H.D. Hudson 19001 User Manual

SAMSUNG SDI Co., Ltd.

Date: January 1st 2019 Revision no.: 01

MODEL INR18650-20R

Safety Data Sheet

Regulation : In accordance with Regulation (EU) 2015/830 (REACH), Annex II, and OSHA 29 CFR

1910.1200

Section I – IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Important Note: As a solid, manufactured article, exposure to hazardous ingredients is not expected with normal use. This battery is an article pursuant to 29 CFR 1910.1200 and, as such, is not subject to the OSHA Hazard Communication Standard requirement. The information contained in this Safety Data Sheet contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product.

1.1 Product identifier

Substance name : INR18650-20R Synonyms :

Lithium-ion Cell, Lithium-ion Pack, Lithium-ion Battery, Li-Ion Cell, Li-Ion Pack, Li-Ion Battery

1.2 Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses : Lithium-ion batteries Uses advised against : Use for recommended use only Further Information : Not available

1.3 Details of the supplier of the safety data sheet

Supplier : SAMSUNG SDI Co., Ltd. Street address/P.O. Box : 150-20, Gongse-ro, Giheung-gu, Yongin-si, Gyeonggi-do, Korea

Country ID/Postcode/Place : Telephone number : 1-800-424-9300: US and Canada / 1-703-527-3887: International

Responsible Department: Quality team e-mail address of competent person responsible for the SDS : Not available

National contact : 1-800-424-9300: US and Canada / 1-703-527-3887: International

1.4 Emergency Telephone

: 1-800-424-9300: US and Canada / 1-703-527-3887: International Opening hours : Not available

Other comments : Not available

1.5 Further Information

Battery-System: Lithium-ion (Li-ion)

Nominal Voltage: 3.6 V

Rated Capacity: 2.0 Ah Wh rating: 7.2 Wh

Anode (negative electrode): based on intercalation graphite Cathode (positive electrode): based on lithiated metal oxide (Cobalt, Nickel or Manganese)

Remark:

Page 1 of 22

SAMSUNG SDI Co., Ltd.

※ This is a product that fulfills a certain function in solid state with specific shape without discharging any chemical substance in its use and has no obligation to write (M)SDS. Since this document contains the precautions for safe handling related to its materials or chemical substances consisting of this product, please note that these overall information is irrelevant to this product.

Date: January 1st 2019 Revision no.: 01

MODEL INR18650-20R

The information and recommendations set forth are made in good faith and believed to be accurate as of

the date of preparation. SAMSUNG SDI Co., Ltd. makes no warranty, expressed or implied, with respect to this information and disclaims all liabilities from reliance on it.

Section II – HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

2.1.1 Classification according to Regulation (EC) No. 1272/2008 [CLP] and OSHA 29 CFR 1910.12 00 : Not classified

2.1.2 Additional information: Classification of the substance or mixture.

Preparation Hazards and Classification: The product is a Lithium ion cell or battery and is therefore

classified as an article and is not hazardous when used according to the recommendations of the manufacturer. The hazard is associated with the contents of the cell or battery. Under recommended use conditions, the electrode materials and liquid electrolyte are non-reactive provided that the cell or battery integrity remains and the seals remain intact. The potential for exposure should not exist unless the cell or battery leaks, is exposed to high temperatures or is mechanically, electrically or physically abused/damaged. If the cell or battery is compromised and starts to leak, based upon the battery ingredients, the contents are classified as Hazardous.

Hazardous Materials Information Label (HMIS)

Health: Not available Flammability: Not available Physical Hazard: Not available

NFPA Hazard Ratings

Health: Not available Flammability: Not available Reactivity: Not available

Unique Hazard:

2.2 Label elements

Hazard pictograms : Not applicable

Signal word : Not applicable Hazard statement : Not applicable

Precautionary statements: Not applicable Supplemental Hazard information (EU) : Not applicable

Page 2 of 22

SAMSUNG SDI Co., Ltd.

CAS No.

EC No.

REACH

Registratio

n No.

%[weight]

Name

Common Name

(Synonyms)

Classification

according to

Regulation(EC) No

1278/2008(CLP)

7782-42-5

231-955-3

15~25

Graphite

Not available

Not classified

12031-65-1

Not available

15~25

Lithium nickelate

Not available

Skin Sens. 1, H317

STOT RE 1, H372

Carc. 1A, H350i

7439-89-6

231-096-4

10~20

Iron

Not available

Not classified

12057-17-9

Not available

5~15

Lithium manganese

oxide

Not available

Pyr. Sol. 1, H250

Water-react. 2, H261

Date: January 1st 2019 Revision no.: 01

MODEL INR18650-20R

2.3 Other hazards :

Appearance, Color and Odor: Solid object with no odor.

Primary Routes(s) of Exposure: These chemicals are contained in a sealed enclosure. Risk of

exposure occurs only if the cell or pack is mechanically, thermally, electrically or physically abused to the point of compromising the enclosure. If this occurs, exposure to the electrolyte solution contained within can occur by inhalation, ingestion, eye contact and skin contact.

Potential Health Effect(s):

Acute (short term): see Section 8 for exposure controls.

In the event that this cell or pack has been ruptured, the electrolyte solution contained within the cell would be corrosive and can cause burns to skin and eyes. Inhalation: Inhalation of materials from a sealed cell is not an expected route of exposure. Vapors or mists from a ruptured cell may cause respiratory irritation. Ingestion: Swallowing of materials from a sealed cell is not an expected route of exposure. Swallowing the contents of an open cell can cause serious chemical burns to mouth, esophagus, and gastrointestinal tract. Skin: Contact between the cell and skin will not cause any harm. Skin contact with the contents of an open cell can cause severe irritation or burns to the skin. Eye: Contact between the cell and the eye will not cause any harm. Eye contact with the contents of an open cell can cause severe irritation or burns to the eye.

CHRONIC (long term): see Section 11 for additional toxicological data.

Interactions with other chemicals: Immersion in high conductivity liquids may cause corrosion and

breaching of the cell or battery enclosure. The electrolyte solution inside of the cells may react with alkaline (basic) materials and present a flammability hazard.

Potential Environmental Effects: Not Available.

Section III – COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Mixture

Page 3 of 22

SAMSUNG SDI Co., Ltd.

12190-79-3

235-362-0

1~10

cobalt lithium dioxide Not available

Flam. Liq. 3, H226

Acute Tox. 4, H332

7440-50-8

231-159-6

1~10

Copper

Not available

Not classified

616-38-6

210-478-4

1~10

dimethyl carbonate

Not available

Flam. Liq. 2, H225

7429-90-5

231-072-3

1~10

Aluminium

Not available

Pyr. Sol. 1, H250

Water-react. 2, H261

9002-88-4

Not available

1~10

Polyethylene

Not available

Not classified

96-49-1

202-510-0

1~10

1,3-Dioxolan-2-one

Not available

Not classified

21324-40-3

244-334-7

1~10

lithium

hexafluorophosphate(1-)

Not available

Not classified

141-78-6

205-500-4

0.1~1

ethyl acetate

Not available

Flam. Liq. 2, H225

Eye Irrit. 2, H319

STOT SE 3, H336

1333-86-4

215-609-9

0.1~1

Carbon black

Not available

Not classified

7440-02-0

231-111-4

0.1~1

Nickel

Not available

Skin Sens. 1, H317

Carc. 2, H351 STOT RE 1, H372 Aquatic Chronic 3,

H412

554-13-2

209-062-5

0.1~1

lithium carbonate

Not available

Not classified

872-50-4

212-828-1

0.1~1

1-Methyl-2-pyrrolidinone

Not available

Skin Irrit. 2, H315

Eye Irrit. 2, H319

STOT SE 3, H335

Repr. 1B, H360D

Date: January 1st 2019 Revision no.: 01

MODEL INR18650-20R

Further Information

Because of the cell structure the dangerous ingredients will not be available if used properly. During charge process a lithium graphite intercalation phase is formed.

Section IV – FIRST-AID MEASURES

4.1 Description of first aid measures Following eye contact :

- Rinse eyes with plenty of water for at least 15 minutes and seek medical attention.

Following skin contact :

- Remove contaminated clothing and wash before reuse.

- Immediately rinse contact area with plenty of clean water.

- Provide first aid to contacted area to prevent infection.

- Get medical attention.

Following inhalation :

Page 4 of 22

SAMSUNG SDI Co., Ltd.

Date: January 1st 2019 Revision no.: 01

MODEL INR18650-20R

- In case of inhalation of organic electrolyte mist, remove from exposure to fresh air.

- If necessary give oxygen. Get medical attention.

Following ingestion :

- In case of ingestion of electrolyte don’t induce vomiting.

- If patient is conscious and alert give 2~4 cupfuls of milk or water.

- Never give anything by mouth to an unconscious person.

- Get medical attention immediately.

Further Information :

- The following first aid measures are required only in case of exposure to interior battery components

after damage of the external battery casing.

- Undamaged, closed cells do not represent a danger to the health.

4.2 Most important symptoms and effects, both acute and delayed Acute effects : Not available

Delayed effects : Not available

4.3 Indication of immediate medical attention and special treatment needed

- Ensure that medical personnel are aware of the material(s) involved and take precautions to protect

themselves.

Section V – FIRE-FIGHTING MEASURES

5.1 Extinguishing media

- When the scale of the fire is small, use a HFC (hydrofluorocarbon) clean-agent fire extinguisher or

alcohol resistant foam fire extinguishers. (In case of battery overheating, wear protective gear and immerse heated battery in water)

- In case of large fire, use large amount of water to extinguish.

5.2 Special hazards arising from the substance or mixture

- Flammable gas leaks before ignition and then the product ignites.

5.3 Advice for firefighters

- The ignited battery has a high temperature, so there is a risk of additional ignition even if the fire is

extinguished at early stage. Sprinkle a large amount of water until the battery temperature drops to normal temperature.

- If the battery is ignited in multi-stacked condition, multi-stack should be disassembled and then extinguished so that heat is not transferred between batteries

- In the event of a battery fire, cool it by spraying water directly on the battery.

- When handling a overheated battery, wear heat-resistant protective equipment.

Section VI – ACCIDENTAL RELEASE MEASURES

Page 5 of 22

SAMSUNG SDI Co., Ltd.

Date: January 1st 2019 Revision no.: 01

MODEL INR18650-20R

6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency personnel

Protective equipment : Use personal protective equipment, see Section 8

Emergency procedures :

- In case of cell damage, possible release of dangerous substances and a flammable gas mixture.

- Eliminate all ignition sources.

- Please note that materials and conditions to avoid.

- Battery may emit electrolyte if charging or discharging rates exceed manufacturer’s recommendations or if pack has been breached.

- Move battery to well ventilated area to prevent gas accumulation.

For emergency responders

- Eliminate all ignition sources.

- Please note that materials and conditions to avoid.

- Move battery to well ventilated area to prevent gas accumulation.

6.2 Environmental precautions :

- Avoid release to the environment.

- Prevent entry into waterways, sewers, basements or confined areas.

6.3 Methods and material for containment and cleaning up For containment : Not available

For cleaning up :

- Cover with Dry earth, DRY sand or other non-combustible material and put on the plastic sheet to

minimize spreading or contact with rain.

- Move battery to well ventilated area to prevent gas accumulation.

- Dispose in accordance with applicable local, state and federal regulations.

Other information: Not available

6.4 Reference to other sections

- See also sections 8 and 13 of the Safety Data Sheet.

Section VII – HANDLING AND STORAGE

7.1 Precautions for safe handling

- In case of cell damage, possible release of dangerous substances and a flammable gas mixture.

- The battery stores electrical energy and is capable of rapid energy discharge.

- Battery cell contents are under pressure.

- Handle battery carefully to avoid puncturing case or electrically shorting terminals.

7.2 Conditions for safe storage, including any incompatibilities

Technical measures and storage conditions : Not available Packaging materials : Not available

Requirements for storage rooms and vessels :

Page 6 of 22

SAMSUNG SDI Co., Ltd.

Name

ACGIH regulation

Biological

exposure index

OSHA

regulation

NIOSH

regulation

Graphite

TWA = 2mg/m3

Not available

Not applicable

Not

applicable

Lithium nickelate

Not applicable

Not available

TWA = 1 mg/m3

(Nickel, metal and insoluble

compounds (as

Ni),Nickel,

soluble

compounds (as

Ni),CAS.no7440-

02-0)

TWA = Ca

0.015 mg/m3 (Nickel, metal and insoluble

compounds

(as Ni),Nickel,

soluble

compounds

(as

Ni),CAS.no744

0-02-0)

Not

applicable

Iron

Not applicable

Not available

Not applicable

Not

applicable

Lithium manganese oxide

TWA = 10 mg/m³

(Magnesium oxide

CAS.no 1309-48-4)

Not available

TWA = 15 mg/m3

(Magnesium oxide fume -

Total Particulate

CAS.no 1309-

48-4)

TWA = 10

mg/m3 (Magnesium oxide fume -

Total

Particulate

CAS.no 1309-

48-4)

Not

applicable

cobalt lithium dioxide

Not applicable

Not

applicable

Cobalt, Co

TWA = 0.02 mg/m3

Not available

TWA = 0.1

mg/m³

TWA 0.05

mg/m3

Not

applicable

Date: January 1st 2019 Revision no.: 01

MODEL INR18650-20R

- Storage at room temperature (approx. 20℃) at approx. 40% of the nominal capacity

- Keep in closed original container.

7.3 Specific end use(s)

Recommendations : Not available

Industrial sector specific solutions : Not available

Section VIII – EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1 Control parameters

Occupational Exposure limits

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