SAFETY DATA SHEET
1. Identification
Cloroben PT4Product identifier
Other means of identification
Product code
Synonyms
Recommended use
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Company Name
Address
7307E
Part Numbers: 137501, 137503, 137504, 137507, 137509
Flow improver for drainage and plumbing systems
None known.
HCC Holdings, Inc. an Oatey Affiliate
4700 West 160th Street
Cleveland, OH 44135
Telephone
E-mail
Transport Emergency
Emergency First Aid
Contact person
2. Hazard(s) identification
Physical hazards
Health hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
216-267-7100
info@oatey.com
Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)
1-877-740-5015
MSDS Coordinator
Category 3Flammable liquids
Category 2Skin corrosion/irritation
Category 2Serious eye damage/eye irritation
Category 1Sensitization, skin
Category 1Aspiration hazard
Not classified.
Danger
Flammable liquid and vapor. May be fatal if swallowed and enters airways. Causes skin irritation.
May cause an allergic skin reaction. Causes serious eye irritation.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly
closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after
handling. Contaminated work clothing must not be allowed out of the workplace. Wear protective
gloves/eye protection/face protection.
If swallowed: Immediately call a poison center/doctor. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. If in eyes: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Do NOT
induce vomiting. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation
persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In
case of fire: Use appropriate media to extinguish.
Store in a well-ventilated place. Keep cool. Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Cloroben PT4 SDS US
925942 Version #: 01 Revision date: - Issue date: 22-April-2015
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Hazard(s) not otherwise
classified (HNOC)
None known.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name
68956-56-9 40-50Terpene hydrocarbons
5989-27-5 5-15Limonene
102-71-6 5-15Triethanolamine
27176-87-0 5-10Dodecylbenzenesulphonic acid
68439-46-3 1-5Alcohols, C9-11, ethoxylated
584-08-7 1-5Potassium carbonate
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
Move to fresh air. Call a physician if symptoms develop or persist.
Remove contaminated clothing immediately and wash skin with soap and water. In case of
eczema or other skin disorders: Seek medical attention and take along these instructions. Wash
contaminated clothing before reuse.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may
include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness
and pain. May cause an allergic skin reaction. Dermatitis. Rash.
Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. Keep victim under observation.
Symptoms may be delayed.
Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the
material(s) involved, and take precautions to protect themselves. Wash contaminated clothing
before reuse.
22.62Other components below reportable levels
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire fighting
equipment/instructions
Specific methods
General fire hazards
Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire.
Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
of ignition and flash back. During fire, gases hazardous to health may be formed.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk.
Use standard firefighting procedures and consider the hazards of other involved materials.
Flammable liquid and vapor.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Cloroben PT4 SDS US
925942 Version #: 01 Revision date: - Issue date: 22-April-2015
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all
ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate
protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate
closed spaces before entering them. Local authorities should be advised if significant spillages
cannot be contained. For personal protection, see section 8 of the SDS.
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Methods and materials for
containment and cleaning up
Environmental precautions
7. Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take
precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles
(wood, paper, oil, etc.) away from spilled material.
Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or
divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to
prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the
product and place into a container for later disposal. Following product recovery, flush area with
water.
Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers
for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Avoid discharge into drains, water courses or onto the ground.
Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect
material from direct sunlight. When using do not smoke. Explosion-proof general and local exhaust
ventilation. Take precautionary measures against static discharges. All equipment used when
handling the product must be grounded. Use non-sparking tools and explosion-proof equipment.
Do not get in eyes, on skin, or on clothing. Avoid breathing mist or vapor. Avoid prolonged
exposure. Wear appropriate personal protective equipment. Wash hands thoroughly after
handling. Observe good industrial hygiene practices.
Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge
build-up by using common bonding and grounding techniques. Store in a cool, dry place out of
direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Keep in an
area equipped with sprinklers. Store away from incompatible materials (see Section 10 of the
SDS).
8. Exposure controls/personal protection
Occupational exposure limits
US. ACGIH Threshold Limit Values
TypeComponents
TWA 5 mg/m3Triethanolamine (CAS
102-71-6)
US. Workplace Environmental Exposure Level (WEEL) Guides
TypeComponents
TWA 165.5 mg/m3Limonene (CAS 5989-27-5)
Biological limit values
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin protection
Hand protection
Other
Respiratory protection
Thermal hazards
General hygiene
considerations
No biological exposure limits noted for the ingredient(s).
Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air
changes per hour) should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency
shower must be available when handling this product.
Face shield is recommended. Wear safety glasses with side shields (or goggles).
Wear appropriate chemical resistant gloves.
Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn.
Wear appropriate thermal protective clothing, when necessary.
When using do not smoke. Always observe good personal hygiene measures, such as washing
after handling the material and before eating, drinking, and/or smoking. Routinely wash work
clothing and protective equipment to remove contaminants. Contaminated work clothing should not
be allowed out of the workplace.
Value
Value
30 ppm
Cloroben PT4 SDS US
925942 Version #: 01 Revision date: - Issue date: 22-April-2015
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9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Flammability limit - upper
(%)
Explosive limit - lower (%)
Explosive limit - upper (%)
Vapor pressure
Vapor density
Relative density
Solubility(ies)
Solubility (water)
Partition coefficient
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity
Other information
VOC (Weight %)
Liquid.
Translucent liquid.
Off-white.
Citrus
Not available.
8
Not available.
219.2 °F (104 °C)
130.0 °F (54.4 °C)
Not available.
Not applicable.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
0.95
Not available.
Not available.
Not available.
Not available.
20 - 40 cP
53 % by weight 500 g/L
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the
flash point. Contact with incompatible materials.
Peroxides. Phenols.
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Inhalation
Skin contact
Cloroben PT4 SDS US
925942 Version #: 01 Revision date: - Issue date: 22-April-2015
Prolonged inhalation may be harmful.
Causes skin irritation. May cause an allergic skin reaction.
Prolonged or repeated exposure may cause liver and kidney damage. These effects have not
been observed in humans.
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Eye contac
t
y
y
Ingestion
Causes serious eye irritation.
Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious
chemical pneumonia.
Symptoms related to the
physical, chemical and
toxicological characteristics
Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may
include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness
and pain. May cause an allergic skin reaction. Dermatitis. Rash.
Information on toxicological effects
Acute toxicit
May be fatal if swallowed and enters airways. May cause an allergic skin reaction.
Alcohols, C9-11, ethoxylated (CAS 68439-46-3)
Acute
Dermal
LD50 Rabbit
Oral
LD50 Rat
Dodecylbenzenesulphonic acid (CAS 27176-87-0)
Acute
Oral
LD50 Rat
Potassium carbonate (CAS 584-08-7)
Acute
Dermal
LD50 Rabbit
Oral
LD50 Rat
Triethanolamine (CAS 102-71-6)
Acute
Dermal
LD50 Rabbit
Oral
LD50 Rat
Test ResultsComponents Species
> 2 g/kg
1378 mg/kg
650 mg/kg
> 2000 mg/kg
> 2000 mg/kg
> 20000 mg/kg
8 g/kg
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Serious eye damage/eye
Causes skin irritation.
Causes serious eye irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Not a respiratory sensitizer.
May cause an allergic skin reaction.
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicit
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Limonene (CAS 5989-27-5) 3 Not classifiable as to carcinogenicity to humans.
Triethanolamine (CAS 102-71-6) 3 Not classifiable as to carcinogenicity to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity
Specific target organ toxicity -
This product is not expected to cause reproductive or developmental effects.
Not classified.
single exposure
Specific target organ toxicity -
Not classified.
repeated exposure
Aspiration hazard
Cloroben PT4 SDS US
925942 Version #: 01 Revision date: - Issue date: 22-April-2015
May be fatal if swallowed and enters airways.
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Chronic effects
May be harmful if absorbed through skin. Prolonged inhalation may be harmful.
Prolonged or repeated exposure may cause liver and kidney damage. These effects have not
been observed in humans.
12. Ecological information
Ecotoxicity
Components Test ResultsSpecies
Dodecylbenzenesulphonic acid (CAS 27176-87-0)
Aquatic
Triethanolamine (CAS 102-71-6)
Aquatic
* Estimates for product may be based on additional component data not shown.
Persistence and degradability
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Limonene (CAS 5989-27-5) 4.232
Triethanolamine (CAS 102-71-6) -1
Mobility in soil
Other adverse effects
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
EC50Crustacea 11 - 23 mg/l, 48 hoursDaphnia
LC50Fish 10.8 mg/l, 96 hoursRainbow Trout
EC50Crustacea 2038 mg/l, 24 hoursWater flea (Daphnia magna)
No data is available on the degradability of this product.
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions
Local disposal regulations
Hazardous waste code
Waste from residues / unused
products
Contaminated packaging
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Dispose in accordance with all applicable regulations.
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
Not established.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
Cloroben PT4 SDS US
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OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
A
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Dodecylbenzenesulphonic acid (CAS 27176-87-0) LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
No
chemical
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
Not regulated.
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Dodecylbenzenesulphonic acid (CAS 27176-87-0)
Triethanolamine (CAS 102-71-6)
US. New Jersey Worker and Community Right-to-Know Act
Dodecylbenzenesulphonic acid (CAS 27176-87-0)
Limonene (CAS 5989-27-5)
Triethanolamine (CAS 102-71-6)
US. Pennsylvania Worker and Community Right-to-Know Law
Dodecylbenzenesulphonic acid (CAS 27176-87-0)
Triethanolamine (CAS 102-71-6)
US. Rhode Island RTK
Dodecylbenzenesulphonic acid (CAS 27176-87-0)
US. California Proposition 65
WARNING: This product contains a chemical known to the State of California to cause cancer.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Sulfuric acid (CAS 7664-93-9)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Domestic Substances List (DSL) YesCanada
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
"No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date
Revision date
Version #
HMIS® ratings
Cloroben PT4 SDS US
925942 Version #: 01 Revision date: - Issue date: 22-April-2015
22-April-2015
-
01
Health: 2
Flammability: 2
Physical hazard: 0
7 / 8
NFPA ratings
2
02
Disclaimer
HCC Holdings Inc. an Oatey Affiliate cannot anticipate all conditions under which this information
and its product, or the products of other manufacturers in combination with its product, may be
used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of
the product, and to assume liability for loss, injury, damage or expense due to improper use. The
information in the sheet was written based on the best knowledge and experience currently
available.
Cloroben PT4 SDS US
925942 Version #: 01 Revision date: - Issue date: 22-April-2015
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