Goop 32 User Manual

SAFETY DATA SHEET

Issuing Date 07-Jun-2012

Revision Date 29-Jul-2015

Revision Number 1

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The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representations or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this information or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved.

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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product identifier

Product Name

Mom’s Magical Goop

Other means of identification

Synonyms

Item #34

Recommended use of the chemical and restrictions on use

Recommended Use

Spot Remover

Uses advised against

No information available

Details of the supplier of the safety data sheet

Supplier Name

CRITZAS INDUSTRIES, INC.

Supplier Address

4041 PARK AVENUE ST. LOUIS MO 63110 US

Supplier Phone Number

Phone:314-7738510 Fax:314-773-4837 Contact Phone314-773-8510

Supplier Email

[email protected]

Emergency telephone number

2. HAZARDS IDENTIFICATION

Classification

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).

Serious eye damage/eye irritation

Category 1

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Skin sensitization

Category 1

GHS Label elements, including precautionary statements

Emergency Overview

Signal word

Danger

Hazard Statements

Causes serious eye damage May cause an allergic skin reaction

.

Appearance White

Physical state Solid Gel Consistency

Paste / Gel Liquid

Odor Sweet

Precautionary Statements - Prevention

Wear protective gloves/protective clothing/eye protection/face protection Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace

Precautionary Statements - Response

Specific treatment (see supplemental first aid instructions on this label)

Eyes

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician

Skin

IF ON SKIN: Wash with plenty of soap and water If skin irritation or rash occurs: Get medical advice/attention Wash contaminated clothing before reuse

Precautionary Statements - Storage

None

Precautionary Statements - Disposal

Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC)

Not applicable

Unknown Toxicity

5.6% of the mixture consists of ingredient(s) of unknown toxicity

Other information

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Causes mild skin irritation Repeated or prolonged skin contact may cause allergic reactions with susceptible persons

Interactions with Other Chemicals

Irritants. Sensitizers. Epoxies.

3. COMPOSITION/INFORMATION ON INGREDIENTS

.

Chemical Name

CAS No

Weight-%

Trade Secret

Petroleum distillates, hydrotreated light

64742-47-8

30 - 60

*

Oleic acid

112-80-1

3 - 7

*

Alcohols, C10-16, ethoxylated

68002-97-1

3 - 7

*

Triethanolamine

102-71-6

1 - 5

*

Glycerin

56-81-5

1 - 5

*

*The exact percentage (concentration) of composition has been withheld as a trade secret

4. FIRST AID MEASURES

First aid measures

General Advice

Immediate medical attention is required. Show this safety data sheet to the doctor in attendance.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Do not rub affected area. Seek immediate medical attention/advice.

Skin contact

Wash off immediately with soap and plenty of water for at least 15 minutes. May cause an allergic skin reaction. In the case of skin irritation or allergic reactions see a physician.

Inhalation

Remove to fresh air. Get medical attention immediately if symptoms occur.

Ingestion

Rinse mouth immediately and drink plenty of water. Never give anything by mouth to an unconscious person. Do NOT induce vomiting. Call a physician.

Self-protection of the first aider

Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Wear personal protective clothing (see section 8).

Most important symptoms and effects, both acute and delayed

Most Important Symptoms and Effects

Burning sensation. Itching. Rashes. Hives.

Indication of any immediate medical attention and special treatment needed Notes to Physician

May cause sensitization of susceptible persons. Treat symptomatically.

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5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media

CAUTION: Use of water spray when fighting fire may be inefficient.

Specific hazards arising from the chemical

Thermal decomposition can lead to release of irritating gases and vapors. In the event of fire and/or explosion do not breathe fumes. May cause sensitization by inhalation and skin contact. Product is or contains a sensitizer. May cause sensitization by skin contact.

Uniform Fire Code

Irritant: Liquid

Hazardous Combustion Products

Carbon oxides.

Explosion Data

Sensitivity to Mechanical Impact

No.

Sensitivity to Static Discharge

No.

Protective equipment and precautions for firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions

Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Ensure adequate ventilation.

Other Information

Refer to protective measures listed in Sections 7 and 8.

Environmental precautions

Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage if safe to do so.

Methods and material for containment and cleaning up Methods for containment

Prevent further leakage or spillage if safe to do so.

Methods for cleaning up

Soak up with inert absorbent material. Pick up and transfer to properly labeled containers.

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7. HANDLING AND STORAGE

Precautions for safe handling

Handling

Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash before reuse.

Conditions for safe storage, including any incompatibilities

Storage

Keep containers tightly closed in a dry, cool and well-ventilated place. Store locked up. Keep out of the reach of children. Protect from moisture. Store away from other materials.

Incompatible Products

Strong oxidizing agents. Strong acids. Strong bases.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters Exposure Guidelines

Chemical Name

ACGIH TLV

OSHA PEL

NIOSH IDLH

Petroleum distillates, hydrotreated light

64742-47-8

TWA: 5 mg/m3

STEL: 10 mg/m3

(as oil mist)

TWA: 5 mg/m3

(as oil mist)

Triethanolamine

102-71-6

TWA: 5 mg/m3

-

Glycerin

56-81-5

TWA: 10 mg/m3 mist

TWA: 15 mg/m3 mist, total

particulate

TWA: 5 mg/m3 mist, respirable

fraction

(vacated) TWA: 10 mg/m3 mist,

total particulate

(vacated) TWA: 5 mg/m3 mist,

respirable fraction

ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits NIOSH IDLH Immediately Dangerous to Life or Health

Other Exposure Guidelines

Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992) See section 15 for national exposure control parameters

Appropriate engineering controls

Engineering Measures

Showers Eyewash stations Ventilation systems

Individual protection measures, such as personal protective equipment Eye/face protection

Tight sealing safety goggles.

Skin and body protection

Wear protective gloves and protective clothing.

Respiratory protection

No protective equipment is needed under normal use conditions. If exposure limits are

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exceeded or irritation is experienced, ventilation and evacuation may be required.

Hygiene Measures

Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do not eat, drink or smoke when using this product.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical and Chemical Properties Physical state

Solid Gel Consistency, Paste / Gel, Liquid

Appearance

White

Odor

Sweet

Color

No information available

Odor Threshold

No information available

Property

Values

Remarks Method

pH

7

None known

Melting / freezing point

No data available

None known

Boiling point / boiling range

No data available

None known

Flash Point

No data available

None known

Evaporation Rate

No data available

None known

Flammability (solid, gas)

No data available

None known

Flammability Limit in Air

Upper flammability limit

No data available

Lower flammability limit

No data available

Vapor pressure

No data available

None known

Vapor density

No data available

None known

Specific Gravity

.90

None known

Water Solubility

Soluble in water

None known

Solubility in other solvents

No data available

None known

Partition coefficient: n-octanol/water

No data available

None known

Autoignition temperature

No data available

None known

Decomposition temperature

No data available

None known

Kinematic viscosity

No data available

None known

Dynamic viscosity

No data available

None known

Explosive properties

No data available

Oxidizing properties

No data available

Other Information Softening Point

No data available

VOC Content (%)

No data available

Particle Size

No data available

Particle Size Distribution

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10. STABILITY AND REACTIVITY

Reactivity

No data available.

Chemical stability

Stable under recommended storage conditions.

Possibility of Hazardous Reactions

None under normal processing.

Hazardous Polymerization

Hazardous polymerization does not occur.

Conditions to avoid

None known based on information supplied.

Incompatible materials

Strong oxidizing agents. Strong acids. Strong bases.

Hazardous Decomposition Products

Carbon oxides.

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure Product Information

.

Inhalation

Specific test data for the substance or mixture is not available. May cause irritation of respiratory tract.

Eye contact

Specific test data for the substance or mixture is not available. Causes serious eye damage. (based on components). Severely irritating to eyes. May cause irreversible damage to eyes.

Skin contact

Specific test data for the substance or mixture is not available. May cause irritation. Prolonged contact may cause redness and irritation. Repeated exposure may cause skin dryness or cracking.

Ingestion

Specific test data for the substance or mixture is not available. Ingestion may cause irritation to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Component Information

Chemical Name

Oral LD50

Dermal LD50

Inhalation LC50

Petroleum distillates, hydrotreated light 64742-47-8

> 5000 mg/kg ( Rat )

> 2000 mg/kg ( Rabbit )

> 5.2 mg/L ( Rat ) 4 h Oleic acid 112-80-1

> 5000 mg/kg ( Rat )

-

Triethanolamine 102-71-6

= 4190 mg/kg ( Rat )

> 20 mL/kg ( Rabbit )

-

Glycerin 56-81-5

-

> 10 g/kg ( Rabbit )

-

Information on toxicological effects Symptoms

Erythema (skin redness). May cause blindness. Burning. Itching. Rashes. Hives.

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Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization

May cause sensitization of susceptible persons. May cause sensitization by skin contact.

Mutagenic Effects

No information available.

Carcinogenicity

The table below indicates whether each agency has listed any ingredient as a carcinogen.

Chemical Name

ACGIH

IARC

NTP

OSHA

Triethanolamine 102-71-6

Group 3

IARC (International Agency for Research on Cancer)

Group 3 - Not Classifiable as to Carcinogenicity in Humans

Reproductive toxicity

No information available.

STOT - single exposure

No information available.

STOT - repeated exposure

No information available.

Chronic Toxicity

No known effect based on information supplied.

Target Organ Effects

Eyes. Skin. Respiratory system.

Aspiration Hazard

No information available.

Numerical measures of toxicity Product Information

The following values are calculated based on chapter 3.1 of the GHS document

ATEmix (oral)

8,375.00 mg/kg

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12. ECOLOGICAL INFORMATION

Ecotoxicity

The environmental impact of this product has not been fully investigated.

Chemical Name

Toxicity to Algae

Toxicity to Fish

Toxicity to Microorganisms

Daphnia Magna (Water

Flea)

Petroleum distillates,

hydrotreated light

64742-47-8

96h LC50: = 2.2 mg/L

(Lepomis macrochirus) 96h

LC50: = 2.4 mg/L

(Oncorhynchus mykiss) 96h

LC50: = 45 mg/L

(Pimephales promelas)

96h LC50: = 4720 mg/L

Oleic acid 112-80-1

96h LC50: = 205 mg/L

(Pimephales promelas)

Triethanolamine

102-71-6

96h EC50: = 169 mg/L

(Desmodesmus subspicatus)

72h EC50: = 216 mg/L

(Desmodesmus subspicatus)

96h LC50: 10600 - 13000

mg/L (Pimephales promelas)

96h LC50: > 1000 mg/L

(Pimephales promelas) 96h

LC50: 450 - 1000 mg/L

(Lepomis macrochirus)

24h EC50: = 1386 mg/L

Glycerin

56-81-5

96h LC50: 51 - 57 mL/L

(Oncorhynchus mykiss)

24h EC50: > 500 mg/L

Persistence and Degradability

No information available.

Bioaccumulation

Chemical Name

Log Pow

Triethanolamine

102-71-6

-2.53

Glycerin

56-81-5

-1.76

Other adverse effects

No information available.

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Disposal methods

This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements.

Contaminated Packaging

Dispose of contents/containers in accordance with local regulations.

California Hazardous Waste Codes

561

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14. TRANSPORT INFORMATION

DOT

NOT REGULATED

Proper Shipping Name

NON REGULATED

Hazard Class

N/A

TDG

Not regulated

MEX

Not regulated

ICAO

Not regulated

IATA

Not regulated

Proper Shipping Name

NON REGULATED

Hazard Class

N/A

IMDG/IMO

Not regulated

Hazard Class

N/A

RID

Not regulated

ADR

Not regulated

ADN

Not regulated

15. REGULATORY INFORMATION

International Inventories

TSCA

Complies

DSL

All components are listed either on the DSL or NDSL.

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory

DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List

US Federal Regulations

SARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

SARA 311/312 Hazard Categories

Acute Health Hazard

Yes

Chronic Health Hazard

No

Fire Hazard

No

Sudden release of pressure hazard

No

Reactive Hazard

No

CWA (Clean Water Act)

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR

122.42)

CERCLA

This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and

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Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material

US State Regulations

California Proposition 65

This product does not contain any Proposition 65 chemicals.

U.S. State Right-to-Know Regulations

.

Chemical Name

New Jersey

Massachusetts

Pennsylvania

Rhode Island

Illinois

Oleic acid 112-80-1

X

Triethanolamine

102-71-6

X

Glycerin

56-81-5

X

International Regulations

Mexico

National occupational exposure limits

Component

Carcinogen Status

Exposure Limits

Glycerin

56-81-5 ( 1 - 5 )

-

10mg/m3 (mist) TWA

Mexico - Occupational Exposure Limits - Carcinogens

Canada

WHMIS Hazard Class

Not determined

16. OTHER INFORMATION

NFPA

Health Hazards 2

Flammability 0

Instability 0

Physical and Chemical Hazards -

HMIS

Health Hazards 3

Flammability 0

Physical Hazard 0

Personal Protection

X

Prepared By

Product Stewardship 23 British American Blvd. Latham, NY 12110 1-800-572-6501

Issuing Date

07-Jun-2012

Revision Date

29-Jul-2015

Revision Note

No information available

Disclaimer

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text

End of Safety Data Sheet

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