Hercules 137303, 137307 User Manual

SAFETY DATA SHEET
1. Identification
Cloroben PT-BIO 1®Product identifier
Other means of identification
Product code
Synonyms Recommended use Recommended restrictions Manufacturer/Importer/Supplier/Distributor information
Company Name
Address
7306E Part Numbers: 137301, 137303, 137304, 137307, 137308, 137309 Liquid bioactive flow improver None known.
HCC Holdings, Inc. an Oatey Affiliate 4700 West 160th Street Cleveland, OH 44135
Telephone
E-mail
Transport Emergency
Emergency First Aid
Contact person
2. Hazard(s) identification
Physical hazards Health hazards OSHA defined hazards Label elements
Signal word
Hazard statement
Precautionary statement
Prevention Response
Storage Disposal
Hazard(s) not otherwise classified (HNOC)
216-267-7100 info@oatey.com Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887) 1-877-740-5015 MSDS Coordinator
Not classified.
Category 2Serious eye damage/eye irritation
Not classified.
Warning Causes serious eye irritation.
Wash thoroughly after handling. Wear eye/face protection. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. None known.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name
7732-18-5 90-100Water
68439-46-3 1-5Alcohols, C9-11, ethoxylated
N/A 1-5Bacterial Cultures
Cloroben PT-BIO 1® SDS US 925937 Version #: 01 Revision date: - Issue date: 23-April-2015
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56-81-5 1-5Glycerin
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation Skin contact Eye contact
Ingestion Most important
symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed
General information
Move to fresh air. Call a physician if symptoms develop or persist. Wash off with soap and water. Get medical attention if irritation develops and persists. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Rinse mouth. Get medical attention if symptoms occur. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
vision.
Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.
5. Fire-fighting measures
Suitable extinguishing media Unsuitable extinguishing
media Specific hazards arising from
the chemical Special protective equipment
and precautions for firefighters Fire fighting
equipment/instructions Specific methods General fire hazards
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire.
During fire, gases hazardous to health may be formed.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Move containers from fire area if you can do so without risk.
Use standard firefighting procedures and consider the hazards of other involved materials. No unusual fire or explosion hazards noted.
0.491Other components below reportable levels
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Methods and materials for containment and cleaning up
Environmental precautions
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Conditions for safe storage, including any incompatibilities
Avoid contact with eyes. Avoid prolonged exposure. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices.
Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
Cloroben PT-BIO 1® SDS US 925937 Version #: 01 Revision date: - Issue date: 23-April-2015
Type
PEL 5 mg/m3 Respirable fraction.Glycerin (CAS 56-81-5)
Value
Form
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US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
Biological limit values Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin protection
Hand protection
Other Respiratory protection Thermal hazards
General hygiene considerations
No biological exposure limits noted for the ingredient(s). Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station.
Wear safety glasses with side shields (or goggles).
Wear appropriate chemical resistant gloves. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.
Type
9. Physical and chemical properties
Appearance
Physical state Form Color
Odor Odor threshold pH Melting point/freezing point Initial boiling point and boiling
range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits
Flammability limit - lower (%)
Flammability limit - upper (%)
Explosive limit - lower (%) Explosive limit - upper (%)
Vapor pressure Vapor density Relative density Solubility(ies)
Solubility (water)
Partition coefficient (n-octanol/water)
Auto-ignition temperature Decomposition temperature
Liquid. Translucent liquid. Off-white.
None. Not available. 7 Not available. 212 °F (100 °C)
> 200.0 °F (> 93.3 °C) Not available.
Not applicable.
Not available.
Not available.
Not available. Not available. Not available. Not available. 1
Not available.
Not available.
Not available. Not available.
Value
15 mg/m3 Total dust.
Form
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Viscosity
t
y
y
Other information
VOC (Weight %)
Not applicable
0 g/l
10. Stability and reactivity
Reactivity Chemical stability Possibility of hazardous
reactions Conditions to avoid Incompatible materials Hazardous decomposition
products
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Avoid temperatures exceeding the flash point. Contact with incompatible materials.
Strong oxidizing agents.
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Inhalation Skin contact Eye contac Ingestion
Symptoms related to the physical, chemical and toxicological characteristics
Information on toxicological effects Acute toxicit
Alcohols, C9-11, ethoxylated (CAS 68439-46-3)
Acute
Dermal
LD50 Rabbit
Oral
LD50 Rat
Glycerin (CAS 56-81-5)
Acute
Oral
LD50 Rat
Prolonged inhalation may be harmful.
No adverse effects due to skin contact are expected.
Causes serious eye irritation.
Expected to be a low ingestion hazard.
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
vision.
Test ResultsComponents Species
> 2 g/kg
1378 mg/kg
12600 mg/kg
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Serious eye damage/eye
irritation Respiratory or skin sensitization
Respiratory sensitization Skin sensitization
Germ cell mutagenicity
Carcinogenicit
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity Specific target organ toxicity -
single exposure Specific target organ toxicity -
repeated exposure
Cloroben PT-BIO 1® SDS US 925937 Version #: 01 Revision date: - Issue date: 23-April-2015
Prolonged skin contact may cause temporary irritation.
Causes serious eye irritation.
Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
This product is not expected to cause reproductive or developmental effects.
Not classified.
Not classified.
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Aspiration hazard Chronic effects
Not an aspiration hazard.
Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity
Persistence and degradability Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Glycerin (CAS 56-81-5) -1.76
Mobility in soil Other adverse effects
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
No data is available on the degradability of this product.
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions
Local disposal regulations Hazardous waste code
Waste from residues / unused products
Contaminated packaging
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Dispose in accordance with all applicable regulations.
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not established.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous chemical
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
No
Cloroben PT-BIO 1® SDS US 925937 Version #: 01 Revision date: - Issue date: 23-April-2015
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SARA 313 (TRI reporting)
A
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
Not regulated.
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Glycerin (CAS 56-81-5)
US. New Jersey Worker and Community Right-to-Know Act
Glycerin (CAS 56-81-5)
US. Pennsylvania Worker and Community Right-to-Know Law
Glycerin (CAS 56-81-5)
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Domestic Substances List (DSL) NoCanada
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
"No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date Revision date Version # HMIS® ratings
NFPA ratings
Disclaimer
23-April-2015
-
01
Health: 2
Flammability: 0
Physical hazard: 0
0
02
HCC Holdings Inc. an Oatey Affiliate cannot anticipate all conditions under which this information
and its product, or the products of other manufacturers in combination with its product, may be
used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of
the product, and to assume liability for loss, injury, damage or expense due to improper use. The
information in the sheet was written based on the best knowledge and experience currently
available.
Cloroben PT-BIO 1® SDS US 925937 Version #: 01 Revision date: - Issue date: 23-April-2015
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