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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 15.04.2014 Revision: 15.04.2014
1 Identification of the substance/mixture and of the company/undertaking
·
1.1 Product identifier
·
Trade name: DURAC Liquid Fill for Thermometers
·
1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
·
Application of the substance / the mixture
·
1.3 Details of the supplier of the Safety Data Sheet
·
Manufacturer/Supplier:
H-B Instrument – A Division of Bel-Art Products
102 West Seventh Avenue
Trappe, PA 19426 USA
Phone: (610) 489-5500
·
1.4 Emergency telephone number:
ChemTel Inc.
(800)255-3924, +1 (813)248-0585
Product Component
2 Hazards identification
·
2.1 Classification of the substance or mixture
·
Classification according to Regulation (EC) No 1272/2008
flame
Flam. Liq. 2 H225 Highly flammable liquid and vapour.
Eye Irrit. 2 H319 Causes serious eye irritation.
STOT SE 3 H336 May cause drowsiness or dizziness.
·
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Xi; Irritant
R36: Irritating to eyes.
F; Highly flammable
R11: Highly flammable.
R66-67: Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and
dizziness.
·
Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
At long or repeated contact with skin it may cause dermatitis due to the degreasing effect of the solvent.
·
Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and
literature data.
(Contd. on page 2)
38.0.33
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 15.04.2014 Revision: 15.04.2014
Trade name: DURAC Liquid Fill for Thermometers
(Contd. of page 1)
The classification is in accordance with the latest editions of international substances lists, and is
supplemented by information from technical literature and by information provided by the company.
·
2.2 Label elements
·
Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
·
Hazard pictograms
GHS02 GHS07
·
Signal word
·
Hazard-determining components of labelling:
acetone
·
Hazard statements
H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
·
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P280 Wear protective gloves / eye protection.
P261 Avoid breathing mist/vapours/spray.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse
P370+P378 In case of fire: Use for extinction: CO2, powder or water spray.
P403+P235 Store in a well-ventilated place. Keep cool.
·
Additional information:
EUH066 Repeated exposure may cause skin dryness or cracking.
·
Hazard description:
·
WHMIS-symbols:
B2 - Flammable liquid
D2B - Toxic material causing other toxic effects
Danger
skin with water/shower.
·
NFPA ratings (scale 0 - 4)
Health = 2
230
·
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
38.0.33
Fire = 3
Reactivity = 0
*2
Health = *2
3
Fire = 3
0
Reactivity = 0
(Contd. on page 3)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 15.04.2014 Revision: 15.04.2014
Trade name: DURAC Liquid Fill for Thermometers
(Contd. of page 2)
·
HMIS Long Term Health Hazard Substances
None of the ingredients is listed.
·
2.3 Other hazards
·
Results of PBT and vPvB assessment
·
PBT:
Not applicable.
·
vPvB:
3 Composition/information on ingredients
·
3.2 Mixtures
·
Description:
·
Dangerous components:
CAS: 67-64-1
EINECS: 200-662-2
Index number: 606-001-00-8
·
Additional information:
Not applicable.
Mixture of substances listed below with nonhazardous additions.
acetone
Xi R36; F R11
R66-67
Flam. Liq. 2, H225
Eye Irrit. 2, H319; STOT SE 3, H336
For the wording of the listed risk phrases refer to section 16.
50-100%
4 First aid measures
·
4.1 Description of first aid measures
·
General information:
Immediately remove any clothing soiled by the product.
Take affected persons out into the fresh air.
·
After inhalation:
·
After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
·
After eye contact:
Remove contact lenses if worn.
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
·
After swallowing:
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
·
4.2 Most important symptoms and effects, both acute and delayed
Irritant to eyes.
Slight irritant effect on skin and mucous membranes.
Dizziness
Nausea
Gastric or intestinal disorders when ingested.
Coughing
Acidosis
Disorientation
Unconsciousness
Supply fresh air; consult doctor in case of complaints.
(Contd. on page 4)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 15.04.2014 Revision: 15.04.2014
Trade name: DURAC Liquid Fill for Thermometers
(Contd. of page 3)
·
Hazards
·
4.3 Indication of any immediate medical attention and special treatment needed
If necessary oxygen respiration treatment.
Medical supervision for at least 48 hours.
5 Firefighting measures
·
5.1 Extinguishing media
·
Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
·
For safety reasons unsuitable extinguishing agents:
·
5.2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
·
5.3 Advice for firefighters
·
Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
·
Additional information
Eliminate all ignition sources if safe to do so.
Cool endangered receptacles with water spray.
Use large quantities of foam as it is partially destroyed by the product.
No further relevant information available.
None.
6 Accidental release measures
·
6.1 Personal precautions, protective equipment and emergency procedures
Use respiratory protective device against the effects of fumes/dust/aerosol.
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources.
Protect from heat.
·
6.2 Environmental precautions:
·
6.3 Methods and material for containment and cleaning up:
Do not allow to enter sewers/ surface or ground water.
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Pick up mechanically.
Send for recovery or disposal in suitable receptacles.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
·
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
·
7.1 Precautions for safe handling
Prevent formation of aerosols.
(Contd. on page 5)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 15.04.2014 Revision: 15.04.2014
Trade name: DURAC Liquid Fill for Thermometers
(Contd. of page 4)
Keep away from heat and direct sunlight.
Rags, metal wools / cuttings / shavings and waste papers soaked with product must be placed in a sealed
metal container rated for flammable waste.
Avoid splashes or spray in enclosed areas.
·
Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Fumes can combine with air to form an explosive mixture.
When heated the product forms flammable fumes.
Flammable gas-air mixtures may form in empty receptacles.
·
7.2 Conditions for safe storage, including any incompatibilities
·
Storage:
·
Requirements to be met by storerooms and receptacles:
Store in a cool location.
Provide ventilation for receptacles.
Avoid storage near extreme heat, ignition sources or open flame.
·
Information about storage in one common storage facility:
Store away from foodstuffs.
Do not store together with oxidizing and acidic materials.
·
Further information about storage conditions:
·
7.3 Specific end use(s)
No further relevant information available.
Store in cool, dry conditions in well sealed receptacles.
8 Exposure controls/personal protection
·
Additional information about design of technical facilities:
·
8.1 Control parameters
·
Ingredients with limit values that require monitoring at the workplace:
67-64-1 acetone
IOELV (EU) Long-term value: 1210 mg/m³, 500 ppm
PEL (USA) Long-term value: 2400 mg/m³, 1000 ppm
REL (USA) Long-term value: 590 mg/m³, 250 ppm
TLV (USA) Short-term value: (1782) NIC-1187 mg/m³, (750) NIC-500 ppm
Long-term value: (1188) NIC-475 mg/m³, (500) NIC-200 ppm
BEI
EL (Canada) Short-term value: 500 ppm
Long-term value: 250 ppm
EV (Canada) Short-term value: 750 ppm
Long-term value: 500 ppm
·
DNELs
·
PNECs
No further relevant information available.
No further relevant information available.
No further data; see item 7.
(Contd. on page 6)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 15.04.2014 Revision: 15.04.2014
Trade name: DURAC Liquid Fill for Thermometers
(Contd. of page 5)
·
Ingredients with biological limit values:
67-64-1 acetone
BEI (USA) 50 mg/L
Medium: urine
Time: end of shift
Parameter: Acetone (nonspecific)
·
Additional information:
·
8.2 Exposure controls
·
Personal protective equipment:
·
General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Avoid close or long term contact with the skin.
Avoid contact with the eyes.
·
Respiratory protection:
Not required under normal conditions of use.
Use suitable respiratory protective device in case of insufficient ventilation.
Use suitable respiratory protective device when aerosol or mist is formed.
For spills, respiratory protection may be advisable.
·
Protection of hands:
The lists valid during the making were used as basis.
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation.
·
Material of gloves
Butyl rubber, BR
Fluorocarbon rubber (Viton)
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.
·
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
·
Not suitable are gloves made of the following materials:
Nitrile rubber, NBR
PVC gloves
PVA gloves
(Contd. on page 7)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 15.04.2014 Revision: 15.04.2014
Trade name: DURAC Liquid Fill for Thermometers
(Contd. of page 6)
·
Eye protection:
Safety glasses
·
Body protection:
·
Limitation and supervision of exposure into the environment
No further relevant information available.
·
Risk management measures
See Section 7 for additional information.
No further relevant information available.
9 Physical and chemical properties
·
9.1 Information on basic physical and chemical properties
·
General Information
·
Appearance:
Form:
Colour:
·
Odour:
·
Odour threshold:
·
pH-value:
·
Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
·
Flash point:
·
Flammability (solid, gaseous):
·
Auto/Self-ignition temperature:
·
Decomposition temperature:
·
Self-igniting:
·
Danger of explosion:
·
Explosion limits:
Lower:
Upper:
·
Vapour pressure:
·
Density at 20 °C:
·
Relative density
·
Vapour density
·
Evaporation rate
Protective work clothing
Liquid
Red
Acetone-like
Not determined.
Not determined.
Not Determined.
131 °F / 55 °C
-4 °F / -20 °C
Not applicable.
Not determined.
Not determined.
Product is not self-igniting.
Product is not explosive. However, formation of explosive air/
vapour mixtures are possible.
2,6 Vol %
13 Vol %
Not determined.
0,8 g/cm³
Not determined.
Not determined.
Not determined.
(Contd. on page 8)
38.0.33
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 15.04.2014 Revision: 15.04.2014
Trade name: DURAC Liquid Fill for Thermometers
(Contd. of page 7)
·
Solubility in / Miscibility with
water:
·
Partition coefficient (n-octanol/water):
·
Viscosity:
Dynamic:
Kinematic:
·
9.2 Other information
10 Stability and reactivity
·
10.1 Reactivity
·
10.2 Chemical stability
·
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
·
10.3 Possibility of hazardous reactions
Flammable.
Reacts violently with oxidizing agents.
Used empty containers may contain product gases which form explosive mixtures with air.
Can form explosive mixtures in air if heated above flash point and/or when sprayed or atomised.
Reacts with acids.
Toxic fumes may be released if heated above the decomposition point.
·
10.4 Conditions to avoid
Keep ignition sources away - Do not smoke.
Store away from oxidizing agents.
·
10.5 Incompatible materials:
·
10.6 Hazardous decomposition products:
No further relevant information available.
Fully miscible.
Not determined.
Not determined.
Not determined.
No further relevant information available.
Carbon monoxide and carbon dioxide
11 Toxicological information
·
11.1 Information on toxicological effects
·
Acute toxicity:
·
LD/LC50 values relevant for classification:
67-64-1 acetone
Oral LD50 5800 mg/kg (rat)
Dermal LD50 20000 mg/kg (rabbit)
·
Primary irritant effect:
·
on the skin:
·
on the eye:
·
Sensitization:
·
Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version:
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Slight irritant effect on skin and mucous membranes.
Irritating effect.
No sensitizing effects known.
(Contd. on page 9)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 15.04.2014 Revision: 15.04.2014
Trade name: DURAC Liquid Fill for Thermometers
(Contd. of page 8)
Irritant
Inhalation of concentrated vapours as well as oral intake will lead to anaesthesia-like conditions and
headache, dizziness, etc.
At long or repeated contact with skin it may cause dermatitis due to the degreasing effect of the solvent.
·
Acute effects (acute toxicity, irritation and corrosivity):
·
Repeated dose toxicity:
Repeated exposure may cause skin dryness or cracking.
12 Ecological information
·
12.1 Toxicity
·
Aquatic toxicity:
·
12.2 Persistence and degradability
·
12.3 Bioaccumulative potential
·
12.4 Mobility in soil
·
Additional ecological information:
·
General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
·
12.5 Results of PBT and vPvB assessment
·
PBT:
Not applicable.
·
vPvB:
·
12.6 Other adverse effects
Not applicable.
No further relevant information available.
No further relevant information available.
No further relevant information available.
No further relevant information available.
No further relevant information available.
Vapours have narcotic effect.
13 Disposal considerations
·
13.1 Waste treatment methods
·
Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Can be burned with household garbage after consulting with the waste disposal facility operator and the
pertinent authorities and adhering to the necessary technical regulations.
Can be reused after reprocessing.
Contact waste processors for recycling information.
·
Uncleaned packaging:
·
Recommendation:
·
Recommended cleansing agents:
Disposal must be made according to official regulations.
Water, if necessary together with cleansing agents.
14 Transport information
·
14.1 UN-Number
·
DOT, ADR, IMDG, IATA
UN1090
(Contd. on page 10)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 15.04.2014 Revision: 15.04.2014
Trade name: DURAC Liquid Fill for Thermometers
(Contd. of page 9)
·
14.2 UN proper shipping name
Limited Quantity for packages less than 30 kg (66 lb) and inner packagings less than 1 L (0.3
gal).
·
DOT
·
ADR
·
IMDG, IATA
·
14.3 Transport hazard class(es)
·
DOT
·
Class
·
Label
·
ADR
Acetone
1090 ACETONE
ACETONE
3 Flammable liquids.
3
·
Class
·
Label
·
IMDG, IATA
·
Class
·
Label
·
14.4 Packing group
·
DOT, ADR, IMDG, IATA
·
14.5 Environmental hazards:
·
Marine pollutant:
·
14.6 Special precautions for user
·
Danger code (Kemler):
·
EMS Number:
·
14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code
·
Transport/Additional information:
·
ADR
·
Limited quantities (LQ)
·
Transport category
·
Tunnel restriction code
3 (F1) Flammable liquids.
3
3 Flammable liquids.
3
II
No
Warning: Flammable liquids.
33
F-E,S-D
Not applicable.
1L
2
D/E
(Contd. on page 11)
38.0.33
Page 11
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 15.04.2014 Revision: 15.04.2014
Trade name: DURAC Liquid Fill for Thermometers
(Contd. of page 10)
·
UN "Model Regulation":
15 Regulatory information
·
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
·
United States (USA)
·
SARA
·
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
·
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
·
TSCA (Toxic Substances Control Act):
All ingredients are listed.
·
Proposition 65 (California):
·
Chemicals known to cause cancer:
None of the ingredients is listed.
·
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
·
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
·
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
·
Carcinogenic Categories
·
EPA (Environmental Protection Agency)
67-64-1 acetone I
·
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
·
TLV (Threshold Limit Value established by ACGIH)
67-64-1 acetone A4
·
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
·
Canada
·
Canadian Domestic Substances List (DSL)
All ingredients are listed.
·
Canadian Ingredient Disclosure list (limit 0.1%)
None of the ingredients is listed.
·
Canadian Ingredient Disclosure list (limit 1%)
67-64-1 acetone
UN1090, ACETONE, 3, II
(Contd. on page 12)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 15.04.2014 Revision: 15.04.2014
Trade name: DURAC Liquid Fill for Thermometers
(Contd. of page 11)
·
Other regulations, limitations and prohibitive regulations
·
Substances of very high concern (SVHC) according to REACH, Article 57
None of the ingredients is listed.
·
15.2 Chemical safety assessment:
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
·
Relevant phrases
H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
R11 Highly flammable.
R36 Irritating to eyes.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
·
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning t he
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
Flam. Liq. 2: Flammable liquids, Hazard Category 2
Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2
STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3
·
Sources
SDS Prepared by:
ChemTel Inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtelinc.com
A Chemical Safety Assessment has not been carried out.
38.0.33
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