Hach MTC10101, MTC10103, MTC10105, MTC10110, MTC10115 User Instructions

...
1
DOC272.53.80033
User instructions
Gel filled ORP/Redox electrode: Model MTC10101, MTC10103, MTC10105, MTC10110, MTC10115 or MTC10130
Safety Information
Precautionary Labels
Overview
The MTC101 series is a non-refillable, gel-filled combination oxidation reduction potential (ORP/Redox) electrode with a built in temperature sensor. The MTC10101 or MTC10103 electrode is available with a 1 or 3 meter cable and is intended for laboratory use. The MTC10105, MTC10110, MTC101 15 or MTC1013 0 electrode is ava ilable with a 5, 10, 15 or 30 meter cable and is intended for field use. The electrode gives direct measurements of absolute mV values in wastewater, drinking water and general applications.
Specifications
Specifications are subject to change without notice.
Electrical equipment marked with this symbol may not be disposed of in European public disposal systems after 12 August of 2005. In conformity with European local and national regulations (EU Directive 2002/96/EC), European electrical equipment users must now return old or end-of life equipment to the Producer for disposal at no charge to the user.
Note: For return for recycling, please contact the equipment producer or supplier for instructions on how to return end-of-life equipment, producer-supplied electrical accessories, and all auxiliary items for proper disposal.
This is the safety alert symbol. Obey all safety messages that follow this symbol to avoid potential injury. If on the instrument, refer to the instruction manual for operation or safety information.
Specification Details
Electrode type
Digital combination electrode with a non-refillable Ag/AgCl reference and a built-in
temperature sensor Range ± 1200 mV Resolution 0.1 mV Temperature accuracy ± 0.3 ºC (± 0.54 ºF) Operating temperature range 0 to 80 °C Storage temperature range 5 to 40 °C Junction Open junction Reference potential versus
Standard Hydrogen Electrode
207 mV at 25 ºC Reference type Ag/AgCl (3M KCl)
Minimum sample depth 20 mm
Dimensions
Standard: Diameter: 12 mm (0.47 in.), Length: 103 mm(4.056 in.), Total length: 200 mm
(7.9 in.), Cable length: 1 or 3 meter (3.3 or 9.8 ft). Rugged: Diameter 12 mm (0.47 in.),
Length: 20 mm (0.78 in.), Total length: 220 mm (8.7 in.), Cable length: 5, 10, 15 or 30
meter (16.4, 32.8, 49.2, or 98.4 ft). Cable connection Digital output and connector compatible with HQd meters Warranty Sensor is covered by a 6 month warranty.
2 DOC272.53.80033
Preparation for use
1. Remove the locking ring and shroud (rugged model).
2. Before first use, remove the tape from the reference junctions and the label from the
electrode body. Refer to Figure 1.
3. Rinse the reference junctions and platinum electrode with deionized water and blot dry with a lint-free cloth.
4. If the electrode will not be used immediately, fill the storage cap halfway with Hach Electrode Storage Solution or 3M KCl and install the cap.
5. Install the shroud and locking ring and hand-tighten (rugged mo del).
Figure 1 Probe overview
1 Shroud (rugged model) 5 Rugged probe (5, 10, 15 or 30 meter cable) 2 Electrode storage cap 6 Standard probe (1 or 3 meter cable) 3 Platinum electrode and temperature sensor 7 Electrode storage cap lid 4 Reference junctions and tape 8 Locking ring (rugged model)
DOC272.53.80033 3
Calibration
Calibration notes
Probes are initially calibrated at the factory. However, re gular calibration by the user is
recommended for best measurement accuracy.
Additional standards can be selected in the MTC101 Calibration Options.
ZoBell’s redox potential is temperature dependent. The HQd calibration routine
factors in this temperature dependency allowing accurate calibrations withi n the temperature range of 0 - 30 ºC. Light’s solution should be read @ 25 ºC. Custom ORP/Redox calibration solution values and temperature are user defined.
The calibration is recorded in the electrode and the data log. The calibration is also sent to a PC, printer or flash memory stick if connected.
Before calibration:
The probe must have the correct service-life time stamp. Set the date and time in the meter before attaching the probe. It is not necessary to recalibrate when moving a probe from one HQd meter to another if the additional meter is configured to
use the same calibration options. If the additional HQd meter uses different calibration options (e.g. standard calibration routine), calibrate the probe or change the method settings/select a different method.
To view the current calibration, select DATA LOG KEY, View Probe Data, then View Current Calibration. If two probes are connected, push the UP or DOWN arrow to change to the single display mode to show the Calibrate
option. ORP/Redox standards should not be diluted. Always use fresh ORP/Redox standard for calibration. Stir gently. Avoid resting the electrode on the bottom or sides of the container. Refer to the troubleshooting section for calibration errors (Troubleshootin g on page 13).
4 DOC272.53.80033
Note: Procedures also apply for rugged model probes.
1. Connect the electrode to the meter.
2. Add fresh ORP/Redox standard to beaker or appropriate container.
3. Select Calibrate. The
display will show the required ORP/Redox standard solution.
4. Rinse the electrode with deionized water , blot dry and place it in the standard solution. Make sure that the sample level is above the reference junction.
5. Push Read. Stir gently. The display will show Stabilizing... and a progress bar as the probe stabilizes in the standard.
6. The display will show the standard solution value and the mV offset when the reading is stable. Select Done to view the calibration summary.
7. The display will show the calibration summary. Select Store to accept the calibration and return to the measurement mode.
DOC272.53.80033 5
Run check standard
The run check standard feature validates instrument performance between sample measurements. Use the run check standard feature for periodic or user-defined interval measurement of a traceable standard solution. Set the criteria for check standards from the MTC101 settings menu.
Note: Access control must be off or a valid password entered before any of the check standard method options can be changed.
1. Select Run Check Standard from the Meter Options menu.
Note: Select the appropriate probe if two probes are connected to the meter.
2. Obtain the standard solution specified in the display.
3. Place the electrode in the standard solution and select
READ. The display will show
Stabilizing... and a progress bar as the electrode stabilizes in the standard. The
display shows the value of the check standard and either Chec k Standard Passed or probe Check Standard Failed.
If the display reads Check Standard Passed, the check standard measurement is within the accepted limits defined by the administrative user. Select
DONE to proceed
with sample measurement. If the display reads Check Standard Failed, the measurement is o utside of accepted
limits defined by the administrative user and a recalibration is suggested. If the acceptance criteria is set to Cal Expires on Failure: Yes, the display will show the calibrate icon with a question mark until the electrode is recalibrated. Recalibrate the electrode to correct the status indicator (Calibration on page 3).
Measurement
Measurement notes
Data is stored automatically in the data log when
PRESS TO READ or INTERVAL is
selected in the Setup Measurement Mode.
To significantly reduce the response time for reducing-type samples:
The platinum disc must be clean and smooth.
Immerse the platinum disc for 3-10 minutes in Reducing Solution for ORP
Electrodes prior to sample analysis.
Rinse the electrode with sample, then measure.
Before measurement:
The electrode must have the correct service-life time stamp. Set the date and time in the meter before attaching the probe.
The probe is factory calibrated and ready for use. For applications that require greater accuracy and precision, verify the user calibration with check standards or perform a user calibration. Routine calibrations are req uired (Calibration on page 3).
Make sure that the platinum electrode is clean before sample measurement (Clean the probe on page 9). If complete traceability is required, enter a sample ID and operator ID before measurement. Refer to the troubleshooting section for measurement errors (Troubleshooting on page 13). Stir samples gently during measurement. When deploying the rugged probe at a distance, toss the cell body with a gentle underhand throw. Swinging the probe by the
cable may cause injury to the user, will cause severe strain on the cable and will shorten the service life of the cell. Damage under these conditions may not be covered by the product warranty.
6 DOC272.53.80033
Note: Procedures also apply for rugged model probes.
1. Prepare the electrode for use (Preparation for use
on page 2).
2. Connect the electrode to the meter.
3. Rinse the electrode with the sample and place the electrode in fresh sample.
4. Push Read. The display will show Stabilizing... and a progress bar as the probe stabilizes in the sample. If required by the application, also record the sample pH and temperature.
5. Repeat steps 3. and 4. for additional measurements.
DOC272.53.80033 7
Measurement - conversion to SHE reference
For some applications it is customary to report redox potential readings relative to the standard hydrogen electrode (SHE), also called normal hydrogen electrode (NHE). To do this, select the value in Table 1 Standard potential of reference elect ro de that corresponds to the temperature of the solution measured. Substitute that value E
ref
into
the equation and solve for E
h
:
E
h
= E + E
ref
where:
E
h
= oxidation reduction potential of the sample relative to the SHE E = potential developed by the ORP/Redox electrode E
ref
= potential developed by the reference electrode portion relative to the SHE (refer to
Table 1 Standard potential of reference electrode). Table 1 shows the potentials, E
ref
, developed by the reference electrode portion relative to
the SHE at various temperatures.
Measurement - Oxidation Titrations
Oxidation-reduction, or redox titrations, provide a simple, reliable method for determining many substances in solution. A redox titration consists of adding to an unknown sample small increments of a titrant that converts the unknown to a different oxidation state. After each addition of titrant, the ORP/Redox electrode develops a potential proportional to the logarithm of the ratio of the activities of the two oxidation states.
At the inflection, or end point, the titrant has completely oxidized or reduced the unkn own, causing a sharp change in the logarithm of the ratio of the activities of the two oxidation states. A corresponding sharp change in the potential is developed by the platinum electrode. Often several oxidizing or reducing species can be precisely determined in the same solution by a single titration with several inflection points.
The following directions represent a general procedure for performing a redox titration once the sample is prepared for measurement.
Table 1 Standard potential of reference electrode
Temperature (ºC) Electrode Potential in mV (E
ref
)
80 163.1
75 167.7
70 172.1
65 176.4
60 180.3
55 184.4
50 188.4
45 192.3
40 196.1
35 199.8
30 203.4
25 207.0
20 210.5
15 214.0
10 217.4
5220.9
0224.2
8 DOC272.53.80033
1. Fill a 10 ml
burette with a standard titrant solution with a normality that is 5-10 times that of the sample.
2. Connect the electrode to the meter.
3. Pipet a 50 mL sample into a 150-mL beaker. Stir with a magnetic stirrer throughout the titration.
4. Begin by adding titrant in 0.5 - 1 mL increments, recording the potential after each addition. Near the end point, when large potential changes appear , add increments of 0.1 -
0.2 mL. Continue the titration 3-4 mL past the end point.
5. Plot the electrode potential versus volume of added titrant and fit a smooth curve through the points. The end point is the point of inflection (the point of greatest slope).
6. Calculate the normality of the sample, N
x
, in equivalents per liter: N
x
= (Vt x Nt) / V
x
where: N
t
= normality of titrant (Eq/L) V
t
= volume of titrant at end point (mL)
V
x
= Volume of
sample (mL)
DOC272.53.80033 9
Maintenance
Clean the probe if the response time becomes slow (Clean the probe on page 9).
Storage
Note: For optimal performance, the reference junction must not dry out.
Short-term storage: Store the electrode in Hach Electrode Storage Solution or 3M potassium chloride
(KCl) solution. The electrode can also be stored for up to 2 hours in a sample (if the
sample pH is not extreme).
Long-term storage:
1. Rinse the electrode with deionized water. Dry the electrode with a lint-free cloth.
2. Fill the electrode storage cap halfway with Hach Electrode Storage Solution or 3M potassium chloride (KCl) solution.
3. Install the electrode storage cap. Make sure that the storage cap covers the refere nce
junction completely.
Rugged probe maintenance
The shroud protects the sensor elements durin g rugged applications. Damage to the sensing elements can occur if the shroud is not installed during field use. Damage under these conditions is not covered under warranty.
To remove the shroud:
1. Unscrew the locking ring and slide the shroud and locking ring off the probe.
2. Slide the shroud and locking ring off the probe.
To install the shroud
1. Place the locking ring on the probe body with the th re ad s tow ar d th e pla tin um disc .
2. Slide the shroud on the probe until it is seated in the locking groove.
3. Hand-tighten the locking-ring on the shroud.
Clean the probe
For general cleaning (including oils, greases, and organics):
Rinse the electrode with deionized water and blot dry with a lint- fr ee cloth .
Immerse the sensor array and platinum disc in Electrod e Clean in g Solu tio n or
warm detergent solution for up to 15 minutes.
Note: The platinum disc can be polished using a soft cloth or cotton swab with detergent solution.
Rinse the electrode sensor array and platinum disc with deionized water. Blot dry
with a lint-free cloth.
For inorganic deposits
Immerse the platinum disc in a solution of 0.1M hydrochloric or nitric acid solution
and soak for up to 15 minutes.
Rinse the electrode sensor array and platinum disc with deionized water. Blot dry
with a lint-free cloth.
After cleaning has been performed, condition the platinum electrode in representative sample prior to use.
10 DOC272.53.80033
Advanced operation
Parameter-specific settings can be changed through the Full Access Options menu. Details about menu navigation, available opti ons and how to change them are given in the screens, tables and procedures throughout this section.
Change measurement options
Methods are groups of default or user defined settings relevant to specific applications. If the meter is set to the default method and the Modify Current Settings option is chosen, a prompt will display to name the method after changes are entered. The settings are saved with this name to distinguish them from the default method settings, which cannot be changed. A saved method can be used instead of repeatedly adjusting individual settings. Changes made to a user defined method are automatically saved with the existing name. Multiple methods can be saved for the same probe.
1. Make sure an electrode is connected to the meter.
2. Push the
METER OPTIONS key and select (MTC101) Settings.
3. Select Modify Current Settings.
4. Select Measurement Options.
5. Update the settings. Refer to Table 3.
Table 2 Parameter-specific settings
Setting Options
Measurement options
• Response time
• Upper and lower range limits (defines pH limits per method)
Calibration options
• Calibration reminder
• Offset limit
Check standard options
• Standard (temperature compensated for ZoBell’s solution)
• Check standard reminder
• Acceptance criteria
• Standard value (at 25 ºC if custom standard selected)
DOC272.53.80033 11
.
6. If prompted, enter a name for the new method settings. Additional changes made to the settings of an existing method are automatically saved with the same method name.
7. Push
EXIT until the meter returns to the meas ur em e nt mod e .
Change calibration options
1. Make sure an electrode is connected to the meter.
2. Push the
METER OPTIONS key and select (MTC101) Settings.
3. Select Modify Current Settings.
4. Select Calibration Options.
5. Update the settings. Refer to Table 4.
Table 3 Measurement options settings
Setting Options Description
Response time
Fast Medium (default) Slow
The response time affects the speed of the measurement by adjusting the stabilization criteria.
Fast: 2 mV/min Medium: 1 mV/min Slow: 0.5 mV/min
Measurement limits
Lower limit (default: -1200.0 mV) Upper limit (default: 1200.00 mV)
The measurement limits can be set to match the acceptable values for the sample. When the measurement is above the upper limit setting or below the lower limit setting, the meter will show an "Out of limits" message.
This message is an alert to a potential problem with process conditions.
Table 4 Calibration options settings
Settings Option Description
Standard
ZoBell’s (221mV -- 25ºC) Light’s (468mV -- 25 ºC) Custom
Temperature compensated for ZoBell’s solution. Standard values will appear on Calibration Options screen. Light’s solution is characterized at 25 ºC. Custom standard values and temperature are user defined.
Calibration reminder
Reminder repeat: Off (default), 1 d, 7 d, 30 d
Meter will make an audible sound when calibration is due. and repeat the sound at selected interval.
Expires: Immediately, Reminder + 30 min, Reminder + 1 hr, Reminder + 2 hr, Continue Reading
Calibration expires after a specified time.
Note: The meter cannot be used to read samples after calibration has expired unless Continue Reading is selected.
12 DOC272.53.80033
6. If prompted, enter a name for the new method settings. Additional changes made to
the settings of an existing method are automatically saved with the same method name.
7. Push
EXIT until the meter returns to the measurement mode.
Change check standard options
1. Make sure an electrode is connected to the meter.
2. Push the
METER OPTIONS key and select (MTC101) Settings.
3. Select Modify Current Settings.
4. Select Calibration Options.
5. Update the settings. Refer to Table 5.
6. If prompted, enter a name for the new method settings. Additional changes made to
the settings of an existing method are automatically saved with the same method name.
7. Push
EXIT until the meter returns to the measurement mode.
Offset limits ± 1 mV - 250 mV (± 25 mV default)
Offset must fall within set limits for successful calibration.
Standard value (for custom standard option)
Enter standard value using up/down arrow keys. Range -1200.0 mV to 1200.0 mV
Custom standard value. Custom standards are characterized at 25 ºC.
Table 4 Calibration options settings
Settings Option Description
Table 5 Check standard options settings
Settings Options Description
Standard
ZoBell’s (221 mV -- 25 ºC) (default) Light’s (135 mV -- 25 ºC) Custom
Temperature compensated for ZoBell’s solution.
Standard value for check standard. Standard value will appear on Check Standard Options screen. Light’s solution is characterized at 25 ºC. Custom standard values and temperature are user defined.
Check standard reminder
Reminder: On or Off (default) Allow Defer:Yes
Meter automatically displays check standard screen if reminder is on. Measurement of check standard can be delayed if Allow defer: is set to Yes.
Acceptance Criteria
Acceptance Limits: ± 1 mV to 25 mV (default: ± 10 mV) Cal Expires on Failure:Yes or No (default)
Values (as mV) that check standard must fall within in order to pass. Calibration expires if check standard fails.
Standard value (for Custom Standard option)
Enter standard value using up/down arrow keys. Range -1200.0 mV to
1200.0 mV
V alue and temperature for custom che ck standard are user defined.
DOC272.53.80033 13
Troubleshooting
Message or symptom
Possible cause Action
Probe not supported
Software not updated
Update the HQd software to the newest revision at
www.hach.com/SoftwareDownloads. Refer to the HQd
Series Meter Manual.
HQd meter does not support IntelliCAL probe.
Contact a Hach Technical Support Representative.
Connect a probe or Probe requires service
Electrode not connected properly
Disconnect, then connect the electrode. Tighten the locking nut.
Software not updated
Update the HQd software to the newest revision at
www.hach.com/download-resources.
Damaged electrode
Verify connectivity with another electrode or meter to confirm isolated issue with the electrode. Contact a Hach Technical Representative.
Large number of methods stored on probe.
Continue to let probe connect. Do not disconnect probe.
Standard not recognized error
Storage cap not removed. Remove storage cap. Incorrect or contaminated standard
solution
Use fresh standard solution as specified in the method.
mV reading is same for all solutions
Storage cap not removed Remove the storage cap. Electrical issue Contact a Hach Technical Support Representative.
Slow response time
Contaminated reference junctions
Rinse reference junction with deionized water thoroughly, shake the electrode downward to remove any air bubbles and soak in 3.0 M KCl storage solution for 1-2 hours.
Contaminated platinum sensor Clean the electrode.
Electrode not conditioned/pre-treated for reducing type samples
To significantly reduce the response time for reducing type samples the platinum disc must undergo the following:
--The platinum disc must be clean and smooth.
--Immerse the platinum disc for 3-10 minutes in Reducing Solution for ORP Electrodes prior to sample analysis.
--Rinse the electrode with sample, then measure.
Low sample temperature or temperature difference between samples.
Check the sample temperature. The lower the temperature or the greater the difference of temperatures between samples, traditionally the longer the response time.
Platinum electrode not conditioned for reducing-type samples.
The platinum disc must be clean and smooth. Immerse the platinum disc for 3-10 minutes in Reducing
Solution for ORP Electrodes prior to sample analysis. Rinse the electrode with sample, then measure.
Out of range
Measure value is outside the calibration/measurement range of the electrode.
Recalibrate using freshly prepared standards Clean the electrode and recalibrate Verify that the sample is within the range of the electrode
14 DOC272.53.80033
Drifting/Inaccurate readings
Contaminated platinum disc Clean the electrode.
Clogged reference
Rinse reference junction holes with deionized water thoroughly and gently tap the electrode with hand or shake the electrode down to remove any air bubbles.
Improper storage conditions
Clean or condition the electrode and attempt recalibration.The electrode may not function correctly if the electrode has been left dry for extended periods of time. Attempt to recondition the reference junctions by soaking the electrode tip in a 3.0 M KCl storage solution for 1-2 hours. Rinse with deionized water prior to use.
Electromagnetic Forces (EMF) such as voltaic cells, thermoelectric devices, electrical generators, resistors and transformers.
Avoid testing in areas where EMF is present. For testing in process units (i.e. spot checking), make sure the equipment is grounded.
Air bubbles around inner reference electrode
Gently tap the electrode with hand or shake the electrode downward to remove any air bubbles
Out of limits
Check standard value is outside of limits set in the current method
Verify that the standard is within the limits of the current method.
Create a new method that expands the acceptable limits.
Measurement value is outside of the measurement limits set in the current method.
Verify that the sample is within the limits of the current method.
Create a new method with an expanded range.
Calibration adjustment offset value outside the limits set in the current method.
Verify that the standard is within the limits of the current method.
Create another method that expands the acceptable limits.
Storage cap not removed Remove storage cap
Temperature out of range
Calibration temperature value is outside of range
Verify that the sample temperature is within the range of the electrode.
Verify that the temperature sensor is working correctly.
Measured temperature is outside range of the electrode
Verify that the standard temperature is within the range of the electrode.
Verify that the temperature sensor is working correctly.
Check standard temperature value is outside of range
Verify that the Check S tandard temperature is within the range of the electrode.
Troubleshooting (continued)
Message or symptom
Possible cause Action
DOC272.53.80033 15
Parts
Description Quantity Catalog Number
IntelliCAL ORP/Redox gel-filled electrode, standard, with 1 m cable
1 MTC10101
IntelliCAL ORP/Redox gel-filled electrode, standard, with 3 m cable
1 MTC10103
IntelliCAL ORP/Redox gel-filled electrode, rugged, with 5 m cable
1 MTC10105
IntelliCAL ORP/Redox gel-filled electrode, rugged, with 10 m cable
1MTC10110
IntelliCAL ORP/Redox gel-filled electrode, rugged, with 15 m cable
1MTC10115
IntelliCAL ORP/Redox gel-filled electrode, rugged, with 30 m cable
1 MTC10130
Accessories
Description Quantity Catalog Number
Standard probe accessories
Citizen PD-24 USB handy printer, 120-220 VAC
1 2960100
Color coded probe clips (5 color coded sets)
10/pkg 5818400
Electrode storage cap 5/pkg 5857305 Electrode storage cap lid 1 5829800 Field kit (Includes glove kit, and 5 120
mL sample cups)
1 5825800
Glove kit only for HQd meters 1 5828700 IntelliCAL probe stand (for standard
probes)
1 8506600
Meter stand 1 8506600 Printer paper for PD-24, thermal 5/pk 5836000 Probe holder for HQd meter (IntelliCAL
standard models only)
1 5829400
Standard probe holder (use with protective glove)
1 5829400
USB and AC power adapters for HQd meters (included w/HQ40d)
1 5826300
USB/DC adapter for HQd meters (must have 5826300, inc w/HQ40d)
1 5813400
USB keyboard for HQd meters (must have 5813400 and 5826300)
1LZV582
Rugged probe accessories
Electrode depth marker (rugged cable markers)
5/pk 5828610
Rugged field case for 2 probes with up to 5 m cables (10 m total). Includes: Empty case and insert for meter and probe storage, (4) containers for sample collection
1 8505500
Rugged field case for three probes with up to 5 m cables (15 m total). Includes same accessories as case 8505500.
1 8505501
HACH Company World Headquarters
P.O. Box 389 Loveland, Colorado 80539-0389 U.S.A. International customers: Tel (800) -227-4224 (U.S.A. only) Tel +001 (970) 669-3050 Fax (970) 669-2932 Fax +001 (970) 669-2932 orders@hach.com • www.hach.com intl@hach.com
Rugged field case for probes with > 5 meter cables (30 m total) Includes: Empty case and insert for meter and two probe storage cavities, space for storage of HQd meter with protective glove
1 8505600
Rugged shroud kit 1 5825900
Consumables
Electrode cleaning solution 500 mL 2965249 Electrode storage solution (3M KCl) 500 mL 2756549 Light’s solution (10 mL ampules) 20/pkg 2612520 Reducing solution for ORP electrodes 500 mL 2965349 ZoBell’s ORP standard solution 1 2316949
Accessories (continued)
Description Quantity Catalog Number
© Hach Company,2009. All rights reserved. Printed in the U.S.A. Edition 1 May 2009
Loading...