Hercules 222031 User Manual

SAFETY DATA SHEET
1. Identification
Hercules BACTA-LifeProduct identifier
Other means of identification
Product code
Synonyms Recommended use Recommended restrictions Manufacturer/Importer/Supplier/Distributor information
Company Name
Address
7396E Part Numbers: 222031, 222041 Drain Opener. None known.
HCC Holdings, Inc. an Oatey Affiliate 4700 West 160th Street Cleveland, OH 44135
Telephone
E-mail
Transport Emergency
Emergency First Aid
Contact person
2. Hazard(s) identification
Physical hazards Health hazards OSHA defined hazards Label elements
Signal word
Hazard statement
Precautionary statement
Prevention Response
Storage Disposal
Hazard(s) not otherwise classified (HNOC)
Supplemental information
216-267-7100 info@oatey.com Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887) 1-877-740-5015 MSDS Coordinator
Not classified.
Category 2ASerious eye damage/eye irritation
Combustible dust
Warning May form combustible dust concentrations in air. Causes serious eye irritation.
Wash thoroughly after handling. Wear eye protection/face protection. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. None. None. None known.
None.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name
144-55-8 20-40Sodium bicarbonate
57-13-6 10-30Urea
N/A 10-20Bi-Chem TD 800
Hercules BACTA-Life SDS US 933041 Version #: 01 Revision date: - Issue date: 10-Oc t ober-2016
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7783-20-2 10-15Ammonium sulfate 7647-14-5 5-15Sodium chloride 7447-40-7 1-10Potassium chloride 7722-76-1 1-5Monoammonium phosphate
15630-89-4 1-5Sodium percarbonate
N/A 0-1.5Esperase 6.0T
68439-46-3 0-1.5Tomadol 91-8
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
4. First-aid measures
Inhalation Skin contact Eye contact
Ingestion Most important
symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed
General information
Move to fresh air. Call a physician if symptoms develop or persist. Wash off with soap and water. Get medical attention if irritation develops and persists. Do not rub eyes. Immediately flush eyes with plenty of water for at least 15 minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Rinse mouth. Get medical attention if symptoms occur. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
vision. Dusts may irritate the respiratory tract, skin and eyes.
Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing media
Specific hazards arising from the chemical
Special protective equipment and precautions for firefighters
Fire fighting equipment/instructions
Specific methods General fire hazards
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Apply extinguishing media carefully to avoid creating airborne dust. Avoid high pressure media which could cause the formation of a potentially explosible dust-air mixture.
Do not use water jet as an extinguisher, as this will spread the fire.
Explosion hazard: Avoid generating dust; fine dust dispersed in air in sufficient concentrations and in the presence of an ignition source is a potential dust explosion hazard. During fire, gases hazardous to health may be formed.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk.
Use standard firefighting procedures and consider the hazards of other involved materials. May form combustible dust concentrations in air.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Use only non-sparking tools. Dust deposits should not be allowed to accumulate on surfaces, as these may form an explosive mixture if they are released into the atmosphere in sufficient concentration. Wear appropriate protective equipment and clothing during clean-up. Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at levels exceeding the exposure limits. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
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Methods and materials for containment and cleaning up
Environmental precautions
7. Handling and storage
Precautions for safe handling
Conditions for safe storage, including any incompatibilities
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air). Collect dust using a vacuum cleaner equipped with HEPA filter. Stop the flow of material, if this is without risk.
Large Spills: Wet down with water and dike for later disposal. Shovel the material into waste container. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water.
Small Spills: Sweep up or vacuum up spillage and collect in suitable container for disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground.
Minimize dust generation and accumulation. Avoid significant deposits of material, especially on horizontal surfaces, which may become airborne and form combustible dust clouds and may contribute to secondary explosions. Routine housekeeping should be instituted to ensure that dusts do not accumulate on surfaces. Dry powders can build static electricity charges when subjected to the friction of transfer and mixing operations. Provide adequate precautions, such as electrical grounding and bonding, or inert atmospheres. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Explosion-proof general and local exhaust ventilation. Avoid contact with eyes. Avoid prolonged exposure. Wear appropriate personal protective equipment. Observe good industrial hygiene practices.
Keep containers tightly closed in a dry, cool and well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-3 (29 CFR 1910.1000)
Components
US. ACGIH Threshold Limit Values
Components
US. Workplace Environmental Exposure Level (WEEL) Guides
Components
Biological limit values Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Eye/face protection
No biological exposure limits noted for the ingredient(s). Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air
changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. If engineering measures are not sufficient to maintain concentrations of dust particulates below the Occupational Exposure Limit (OEL), suitable respiratory protection must be worn. Provide eyewash station.
Wear safety glasses with side shields (or goggles).
Type
TWA 5 mg/m3 Respirable fraction.Dust
Type
TWA 3 mg/m3 Respirable particles.Dust
Type
TWA 10 mg/m3 Total particulate.Urea (CAS 57-13-6)
Value
15 mg/m3 Total dust. 50 mppcf Total dust. 15 mppcf Respirable fraction.
Value
10 mg/m3 Inhalable particles.
Value
Form
Form
Form
Skin protection
Hand protection
Skin protection
Other
Hercules BACTA-Life SDS US 933041 Version #: 01 Revision date: - Issue date: 10-Oc t ober-2016
Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier.
Wear suitable protective clothing.
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Respiratory protection
Thermal hazards General hygiene
considerations
If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at levels exceeding the exposure limits.
Wear appropriate thermal protective clothing, when necessary. When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such
as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Physical state
Form
Color Odor Odor threshold pH Melting point/freezing point Initial boiling point and boiling
range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Flammability limit - upper
(%)
Explosive limit - lower (%)
Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies)
Solubility (water) Partition coefficient
(n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information
Explosive properties
Oxidizing properties
VOC
Solid. Powder. Tan.
Odorless. Not available. Not available. Not available. None
None Not available.
Combustible.
Not available.
Not available.
Not available. Not available. Not available. Not applicable.
1.1
5 - 8 % self dispersing
Not available.
Not available. Not available. Not applicable.
No data available.
Not oxidizing. 0 g/l 0% by weight
10. Stability and reactivity
Reactivity Chemical stability Possibility of hazardous
reactions Conditions to avoid
Incompatible materials
Hercules BACTA-Life SDS US 933041 Version #: 01 Revision date: - Issue date: 10-Oc t ober-2016
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Keep away from heat, sparks and open flame. Contact with incompatible materials. Minimize dust
generation and accumulation.
Strong oxidizing agents. Caustics. Acids. Bleach.
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Hazardous decomposition
t
y
products
Carbon oxides. Sulphur oxides.
11. Toxicological information
Information on likely routes of exposure
Inhalation Skin contact Eye contac Ingestion
Symptoms related to the physical, chemical and toxicological characteristics
Information on toxicological effects Acute toxicit
Ammonium sulfate (CAS 7783-20-2)
Acute
Dermal
LD50 Rat
Inhalation
LC50 Rat
Oral
LD50 Rat
Monoammonium phosphate (CAS 7722-76-1)
Acute
Dermal
LD50 Rabbit
Oral
LD50 Rat
Potassium chloride (CAS 7447-40-7)
Acute
Oral
LD50 Rat
Sodium bicarbonate (CAS 144-55-8)
Acute
Oral
LD50 Rat
Sodium chloride (CAS 7647-14-5)
Acute
Dermal
LD50 Rabbit
Inhalation
LC50 Rat
Oral
LD50 Rat
Tomadol 91-8 (CAS 68439-46-3)
Acute
Dermal
LD50 Rabbit
Dust may irritate respiratory system. Prolonged inhalation may be harmful.
Dust or powder may irritate the skin.
Causes serious eye irritation.
Expected to be a low ingestion hazard.
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
vision. Dusts may irritate the respiratory tract, skin and eyes.
Test ResultsComponents Species
> 2000 mg/kg
> 1000 mg/m³, 8 Hours
2000 - 4250 mg/kg
> 5000 mg/kg
> 2000 mg/kg
3020 mg/kg
4220 mg/kg
> 10000 mg/kg
> 42 mg/l, 1 Hours
3550 mg/kg
> 2 g/kg
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Urea (CAS 57-13-6)
y
A
A
Acute
Oral
LD50 Rat
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Serious eye damage/eye
irritation Respiratory or skin sensitization
Respiratory sensitization Skin sensitization
Germ cell mutagenicity
Carcinogenicit
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
NTP Report on Carcinogens
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
Reproductive toxicity Specific target organ toxicity -
single exposure Specific target organ toxicity -
repeated exposure Aspiration hazard Chronic effects
Prolonged skin contact may cause temporary irritation.
Causes serious eye irritation.
Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
This product is not expected to cause reproductive or developmental effects.
Not classified.
Not classified.
Not an aspiration hazard.
Prolonged inhalation may be harmful.
Test ResultsComponents Species
8471 mg/kg
12. Ecological information
Ecotoxicity
Components Test ResultsSpecies
Ammonium sulfate (CAS 7783-20-2)
Aquatic
cute
Chronic
Monoammonium phosphate (CAS 7722-76-1)
Aquatic
cute
Potassium chloride (CAS 7447-40-7)
Aquatic
Sodium bicarbonate (CAS 144-55-8)
Aquatic
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
EC50Crustacea > 100 mg/l, 96 HoursDaphnia magna LC50Fish > 100 mg/l, 96 HoursPimephales promelas
NOECFish 300 mg/l, 10 daysPimephales promelas
LC50Fish > 85.9 mg/l, 96 HoursOncorhynchus mykiss
EC50Crustacea 149 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 435 mg/l, 96 hoursWestern mosquitofish (Gambusia affinis)
EC50Crustacea 2350 mg/l, 48 hoursDaphnia LC50Fish 8600 mg/l, 96 hoursBluegill (Lepomis macrochirus)
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Components Test ResultsSpecies
Sodium chloride (CAS 7647-14-5)
Aquatic
EC50Crustacea 340.7 - 469.2 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 1294.6 mg/l, 96 hoursBluegill (Lepomis macrochirus)
Sodium percarbonate (CAS 15630-89-4)
Aquatic
LC50Fish 70.7 mg/l, 96 hoursPimephales promelas
Tomadol 91-8 (CAS 68439-46-3)
Aquatic
LC50Fish 6 - 12 mg/l, 96 hoursFathead minnow (Pimephales promelas)
Urea (CAS 57-13-6)
Aquatic
EC50Crustacea 3910 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 5 mg/l, 96 hoursGiant gourami (Colisa fasciata)
* Estimates for product may be based on additional component data not shown.
Persistence and degradability Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Urea (CAS 57-13-6) -2.11
Mobility in soil Other adverse effects
Biodegradable.
Disperses in water.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions
Local disposal regulations Hazardous waste code
Waste from residues / unused products
Contaminated packaging
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Dispose in accordance with all applicable regulations.
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
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CERCLA Hazardous Substance List (40 CFR 302.4)
A
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
Yes
chemical SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
Not regulated.
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Ammonium sulfate (CAS 7783-20-2)
US. New Jersey Worker and Community Right-to-Know Act
Not listed.
US. Pennsylvania Worker and Community Right-to-Know Law
Ammonium sulfate (CAS 7783-20-2)
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Domestic Substances List (DSL) YesCanada
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
"No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date Revision date Version # Further information
HMIS® ratings
NFPA ratings
Hercules BACTA-Life SDS US 933041 Version #: 01 Revision date: - Issue date: 10-Oc t ober-2016
10-October-2016
-
01
Refer to NFPA 654, Standard for the Prevention of Fire and Dust Explosions from the
Manufacturing, Processing, and Handling of Combustible Particulate Solids, for safe handling.
Health: 2
Flammability: 2
Physical hazard: 0
2
02
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Disclaimer
HCC Holdings Inc. an Oatey Affiliate cannot anticipate all conditions under which this information
and its product, or the products of other manufacturers in combination with its product, may be
used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of
the product, and to assume liability for loss, injury, damage or expense due to improper use. The
information in the sheet was written based on the best knowledge and experience currently
available.
Hercules BACTA-Life SDS US 933041 Version #: 01 Revision date: - Issue date: 10-Oc t ober-2016
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