according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date: 25.02.2016Revision: 25.02.2016
SE CTION 1: Identification of the substance/mixture and of the company/
undertaking
·
1.1 Product identifier
·
Trade name: Blue Liquid in ASTM Precision Thermometers
·
CAS number:
108-32-7
·
EC number:
203-572-1
·
1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
·
Application of the substance / the mixture:
·
1.3 Details of the supplier of the Safety Data Sheet
·
Manufacturer/Supplier:
SP Industries, Inc.
102 West Seventh Avenue
Trappe, PA 19426
(610) 489-5500
·
1.4 Emergency telephone number:
ChemTel Inc.
+1 (800)255-3924, +1 (813)248-0585
Laboratory chemicals
SECTION 2: Hazards identification
·
2.1 Classification of the substance or mixture
·
Classification according to Regulation (EC) No 1272/2008
Classif ic a t i o n s li s ted are ap p l i c a b l e to t he OSHA G H S H a za r d Com m unication St a n d a r d
(29CFR1910.1200).
Eye Irrit. 2 H319 Causes serious eye irritation.
·
2.2 Label elements
·
Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the Globally Harmonized System within the United
States.
The substance is classified and labelled according to the CLP regulation.
·
Hazard pictograms
GHS07
·
Signal word
·
Hazard-determining components of labelling:
propylene carbonate
·
Hazard statements
H319 Causes serious eye irritation.
·
Precautionary statements
P264Wash thoroughly after handling.
Warning
(Cont'd. on page 2)
42.0.18
Page: 2/9
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date: 25.02.2016Revision: 25.02.2016
Trade name:
P280Wear protective gloves / eye protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
P337+P313If eye irritation persists: Get medical advice/attention.
·
2.3 Other hazards
·
Results of PBT and vPvB assessment
·
PBT:
·
vPvB:
Blue Liquid in ASTM Precision Thermometers
(Cont'd. from page 1)
present and easy to do. Continue rinsing.
There are no other hazards not otherwise classified that have been identified.
Not applicable.
Not applicable.
SECTION 3: Composition/information on ingredients
·
3.1 Substances
·
CAS No. Description
108-32-7 propylene carbonate
·
Identification number(s)
·
EC number:
·
Index number:
203-572-1
607-194-00-1
SECTION 4: First aid measures
·
4.1 Description of first aid measures
·
After inhalation:
·
After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation is experienced, consult a doctor.
·
After eye contact:
Remove contact lenses if worn.
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
·
After swallowing:
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
·
4.2 Most important symptoms and effects, both acute and delayed
Headache
Irritant to eyes.
Gastric or intestinal disorders when ingested.
Nausea in case of ingestion.
·
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
Supply fresh air; consult doctor in case of complaints.
SECTION 5: Firefighting measures
·
5.1 Extinguishing media
·
Suitable extinguishing agents:
The product is not flammable.
(Cont'd. on page 3)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date: 25.02.2016Revision: 25.02.2016
Trade name:
Use fire extinguishing methods suitable to surrounding conditions.
·
For safety reasons unsuitable extinguishing agents:
·
5.2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
6.1 Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation
Wear protective equipment. Keep unprotected persons away.
For large spills, use respiratory protective device against the effects of fumes/dust/aerosol.
·
6.2 Environmental precautions
·
6.3 Methods and material for containment and cleaning up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of the material collected according to regulations.
·
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Avoid release to the environment.
(Cont'd. from page 2)
SECTION 7: Handling and storage
·
7.1 Precautions for safe handling
Prevent formation of aerosols.
Avoid splashes or spray in enclosed areas.
·
Information about fire - and explosion protection:
·
7.2 Conditions for safe storage, including any incompatibilities
·
Storage:
·
Requirements to be met by storerooms and receptacles:
Avoid storage near extreme heat, ignition sources or open flame.
·
Information about storage in one common storage facility:
·
Further information about storage conditions:
·
7.3 Specific end use(s)
No further relevant information available.
No special measures required.
Store away from foodstuffs.
Keep container tightly sealed.
SECTION 8: Exposure controls/personal protection
·
8.1 Control parameters
·
Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
(Cont'd. on page 4)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date: 25.02.2016Revision: 25.02.2016
Trade name:
·
DNELs:
·
PNECs:
·
8.2 Exposure controls
·
Personal protective equipment:
·
General protective and hygienic measures:
Blue Liquid in ASTM Precision Thermometers
(Cont'd. from page 3)
No further relevant information available.
No further relevant information available.
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes.
Avoid close or long term contact with the skin.
·
Respiratory protection:
Not required under normal conditions of use.
Use suitable respiratory protective device when aerosol or mist is formed.
For spills, respiratory protection may be advisable.
·
Protection of hands:
Wear protective gloves to handle contents of damaged or leaking units.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
·
Eye protection:
Safety glasses
·
Body protection:
Not required under normal conditions of use.
Protection may be required for spills.
·
Limitation and supervision of exposure into the environment:
No further relevant information available.
·
Risk management measures:
No special requirements.
SECTION 9: Physical and chemical properties
·
9.1 Information on basic physical and chemical properties
·
Appearance
Form:
Colour:
·
Odour:
·
Odour threshold:
·
pH-value:
·
Melting point/Melting range:
·
Boiling point/Boiling range:
·
Flash point:
·
Flammability (solid, gaseous):
Fluid
Colourless
Fruit-like
Not determined.
~7
-55 °C (-67 °F)
240 °C (464 °F)
132 °C (270 °F)
Not applicable.
(Cont'd. on page 5)
42.0.18
Page: 5/9
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date: 25.02.2016Revision: 25.02.2016
Trade name:
·
Auto/Self-ignition temperature:
·
Decomposition temperature:
·
Self-igniting:
·
Danger of explosion:
·
Explosion limits
Lower:
Upper:
·
Oxidising properties
·
Vapour pressure at 20 °C (68 °F):
·
Density at 20 °C (68 °F):
·
Relative density:
·
Vapour density:
·
Evaporation rate:
·
Solubility in / Miscibility with
water:
·
Partition coefficient (n-octanol/water):
·
Viscosity
Dynamic at 20 °C (68 °F):
Kinematic:
·
9.2 Other information
Blue Liquid in ASTM Precision Thermometers
(Cont'd. from page 4)
Not determined.
Not determined.
Not determined.
Product does not present an explosion hazard.
Not determined.
Not determined.
Not determined.
0,17 hPa
1,189 g/cm³ (9,922 lbs/gal)
Not determined.
Not determined.
Not determined.
Fully miscible.
Not determined.
2,8 mPas
Not determined.
No further relevant information available.
SECTION 10: Stability and reactivity
·
10.1 Reactivity
·
10.2 Chemical stability
·
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
To avoid thermal decomposition do not overheat.
·
10.3 Possibility of hazardous reactions
Toxic fumes may be released if heated above the decomposition point.
Reacts with strong oxidising agents.
Reacts with strong acids and alkali.
·
10.4 Conditions to avoid
·
10.5 Incompatible materials
·
10.6 Hazardous decomposition products
No further relevant information available.
Stable under normal temperatures and pressures.
Excessive heat.
Oxidizers, strong bases, strong acids
Carbon monoxide and carbon dioxide
(Cont'd. on page 6)
42.0.18
Page: 6/9
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date: 25.02.2016Revision: 25.02.2016
Trade name:
Blue Liquid in ASTM Precision Thermometers
SECTION 11: Toxicological information
·
11.1 Information on toxicological effects
·
Acute toxicity:
·
LD/LC50 values relevant for classification:
108-32-7 propylene carbonate
IARC (International Agency for Research on Cancer):
Substance is not listed.
·
NTP (National Toxicology Program):
Substance is not listed.
·
OSHA-Ca (Occupational Safety & Health Administration):
Substance is not listed.
·
Probable routes of exposure:
Ingestion.
Inhalation.
Eye contact.
Skin contact.
·
Repeated dose toxicity:
·
Germ cell mutagenicity:
·
Carcinogenicity:
·
Reproductive toxicity:
·
STOT-single exposure:
·
STOT-repeated exposure:
·
Aspiration hazard:
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
No further relevant information available.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
(Cont'd. from page 5)
SECTION 12: Ecological information
·
12.1 Toxicity
·
Aquatic toxicity:
·
12.2 Persistence and degradability
·
12.3 Bioaccumulative potential
·
12.4 Mobility in soil
42.0.18
No further relevant information available.
Easily biodegradable
No further relevant information available.
No further relevant information available.
(Cont'd. on page 7)
Page: 7/9
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date: 25.02.2016Revision: 25.02.2016
Trade name:
·
Additional ecological information:
·
General notes:
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
·
12.5 Results of PBT and vPvB assessment
·
PBT:
·
vPvB:
·
12.6 Other adverse effects
Blue Liquid in ASTM Precision Thermometers
(Cont'd. from page 6)
Not applicable.
Not applicable.
No further relevant information available.
SECTION 13: Disposal considerations
·
13.1 Waste treatment methods
·
Recommendation
Small amounts may be diluted with plenty of water and washed away. Dispose of larger amounts in
accordance with Local Authority requirements.
The user of this material has the responsibility to dispose of unused material, residues and containers in
compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and
disposal for hazardous and nonhazardous wastes.
·
Uncleaned packaging:
·
Recommendation:
·
Recommended cleansing agents:
Disposal must be made according to official regulations.
Water, if necessary together with cleansing agents.
SECTION 14: Transport information
·
14.1 UN-Number
·
DOT, ADR, IMDG, IATA
·
14.2 UN proper shipping name
·
DOT, ADR, IMDG, IATA
·
14.3 Transport hazard class(es)
·
DOT, ADR, IMDG, IATA
·
Class
·
14.4 Packing group
·
DOT, ADR, IMDG, IATA
·
14.5 Environmental hazards:
·
Marine pollutant:
·
14.6 Special precautions for user
Not Regulated
Not Regulated
Not Regulated
Not Regulated
No
Not applicable.
(Cont'd. on page 8)
42.0.18
Page: 8/9
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date: 25.02.2016Revision: 25.02.2016
Trade name:
·
14.7 Transport in bulk according to Annex II
of Marpol and the IBC Code
Blue Liquid in ASTM Precision Thermometers
(Cont'd. from page 7)
Not applicable.
SECTION 15: Regulatory information
·
15.1 Safety, health and environmental regulations/legislation specific for the substance
or mixture
·
United States (USA)
·
SARA
·
Section 355 (extremely hazardous substances):
Substance is not listed.
·
Section 313 (Specific toxic chemical listings):
Substance is not listed.
·
TSCA (Toxic Substances Control Act):
Substance is listed.
·
Proposition 65 (California):
·
Chemicals known to cause cancer:
Substance is not listed.
·
Chemicals known to cause reproductive toxicity for females:
Substance is not listed.
·
Chemicals known to cause reproductive toxicity for males:
Substance is not listed.
·
Chemicals known to cause developmental toxicity:
Substance is not listed.
·
Carcinogenic Categories
·
EPA (Environmental Protection Agency)
Substance is not listed.
·
IARC (International Agency for Research on Cancer)
Substance is not listed.
·
NIOSH-Ca (National Institute for Occupational Safety and Health)
Substance is not listed.
·
Canada
·
Canadian Domestic Substances List (DSL)
Substance is listed.
·
Canadian Ingredient Disclosure list (limit 0,1%)
Substance is not listed.
·
Canadian Ingredient Disclosure list (limit 1%)
Substance is listed.
(Cont'd. on page 9)
42.0.18
Page: 9/9
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date: 25.02.2016Revision: 25.02.2016
Trade name:
·
Directive 2012/18/EU
·
Named dangerous substances - ANNEX I
·
Other regulations, limitations and prohibitive regulations
·
Substances of very high concern (SVHC) according to REACH, Article 57
Blue Liquid in ASTM Precision Thermometers
(Cont'd. from page 8)
Substance is not listed.
Substance is not listed.
·
15.2 Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
·
Abbreviations and acronyms:
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2
·
Sources
Website, European Chemicals Agency (echa.europa.eu)
Website, US EPA Substance Registry Services (ofmpub.epa.gov/sor internet/registry/substreg/home/
overview/home.do)
Website, Chemical Abstracts Registry, American Chemical Society (www.cas.org)
Patty's Industrial Hygiene, 6th ed., Rose, Vernon, ed. ISBN: ISBN: 978-0-470-07488-6
Casarett and Doull's Toxicology: The Basic Science of Poisons, 8th Ed., Klaasen, Curtis D., ed., ISBN:
978-0-07-176923-5.
Safety Data Sheets, Individual Manufacturers
SDS Prepared by:
ChemTel Inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtelinc.com
42.0.18
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