Gorilla B2320796 User Manual
Safety Data Sheet
-
Gorilla
Super
Glue
FOR CHEMICAL EMERGENCY:
Version
:
1.1
Name, Address, and Telephone
of the Responsible Party
Date Revised: 08/09/2015
Date Issued: 05/22/2015
During Business Hours: (800) 966-3458 | Outside Business Hours: (800) 420-7186
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
SECTION 1: IDENTIFICATION
Product Identifier
Product Form: Mixture
Product Name: Gorilla Super Glue
Synonyms: Ethyl Cyanoacrylate Adhesive
Intended Use of the Product
Adhesive for metal, wood, ceramics, leather, paper, most plastics and more
Company
The Gorilla Glue Company
4550 Red Bank Expressway
Cincinnati, Ohio 45227
513-271-3300
www.gorillatough.com
Emergency Telephone Number �
Emergency number : 1-800-420-7186 (Prosar) -
SECTION 2: HAZARDS IDENTIFICATION
Classification of the Substance or Mixture �
Classification (GHS-US)
Flam. Liq. 4 H227
Skin Irrit. 2 H315
Eye Irrit. 2A H319
STOT SE 3 H335
Full text of H-phrases: see section 16
Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US) :
Signal Word (GHS-US) : -Warning
Hazard Statements (GHS-US) : -H227 - Combustible liquid.
Precautionary Statements (GHS-US) : -P210 - Keep away from extremely high or low temperatures, ignition sources, and
Gorilla Super Glue SDS 08/09/2015 - Page 1 of 7
GHS07
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H335 - May cause respiratory irritation.
incompatible materials. - No smoking.
P261 - Avoid breathing vapors, mist, or spray.
P264 - Wash hands, forearms, and other exposed areas thoroughly after handling.
P271 - Use only outdoors or in a well-ventilated area.
P280 - Wear protective gloves, protective clothing, and eye protection.
P302+P352 - If on skin: Wash with plenty of water.
P304+P340 - IF INHALED: Remove person to fresh air and keep at rest in a position
comfortable for breathing.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Safety Data Sheet
-
Gorilla
Super
Glue
Version
:
1.1
FOR CHEMICAL EMERGENCY:
According to Federal Register /
Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations -
Date Revised: 08/09/2015
Date Issued: 05/22/2015
During Business Hours: (800) 966-3458 | Outside Business Hours: (800) 420-7186
P312 - Call a poison center or doctor if you feel unwell. P332+P313 - If skin irritation occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P362 - Take off contaminated clothing and wash before reuse. P370+P378 - In case of fire: Use appropriate media (see section 5) to extinguish. P233 - Keep container tightly closed. P403+P235 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. P501 - Dispose of contents/container in accordance with local, regional, national, -
Other Hazards
Other Hazards Not Contributing to the Classification: Rapid polymerization occurs upon contact with water or alkaline substances.
As a result, heat is generated. Skin inflammation or burns may occur upon contact during this polymerization. Contains
Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children.
Unknown Acute Toxicity (GHS-US)
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
Mixture �
Name Product Identifier % (w/w) Classification (GHS-US)
Ethyl cyanoacrylate (CAS No) 7085-85-0 86 - 100 Flam. Liq. 4, H227
Full text of H-phrases: see section 16
SECTION 4: FIRST AID MEASURES
Description of First Aid Measures �
General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label if possible). -
Inhalation: If inhaled, remove to fresh air and keep at rest in a position comfortable for breathing. If you feel unwell, seek medical -
advice. Skin Contact: Remove contaminated clothing. Gently wash with plenty of soap and water followed by rinsing with water for at least 15 minutes. Call a POISON CENTER or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. -
Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention. -
Ingestion: Rinse mouth. Do not induce vomiting. Immediately call a POISON CENTER or doctor/physician. -
Most Important Symptoms and Effects Both Acute and Delayed �
General: Irritation to eyes, skin and respiratory tract. -
Inhalation: May cause respiratory irritation. -
Skin Contact: Causes skin irritation. -
Eye Contact: Causes serious eye irritation. -
Ingestion: Ingestion is likely to be harmful or have adverse effects. -
Chronic Symptoms: Bonds skin and eyes in seconds. -
Indication of Any Immediate Medical Attention and Special Treatment Needed
If medical advice is needed, have product container or label at hand.
SECTION 5: FIRE FIGHTING MEASURES
Extinguishing Media �
Suitable Extinguishing Media: Dry chemical powder, alcohol-resistant foam, carbon dioxide (CO
Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire. -
-
territorial, provincial, and international regulations. -
Not available
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
STOT SE 3, H335
). -
2
Gorilla Super Glue SDS 08/09/2015 Page 2 of 7
Safety Data Sheet
-
Gorilla
Super
Glue
Version
:
1.1
FOR CHEMICAL EMERGENCY:
According to Federal Register /
Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Reference to Other Sections �
Date Revised: 08/09/2015
Date Issued: 05/22/2015
During Business Hours: (800) 966-3458 | Outside Business Hours: (800) 420-7186
Special Hazards Arising From the Substance or Mixture �
Fire Hazard: Not flammable. -
Explosion Hazard: Product is not explosive. -
Reactivity: Rapid polymerization occurs upon contact with water or alkaline substances. As a result, heat is generated. Skin
inflammation or burns may occur upon contact during this polymerization. May react with strong oxidizers, increasing risk of fire or
explosion.
Advice for Firefighters �
Precautionary Measures Fire: Exercise caution when fighting any chemical fire. -
Firefighting Instructions: Do not allow run-off from fire fighting to enter drains or water courses. -
Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. -
Hazardous Combustion Products: Irritating organic vapors may be formed. -
Refer to section 9 for flammability properties.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Do not get in eyes, on skin, or on clothing. Keep away from heat, hot surfaces, sparks, open flames, and other
ignition sources. No smoking.
For Non-Emergency Personnel �
Protective Equipment: Use appropriate personal protection equipment (PPE). -
Emergency Procedures: Evacuate unnecessary personnel. -
For Emergency Personnel �
Protective Equipment: Equip cleanup crew with proper protection. -
Emergency Procedures: Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods, -
protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit. -
Environmental Precautions
Prevent entry to sewers and public waters.
Methods and Material for Containment and Cleaning Up
For Containment: Absorb and/or contain spill with inert material, then place in suitable container. Take up in non-combustible
materials.
Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Use only non-sparking tools.
Reference to Other Sections
See heading 8, Exposure Controls and Personal Protection. Concerning disposal elimination after cleaning, see item 13.
SECTION 7: HANDLING AND STORAGE
Precautions for Safe Handling
Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas
with mild soap and water before eating, drinking, or smoking and again when leaving work.
Conditions for Safe Storage, Including Any Incompatibilities �
Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Store away from heat and -
incompatible materials. Protect from moisture. -
Incompatible Materials: Strong acids, strong bases, strong oxidizers. Water. -
Storage Temperature: 5 - 25 °C (41 - 77 °F) -
Specific End Use(s)
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Control Parameters
For substances listed in section 3 that are not listed here, there are no established Exposure limits from the manufacturer, supplier,
importer, or the appropriate advisory agency including: ACGIH (TLV), NIOSH (REL), OSHA (PEL), Canadian provincial governments, or
the Mexican government.
Gorilla Super Glue SDS 08/09/2015 Page 3 of 7
Adhesive for metal, wood, ceramics, leather, paper, most plastics and more. -
Safety Data Sheet
-
Gorilla
Super
Glue
FOR CHEMICAL EMERGENCY:
Version
:
1.1
According to Federal Register /
Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date Revised: 08/09/2015
Date Issued: 05/22/2015
During Business Hours: (800) 966-3458 | Outside Business Hours: (800) 420-7186
Ethyl cyanoacrylate (7085-85-0)
USA ACGIH ACGIH TWA (ppm) 0.2 ppm
Alberta OEL TWA (mg/m³) 1 mg/m³
Alberta OEL TWA (ppm) 0.2 ppm
British Columbia OEL TWA (ppm) 0.2 ppm
Manitoba OEL TWA (ppm) 0.2 ppm
Newfoundland & Labrador OEL TWA (ppm) 0.2 ppm
Nova Scotia OEL TWA (ppm) 0.2 ppm
Ontario OEL TWA (ppm) 0.2 ppm
Prince Edward Island OEL TWA (ppm) 0.2 ppm
Saskatchewan OEL STEL (ppm) 0.6 ppm
Saskatchewan OEL TWA (ppm) 0.2 ppm
Exposure Controls
Appropriate Engineering Controls: Emergency eye wash fountains and safety showers should be available in the immediate vicinity
of any potential exposure. Provide sufficient ventilation to keep vapors below permissible exposure limit. Ensure all national/local
regulations are observed.
Personal Protective Equipment: Protective clothing. Safety glasses. Gloves. Insufficient ventilation: wear respiratory protection.
Materials for Protective Clothing: Chemically resistant materials and fabrics. Wear fire/flame resistant/retardant clothing. -
Hand Protection: Wear chemically resistant protective gloves. -
Eye Protection: Chemical goggles or safety glasses. -
Skin and Body Protection: Wear suitable protective clothing. -
Respiratory Protection: If exposure limits are exceeded or irritation is experienced, approved respiratory protection should be worn. -
Other Information: When using, do not eat, drink or smoke. -
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on Basic Physical and Chemical Properties �
Physical State : Liquid
Appearance : White Water / Straw colored
Odor : Sharp, irritating
Odor Threshold : Not available
pH : Not applicable
Evaporation Rate : Not available
Melting Point : Not available
Freezing Point : Not available
Boiling Point : > 100 °C (212 °F)
Flash Point : > 81 °C (177.8 °F)
Auto-ignition Temperature : Not available
Decomposition Temperature : Not available
Flammability (solid, gas) : Not available
Lower Flammable Limit : Not available
Upper Flammable Limit : Not available
Vapor Pressure : < 0.5 mm Hg
Relative Vapor Density at 20 °C : Not available
Gorilla Super Glue SDS 08/09/2015 Page 4 of 7
Safety Data Sheet
-
Gorilla
Super
Glue
Version
:
1.1
FOR CHEMICAL EMERGENCY:
According to Federal Register /
Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations -
Date Revised: 08/09/2015
Date Issued: 05/22/2015
During Business Hours: (800) 966-3458 | Outside Business Hours: (800) 420-7186
Relative Density : 1.1 (water = 1) -
Specific Gravity : 1.1 -
Solubility : Immiscible in water. -
Partition Coefficient: N-Octanol/Water : Not available -
Viscosity : Not available -
Explosion Data – Sensitivity to Mechanical Impact : Not expected to present an explosion hazard due to mechanical impact. -
Explosion Data – Sensitivity to Static Discharge : Not expected to present an explosion hazard due to static discharge. -
VOC Content : < 20 g/l estimated (California SCAQMD Method 316B) -
SECTION 10: STABILITY AND REACTIVITY
Reactivity: Rapid polymerization occurs upon contact with water or alkaline substances. As a result, heat is generated. Skin -
inflammation or burns may occur upon contact during this polymerization. May react with strong oxidizers, increasing risk of fire or explosion. -
Chemical Stability: Stable under recommended handling and storage conditions (see section 7). -
Possibility of Hazardous Reactions: Hazardous polymerization will not occur. -
Conditions to Avoid: Direct sunlight. Extremely high or low temperatures. -
Incompatible Materials: Strong acids, strong bases, strong oxidizers. Water. -
Hazardous Decomposition Products: Carbon Oxides (CO and CO
SECTION 11: TOXICOLOGICAL INFORMATION
Information on Toxicological Effects - Product
Acute Toxicity: Not classified
LD50 and LC50 Data: Not available
Skin Corrosion/Irritation: Causes skin irritation.
pH: Not applicable
Serious Eye Damage/Irritation: Causes serious eye irritation.
pH: Not applicable
Respiratory or Skin Sensitization: Not classified
Germ Cell Mutagenicity: Not classified
Teratogenicity: Not available
Carcinogenicity: Not classified
Specific Target Organ Toxicity (Repeated Exposure): Not classified
Reproductive Toxicity: Not classified
Specific Target Organ Toxicity (Single Exposure): May cause respiratory irritation.
Aspiration Hazard: Not classified
Symptoms/Injuries After Inhalation: May cause respiratory irritation.
Symptoms/Injuries After Skin Contact: Causes skin irritation.
Symptoms/Injuries After Eye Contact: Causes serious eye irritation.
Symptoms/Injuries After Ingestion: Ingestion is likely to be harmful or have adverse effects.
Information on Toxicological Effects - Ingredient(s)
LD50 and LC50 Data: Estimated Oral LD50: >5000 mg/kg; Estimated Dermal LD50: >2000 mg/kg;
SECTION 12: ECOLOGICAL INFORMATION
Toxicity
Persistence and Degradability
Bioaccumulative Potential
Mobility in Soil Not available
Gorilla Super Glue SDS 08/09/2015 Page 5 of 7
) and other irritating compounds. -
2
Estimated Inhalation LC50: Vapors may be irritating.
Not classified
Not available
Not available
Safety Data Sheet
-
Gorilla
Super
Glue
Version
:
1.1
FOR CHEMICAL EMERGENCY:
According to Federal Register /
Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date Revised: 08/09/2015
Date Issued: 05/22/2015
During Business Hours: (800) 966-3458 | Outside Business Hours: (800) 420-7186
Other Adverse Effects
Other Information: Avoid release to the environment.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, provincial, territorial
and international regulations.
SECTION 14: TRANSPORT INFORMATION
In Accordance with DOT
In Accordance with IMDG
In Accordance with IATA
In Accordance with TDG
SECTION 15: REGULATORY INFORMATION
US Federal Regulations �
Gorilla Super Glue
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Ethyl cyanoacrylate (7085-85-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
US State Regulations �
Gorilla Super Glue
California Prop 65: To the best of our knowledge, this product does not contain any of the listed chemicals, which the State of
California has found to cause cancer, birth defects or reproductive harm.
Ethyl cyanoacrylate (7085-85-0)
U.S. - New Jersey - Right to Know Hazardous Substance List
Canadian Regulations �
Gorilla Super Glue
WHMIS Classification Class B Division 3 - Combustible Liquid
Not regulated for transport
Not regulated for transport
Not regulated for transport
Not regulated for transport
Class D Division 2 Subdivision B - Toxic material causing other toxic effects
Ethyl cyanoacrylate (7085-85-0)
Listed on the Canadian DSL (Domestic Substances List)
WHMIS Classification Class B Division 3 - Combustible Liquid
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS
contains all of the information required by CPR.
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Revision Date
Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA
Class D Division 2 Subdivision B - Toxic material causing other toxic effects
:
08/09/2015
Hazard Communication Standard 29 CFR 1910.1200.
GHS Full Text Phrases:
------
------
------
Gorilla Super Glue SDS 08/09/2015 Page 6 of 7
Eye Irrit. 2A Serious eye damage/eye irritation Category 2A
Flam. Liq. 4 Flammable liquids Category 4
Skin Irrit. 2 Skin corrosion/irritation Category 2
Safety Data Sheet
-
Gorilla
Super
Glue
FOR CHEMICAL EMERGENCY:
Version
:
1.1
According to Federal Register /
Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date Revised: 08/09/2015
Date Issued: 05/22/2015
During Business Hours: (800) 966-3458 | Outside Business Hours: (800) 420-7186
------
------
------
------
------
Party Responsible for the Preparation of This Document
The Gorilla Glue Company
+1 513-271-3300
STOT SE 3 Specific target organ toxicity (single exposure) Category 3
H227 Combustible liquid
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
The information presented in this Safety Data Sheet was prepared by qualified personnel and to the best of our knowledge is true and
accurate. The information and recommendations are furnished for this product with the understanding that the purchaser will
independently determine the suitability of the product for this purpose. This data does not constitute a warranty, expressed or implied,
statutory or otherwise, nor is it representation for which The Gorilla Glue Company assumes legal responsibility. The data is submitted
for the user’s information and consideration only. Any use of this product must be determined by the user to be in accordance with
applicable federal, state, provincial and local laws and regulations.
North America GHS US 2012 & WHMIS 2 GG
Gorilla Super Glue SDS 08/09/2015 Page 7 of 7
Loading...