SAFETY DATA SHEET
1. Identification
Product identifier Hercules Pro Dope
Other means of identification
Product code
Synonyms
Recommended use
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Company Name
Address
Telephone
E-mail
Transport Emergency
Emergency First Aid
Contact person
2. Hazard(s) identification
Physical hazards
7377E
Part Numbers: 15420, 15427, 15433, 15435, 15445
Not available.
None known.
HCC Holdings, Inc. an Oatey Affiliate
4700 West 160th Street
Cleveland, OH 44135
216-267-7100
info@oatey.com
Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)
1-877-740-5015
MSDS Coordinator
Not classified.
Health hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Not classified.
Warning
May cause an allergic skin reaction.
Avoid breathing mist or vapor. Contaminated work clothing must not be allowed out of the
workplace. Wear protective gloves.
If on skin: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
Store away from incompatible materials.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.
3. Composition/information on ingredients
Mixtures
Category 1Sensitization, skin
CAS number %Chemical name
1317-65-3 50-60Calcium carbonate
64741-88-4 20-40Petroleum-based Lubricating
Oil
1332-58-7 10-20Kaolin
8002-50-4 1-5Menhaden oil
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14808-60-7 <1Quartz
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
Call a physician if symptoms develop or persist.
Remove contaminated clothing immediately and wash skin with soap and water. In case of
eczema or other skin disorders: Seek medical attention and take along these instructions.
Rinse with water. Get medical attention if irritation develops and persists.
Rinse mouth. If ingestion of a large amount does occur, call a poison control center immediately.
Upper respiratory tract irritation. Irritation of eyes and mucous membranes. Coughing. Skin
irritation. May cause an allergic skin reaction. Dermatitis. Rash.
Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. Wash contaminated clothing before reuse.
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire fighting
equipment/instructions
Specific methods
General fire hazards
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire.
During fire, gases hazardous to health may be formed.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Move containers from fire area if you can do so without risk.
Use standard firefighting procedures and consider the hazards of other involved materials.
No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Environmental precautions
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do
not touch damaged containers or spilled material unless wearing appropriate protective clothing.
Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be
contained. For personal protection, see section 8 of the SDS.
Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or
divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to
prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following
product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged
exposure. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe
good industrial hygiene practices. Use care in handling/storage.
Store in original tightly closed container. Store away from incompatible materials (see Section 10
of the SDS).
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8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
1317-65-3)
Lubricating Oil (CAS
64741-88-4)
US. OSHA Table Z-3 (29 CFR 1910.1000)
Components
US. ACGIH Threshold Limit Values
Components
US. NIOSH: Pocket Guide to Chemical Hazards
Components
1317-65-3)
Lubricating Oil (CAS
64741-88-4)
Biological limit values
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin protection
Hand protection
Other
Respiratory protection
Thermal hazards
General hygiene
considerations
No biological exposure limits noted for the ingredient(s).
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
Face shield is recommended. Wear safety glasses with side shields (or goggles).
Wear appropriate chemical resistant gloves.
Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
In case of insufficient ventilation, wear suitable respiratory equipment.
Wear appropriate thermal protective clothing, when necessary.
Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Contaminated work clothing should not be allowed out of the
workplace.
Type
PEL 5 mg/m3 Respirable fraction.Calcium carbonate (CAS
PEL 5 mg/m3 Respirable fraction.Kaolin (CAS 1332-58-7)
PEL 5 mg/m3 Mist.Petroleum-based
Type
TWA 0.3 mg/m3 Total dust.Quartz (CAS 14808-60-7)
Type
TWA 2 mg/m3 Respirable fraction.Kaolin (CAS 1332-58-7)
TWA 0.025 mg/m3 Respirable fraction.Quartz (CAS 14808-60-7)
Type
TWA 5 mg/m3 Respirable.Calcium carbonate (CAS
TWA 5 mg/m3 Respirable.Kaolin (CAS 1332-58-7)
STEL 10 mg/m3 Mist.Petroleum-based
TWA 5 mg/m3 Mist.
TWA 0.05 mg/m3 Respirable dust.Quartz (CAS 14808-60-7)
Value
15 mg/m3 Total dust.
15 mg/m3 Total dust.
2000 mg/m3
500 ppm
Value
0.1 mg/m3 Respirable.
2.4 mppcf Respirable.
Value
Value
10 mg/m3 Total
10 mg/m3 Total
Form
Form
Form
Form
9. Physical and chemical properties
Appearance
Physical state
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Liquid.
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Form
t
y
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Flammability limit - upper
(%)
Explosive limit - lower (%)
Explosive limit - upper (%)
Vapor pressure
Vapor density
Relative density
Solubility(ies)
Solubility (water)
Partition coefficient
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity
Other information
VOC (Weight %)
Liquid. Paste.
Gray.
Fish oil
Not available.
Not available.
Not available.
Not available.
> 212.0 °F (> 100.0 °C)
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
30000 cP
11 g/l
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Contact with incompatible materials.
Acids. Fluorine.
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Inhalation
Skin contact
Eye contac
Ingestion
Symptoms related to the
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicit
Skin corrosion/irritation
Hercules Pro Dope SDS US
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Prolonged inhalation may be harmful.
May cause an allergic skin reaction.
Direct contact with eyes may cause temporary irritation.
Expected to be a low ingestion hazard.
Irritation of eyes and mucous membranes. Upper respiratory tract irritation. Coughing. May cause
an allergic skin reaction. Dermatitis. Rash. Frequent or prolonged contact may defat and dry the
skin, leading to discomfort and dermatitis.
May cause an allergic skin reaction.
Prolonged skin contact may cause temporary irritation.
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Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Carcinogenicity
IARC Monographs. Overall Evaluation of Carcinogenicity
Quartz (CAS 14808-60-7) 1 Carcinogenic to humans.
NTP Report on Carcinogens
Quartz (CAS 14808-60-7) Known To Be Human Carcinogen.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity
Specific target organ toxicity -
single exposure
Specific target organ toxicity -
repeated exposure
Aspiration hazard
Chronic effects
Direct contact with eyes may cause temporary irritation.
Not a respiratory sensitizer.
May cause an allergic skin reaction.
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
In 1997, IARC (the International Agency for Research on Cancer) concluded that crystalline silica
inhaled from occupational sources can cause lung cancer in humans. However in making the
overall evaluation, IARC noted that "carcinogenicity was not detected in all industrial
circumstances studied. Carcinogenicity may be dependent on inherent characteristics of the
crystalline silica or on external factors affecting its biological activity or distribution of its
polymorphs." (IARC Monographs on the evaluation of the carcinogenic risks of chemicals to
humans, Silica, silicates dust and organic fibres, 1997, Vol. 68, IARC, Lyon, France.)
This product is not expected to cause reproductive or developmental effects.
Not classified.
Not classified.
Not an aspiration hazard.
Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.
12. Ecological information
Ecotoxicity
Persistence and degradability
Bioaccumulative potential
Mobility in soil
Other adverse effects
13. Disposal considerations
Disposal instructions
Local disposal regulations
Hazardous waste code
Waste from residues / unused
products
Contaminated packaging
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
No data is available on the degradability of this product.
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Dispose in accordance with all applicable regulations.
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
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Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
Not established.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
SARA 313 (TRI reporting)
Not regulated.
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
One or more components are not listed on TSCA.
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
No
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Calcium carbonate (CAS 1317-65-3)
Kaolin (CAS 1332-58-7)
Petroleum-based Lubricating Oil (CAS 64741-88-4)
Quartz (CAS 14808-60-7)
US. New Jersey Worker and Community Right-to-Know Act
Calcium carbonate (CAS 1317-65-3)
Kaolin (CAS 1332-58-7)
Petroleum-based Lubricating Oil (CAS 64741-88-4)
Quartz (CAS 14808-60-7)
US. Pennsylvania Worker and Community Right-to-Know Law
Calcium carbonate (CAS 1317-65-3)
Kaolin (CAS 1332-58-7)
Quartz (CAS 14808-60-7)
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other
reproductive harm.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Methanol (CAS 67-56-1)
Quartz (CAS 14808-60-7)
Not regulated.
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International Inventories
A
Country(s) or region Inventory name On inventory (yes/no)*
Domestic Substances List (DSL) YesCanada
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
"No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date
Revision date
Version #
HMIS® ratings
NFPA ratings
05-February-2015
-
01
Health: 1
Flammability: 0
Physical hazard: 0
0
01
Disclaimer
HCC Holdings Inc. an Oatey Affiliate cannot anticipate all conditions under which this information
and its product, or the products of other manufacturers in combination with its product, may be
used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of
the product, and to assume liability for loss, injury, damage or expense due to improper use. The
information in the sheet was written based on the best knowledge and experience currently
available.
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