Hercules 20475, 20470, 20450, 20455 User Manual

SAFETY DATA SHEET
1. Identification
Hercules Glug Kitchen - LiquidProduct identifier
Other means of identification
Product code
Synonyms Recommended use Recommended restrictions Manufacturer/Importer/Supplier/Distributor information
Company Name
Address
7302E Part Numbers: 20470, 20475 Liquid Drain Cleaner None known.
HCC Holdings, Inc. an Oatey Affiliate 4700 West 160th Street Cleveland, OH 44135
Telephone
E-mail
Transport Emergency
Emergency First Aid
Contact person
2. Hazard(s) identification
Physical hazards Health hazards
OSHA defined hazards Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage Disposal
Hazard(s) not otherwise classified (HNOC)
216-267-7100 info@oatey.com Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887) 1-877-740-5015 MSDS Coordinator
Not classified.
Category 1ASkin corrosion/irritation Category 1Serious eye damage/eye irritation
Not classified.
Danger Causes severe skin burns and eye damage.
Do not breathe mist or vapor. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Wash contaminated clothing before reuse.
Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. None known.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name
7732-18-5 50-80Water
Hercules Glug Kitchen - Liquid SDS US 925655 Version #: 01 Revision date: - Issue date: 22-April-2015
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1310-73-2 10-20Sodium hydroxide 1310-58-3 1-5Potassium hydroxide
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation Skin contact
Eye contact
Ingestion
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed
General information
Move to fresh air. Call a physician if symptoms develop or persist. Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a physician or
poison control center immediately. Chemical burns must be treated by a physician. Wash contaminated clothing before reuse.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician or poison control center immediately.
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result.
Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim under observation. Symptoms may be delayed.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.
5. Fire-fighting measures
Suitable extinguishing media Unsuitable extinguishing
media Specific hazards arising from
the chemical Special protective equipment
and precautions for firefighters Fire fighting
equipment/instructions Specific methods General fire hazards
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire.
During fire, gases hazardous to health may be formed.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Move containers from fire area if you can do so without risk.
Use standard firefighting procedures and consider the hazards of other involved materials. No unusual fire or explosion hazards noted.
1.001Other components below reportable levels
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Methods and materials for containment and cleaning up
Environmental precautions
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Conditions for safe storage, including any incompatibilities
Hercules Glug Kitchen - Liquid SDS US 925655 Version #: 01 Revision date: - Issue date: 22-April-2015
Do not breathe mist or vapor. Do not get in eyes, on skin, or on clothing. Avoid prolonged exposure. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices.
Store locked up. Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS).
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8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
TypeComponents
PEL 2 mg/m3Sodium hydroxide (CAS
1310-73-2)
US. ACGIH Threshold Limit Values
TypeComponents
Ceiling 2 mg/m3Potassium hydroxide (CAS
1310-58-3)
Ceiling 2 mg/m3Sodium hydroxide (CAS
1310-73-2)
US. NIOSH: Pocket Guide to Chemical Hazards
TypeComponents
TWA 2 mg/m3Potassium hydroxide (CAS
1310-58-3)
Ceiling 2 mg/m3Sodium hydroxide (CAS
1310-73-2)
Biological limit values Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin protection
Hand protection
Other Respiratory protection Thermal hazards
General hygiene considerations
No biological exposure limits noted for the ingredient(s). Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product.
Wear safety glasses with side shields (or goggles) and a face shield.
Wear appropriate chemical resistant gloves. Wear appropriate chemical resistant clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.
Value
Value
Value
9. Physical and chemical properties
Appearance
Physical state Form Color
Odor Odor threshold pH Melting point/freezing point Initial boiling point and boiling
range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits
Flammability limit - lower (%)
Flammability limit - upper (%)
Hercules Glug Kitchen - Liquid SDS US 925655 Version #: 01 Revision date: - Issue date: 22-April-2015
Liquid. Liquid. Clear.
None. Not available. 13 Not available. 212 °F (100 °C)
> 212.0 °F (> 100.0 °C) Not available.
Not applicable.
Not available.
Not available.
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Explosive limit - lower (%)
t
y
y
Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies)
Solubility (water) Partition coefficient
(n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information
VOC (Weight %)
10. Stability and reactivity
Reactivity Chemical stability Possibility of hazardous
reactions Conditions to avoid Incompatible materials Hazardous decomposition
products
Not available. Not available. Not available. Not available.
1.175
Not available.
Not available.
Not available. Not available. 10 cP
0 g/l
Reacts violently with strong acids. This product may react with oxidizing agents. Material is stable under normal conditions. No dangerous reaction known under conditions of normal use.
Do not mix with other chemicals. Contact with incompatible materials. Strong acids. Acids. Oxidizing agents. Maleic anhydride. No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Inhalation
Skin contact
Eye contac
Ingestion Symptoms related to the
physical, chemical and toxicological characteristics
Information on toxicological effects Acute toxicit
Potassium hydroxide (CAS 1310-58-3)
Acute
Oral
LD50 Rat
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Serious eye damage/eye
irritation Respiratory or skin sensitization
Respiratory sensitization
Skin sensitization Germ cell mutagenicity
Carcinogenicit
May cause irritation to the respiratory system. Prolonged inhalation may be harmful. Causes severe skin burns. Causes serious eye damage. Causes digestive tract burns. Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may
include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result.
Causes severe skin burns and eye damage. Causes serious eye damage.
Not a respiratory sensitizer. This product is not expected to cause skin sensitization. No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Test ResultsComponents Species
273 mg/kg
Hercules Glug Kitchen - Liquid SDS US 925655 Version #: 01 Revision date: - Issue date: 22-April-2015
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OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity Specific target organ toxicity -
single exposure Specific target organ toxicity -
repeated exposure Aspiration hazard Chronic effects
This product is not expected to cause reproductive or developmental effects. Not classified.
Not classified.
Not an aspiration hazard. Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity
Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects
The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.
No data is available on the degradability of this product. No data available. No data available. No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions
Local disposal regulations Hazardous waste code
Waste from residues / unused products
Contaminated packaging
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations.
Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste
disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).
Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied.
14. Transport information
DOT
UN number
UN proper shipping name
Transport hazard class(es)
Class Subsidiary risk
Label(s) Packing group Special precautions for user Special provisions Packaging exceptions Packaging non bulk Packaging bulk
IATA
UN number UN proper shipping name Transport hazard class(es)
Class
Subsidiary risk Packing group Environmental hazards ERG Code Special precautions for user
IMDG
UN number
Hercules Glug Kitchen - Liquid SDS US 925655 Version #: 01 Revision date: - Issue date: 22-April-2015
UN3266 Corrosive liquid, basic, inorganic, n.o.s. (Sodium hydroxide RQ = 5263 LBS, Potassium hydroxide
RQ = 20000 LBS)
8
­8 II Read safety instructions, SDS and emergency procedures before handling. B2, IB2, T11, TP2, TP27 154 202 242
UN3266 Corrosive liquid, basic, inorganic, n.o.s. (Sodium hydroxide, Potassium hydroxide)
8
­II No. 8L Read safety instructions, SDS and emergency procedures before handling.
UN3266
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UN proper shipping name Transport hazard class(es)
Class
Subsidiary risk Packing group Environmental hazards
Marine pollutant EmS Special precautions for user
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Corrosive liquid, basic, inorganic, n.o.s. (Sodium hydroxide, Potassium hydroxide)
8
­II
No. F-A, S-B Read safety instructions, SDS and emergency procedures before handling. Not established.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Potassium hydroxide (CAS 1310-58-3) LISTED
Sodium hydroxide (CAS 1310-73-2) LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous chemical
SARA 313 (TRI reporting)
Not regulated.
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No
No
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act (SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Potassium hydroxide (CAS 1310-58-3)
Sodium hydroxide (CAS 1310-73-2)
US. New Jersey Worker and Community Right-to-Know Act
Potassium hydroxide (CAS 1310-58-3)
Sodium hydroxide (CAS 1310-73-2)
US. Pennsylvania Worker and Community Right-to-Know Law
Potassium hydroxide (CAS 1310-58-3)
Sodium hydroxide (CAS 1310-73-2)
US. Rhode Island RTK
Potassium hydroxide (CAS 1310-58-3)
Sodium hydroxide (CAS 1310-73-2)
Hercules Glug Kitchen - Liquid SDS US 925655 Version #: 01 Revision date: - Issue date: 22-April-2015
Not regulated.
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US. California Proposition 65
A
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Domestic Substances List (DSL) YesCanada Non-Domestic Substances List (NDSL) NoCanada Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
"No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date Revision date Version # HMIS® ratings
NFPA ratings
22-April-2015
­01
Health: 3 Flammability: 0 Physical hazard: 1
0
13
Disclaimer
HCC Holdings Inc. an Oatey Affiliate cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available.
Hercules Glug Kitchen - Liquid SDS US 925655 Version #: 01 Revision date: - Issue date: 22-April-2015
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