 1800 mg/m3Petroleum-based
Lubricating Oil (CAS
64741-88-4)
STEL 10 mg/m3 Mist.
TWA 5 mg/m3 Mist.
Biological limit values
Exposure guidelines
No biological exposure limits noted for the ingredient(s).
Occupational exposure to nuisance dust (total and respirable) and respirable crystalline silica
should be monitored and controlled.
Appropriate engineering
controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection
Other
Respiratory protection
Wear appropriate chemical resistant gloves.
Wear suitable protective clothing.
Use a particulate filter respirator for particulate concentrations exceeding the Occupational
Exposure Limit.
Thermal hazards
General hygiene
considerations
Wear appropriate thermal protective clothing, when necessary.
Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
Value
Form
0.1 mg/m3 Respirable.
Value
Value
Form
Form
10 mg/m3 Total
10 mg/m3 Total
3 fibers/cm3 Fiber.
5 mg/m3 Fiber, total
5 mg/m3 fibers, total dust
9. Physical and chemical properties
Appearance
Physical state
Form
Hercules Staput SDS US
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Solid.
Putty.
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Color
t
y
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Flammability limit - upper
(%)
Explosive limit - lower (%)
Explosive limit - upper (%)
Vapor pressure
Vapor density
Relative density
Solubility(ies)
Solubility (water)
Partition coefficient
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity
Other information
VOC (Weight %)
Off-white.
Slight.
Not available.
Not applicable
Not available.
Not determined
> 212.0 °F (> 100.0 °C)
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
1.8
Not available.
Not available.
Not available.
Not available.
> 5000000 cP
6 g/l
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Contact with incompatible materials.
Acids. Fluorine.
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Inhalation
Skin contact
Eye contac
Ingestion
Symptoms related to the
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicit
Skin corrosion/irritation
Prolonged inhalation may be harmful.
No adverse effects due to skin contact are expected.
Direct contact with eyes may cause temporary irritation.
Expected to be a low ingestion hazard.
Coughing.
Not available.
Prolonged skin contact may cause temporary irritation.
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Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Carcinogenicity
IARC Monographs. Overall Evaluation of Carcinogenicity
Crystalline silica (Quartz) (CAS 14808-60-7) 1 Carcinogenic to humans.
Petroleum-based Lubricating Oil (CAS 64741-88-4) 3 Not classifiable as to carcinogenicity to humans.
NTP Report on Carcinogens
Crystalline silica (Quartz) (CAS 14808-60-7) Known To Be Human Carcinogen.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity
Specific target organ toxicity -
single exposure
Specific target organ toxicity -
repeated exposure
Aspiration hazard
Chronic effects
Further information
Direct contact with eyes may cause temporary irritation.
Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
In 1997, IARC (the International Agency for Research on Cancer) concluded that crystalline silica
inhaled from occupational sources can cause lung cancer in humans. However in making the
overall evaluation, IARC noted that "carcinogenicity was not detected in all industrial
circumstances studied. Carcinogenicity may be dependent on inherent characteristics of the
crystalline silica or on external factors affecting its biological activity or distribution of its
polymorphs." (IARC Monographs on the evaluation of the carcinogenic risks of chemicals to
humans, Silica, silicates dust and organic fibres, 1997, Vol. 68, IARC, Lyon, France.) Risk of
cancer cannot be excluded with prolonged exposure.
This product is not expected to cause reproductive or developmental effects.
Not classified.
Not classified.
Not an aspiration hazard.
Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.
This product has no known adverse effect on human health.
12. Ecological information
Ecotoxicity
Persistence and degradability
Bioaccumulative potential
Mobility in soil
Other adverse effects
13. Disposal considerations
Disposal instructions
Local disposal regulations
Hazardous waste code
Waste from residues / unused
products
Contaminated packaging
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
No data is available on the degradability of this product.
No data available.
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
Collect and reclaim or dispose in sealed containers at licensed waste disposal site.
Dispose in accordance with all applicable regulations.
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
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IMDG
Not regulated as dangerous goods.
Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
Not applicable.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
SARA 313 (TRI reporting)
Not regulated.
This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200.
One or more components are not listed on TSCA.
Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
No
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Calcium carbonate (CAS 1317-65-3)
Crystalline silica (Quartz) (CAS 14808-60-7)
Kaolin (CAS 1332-58-7)
Petroleum-based Lubricating Oil (CAS 64741-88-4)
US. New Jersey Worker and Community Right-to-Know Act
Calcium carbonate (CAS 1317-65-3)
Crystalline silica (Quartz) (CAS 14808-60-7)
Kaolin (CAS 1332-58-7)
Mineral Wool (CAS 65997-17-3)
US. Pennsylvania Worker and Community Right-to-Know Law
Calcium carbonate (CAS 1317-65-3)
Crystalline silica (Quartz) (CAS 14808-60-7)
Kaolin (CAS 1332-58-7)
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
WARNING: This product contains a chemical known to the State of California to cause cancer.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Crystalline silica (Quartz) (CAS 14808-60-7)
Hercules Staput SDS US
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Not regulated.
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International Inventories
A
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) NoAustralia
Domestic Substances List (DSL) NoCanada
Non-Domestic Substances List (NDSL) YesCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial Chemical
Substances (EINECS)
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) NoJapan
Existing Chemicals List (ECL) NoKorea
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
"No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date
Revision date
Version #
HMIS® ratings
NFPA ratings
22-April-2015
-
01
Health: 0
Flammability: 0
Physical hazard: 0
0
00
NoEurope
NoPhilippines
Disclaimer
HCC Holdings Inc. an Oatey Affiliate cannot anticipate all conditions under which this information
and its product, or the products of other manufacturers in combination with its product, may be
used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of
the product, and to assume liability for loss, injury, damage or expense due to improper use. The
information in the sheet was written based on the best knowledge and experience currently
available.
Hercules Staput SDS US
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