HCC Holdings, Inc. an Oatey Affiliate
4700 West 160th Street
Cleveland, OH 44135
216-267-7100
info@oatey.com
Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)
1-877-740-5015
MSDS Coordinator
Not classified.
Health hazards
OSHA defined hazards
Label elements
Hazard symbol
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Supplemental information
Not applicable.
Not classified.
Not classified.
None.
None.
The mixture does not meet the criteria for classification.
Observe good industrial hygiene practices.
Wash hands after handling.
Store away from incompatible materials.
Dispose of waste and residues in accordance with local authority requirements.
None known.
Hercules Real TuffSDS US
921101 Version #: 02 Revision date: 10-Dec ember-2014 Issue date: 30-July-2014
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112945-52-51-5Silica, amorphous, fumed
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
Move to fresh air. Call a physician if symptoms develop or persist.
Wash off with soap and water. Get medical attention if irritation develops and persists.
Rinse with water. Get medical attention if irritation develops and persists.
Rinse mouth. Get medical attention if symptoms occur.
Direct contact with eyes may cause temporary irritation.
Treat symptomatically.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire fighting
equipment/instructions
Specific methods
General fire hazards
Water spray. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire.
During fire, gases hazardous to health may be formed.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Use water spray to cool unopened containers.
Use standard firefighting procedures and consider the hazards of other involved materials.
No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Environmental precautions
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Do not touch damaged containers or spilled material unless wearing appropriate
protective clothing. For personal protection, see section 8 of the SDS.
This product is miscible in water. Prevent entry into waterways, sewer, basements or confined
areas. Following product recovery, flush area with water. For waste disposal, see section 13 of the
SDS.
Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Avoid prolonged exposure. Observe good industrial hygiene practices.
Store in original tightly closed container. Store away from incompatible materials (see Section 10
of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
solvent refined heavy
parrafinic (CAS 64741-88-4)
13463-67-7)
Type
PEL5 mg/m3Mist.Petroleum distillates,
PEL15 mg/m3Total dust.Titanium dioxide (CAS
Value
2000 mg/m3
500 ppm
Form
Hercules Real TuffSDS US
921101 Version #: 02 Revision date: 10-Dec ember-2014 Issue date: 30-July-2014
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US. OSHA Table Z-3 (29 CFR 1910.1000)
TypeComponents
TWA0.8 mg/m3Silica, amorphous, fumed
(CAS 112945-52-5)
US. ACGIH Threshold Limit Values
Components
solvent refined heavy
parrafinic (CAS 64741-88-4)
13463-67-7)
US. NIOSH: Pocket Guide to Chemical Hazards
Components
solvent refined heavy
parrafinic (CAS 64741-88-4)
(CAS 112945-52-5)
Biological limit values
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin protection
Hand protection
Other
Respiratory protection
Thermal hazards
General hygiene
considerations
No biological exposure limits noted for the ingredient(s).
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
Wear safety glasses with side shields (or goggles).
Wear protective gloves.
Wear appropriate chemical resistant clothing.
In case of insufficient ventilation, wear suitable respiratory equipment.
Wear appropriate thermal protective clothing, when necessary.
Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
Flammability (solid, gas)
Hercules Real TuffSDS US
921101 Version #: 02 Revision date: 10-Dec ember-2014 Issue date: 30-July-2014
Paste.
Solid.
Solid.
White.
Odorless
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
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Upper/lower flammability or explosive limits
t
y
y
Flammability limit - lower
(%)
Flammability limit - upper
(%)
Explosive limit - lower (%)
Explosive limit - upper (%)
Vapor pressure
Vapor density
Relative density
Solubility(ies)
Solubility (water)
Partition coefficient
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity
Other information
VOC (Weight %)
Not available.
Not available.
Not available.
Not available.
Not available.
< 1
1.56
slightly soluble
Not available.
Not available.
Not available.
20000 - 50000 cP
6 g/l
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Contact with incompatible materials.
Strong oxidizing agents.
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Inhalation
Skin contact
Eye contac
Ingestion
Symptoms related to the
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicit
Skin corrosion/irritation
Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Carcinogenicit
IARC Monographs. Overall Evaluation of Carcinogenicity
Silica, amorphous, fumed (CAS 112945-52-5)3 Not classifiable as to carcinogenicity to humans.
Titanium dioxide (CAS 13463-67-7)2B Possibly carcinogenic to humans.
Prolonged inhalation may be harmful.
No adverse effects due to skin contact are expected.
Direct contact with eyes may cause temporary irritation.
Expected to be a low ingestion hazard.
Direct contact with eyes may cause temporary irritation.
Not available.
Prolonged skin contact may cause temporary irritation.
Direct contact with eyes may cause temporary irritation.
Not available.
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Risk of cancer cannot be excluded with prolonged exposure.
Hercules Real TuffSDS US
921101 Version #: 02 Revision date: 10-Dec ember-2014 Issue date: 30-July-2014
This product is not expected to cause reproductive or developmental effects.
Not classified.
Not classified.
Not available.
Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.
12. Ecological information
Ecotoxicity
Persistence and degradability
Bioaccumulative potential
Mobility in soil
Other adverse effects
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
No data is available on the degradability of this product.
No data available.
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions
Local disposal regulations
Hazardous waste code
Waste from residues / unused
products
Contaminated packaging
Collect and reclaim or dispose in sealed containers at licensed waste disposal site.
Dispose in accordance with all applicable regulations.
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
WARNING: This product contains a chemical known to the State of California to cause cancer.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Titanium dioxide (CAS 13463-67-7)
International Inventories
Country(s) or regionInventory nameOn inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS)YesAustralia
Domestic Substances List (DSL)YesCanada
Non-Domestic Substances List (NDSL)NoCanada
Inventory of Existing Chemical Substances in China (IECSC)YesChina
European Inventory of Existing Commercial Chemical
Substances (EINECS)
European List of Notified Chemical Substances (ELINCS)NoEurope
Inventory of Existing and New Chemical Substances (ENCS)NoJapan
Existing Chemicals List (ECL)YesKorea
New Zealand InventoryYesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
Toxic Substances Control Act (TSCA) InventoryYesUnited States & Puerto Rico
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
"No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
NoEurope
YesPhilippines
16. Other information, including date of preparation or last revision
Issue date
Revision date
Version #
HMIS® ratings
Hercules Real TuffSDS US
921101 Version #: 02 Revision date: 10-Dec ember-2014 Issue date: 30-July-2014
30-July-2014
10-December-2014
02
Health: 0
Flammability: 0
Physical hazard: 0
6 / 7
Disclaimer
The information in the sheet was written based on the best knowledge and experience currently
available.
Hercules Real TuffSDS US
921101 Version #: 02 Revision date: 10-Dec ember-2014 Issue date: 30-July-2014
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