Hercules 10619 User Manual

SAFETY DATA SHEET
1. Identification
Product identifier Hercules Climate Smooth Other means of identification
SDS number
Synonyms Recommended use Recommended restrictions Manufacturer/Importer/Supplier/Distributor information
Company Name
Address
Telephone
E-mail
Transport Emergency
Emergency First Aid
Contact person
2. Hazard(s) identification
Physical hazards
7390E Part Numbers: 10606, 10608, 10616, 10619, 10621 Flux for joining copper tubing and pipe None known.
HCC Holdings, Inc. an Oatey Affiliate 4700 West 160th Street Cleveland, OH 44135 216-267-7100 info@oatey.com Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887) 1-877-740-5015 MSDS Coordinator
Not classified.
Health hazards
OSHA defined hazards Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage Disposal
Hazard(s) not otherwise classified (HNOC)
Supplemental information
Not applicable.
Category 1BSkin corrosion/irritation Category 1Serious eye damage/eye irritation
Not classified.
Danger Causes severe skin burns and eye damage.
Do not breathe dust or mists. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection.
Wash contaminated clothing before reuse. If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. Immediately call a poison center/doctor. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. None known.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name
64742-61-6 30-60Slack wax (petroleum)
Hercules Climate Smooth SDS US 920704 Version #: 03 Revision date: 19-February-2015 Issue date: 05-August-2014
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64741-88-4 15-40Petroleum distillates, solvent
refined heavy parrafinic
7646-85-7 10-30Zinc chloride
12125-02-9 1-5Ammonium chloride
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation Skin contact
Eye contact
Ingestion
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed
General information
Move to fresh air. Call a physician if symptoms develop or persist. Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a physician or
poison control center immediately. Chemical burns must be treated by a physician. Wash contaminated clothing before reuse.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician or poison control center immediately.
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result.
Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim under observation. Symptoms may be delayed.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.
5.92Other components below reportable levels
5. Fire-fighting measures
Suitable extinguishing media Unsuitable extinguishing
media Specific hazards arising from
the chemical Special protective equipment
and precautions for firefighters Fire fighting
equipment/instructions Specific methods General fire hazards
Water spray. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire.
During fire, gases hazardous to health may be formed.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Use water spray to cool unopened containers.
Use standard firefighting procedures and consider the hazards of other involved materials. No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Methods and materials for containment and cleaning up
Environmental precautions
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
This product is miscible in water. Stop the flow of material, if this is without risk. Dike far ahead of spill for later disposal. Use water spray to reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS.
Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Conditions for safe storage, including any incompatibilities
Hercules Climate Smooth SDS US 920704 Version #: 03 Revision date: 19-February-2015 Issue date: 05-August-2014
Do not get this material in contact with eyes. Do not get this material in contact with skin. Avoid prolonged exposure. Do not get this material on clothing. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices.
Store locked up. Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS).
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8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
solvent refined heavy
parrafinic (CAS 64741-88-4)
7646-85-7)
US. ACGIH Threshold Limit Values
Components
12125-02-9)
solvent refined heavy
parrafinic (CAS 64741-88-4)
7646-85-7)
US. NIOSH: Pocket Guide to Chemical Hazards
Components
12125-02-9)
solvent refined heavy
parrafinic (CAS 64741-88-4)
7646-85-7)
Biological limit values Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin protection
Hand protection
Other Respiratory protection Thermal hazards
General hygiene considerations
No biological exposure limits noted for the ingredient(s). Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product.
Wear safety glasses with side shields (or goggles) and a face shield.
Wear appropriate chemical resistant gloves. Wear appropriate chemical resistant clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.
Type
PEL 5 mg/m3 Mist.Petroleum distillates,
PEL 1 mg/m3 Fume.Zinc chloride (CAS
Type
STEL 20 mg/m3 Fume.Ammonium chloride (CAS TWA 10 mg/m3 Fume.
TWA 5 mg/m3 Inhalable fraction.Petroleum distillates,
STEL 2 mg/m3 Fume.Zinc chloride (CAS TWA 1 mg/m3 Fume.
Type
STEL 20 mg/m3 Fume.Ammonium chloride (CAS TWA 10 mg/m3 Fume.
STEL 10 mg/m3 Mist.Petroleum distillates,
TWA 5 mg/m3 Mist. STEL 2 mg/m3 Fume.Zinc chloride (CAS
TWA 1 mg/m3 Fume.
Value
2000 mg/m3 500 ppm
Value
Value
Form
Form
Form
9. Physical and chemical properties
Appearance
Physical state Form Color
Odor
Hercules Climate Smooth SDS US 920704 Version #: 03 Revision date: 19-February-2015 Issue date: 05-August-2014
Paste. Solid. Solid. Amber to dark brown. Odorless.
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Odor threshold
t
y
pH Melting point/freezing point Initial boiling point and boiling
range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits
Flammability limit - lower (%)
Flammability limit - upper (%)
Explosive limit - lower (%) Explosive limit - upper (%)
Vapor pressure Vapor density Relative density Solubility(ies)
Solubility (water)
Partition coefficient (n-octanol/water)
Auto-ignition temperature Decomposition temperature Viscosity Other information
VOC (Weight %)
Not available. Not available. 120 - 140 °F (48.89 - 60 °C) Not available.
Not available. Not available.
Not available.
Not available.
Not available.
Not available. Not available. Not available. < 1
0.95
slightly soluble
Not available.
Not available. Not available. 20000 - 50000 cP
14 g/l
10. Stability and reactivity
Reactivity Chemical stability Possibility of hazardous
reactions Conditions to avoid Incompatible materials Hazardous decomposition
products
The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. No dangerous reaction known under conditions of normal use.
Contact with incompatible materials. Strong oxidizing agents. No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Inhalation Skin contact Eye contac Ingestion
Symptoms related to the physical, chemical and toxicological characteristics
Information on toxicological effects Acute toxicit Skin corrosion/irritation Serious eye damage/eye
irritation
Prolonged inhalation may be harmful. May cause irritation to the respiratory system. Causes severe skin burns. Causes serious eye damage. Causes digestive tract burns. Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may
include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result.
Not available. Causes severe skin burns and eye damage. Causes serious eye damage.
Hercules Climate Smooth SDS US 920704 Version #: 03 Revision date: 19-February-2015 Issue date: 05-August-2014
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Respiratory or skin sensitization
y
Respiratory sensitization Skin sensitization
Germ cell mutagenicity
Carcinogenicit
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity Specific target organ toxicity -
single exposure Specific target organ toxicity -
repeated exposure Aspiration hazard Chronic effects
Not available. This product is not expected to cause skin sensitization. No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
This product is not expected to cause reproductive or developmental effects. Not classified.
Not classified.
Not available. Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity
Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects
The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.
No data is available on the degradability of this product. No data available. No data available. No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions
Local disposal regulations Hazardous waste code
Waste from residues / unused products
Contaminated packaging
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations.
Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste
disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).
Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied.
Not applicable.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
Hercules Climate Smooth SDS US 920704 Version #: 03 Revision date: 19-February-2015 Issue date: 05-August-2014
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List.
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OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Ammonium chloride (CAS 12125-02-9) LISTED
Zinc chloride (CAS 7646-85-7) LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
No
chemical SARA 313 (TRI reporting)
Chemical name CAS number % by wt.
Zinc chloride 7646-85-7 10-30
Ammonium chloride 12125-02-9 1-5
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
Not regulated.
(SDWA)
US state regulations
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins.
US. Massachusetts RTK - Substance List
Ammonium chloride (CAS 12125-02-9) Petroleum distillates, solvent refined heavy parrafinic (CAS 64741-88-4) Zinc chloride (CAS 7646-85-7)
US. New Jersey Worker and Community Right-to-Know Act
Ammonium chloride (CAS 12125-02-9) Zinc chloride (CAS 7646-85-7)
US. Pennsylvania Worker and Community Right-to-Know Law
Ammonium chloride (CAS 12125-02-9) Zinc chloride (CAS 7646-85-7)
US. Rhode Island RTK
Ammonium chloride (CAS 12125-02-9) Zinc chloride (CAS 7646-85-7)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia Domestic Substances List (DSL) YesCanada Non-Domestic Substances List (NDSL) NoCanada Inventory of Existing Chemical Substances in China (IECSC) YesChina European Inventory of Existing Commercial Chemical
Substances (EINECS) European List of Notified Chemical Substances (ELINCS) NoEurope Inventory of Existing and New Chemical Substances (ENCS) NoJapan Existing Chemicals List (ECL) YesKorea New Zealand Inventory YesNew Zealand
YesEurope
Hercules Climate Smooth SDS US 920704 Version #: 03 Revision date: 19-February-2015 Issue date: 05-August-2014
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Country(s) or region Inventory name On inventory (yes/no)*
A
Philippine Inventory of Chemicals and Chemical Substances (PICCS)
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
"No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date Revision date Version # HMIS® ratings
Disclaimer
05-August-2014 19-February-2015 03 Health: 3
Flammability: 0 Physical hazard: 0
The information in the sheet was written based on the best knowledge and experience currently available.
YesPhilippines
Hercules Climate Smooth SDS US 920704 Version #: 03 Revision date: 19-February-2015 Issue date: 05-August-2014
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