During Business Hours: (800) 966-3458 | Outside Business Hours: (800) 420-7186
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
SECTION 1: IDENTIFICATION
Product Identifier
Product Name: Gorilla Glue White
Synonyms: Polyurethane Adhesive
Intended Use of the Product
Consumer Adhesives for building, carpentry, or hobby projects.
Company
The Gorilla Glue Company
4550 Red Bank Expressway
Cincinnati, Ohio 45227
513-271-3300
www.gorillatough.com
Emergency Telephone Number �
Emergency number : 1-800-420-7186 (Prosar) -
SECTION 2: HAZARDS IDENTIFICATION
Classification of the Substance or Mixture �
Classification (GHS-US)
Acute Tox. 4 (Inhalation:dust,mist) H332
Skin Irrit. 2 H315
Eye Irrit. 2B H320
Resp. Sens. 1 H334
Skin Sens. 1 H317
STOT SE 3 H335
STOT RE 1 H372
Full text of H-phrases: see section 16
Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US) :
Signal Word (GHS-US) : -Danger
Hazard Statements (GHS-US) : -H315 - Causes skin irritation.
Precautionary Statements (GHS-US) : -P260 - Do not breathe vapors, mist, or spray.
Gorilla Glue White SDS 07/09/2015 -Page 1 of 9
GHS07 GHS08
H317 - May cause an allergic skin reaction.
H320 - Causes eye irritation.
H332 - Harmful if inhaled.
H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 - May cause respiratory irritation.
H372 - Causes damage to organs through prolonged or repeated exposure.
P264 - Wash hands, forearms, and other exposed areas thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P271 - Use only outdoors or in a well-ventilated area.
P272 - Contaminated work clothing must not be allowed out of the workplace.
P280 - Wear protective gloves, protective clothing, and eye protection.
Safety Data Sheet
-
Gorilla
Glue
White
Version
:
1.0
FOR CHEMICAL EMERGENCY:
According to Federal Register /
Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations-
Date Revised: 07/09/2015
Date Issued: 07/09/2015
During Business Hours: (800) 966-3458 | Outside Business Hours: (800) 420-7186
P284 - [In case of inadequate ventilation] wear respiratory protection. P302+P352 – IF ON SKIN: Wash with plenty of water. P304+P340 – IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 - Call a poison center or doctor if you feel unwell. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P342+P311 - If experiencing respiratory symptoms: Call a poison center or doctor. P362+P364 - Take off contaminated clothing and wash it before reuse. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up. P501 - Dispose of contents/container in accordance with local, regional, national, -
Other Hazards
Other Hazards: Contains isocyanates. May produce an allergic reaction.
Unknown Acute Toxicity (GHS-US)
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
Mixture �
Name Product Identifier % (w/w) Classification (GHS-US)
Aromatic Polyisocyanate based on MDI (CAS No) 167883-19-4 60 - 100 Acute Tox. 4 (Inhalation:dust,mist), H332
General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label if possible). -
Inhalation: Using proper respiratory protection, immediately move the exposed person to fresh air. Seek medical attention -
immediately. -
Gorilla Glue White SDS /09/2015 Page 2 of 9
territorial, provincial, and international regulations. -
Not available
Skin Irrit. 2, H315
Eye Irrit. 2B, H320
Resp. Sens. 1, H334
Skin Sens. 1, H317
STOT SE 3, H335
STOT RE 1, H372
Skin Irrit. 2, H315
Eye Irrit. 2B, H320
Resp. Sens. 1, H334
Skin Sens. 1, H317
STOT SE 3, H335
STOT RE 1, H372
Skin Irrit. 2, H315
Eye Irrit. 2B, H320
Resp. Sens. 1, H334
Skin Sens. 1, H317
STOT SE 3, H335
STOT RE 1, H372
⫺
Safety Data Sheet
-
Gorilla
Glue
White
Version
:
1.0
FOR CHEMICAL EMERGENCY:
According to Federal Register /
Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Reference to Other Sections�
Date Revised: 07/09/2015
Date Issued: 07/09/2015
During Business Hours: (800) 966-3458 | Outside Business Hours: (800) 420-7186
Skin Contact: Remove contaminated clothing. Gently wash with plenty of soap and water followed by rinsing with water for at least
15 minutes. Call a POISON CENTER or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. -
Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention. -
Ingestion: Rinse mouth. Do not induce vomiting. Immediately call a POISON CENTER or doctor/physician. -
Most Important Symptoms and Effects Both Acute and Delayed �
General: Harmful if inhaled. Exposure may produce an allergic reaction. Inhalation may cause allergic respiratory reaction with -
asthma-like symptoms and difficulty breathing. Causes skin irritation. Causes serious eye irritation. Inhalation: May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. Harmful if -
inhaled. -
Skin Contact: Exposure may produce an allergic reaction. Causes skin irritation. -
Eye Contact: Causes eye irritation. -
Ingestion: Ingestion is likely to be harmful or have adverse effects. -
Chronic Symptoms: Causes damage to organs through prolonged or repeated exposure. -
Indication of Any Immediate Medical Attention and Special Treatment Needed �
If medical advice is needed, have product container or label at hand.
SECTION 5: FIRE FIGHTING MEASURES
Extinguishing Media �
Suitable Extinguishing Media: Carbon dioxide, dry powder, and foam. In cases of large scale fires, alcohol-resistant foams are -
preferred. If water is used, it should be used in very large quantities. The reaction between water and isocyanate may be vigorous. -
Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire. -
Special Hazards Arising From the Substance or Mixture �
Fire Hazard: Not flammable. -
Explosion Hazard: Product is not explosive. -
Reactivity: Exothermic reactions with amines and alcohols; reacts with water forming heat, carbon dioxide, and insoluble polyurea. -
The combined effect of CO
Advice for Firefighters �
Precautionary Measures Fire: Exercise caution when fighting any chemical fire. -
Firefighting Instructions: Do not allow run-off from fire fighting to enter drains or water courses. -
Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. -
Hazardous Combustion Products: Carbon oxides (CO, CO
-
and heat can produce enough pressure to rupture a closed container. -
2
). Nitrogen compounds. Dense black smoke, isocyanate, isocyanic acid. -
2
Refer to section 9 for flammability properties.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Do not get in eyes, on skin, or on clothing.
For Non-Emergency Personnel
Protective Equipment: Use appropriate personal protection equipment (PPE).
Emergency Procedures: Evacuate unnecessary personnel.
For Emergency Personnel
Protective Equipment: Equip cleanup crew with proper protection.
Emergency Procedures: Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods,
protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit.
Environmental Precautions
Prevent entry to sewers and public waters.
Methods and Material for Containment and Cleaning Up
For Containment: Absorb and/or contain spill with inert material, then place in suitable container.
Gorilla Glue White SDS 07/09/2015 Page 3 of 9
Safety Data Sheet
-
Gorilla
Glue
White
Version
:
1.0
FOR CHEMICAL EMERGENCY:
According to Federal Register /
Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations-
Date Revised: 07/09/2015
Date Issued: 07/09/2015
During Business Hours: (800) 966-3458 | Outside Business Hours: (800) 420-7186
Methods for Cleaning Up: Remove mechanically; cover remainders with wet absorbent material (e. g. sand, earth, sawdust). After approx. 15 min. transfer to waste container and do not seal (evolution of CO
Clean up spills immediately and dispose of waste safely. -
Reference to Other Sections
See heading 8, Exposure Controls and Personal Protection. Concerning disposal elimination after cleaning, see item 13.
SECTION 7: HANDLING AND STORAGE
Precautions for Safe Handling
Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas
with mild soap and water before eating, drinking, or smoking and again when leaving work.
Conditions for Safe Storage, Including Any Incompatibilities �
Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Store away from -
incompatible materials. Keep product away from sources of alcohols, amines, or other materials that react with isocyanates. Keep out of reach of children and animals. -
Consumer Adhesives for building, carpentry, or hobby projects.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Control Parameters
For substances listed in section 3 that are not listed here, there are no established Exposure limits from the manufacturer, supplier,
importer, or the appropriate advisory agency including: ACGIH (TLV), NIOSH (REL), OSHA (PEL), Canadian provincial governments, or
the Mexican government.
4,4’-Diphenylmethane Diisocyanate (MDI)
USA ACGIH ACGIH TWA (ppm) 0.005 ppm
USA OSHA OSHA PEL (Ceiling) (mg/m³) 0.2 mg/m³
USA OSHA OSHA PEL (Ceiling) (ppm) 0.02 ppm
USA NIOSH NIOSH REL (TWA) (mg/m³) 0.05 mg/m³
USA NIOSH NIOSH REL (TWA) (ppm) 0.005 ppm
USA NIOSH NIOSH REL (ceiling) (mg/m³) 0.2 mg/m³
USA NIOSH NIOSH REL (ceiling) (ppm) 0.020 ppm
USA IDLH US IDLH (mg/m³) 75 mg/m³
Alberta OEL TWA (mg/m³) 0.05 mg/m³
Alberta OEL TWA (ppm) 0.005 ppm
British Columbia OEL Ceiling (ppm) 0.01 ppm
British Columbia OEL TWA (ppm) 0.005 ppm
Manitoba OEL TWA (ppm) 0.005 ppm
New Brunswick OEL TWA (mg/m³) 0.051 mg/m³
New Brunswick OEL TWA (ppm) 0.005 ppm
Newfoundland & Labrador OEL TWA (ppm) 0.005 ppm
Nova Scotia OEL TWA (ppm) 0.005 ppm
Ontario OEL Ceiling (ppm) 0.02 ppm (designated substances regulation)
Ontario OEL TWA (ppm) 0.005 ppm (designated substances regulation)
Prince Edward Island OEL TWA (ppm) 0.005 ppm
Québec VEMP (mg/m³) 0.051 mg/m³
Québec VEMP (ppm) 0.005 ppm
Saskatchewan OEL STEL (ppm) 0.015 ppm
Gorilla Glue White SDS 07/09/2015 Page 4 of 9
). Keep damp in a safe ventilated area for several days. -
2
0.005 ppm (applies to workplaces to which the designated
substances regulation does not apply)
Safety Data Sheet
-
Gorilla
Glue
White
FOR CHEMICAL EMERGENCY:
Version
:
1.0
According to Federal Register /
Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date Revised: 07/09/2015
Date Issued: 07/09/2015
During Business Hours: (800) 966-3458 | Outside Business Hours: (800) 420-7186
Appropriate Engineering Controls: Emergency eye wash fountains and safety showers should be available in the immediate vicinity
of any potential exposure. Provide sufficient ventilation to keep vapors below permissible exposure limit. Ensure all national/local
regulations are observed.
Materials for Protective Clothing: Chemically resistant materials and fabrics.
Hand Protection: Wear chemically resistant protective gloves.
Eye Protection: Chemical goggles or safety glasses.
Skin and Body Protection: Wear suitable protective clothing.
Respiratory Protection: Use a NIOSH-approved respirator or self-contained breathing apparatus whenever exposure may exceed
established Occupational Exposure Limits.
Other Information: When using, do not eat, drink or smoke.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on Basic Physical and Chemical Properties �
Physical State : Liquid
Appearance : Clear/Transparent/Yellowish
Odor : Musty
Odor Threshold : Not available
pH : Not applicable
Evaporation Rate : Not available
Melting Point : Not available
Freezing Point : Not available
Boiling Point : > 300 °C (572 °F)
Flash Point : 198 °C (388.4 °F) @ 1,013 mbar
Auto-ignition Temperature : Not available
Decomposition Temperature : Not available
Flammability (solid, gas) : Not available
Lower Flammable Limit : Not available
Upper Flammable Limit : Not available
Vapor Pressure : < 0.0001 mm Hg @ 25 °C (77 °F)
Relative Vapor Density at 20 °C : Not available
Relative Density : 1.123 g/cm³
Specific gravity / density : 1.123 g/cm³
Solubility : Insoluble in water.
Partition Coefficient: N-Octanol/Water : Not available
Viscosity : 3800 - 6000 mPa.s at 25 °C (77 °F)
Explosion Data – Sensitivity to Mechanical Impact : Not expected to present an explosion hazard due to mechanical impact.
Explosion Data – Sensitivity to Static Discharge : Not expected to present an explosion hazard due to static discharge.
Gorilla Glue White SDS 07/09/2015 Page 5 of 9
Safety Data Sheet
-
Gorilla
Glue
White
FOR CHEMICAL EMERGENCY:
Version
:
1.0
According to Federal Register /
Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date Revised: 07/09/2015
Date Issued: 07/09/2015
During Business Hours: (800) 966-3458 | Outside Business Hours: (800) 420-7186
SECTION 10: STABILITY AND REACTIVITY
Reactivity: Exothermic reactions with amines and alcohols; reacts with water forming heat, carbon dioxide, and insoluble polyurea. -
The combined effect of CO
Chemical Stability: Stable under recommended handling and storage conditions (see section 7). -
Possibility of Hazardous Reactions: Contact with moisture, other materials that react with isocyanates, or temperatures above -
350°F (177°C) may cause polymerization. -
Conditions to Avoid: Direct sunlight. Extremely high or low temperatures. -
Incompatible Materials: Strong acids, strong bases, strong oxidizers. Acids. Alcohols. Water, Copper Alloys. -
Hazardous Decomposition Products: Carbon oxides (CO, CO
SECTION 11: TOXICOLOGICAL INFORMATION
Information on Toxicological Effects - Product
Acute Toxicity: Inhalation:dust,mist: Harmful if inhaled.
LD50 and LC50 Data:
Gorilla Glue White
ATE US (dust, mist) 1.50 mg/l/4h
Skin Corrosion/Irritation: Causes skin irritation.
pH: Not applicable -
Respiratory or Skin Sensitization: May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic -
skin reaction. -
Germ Cell Mutagenicity: Not classified -
Teratogenicity: Not available -
Carcinogenicity: Not classified -
Specific Target Organ Toxicity (Repeated Exposure): Causes damage to organs through prolonged or repeated exposure. -
Reproductive Toxicity: Not classified
Specific Target Organ Toxicity (Single Exposure): May cause respiratory irritation.
Aspiration Hazard: Not classified
Symptoms/Injuries After Inhalation: May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause -
respiratory irritation. Harmful if inhaled. -
Symptoms/Injuries After Skin Contact: Exposure may produce an allergic reaction. Causes skin irritation. -
Symptoms/Injuries After Eye Contact: Causes eye irritation. -
Symptoms/Injuries After Ingestion: Ingestion is likely to be harmful or have adverse effects. -
Chronic Symptoms: Causes damage to organs through prolonged or repeated exposure. -
Information on Toxicological Effects - Ingredient(s) �
LD50 and LC50 Data: �
Aromatic Polyisocyanate based on MDI (167883-19-4)
ATE US (dust, mist) 1.50 mg/l/4h
4,4’-Diphenylmethane Diisocyanate (MDI) (101-68-8)
LD50 Oral Rat 31600 mg/kg
LD50 Dermal Rabbit > 9400 mg/kg
LC50 Inhalation Rat 369 mg/m³ (Exposure time: 4 h)
ATE US (dust, mist) 0.37 mg/l/4h
2,4’-Diphenylmethane Diisocyanate (MDI) (5873-54-1)
and heat can produce enough pressure to rupture a closed container. -
2
). Nitrogen compounds. Isocyanates. Dense black smoke. -
2
Safety Data Sheet
-
Gorilla
Glue
White
FOR CHEMICAL EMERGENCY:
Version
:
1.0
According to Federal Register /
Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date Revised: 07/09/2015
Date Issued: 07/09/2015
During Business Hours: (800) 966-3458 | Outside Business Hours: (800) 420-7186
ATE US (dust, mist) 1.50 mg/l/4h
4,4’-Diphenylmethane Diisocyanate (MDI) (101-68-8)
IARC Group 3
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity data based on polymeric MDI (a mixture of monomers and higher molecular weight oligomers).
Toxicity
Persistence and Degradability
Gorilla Glue White
Biodegradation 0 % after 28 days
Bioaccumulative Potential
Mobility in Soil Not available
Other Adverse Effects
Other Information: Avoid release to the environment.
SECTION 13: DISPOSAL CONSIDERATIONS
Sewage Disposal Recommendations: Do not dispose of waste into sewer. -
Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, provincial, territorial -
and international regulations. -
SECTION 14: TRANSPORT INFORMATION
In Accordance with DOT
In Accordance with IMDG
In Accordance with IATA
In Accordance with TDG
SECTION 15: REGULATORY INFORMATION
US Federal Regulations �
Gorilla Glue White
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Aromatic Polyisocyanate based on MDI (167883-19-4)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Listed on United States SARA Section 313
US EPA CERCLA Hazardous substance component (40 CFR 302), Reportable quantity: 5000 lbs
Listed on the United States TSCA (Toxic Substances Control Act) inventory
US State Regulations �
Gorilla Glue White
This product contains a trace (ppm) amount of phenyl isocyanate (CAS # 103-71-9) and monochlorobenzene (CAS # 108-90-7) as
impurities.
California Prop 65: To the best of our knowledge, this product does not contain any of the listed chemicals, which the State of
California has found to cause cancer, birth defects or reproductive harm.
Listed on the Canadian DSL (Domestic Substances List)
Listed on the Canadian IDL (Ingredient Disclosure List)
IDL Concentration 0.1 %
WHMIS Classification Class D Division 2 Subdivision A - Very toxic material causing other toxic effects
Listed on the Canadian DSL (Domestic Substances List)
WHMIS Classification Class D Division 2 Subdivision A - Very toxic material causing other toxic effects
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS
contains all of the information required by CPR.
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Revision Date
Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA
GHS Full Text Phrases:
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Gorilla Glue White SDS 07/09/2015 Page 8 of 9
Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4
Eye Irrit. 2B Serious eye damage/eye irritation Category 2B
Resp. Sens. 1 Respiratory sensitisation Category 1
Skin Irrit. 2 Skin corrosion/irritation Category 2
Skin Sens. 1 Skin sensitization Category 1
STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1
STOT SE 3 Specific target organ toxicity (single exposure) Category 3
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H320 Causes eye irritation
H332 Harmful if inhaled
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335 May cause respiratory irritation
H372 Causes damage to organs through prolonged or repeated exposure
Class D Division 2 Subdivision B - Toxic material causing other toxic effects
Class D Division 2 Subdivision B - Toxic material causing other toxic effects
Class D Division 1 Subdivision A - Very toxic material causing immediate and serious toxic effects
:
07/09/2015
Hazard Communication Standard 29 CFR 1910.1200.
Safety Data Sheet
-
Gorilla
Glue
White
Version
:
1.0
FOR CHEMICAL EMERGENCY:
According to Federal Register /
Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date Revised: 07/09/2015
Date Issued: 07/09/2015
During Business Hours: (800) 966-3458 | Outside Business Hours: (800) 420-7186
Party Responsible for the Preparation of This Document
The Gorilla Glue Company
+1 513-271-3300
The information presented in this Safety Data Sheet was prepared by qualified personnel and to the best of our knowledge is true and
accurate. The information and recommendations are furnished for this product with the understanding that the purchaser will
independently determine the suitability of the product for this purpose. This data does not constitute a warranty, expressed or implied,
statutory or otherwise, nor is it representation for which The Gorilla Glue Company assumes legal responsibility. The data is submitted
for the user’s information and consideration only. Any use of this product must be determined by the user to be in accordance with
applicable federal, state, provincial and local laws and regulations.
Gorilla Glue NA GHS SDS
Gorilla Glue White SDS 07/09/2015 Page 9 of 9
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