GoJo 7572-02, 7272-04 User Manual

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SAFETY DATA SHEET
GOJO® SUPRO MAX™ Hand Cleaner
Version 1.0
Revision Date: 01/16/2020
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SECTION 1. IDENTIFICATION
Product name
:
GOJO® SUPRO MAX™ Hand Cleaner
Manufacturer or supplier's details
Company name of supplier
:
GOJO Industries, Inc.
Address
:
One GOJO Plaza, Suite 500 Akron, Ohio 44311
Telephone
:
1 (330) 255-6000
Emergency telephone number
:
CHEMTREC 1-800-424-9300 CHEMTREC +1-703-527-3887: Outside USA & CANADA
Recommended use of the chemical and restrictions on use
Recommended use
:
Skin-care
Restrictions on use
:
This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet.
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
Not a hazardous substance or mixture.
GHS label elements
Not a hazardous substance or mixture.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
Chemical name
CAS-No.
Concentration (%)
C11-15 Alkane/cycloalkane
64742-47-8
>= 10
- < 20
Sodium Laureth Sulfate
68585-34-2
>= 5
- < 10
Cocamidopropyl Betaine
61789-40-0
>= 1
- < 5
Titanium Dioxide (CI 77891)
13463-67-7
> 0.1
- < 1
SECTION 4. FIRST AID MEASURES
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General advice
:
In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice.
If inhaled
:
If inhaled, remove to fresh air. If symptoms persist, call a physician.
In case of skin contact
:
Get medical attention if irritation develops and persists.
In case of eye contact
:
Rinse thoroughly with plenty of water, also under the eyelids. If easy to do, remove contact lens, if worn. Get medical attention if irritation develops and persists.
If swallowed
:
If swallowed, DO NOT induce vomiting. Rinse mouth with water. Obtain medical attention.
Most important symptoms and effects, both acute and delayed
:
None known. Protection of first-aiders
:
First Aid responders should pay attention to self-protection and use the recommended protective clothing
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media
:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable extinguishing media
:
None known.
Hazardous combustion products
:
Carbon oxides Sulphur oxides Metal oxides Nitrogen oxides (NOx) Chlorine compounds
Specific extinguishing methods
:
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers.
Further information
:
Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Special protective equipment for firefighters
:
In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
:
Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas. Material can create slippery conditions.
Environmental precautions
:
Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.
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Methods and materials for containment and cleaning up
:
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Keep in suitable, closed containers for disposal. Clean contaminated floors and objects thoroughly while observing environmental regulations.
SECTION 7. HANDLING AND STORAGE
Advice on safe handling
:
For personal protection see section 8. Do not swallow. Avoid contact with eyes. Keep container closed when not in use.
Conditions for safe storage
:
Keep in properly labelled containers. Keep containers tightly closed in a dry, cool and well­ventilated place. Store in accordance with the particular national regulations.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components
CAS-No.
Value type (Form of exposure)
Control parameters / Permissible concentration
Basis
C11-15 Alkane/cycloalkane
64742-47-8
TWA (Mist)
5 mg/m3
OSHA Z-1
TWA
200 mg/m3 (as total hydrocarbon vapor)
ACGIH
TWA (Mist)
5 mg/m3
NIOSH REL
ST (Mist)
10 mg/m3
NIOSH REL
Titanium Dioxide (CI 77891)
13463-67-7
TWA (total dust)
15 mg/m3
OSHA Z-1
TWA
10 mg/m3 (Titanium dioxide)
ACGIH
Hazardous components without workplace control parameters
Personal protective equipment
Respiratory protection
:
No personal respiratory protective equipment normally required.
Eye protection
:
No special protective equipment required. Wear face-shield and protective suit for abnormal processing problems.
Skin and body protection
:
No special protective equipment required.
Protective measures
:
Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place.
Hygiene measures
:
Handle in accordance with good industrial hygiene and safety practice.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
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Appearance
:
liquid
Colour
:
opaque, tan
Odour
:
floral
Odour Threshold
:
No data available
pH :
4.5 - 8.0, (20 °C)
Solidification / Setting point
:
5.5 °C Melting point/freezing point
No data available
Initial boiling point and boiling range
:
94 °C
Flash point
:
> 100 °C Method: Pensky-Martens closed cup
Evaporation rate
:
No data available
Flammability (solid, gas)
:
Not applicable
Flammability (liquids)
:
No data available
Upper explosion limit
:
No data available
Lower explosion limit
:
No data available
Vapour pressure
:
No data available
Relative vapour density
:
No data available
Density
:
1.02 g/cm3
Solubility(ies)
Water solubility
:
soluble
Partition coefficient: n­octanol/water
:
Not applicable
Auto-ignition temperature
:
No data available
Thermal decomposition
:
The substance or mixture is not classified self-reactive.
Viscosity
Viscosity, kinematic
:
12000 - 40000 mm2/s (20 °C) Explosive properties
:
Not explosive
Oxidizing properties
:
The substance or mixture is not classified as oxidizing.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
:
Not classified as a reactivity hazard.
Chemical stability
:
Stable under normal conditions.
Incompatible materials
:
Strong oxidizing agents
Hazardous decomposition products
:
No hazardous decomposition products are known.
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SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation Eye contact Skin contact
Acute toxicity
Not classified based on available information.
Product:
Acute oral toxicity
:
Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method
Components:
C11-15 Alkane/cycloalkane:
Acute oral toxicity
:
LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity
:
LC50 (Rat): > 5.3 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity Remarks: Based on data from similar materials
Acute dermal toxicity
:
LD50 (Rabbit): > 3,160 mg/kg Assessment: The substance or mixture has no acute dermal toxicity
Sodium Laureth Sulfate:
Acute oral toxicity
:
LD50 (Rat): > 2,000 mg/kg Assessment: The substance or mixture has no acute oral toxicity
Cocamidopropyl Betaine:
Acute oral toxicity
:
LD50 : > 5,000 mg/kg Method: OECD Test Guideline 401 Remarks: Based on data from similar materials
Acute dermal toxicity
:
LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 402 Assessment: The substance or mixture has no acute dermal toxicity Remarks: Based on data from similar materials
Titanium Dioxide (CI 77891):
Acute oral toxicity
:
LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity
:
LC50 (Rat): > 6.82 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity
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Skin corrosion/irritation
Not classified based on available information.
Product:
Assessment: Not irritating when applied to human skin. Result: No skin irritation
Components:
C11-15 Alkane/cycloalkane:
Assessment: Repeated exposure may cause skin dryness or cracking.
Sodium Laureth Sulfate:
Result: Skin irritation
Cocamidopropyl Betaine:
Result: Skin irritation
Titanium Dioxide (CI 77891):
Species: Rabbit Result: No skin irritation
Serious eye damage/eye irritation
Not classified based on available information.
Components:
C11-15 Alkane/cycloalkane:
Species: Rabbit Result: No eye irritation
Sodium Laureth Sulfate:
Result: Eye irritation Remarks: Severe eye irritation
Cocamidopropyl Betaine:
Result: Eye irritation Remarks: Severe eye irritation
Titanium Dioxide (CI 77891):
Species: Rabbit Result: No eye irritation
Respiratory or skin sensitisation
Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information.
Components:
C11-15 Alkane/cycloalkane:
Test Type: Maximisation Test (GPMT) Exposure routes: Skin contact Species: Guinea pig Result: negative Remarks: Based on data from similar materials
Cocamidopropyl Betaine:
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Test Type: Maximisation Test (GPMT) Exposure routes: Skin contact Species: Guinea pig Result: negative Remarks: Based on data from similar materials
Titanium Dioxide (CI 77891):
Test Type: Local lymph node assay (LLNA) Exposure routes: Skin contact Species: Mouse Result: negative
Germ cell mutagenicity
Not classified based on available information.
Components:
C11-15 Alkane/cycloalkane:
Genotoxicity in vitro
:
Test Type: Bacterial reverse mutation assay (AMES) Result: negative
Genotoxicity in vivo
:
Test Type: Chromosomal aberration Test species: Rat Application Route: Intraperitoneal injection Result: negative Remarks: Based on data from similar materials
Cocamidopropyl Betaine:
Genotoxicity in vitro
:
Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative Remarks: Based on data from similar materials
Genotoxicity in vivo
:
Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Test species: Mouse Application Route: Ingestion Result: negative Remarks: Based on data from similar materials
Titanium Dioxide (CI 77891):
Genotoxicity in vitro
:
Test Type: Bacterial reverse mutation assay (AMES) Result: negative
Genotoxicity in vivo
:
Test Type: In vivo micronucleus test Test species: Mouse Result: negative
Carcinogenicity
Not classified based on available information.
Components:
Titanium Dioxide (CI 77891):
Species: Rat Application Route: inhalation (dust/mist/fume)
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Method: OECD Test Guideline 453 Result: positive Remarks: The mechanism or mode of action may not be releva nt in humans., The substance is inextricably bound in the product and therefore does not contribute to a dust inhalation hazard.
IARC
Group 2B: Possibly carcinogenic to humans
Titanium Dioxide (CI 77891)
13463-67-7
OSHA
No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
NTP
No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
Reproductive toxicity
Not classified based on available information.
Components:
C11-15 Alkane/cycloalkane:
Effects on fertility
:
Test Type: One-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative Remarks: Based on data from similar materials
Effects on foetal development
:
Test Type: Embryo-foetal development Species: Rat Application Route: Ingestion Result: negative
Cocamidopropyl Betaine:
Effects on foetal development
:
Test Type: Embryo-foetal development Species: Rat Application Route: Ingestion Method: OECD Test Guideline 414 Result: negative Remarks: Based on data from similar materials
STOT - single exposure
Not classified based on available information.
STOT - repeated exposure
Not classified based on available information.
Repeated dose toxicity
Components:
C11-15 Alkane/cycloalkane:
Species: Rat NOAEL: > 10.4 mg/l Application Route: inhalation (vapour) Exposure time: 90 d Remarks: Based on data from similar materials
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Cocamidopropyl Betaine:
Species: Rat NOAEL: 250 mg/kg Application Route: Ingestion Exposure time: 90 d Method: OECD Test Guideline 408 Remarks: Based on data from similar materials
Titanium Dioxide (CI 77891):
Species: Rat NOAEL: 24,000 mg/kg Application Route: Ingestion
Species: Rat NOAEL: 10 mg/m3 Application Route: inhalation (dust/mist/fume) Exposure time: 2 y Remarks: The substance is inextricably bound in the product and therefore does not contribute to a dust inhalation hazard.
Aspiration toxicity
Not classified based on available information.
Components:
C11-15 Alkane/cycloalkane:
The substance or mixture is known to cause human aspiration toxicity hazards or has to be regarded as if it causes a human aspiration toxicity hazard.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity Components:
C11-15 Alkane/cycloalkane:
Toxicity to fish
:
LL50 (Danio rerio (zebra fish)): > 250 mg/l Exposure time: 96 h Test substance: Water Accommodated Fraction Method: OECD Test Guideline 203
Toxicity to daphnia and other aquatic invertebrates
:
EL50 (Acartia tonsa): > 3,193 mg/l Exposure time: 48 h Test substance: Water Accommodated Fraction
Toxicity to algae
:
EL50 (Skeletonema costatum (marine diatom)): > 3,200 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction
NOELR (Skeletonema costatum (marine diatom)): 993 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction
Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity)
:
NOELR (Ceriodaphnia Dubia (water flea)): > 70 mg/l Exposure time: 8 d Test substance: Water Accommodated Fraction
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Toxicity to bacteria
:
EC50: > 100 mg/l Exposure time: 3 h
Cocamidopropyl Betaine:
Toxicity to fish
:
LC50: > 1 - 10 mg/l Exposure time: 96 h Method: ISO 7346/2 Remarks: Based on data from similar materials
Toxicity to bacteria
:
EC50: > 100 mg/l Method: OECD Test Guideline 209 Remarks: Based on data from similar materials
Titanium Dioxide (CI 77891):
Toxicity to fish
:
LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l Exposure time: 96 h Method: OECD Test Guideline 203
Toxicity to daphnia and other aquatic invertebrates
:
EC50 (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 48 h
Toxicity to algae
:
EC50 (Skeletonema costatum (marine diatom)): > 10,000 mg/l Exposure time: 72 h
Toxicity to bacteria
:
EC50: > 1,000 mg/l Exposure time: 3 h Method: OECD Test Guideline 209
Persistence and degradability Components:
C11-15 Alkane/cycloalkane:
Biodegradability
:
Result: Readily biodegradable. Biodegradation: 82 % Exposure time: 24 d Method: OECD Test Guideline 301F
Sodium Laureth Sulfate:
Biodegradability
:
Result: Readily biodegradable.
Cocamidopropyl Betaine:
Biodegradability
:
Result: Readily biodegradable. Biodegradation: > 60 % Exposure time: 28 d Method: OECD Test Guideline 301 Remarks: Based on data from similar materials
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects
No data available
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Product:
Regulation
40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances
Remarks
This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues
:
Dispose of in accordance with local regulations.
Contaminated packaging
:
Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal.
SECTION 14. TRANSPORT INFORMATION
International Regulation
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
National Regulations
49 CFR
Not regulated as a dangerous good
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
SARA 311/312 Hazards
:
No SARA Hazards
SARA 302
:
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313
:
This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Clean Air Act
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). This product does not contain any VOC exemptions listed under the U.S. Clean Air Act Section
450.
Clean Water Act
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This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307
California Prop 65
This product does not require a warning label under California Proposition 65.
The components of this product are reported in the following inventories:
TSCA
:
On the inventory, or in compliance with the inventory
AICS
:
On the inventory, or in compliance with the inventory
DSL :
All components of this product are on the Canadian DSL.
ENCS
:
On the inventory, or in compliance with the inventory
ISHL
:
On the inventory, or in compliance with the inventory
KECI
:
On the inventory, or in compliance with the inventory
PICCS
:
On the inventory, or in compliance with the inventory
IECSC
:
On the inventory, or in compliance with the inventory
NZIoC
:
On the inventory, or in compliance with the inventory
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)
SECTION 16. OTHER INFORMATION
Further information
NFPA:
HMIS III:
Revision Date
:
01/16/2020
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release
Flammability
Health
Instability
0 1 0
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
1
0
0
Special hazard.
0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
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and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
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