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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 05.06.2014 Revision: 05.06.2014
1 Identification of the substance/mixture and of the company/undertaking
·
1.1 Product identifier
·
Trade name: Steel Shot
·
1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
·
Application of the substance / the mixture
·
1.3 Details of the supplier of the Safety Data Sheet
·
Manufacturer/Supplier:
H-B Instrument – A Division of Bel-Art Products
102 West Seventh Avenue
Trappe, PA 19426 USA
Phone: (610) 489-5500
·
1.4 Emergency telephone number:
ChemTel Inc.
(800)255-3924, +1 (813)248-0585
Surface cleaning
2 Hazards identification
·
2.1 Classification of the substance or mixture
·
Classification according to Regulation (EC) No 1272/2008
The product is not classified as hazardous according to GHS regulations.
The product is not classified as hazardous according to the CLP regulation.
·
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
·
Information concerning particular hazards for human and environment:
The product does not have to be labelled due to the calculation procedure of the "General Classification
guideline for preparations of the EU" in the latest valid version.
·
Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and
literature data.
The classification is in accordance with the latest editions of international substances lists, and is
supplemented by information from technical literature and by information provided by the company.
·
2.2 Label elements
·
Labelling according to Regulation (EC) No 1272/2008
·
Hazard pictograms
·
Signal word
·
Hazard-determining components of labelling:
·
Hazard statements
·
Hazard description:
·
WHMIS-symbols:
·
NFPA ratings (scale 0 - 4)
000
Not Regulated
Health = 0
Fire = 0
Reactivity = 0
Not Regulated
None.
Not Regulated
Not hazardous under WHMIS.
Not Regulated
Not applicable.
(Contd. on page 2)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 05.06.2014 Revision: 05.06.2014
Trade name: Steel Shot
(Contd. of page 1)
·
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
·
HMIS Long Term Health Hazard Substances
*0
Health = *0
0
Fire = 0
0
Reactivity = 0
None of the ingredients is listed.
·
2.3 Other hazards
·
Results of PBT and vPvB assessment
·
PBT:
Not applicable.
·
vPvB:
Not applicable.
3 Composition/information on ingredients
·
Description:
·
Dangerous components:
None in reportable quantities.
CAS: 7439-89-6
EINECS: 231-096-4
CAS: 7439-96-5
EINECS: 231-105-1
CAS: 7440-21-3
EINECS: 231-130-8
CAS: 7440-44-0
EINECS: 231-153-3
·
Additional information:
Mixture of substances listed below with nonhazardous additions.
iron
substance with a Community workplace exposure limit
manganese
Xn R48
silicon
substance with a Community workplace exposure limit
Flam. Sol. 2, H228
carbon
Xi R36/37
Eye Irrit. 2, H319; STOT SE 3, H335
For the wording of the listed risk phrases refer to section 16.
50-100%
< 3,0%
< 3,0%
< 2,1%
4 First aid measures
·
4.1 Description of first aid measures
·
General information:
·
After inhalation:
Unlikely route of exposure.
Supply fresh air; consult doctor in case of complaints.
·
After skin contact:
Generally the product does not irritate the skin.
If skin irritation continues, consult a doctor.
·
After eye contact:
Remove contact lenses if worn.
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
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No special measures required.
(Contd. on page 3)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 05.06.2014 Revision: 05.06.2014
Trade name: Steel Shot
(Contd. of page 2)
·
After swallowing:
Unlikely route of exposure.
Do not induce vomiting; call for medical help immediately.
·
4.2 Most important symptoms and effects, both acute and delayed
Adverse health effects are not reasonably expected from normal use of product.
Gastric or intestinal disorders when ingested.
·
Hazards
·
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Firefighting measures
·
5.1 Extinguishing media
·
Suitable extinguishing agents:
·
For safety reasons unsuitable extinguishing agents:
·
5.2 Special hazards arising from the substance or mixture
·
5.3 Advice for firefighters
·
Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
·
Additional information
No further relevant information available.
Use fire extinguishing methods suitable to surrounding conditions.
None.
No further relevant information available.
No further relevant information available.
6 Accidental release measures
·
6.1 Personal precautions, protective equipment and emergency procedures
No special measures required.
·
6.2 Environmental precautions:
·
6.3 Methods and material for containment and cleaning up:
No special measures required.
Pick up mechanically.
Send for recovery or disposal in suitable receptacles.
Dispose contaminated material as waste according to item 13.
·
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
·
7.1 Precautions for safe handling
·
Information about fire - and explosion protection:
·
7.2 Conditions for safe storage, including any incompatibilities
·
Storage:
·
Requirements to be met by storerooms and receptacles:
·
Information about storage in one common storage facility:
·
Further information about storage conditions:
No special measures required.
No special measures required.
No special requirements.
Protect from humidity and water.
None.
(Contd. on page 4)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 05.06.2014 Revision: 05.06.2014
Trade name: Steel Shot
(Contd. of page 3)
·
7.3 Specific end use(s)
8 Exposure controls/personal protection
·
Additional information about design of technical facilities:
·
8.1 Control parameters
·
Ingredients with limit values that require monitoring at the workplace:
7439-89-6 iron
EV (Canada) Long-term value: 1* 5** mg/m³
as iron;*salts, water-soluble;**welding fume
7439-96-5 manganese
PEL (USA) Ceiling limit: 5 mg/m³
as Mn
REL (USA) Short-term value: 3 mg/m³
Long-term value: 1 mg/m³
fume, as Mn
TLV (USA) Long-term value: 0,02* 0,1* mg/m³
as Mn; *respirable **inhalable fraction
EL (Canada) Long-term value: 0,2 mg/m³
as Mn; R
EV (Canada) Long-term value: 0,2 mg/m³
as manganese
7440-21-3 silicon
PEL (USA) Long-term value: 15* 5** mg/m³
*total dust **respirable fraction
REL (USA) Long-term value: 10* 5** mg/m³
*total dust **respirable fraction
TLV (USA) TLV withdrawn
EL (Canada) Long-term value: 10 mg/m³
EV (Canada) Long-term value: 10 mg/m³
total dust
·
DNELs
·
PNECs
·
Additional information:
·
8.2 Exposure controls
·
Personal protective equipment:
·
General protective and hygienic measures:
·
Respiratory protection:
·
Protection of hands:
Wear gloves for the protection against mechanical hazards according to NIOSH or EN 388.
No further relevant information available.
No further relevant information available.
No further relevant information available.
No further data; see item 7.
The lists valid during the making were used as basis.
No further relevant information available.
Not required under normal conditions of use.
(Contd. on page 5)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 05.06.2014 Revision: 05.06.2014
Trade name: Steel Shot
(Contd. of page 4)
·
Eye protection:
Safety glasses
·
Body protection:
Not required under normal conditions of use.
Protection may be required for spills.
·
Limitation and supervision of exposure into the environment
·
Risk management measures
No special requirements.
9 Physical and chemical properties
·
9.1 Information on basic physical and chemical properties
·
General Information
·
Appearance:
Form:
Colour:
·
Odour:
·
Odour threshold:
·
pH-value:
·
Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
·
Flash point:
·
Auto/Self-ignition temperature:
·
Decomposition temperature:
·
Self-igniting:
·
Danger of explosion:
·
Explosion limits:
Lower:
Upper:
·
Vapour pressure:
·
Density at 20 °C:
·
Relative density
·
Vapour density
·
Evaporation rate
·
Solubility in / Miscibility with
water:
·
Partition coefficient (n-octanol/water):
Pellets
Silver grey
Odourless
Not determined.
Not applicable.
Not Determined.
Boiling Point Range: 2851 - 3137 ° F / 1566 - 1725 °C.
Not applicable.
Not determined.
Not determined.
Product is not self-igniting.
May form combustible dust concentrations in air.
Not determined.
Not determined.
Not applicable.
7,6 g/cm³
Not determined.
Not applicable.
Not applicable.
Insoluble.
Not determined.
No special requirements.
(Contd. on page 6)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 05.06.2014 Revision: 05.06.2014
Trade name: Steel Shot
(Contd. of page 5)
·
Viscosity:
Dynamic:
Kinematic:
·
9.2 Other information
10 Stability and reactivity
·
10.1 Reactivity
·
10.2 Chemical stability
·
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
·
10.3 Possibility of hazardous reactions
Reacts when heated with acids and alkalis releasing hydrogen.
Exothermic polymerization.
Reacts with strong oxidizing agents.
Reacts with humid air.
·
10.4 Conditions to avoid
·
10.5 Incompatible materials:
·
10.6 Hazardous decomposition products:
Toxic metal compounds
Toxic metal oxide smoke
No further relevant information available.
No further relevant information available.
Not applicable.
Not applicable.
No further relevant information available.
11 Toxicological information
·
11.1 Information on toxicological effects
·
Acute toxicity:
·
Primary irritant effect:
·
on the skin:
·
on the eye:
·
Sensitization:
·
Additional toxicological information:
No irritant effect.
No irritating effect.
No sensitizing effects known.
The product is not subject to classification according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version.
When used and handled according to specifications, the product does not have any harmful effects to our
experience and the information provided to us.
12 Ecological information
·
12.1 Toxicity
·
Aquatic toxicity:
·
12.2 Persistence and degradability
Inorganic product, is not eliminable from water by means of biological cleaning processes.
·
12.3 Bioaccumulative potential
·
12.4 Mobility in soil
No further relevant information available.
May be accumulated in organism
No further relevant information available.
(Contd. on page 7)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 05.06.2014 Revision: 05.06.2014
Trade name: Steel Shot
(Contd. of page 6)
·
Additional ecological information:
·
General notes:
This statement was deduced from products with a similar structure or composition.
Not known to be hazardous to water.
·
12.5 Results of PBT and vPvB assessment
·
PBT:
Not applicable.
·
vPvB:
·
12.6 Other adverse effects
13 Disposal considerations
·
13.1 Waste treatment methods
·
Recommendation
Contact waste processors for recycling information.
Smaller quantities can be disposed of with household waste.
The user of this material has the responsibility to dispose of unused material, residues and containers in
compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and
disposal for hazardous and nonhazardous wastes. Residual materials should be treated as hazardous.
·
Uncleaned packaging:
·
Recommendation:
Not applicable.
No further relevant information available.
Disposal must be made according to official regulations.
14 Transport information
·
14.1 UN-Number
·
DOT, ADR, ADN, IMDG, IATA
·
14.2 UN proper shipping name
·
DOT, ADR, ADN, IMDG, IATA
·
14.3 Transport hazard class(es)
·
DOT, ADR, ADN, IMDG, IATA
·
Class
·
14.4 Packing group
·
DOT, ADR, IMDG, IATA
·
14.5 Environmental hazards:
·
Marine pollutant:
·
14.6 Special precautions for user
·
14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code
·
UN "Model Regulation":
Not Regulated
Not Regulated
Not Regulated
Not Regulated
No
Not applicable.
Not applicable.
-
(Contd. on page 8)
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Page 8
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 05.06.2014 Revision: 05.06.2014
Trade name: Steel Shot
(Contd. of page 7)
15 Regulatory information
·
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
·
United States (USA)
·
SARA
·
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
·
Section 313 (Specific toxic chemical listings):
7439-96-5 manganese
·
TSCA (Toxic Substances Control Act):
All ingredients are listed.
·
Proposition 65 (California):
·
Chemicals known to cause cancer:
None of the ingredients is listed.
·
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
·
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
·
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
·
Carcinogenic Categories
·
EPA (Environmental Protection Agency)
7439-96-5 manganese D
·
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
·
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
·
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
·
Canada
·
Canadian Domestic Substances List (DSL)
All ingredients are listed.
·
Canadian Ingredient Disclosure list (limit 0.1%)
None of the ingredients is listed.
·
Canadian Ingredient Disclosure list (limit 1%)
7439-96-5 manganese
(Contd. on page 9)
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Page 9
Page 9/9
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 05.06.2014 Revision: 05.06.2014
Trade name: Steel Shot
(Contd. of page 8)
·
Other regulations, limitations and prohibitive regulations
·
Substances of very high concern (SVHC) according to REACH, Article 57
None of the ingredients is listed.
·
15.2 Chemical safety assessment:
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
·
Relevant phrases
H228 Flammable solid.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
R36/37 Irritating to eyes and respiratory system.
R48 Danger of serious damage to health by prolonged exposure.
·
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning t he
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
Flam. Sol. 2: Flammable solids, Hazard Category 2
Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2
STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3
·
Sources
SDS Prepared by:
ChemTel Inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtelinc.com
A Chemical Safety Assessment has not been carried out.
38.0.33
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