GoJo 1912-02, 8812-03 User Manual

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SAFETY DATA SHEET
GOJO® Antibacterial Plum Foam Handwash
Version 1.0
Revision Date: 02/24/2017
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SECTION 1. IDENTIFICATION
Product name
:
GOJO® Antibacterial Plum Foam Handwash
Manufacturer or supplier's details
Company name of supplier
:
GOJO Industries, Inc.
Address
:
One GOJO Plaza, Suite 500 Akron, Ohio 44311
Telephone
:
1 (330) 255-6000
Emergency telephone number
:
1-800-424-9300 CHEMTREC
Recommended use of the chemical and restrictions on use
Recommended use
:
Human hygiene biocidal products
Restrictions on use
:
This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet.
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
Eye irritation
:
Category 2A
GHS label elements
Hazard pictograms
:
Signal word
:
Warning
Hazard statements
:
H319 Causes serious eye irritation. Precautionary statements
:
Prevention:
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P280 Wear eye protection/ face protection.
Response:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
Chemical name
CAS-No.
Concentration (%)
Propylene Glycol
57-55-6
>= 1
- < 5
Glycerin
56-81-5
>= 1
- < 5
Cocamidopropyl Betaine
61789-40-0
>= 1
- < 5
Benzalkonium Chloride
68391-01-5
>= 0.25
- < 1
SECTION 4. FIRST AID MEASURES
General advice
:
In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice.
If inhaled
:
If inhaled, remove to fresh air. If symptoms persist, call a physician.
In case of skin contact
:
Wash with water and soap as a precaution. Get medical attention if irritation develops and persists.
In case of eye contact
:
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Seek medical advice.
If swallowed
:
If swallowed, DO NOT induce vomiting. Rinse mouth with water. Obtain medical attention.
Most important symptoms and effects, both acute and delayed
:
Causes serious eye irritation. Protection of first-aiders
:
First Aid responders should pay attention to self-protection and use the recommended protective clothing
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media
:
Use water spray, alcohol-resistant foam, dry chemical or
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carbon dioxide.
Unsuitable extinguishing media
:
None known.
Hazardous combustion products
:
Carbon oxides Nitrogen oxides (NOx)
Specific extinguishing methods
:
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers.
Further information
:
Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Special protective equipment for firefighters
:
In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
:
Use personal protective equipment. Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Material can create slippery conditions.
Environmental precautions
:
Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.
Methods and materials for containment and cleaning up
:
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Keep in suitable, closed containers for disposal. Clean contaminated floors and objects thoroughly while observing environmental regulations.
SECTION 7. HANDLING AND STORAGE
Advice on safe handling
:
For personal protection see section 8. Do not swallow. Avoid contact with eyes. Keep container closed when not in use.
Conditions for safe storage
:
Keep in properly labelled containers. Keep tightly closed in a dry, cool and well-ventilated place. Store in accordance with the particular national regulations.
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SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components
CAS-No.
Value type (Form of exposure)
Control parameters / Permissible concentration
Basis
Propylene Glycol
57-55-6
TWA
10 mg/m3
US WEEL
Glycerin
56-81-5
TWA (mist, respirable fraction)
5 mg/m3
OSHA Z-1 TWA (mist, total dust)
15 mg/m3
OSHA Z-1
Personal protective equipment
Respiratory protection
:
No personal respiratory protective equipment normally required.
Eye protection
:
No special measures necessary provided product is used correctly. Wear face-shield and protective suit for abnormal processing problems.
Skin and body protection
:
No special measures necessary provided product is used correctly.
Protective measures
:
Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place. Ensure that eye flushing systems and safety showers are located close to the working place.
Hygiene measures
:
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
:
liquid
Colour
:
clear, purple
Odour
:
citrus, floral
Odour Threshold
:
No data available
pH :
5.0 - 7.0, (20 °C)
Melting point/freezing point
:
No data available
Boiling point/boiling range
:
99 °C Flash point
:
> 100 °C
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Evaporation rate
:
No data available
Flammability (solid, gas)
:
Not applicable
Upper explosion limit
:
No data available
Lower explosion limit
:
No data available
Vapour pressure
:
No data available
Relative vapour density
:
No data available
Density
:
1.007 g/cm3
Solubility(ies)
Water solubility
:
soluble
Partition coefficient: n­octanol/water
:
Not applicable Auto-ignition temperature
:
not determined
Thermal decomposition
:
The substance or mixture is not classified self-reactive.
Viscosity
Viscosity, kinematic
:
75 mm2/s (20 °C) Explosive properties
:
Not explosive
Oxidizing properties
:
The substance or mixture is not classified as oxidizing.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
:
Stable under recommended storage conditions. Not classified as a reactivity hazard.
Chemical stability
:
No decomposition if stored and applied as directed. Stable under normal conditions.
Incompatible materials
:
Oxidizing agents
Hazardous decomposition products
:
No hazardous decomposition products are known.
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation Eye contact Skin contact
Acute toxicity
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Not classified based on available information.
Components:
Propylene Glycol:
Acute oral toxicity
:
LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity
:
LC50 (Rabbit): > 159 mg/l, > 51091 ppm Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity
Acute dermal toxicity
:
LD50 (Rabbit): > 2,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity
Glycerin:
Acute oral toxicity
:
LD50 (Rat): > 5,000 mg/kg
Cocamidopropyl Betaine:
Acute oral toxicity
:
LD50 : > 5,000 mg/kg Method: OECD Test Guideline 401 Remarks: Based on data from similar materials
Acute dermal toxicity
:
LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 402 Assessment: The substance or mixture has no acute dermal toxicity Remarks: Based on data from similar materials
Benzalkonium Chloride:
Acute oral toxicity
:
LD50 (Rat): 850 mg/kg
Acute dermal toxicity
:
LD50 (Rat): 2,300 mg/kg
Skin corrosion/irritation
Not classified based on available information.
Components:
Propylene Glycol:
Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation
Glycerin:
Result: No skin irritation
Cocamidopropyl Betaine:
Result: Skin irritation
Benzalkonium Chloride:
Species: Rabbit Result: Corrosive after 3 minutes to 1 hour of exposure Remarks: Based on data from similar materials
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Serious eye damage/eye irritation
Causes serious eye irritation.
Product:
Result: Irritating to eyes.
Components:
Propylene Glycol:
Species: Rabbit Result: No eye irritation Method: OECD Test Guideline 405
Glycerin:
Result: No eye irritation
Cocamidopropyl Betaine:
Result: Eye irritation Remarks: Severe eye irritation
Benzalkonium Chloride:
Species: Rabbit Result: Irreversible effects on the eye Remarks: Based on data from similar materials
Respiratory or skin sensitisation
Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information.
Components:
Propylene Glycol:
Test Type: Maximisation Test (GPMT) Exposure routes: Skin contact Species: Guinea pig Result: negative
Cocamidopropyl Betaine:
Test Type: Maximisation Test (GPMT) Exposure routes: Skin contact Species: Guinea pig Result: negative Remarks: Based on data from similar materials
Benzalkonium Chloride:
Test Type: Buehler Test Exposure routes: Skin contact Species: Guinea pig Method: OECD Test Guideline 406 Result: negative Remarks: Based on data from similar materials
Germ cell mutagenicity
Not classified based on available information.
Components:
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Propylene Glycol:
Genotoxicity in vitro
:
Test Type: Bacterial reverse mutation assay (AMES) Result: negative
Genotoxicity in vivo
:
Test Type: In vivo micronucleus test Test species: Mouse Application Route: Intraperitoneal injection Result: negative
Glycerin:
Genotoxicity in vitro
:
Test Type: In vitro mammalian cell gene mutation test Method: OECD Test Guideline 476 Result: negative
Cocamidopropyl Betaine:
Genotoxicity in vitro
:
Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative Remarks: Based on data from similar materials
Genotoxicity in vivo
:
Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Test species: Mouse Application Route: Ingestion Result: negative Remarks: Based on data from similar materials
Benzalkonium Chloride:
Genotoxicity in vitro
:
Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative Remarks: Based on data from similar materials
Genotoxicity in vivo
:
Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Test species: Mouse Application Route: Ingestion Method: OECD Test Guideline 474 Result: negative Remarks: Based on data from similar materials
Carcinogenicity
Not classified based on available information.
Components:
Propylene Glycol:
Species: Rat Application Route: Ingestion Exposure time: 2 Years Result: negative
Glycerin:
Species: Rat Application Route: Ingestion Exposure time: 2 Years
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Result: negative
IARC
No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
OSHA
No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
NTP
No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
Reproductive toxicity
Not classified based on available information.
Components:
Propylene Glycol:
Effects on fertility
:
Species: Mouse Application Route: Ingestion Result: negative
Effects on foetal development
:
Test Type: Embryo-foetal development Species: Mouse Application Route: Ingestion Result: negative
Glycerin:
Effects on fertility
:
Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative
Effects on foetal development
:
Test Type: Embryo-foetal development Species: Rabbit Application Route: Ingestion Result: negative
Cocamidopropyl Betaine:
Effects on foetal development
:
Test Type: Embryo-foetal development Species: Rat Application Route: Ingestion Method: OECD Test Guideline 414 Result: negative Remarks: Based on data from similar materials
Benzalkonium Chloride:
Effects on fertility
:
Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative Remarks: Based on data from similar materials
Effects on foetal development
:
Test Type: Embryo-foetal development Species: Rat
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Application Route: Ingestion Result: negative Remarks: Based on data from similar materials
STOT - single exposure
Not classified based on available information.
STOT - repeated exposure
Not classified based on available information.
Repeated dose toxicity
Components:
Propylene Glycol:
Species: Rat NOAEL: 1,700 mg/kg Application Route: Ingestion Exposure time: 2 y
Glycerin:
Species: Rat NOAEL: 167 mg/m3 LOAEL: 660 mg/m3 Application Route: inhalation (dust/mist/fume) Exposure time: 13 w Symptoms: Local irritation
Cocamidopropyl Betaine:
Species: Rat NOAEL: 250 mg/kg Application Route: Ingestion Exposure time: 90 d Method: OECD Test Guideline 408 Remarks: Based on data from similar materials
Benzalkonium Chloride:
Species: Mouse NOAEL: 192 mg/kg Application Route: Ingestion Exposure time: 94 d Remarks: Based on data from similar materials
Aspiration toxicity
Not classified based on available information.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity Components:
Propylene Glycol:
Toxicity to fish
:
LC50 (Oncorhynchus mykiss (rainbow trout)): 40,613 mg/l Exposure time: 96 h Toxicity to daphnia and other
:
EC50 (Ceriodaphnia Dubia (water flea)): 18,340 mg/l
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aquatic invertebrates
Exposure time: 48 h
Toxicity to algae
:
EC50 (Skeletonema costatum (marine diatom)): 19,000 mg/l Exposure time: 48 h Method: OECD Test Guideline 201
Toxicity to fish (Chronic toxicity)
:
Chronic Toxicity Value: 2,500 mg/l Exposure time: 30 d
Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity)
:
NOEC (Ceriodaphnia Dubia (water flea)): 29,000 mg/l Exposure time: 7 d
Toxicity to bacteria
:
NOEC (Pseudomonas putida): > 20,000 mg/l Exposure time: 18 h
Glycerin:
Toxicity to fish
:
LC50 (Oncorhynchus mykiss (rainbow trout)): 54,000 mg/l Exposure time: 96 h
Toxicity to daphnia and other aquatic invertebrates
:
EC50 (Daphnia magna (Water flea)): 1,955 mg/l Exposure time: 48 h
Toxicity to bacteria
:
NOEC (Pseudomonas putida): > 10,000 mg/l Exposure time: 16 h
Cocamidopropyl Betaine:
Toxicity to fish
:
LC50: > 1 - 10 mg/l Exposure time: 96 h Method: ISO 7346/2 Remarks: Based on data from similar materials
Toxicity to bacteria
:
EC50: > 100 mg/l Method: OECD Test Guideline 209 Remarks: Based on data from similar materials
Benzalkonium Chloride:
Toxicity to fish
:
LC50 (Lepomis macrochirus (Bluegill sunfish)): 0.515 mg/l Exposure time: 96 h Remarks: Based on data from similar materials
Toxicity to daphnia and other aquatic invertebrates
:
EC50 (Daphnia magna (Water flea)): 0.016 mg/l Exposure time: 48 h Method: Directive 67/548/EEC, Annex V, C.2. Remarks: Based on data from similar materials
Toxicity to algae
:
ErC50 (Selenastrum capricornutum (green algae)): 0.049 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Remarks: Based on data from similar materials
EC10 (Selenastrum capricornutum (green algae)): 0.009 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Remarks: Based on data from similar materials M-Factor (Acute aquatic
:
10
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toxicity)
Toxicity to fish (Chronic toxicity)
:
NOEC (Pimephales promelas (fathead minnow)): 0.0322 mg/l Exposure time: 34 d Remarks: Based on data from similar materials
Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity)
:
NOEC (Daphnia magna (Water flea)): 0.0125 mg/l Exposure time: 21 d Method: OECD Test Guideline 211 Remarks: Based on data from similar materials
M-Factor (Chronic aquatic toxicity)
:
1
Persistence and degradability Components:
Propylene Glycol:
Biodegradability
:
Result: Readily biodegradable. Biodegradation: 98.3 % Exposure time: 28 d Method: OECD Test Guideline 301F
Glycerin:
Biodegradability
:
Result: Readily biodegradable. Biodegradation: 94 % Exposure time: 1 d
Cocamidopropyl Betaine:
Biodegradability
:
Result: Readily biodegradable. Biodegradation: > 60 % Exposure time: 28 d Method: OECD Test Guideline 301 Remarks: Based on data from similar materials
Benzalkonium Chloride:
Biodegradability
:
Result: Readily biodegradable. Biodegradation: 72 % Exposure time: 28 d
Bioaccumulative potential Components:
Propylene Glycol:
Partition coefficient: n­octanol/water
:
log Pow: -1.07
Glycerin:
Partition coefficient: n­octanol/water
:
log Pow: -1.76
Benzalkonium Chloride:
Partition coefficient: n­octanol/water
:
log Pow: 2.75 Remarks: Based on data from similar materials
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Mobility in soil
No data available
Other adverse effects
No data available
Product:
Regulation
40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances
Remarks
This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues
:
Dispose of in accordance with local regulations.
Contaminated packaging
:
Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal.
SECTION 14. TRANSPORT INFORMATION
International Regulation
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
National Regulations
49 CFR
Not regulated as a dangerous good
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards
:
Acute Health Hazard
SARA 302
:
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
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SARA 313
:
This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Clean Air Act
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489):
Propylene Glycol
57-55-6
2.5 %
Glycerin
56-81-5
2 %
This product does not contain any VOC exemptions listed under the U.S. Clean Air Act Section
450.
Clean Water Act
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307
US State Regulations Massachusetts Right To Know
Glycerin
56-81-5
1 - 5 %
Pennsylvania Right To Know
Water (Aqua)
7732-18-5
90 - 100 %
Propylene Glycol
57-55-6
1 - 5 %
Glycerin
56-81-5
1 - 5 %
Phenoxyethanol
122-99-6
0.1 - 1 %
New Jersey Right To Know
Water (Aqua)
7732-18-5
90 - 100 %
Propylene Glycol
57-55-6
1 - 5 %
Glycerin
56-81-5
1 - 5 %
Cocamidopropyl Betaine
61789-40-0
1 - 5 %
PEG-80 Sorbitan Laurate
9005-64-5
1 - 5 %
California Prop 65
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
The components of this product are reported in the following inventories:
TSCA
:
On the inventory, or in compliance with the inventory
AICS
:
On the inventory, or in compliance with the inventory
DSL :
On the inventory, or in compliance with the inventory
ENCS
:
On the inventory, or in compliance with the inventory
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ISHL
:
On the inventory, or in compliance with the inventory
KECI
:
On the inventory, or in compliance with the inventory
PICCS
:
On the inventory, or in compliance with the inventory
IECSC
:
On the inventory, or in compliance with the inventory
NZIoC
:
On the inventory, or in compliance with the inventory
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)
SECTION 16. OTHER INFORMATION
Further information
NFPA:
HMIS III:
Revision Date
:
02/24/2017
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
Flammability
Health
Instability
2
1
0
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
1
0
2
Special hazard.
0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
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