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SAFETY DATA SHEET
GOJO® MULTI GREEN® Hand Cleaner
GOJO® MULTI GREEN® Eco Hand Cleaner
Version 1.4
SDS Number: 400000005228
Revision Date: 10/18/2018
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Product name
:
GOJO® MULTI GREEN® Hand Cleaner
GOJO® MULTI GREEN® Eco Hand Cleaner
Company name of supplier
: GOJO Industries, Inc.
Address :
One GOJO Plaza, Suite 500
Akron, Ohio 44311
Telephone :
1 (330) 255-6000
Emergency telephone
number
: CHEMTREC 1-800-424-9300
CHEMTREC +1-703-527-3887: Outside USA & CANADA
Recommended use
:
Skin-care
Restrictions on use
:
This is a personal care or cosmetic product that is safe for
provided on the package or instruction sheet.
Eye irritation
:
Category 2B
Signal word
: Warning
to do. Continue rinsing.
SECTION 1. IDENTIFICATION
Manufacturer or supplier's details
Recommended use of the chemical and restrictions on use
consumers and other users under normal and reasonably
foreseeable use. Cosmetics and consumer products,
specifically defined by regulations around the world, are
exempt from the requirement of an SDS for the consumer.
While this material is not considered hazardous, this SDS
contains valuable information critical to the safe handling and
proper use of the product for industrial workplace conditions
as well as unusual and unintended exposures such as large
spills. This SDS should be retained and available for
employees and other users of this product. For specific
intended-use guidance, please refer to the information
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
GHS label elements
Hazard statements
Precautionary statements
:
H320 Causes eye irritation.
Response:
:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
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SAFETY DATA SHEET
GOJO® MULTI GREEN® Hand Cleaner
GOJO® MULTI GREEN® Eco Hand Cleaner
Version 1.4
SDS Number: 400000005228
Revision Date: 10/18/2018
Chemical name
CAS-No.
Concentration (%)
Laureth-6
68439-50-9
>= 5 - < 10
Limonene
5989-27-5
>= 0.1 - < 1
Chemical name
CAS-No.
Concentration (%)
Laureth-6
68439-50-9
>= 5 - < 10
Limonene
5989-27-5
>= 0.1 - < 1
Sodium Hydroxymethylglycinate
70161-44-3
>= 0.1 - < 1
General advice
:
In the case of accident or if you feel unwell, seek medical
advice.
If inhaled
:
If inhaled, remove to fresh air.
Seek medical advice.
If swallowed
:
If swallowed, DO NOT induce vomiting. Rinse mouth with water.
Most important symptoms
delayed
: Causes eye irritation.
Protection of first-aiders
:
First Aid responders should pay attention to self-protection
Suitable extinguishing media
: Water spray
Carbon dioxide (CO2)
Unsuitable extinguishing
media
: None known.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components:
GOJO® MULTI GREEN® Hand Cleaner
Hazardous components:
GOJO® MULTI GREEN® ECOPREFERRED™ Hand
Cleaner
SECTION 4. FIRST AID MEASURES
In case of skin contact
In case of eye contact
and effects, both acute and
advice immediately.
When symptoms persist or in all cases of doubt seek medical
If symptoms persist, call a physician.
:
Wash with water and soap as a precaution.
Get medical attention if irritation develops and persists.
:
Rinse thoroughly with plenty of water, also under the eyelids.
If easy to do, remove contact lens, if worn.
Obtain medical attention.
and use the recommended protective clothing
SECTION 5. FIREFIGHTING MEASURES
Alcohol-resistant foam
Dry chemical
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SAFETY DATA SHEET
GOJO® MULTI GREEN® Hand Cleaner
GOJO® MULTI GREEN® Eco Hand Cleaner
Version 1.4
SDS Number: 400000005228
Revision Date: 10/18/2018
Hazardous combustion
: Carbon oxides
Use water spray to cool unopened containers.
Further information
:
Collect contaminated fire extinguishing water separately. This
be disposed of in accordance with local regulations.
Special protective equipment
:
In the event of fire, wear self-contained breathing apparatus.
Personal precautions,
:
Use personal protective equipment.
Advice on safe handling
:
For personal protection see section 8.
Keep container closed when not in use.
Conditions for safe storage
: Keep in properly labelled containers.
Components
CAS-No.
Value type
(Form of
Control
parameters /
Basis
products
Specific extinguishing
methods
:
Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
for firefighters
Use personal protective equipment.
SECTION 6. ACCIDENTAL RELEASE MEASURES
protective equipment and
emergency procedures
Ensure adequate ventilat ion.
Evacuate personnel to safe areas.
Material can create slippery conditions.
:
Environmental precautions
Discharge into the environment must be avoided.
Prevent further leakage or spillage if safe to do so.
Retain and dispose of contaminated wash water.
Local authorities should be advised if significant spillages
cannot be contained.
Soak up with inert absorbent material.
:
Methods and materials for
containment and cleaning up
Keep in suitable, closed containers for disposal.
Clean contaminated floors and objects thoroughly while
observing environmental regulations.
SECTION 7. HANDLING AND STORAGE
Do not swallow.
Avoid contact with eyes.
Keep containers tightly closed in a cool, well-ventilated place.
Store in accordance with the particular national regulations.
SECTION 8. EXPOS URE CONTROL S/PER SO NAL PROTECT IO N
Components with workplace control parameters
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SAFETY DATA SHEET
GOJO® MULTI GREEN® Hand Cleaner
GOJO® MULTI GREEN® Eco Hand Cleaner
Version 1.4
SDS Number: 400000005228
Revision Date: 10/18/2018
exposure)
Permissible
concentration
Limonene
5989-27-5
TWA
20 ppm
ACGIH
Respiratory protection
:
No personal respiratory protective equipment normally
required.
Eye protection
:
No special measures necessary provided product is used
the specific work-place.
Hygiene measures
:
Handle in accordance with good indus tri al h ygie ne and saf et y
Appearance :
liquid
Colour :
green, opaque
Odour
:
citrus
Odour Threshold
:
No data available
pH
:
6 - 9
Melting point/freezing point
: No data available
Initial boiling point and boiling
range
: 98 °C
Flash point :
> 100 °C
Evaporation rate
:
No data available
Flammability (solid, gas)
: Not applicable
Flammability (liquids)
: No data available
Upper explosion limit
:
No data available
Lower explosion limit
:
No data available
Personal protective equipment
Skin and body protection
correctly.
Wear face-shield and protective suit for abnormal processing
problems.
:
No special measures necessary provided product is used
correctly.
:
Protective measures
Choose body protection in relation to its type, to the
concentration and amount of dangerous substances, and to
practice.
Avoid contact with eyes.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
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SAFETY DATA SHEET
GOJO® MULTI GREEN® Hand Cleaner
GOJO® MULTI GREEN® Eco Hand Cleaner
Version 1.4
SDS Number: 400000005228
Revision Date: 10/18/2018
Relative vapour density
: No data available
Density :
1.033 g/cm3
Water solubility
:
soluble
Partition coefficient: noctanol/water
:
Not applicable
Auto-ignition temper atur e
: not determined
Thermal decomposition
: The substance or mixture is not classified self-reactive.
Viscosity, kinematic
:
25000 - 45000 mm2/s (20 °C)
Explosive properties
:
Not explosive
Oxidizing properties
:
The substance or mixture is not classified as oxidizing.
Reactivity
:
Not classified as a reactivity hazard.
Incompatible materials
:
Strong oxidizing agents
Hazardous decompositio n
: No hazardous decomposition products are known.
Acute oral toxicity
:
Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method
Acute oral toxicity
:
LD50 (Rat): > 500 - 2, 000 mg/kg
Vapour pressure
:
No data available
Solubility(ies)
Viscosity
SECTION 10. STABILITY AND REACTIVITY
Chemical stability
:
Stable under normal conditions.
products
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of ex p osure
Inhalation
Eye contact
Skin contact
Acute toxicity
Not classified based on available information.
Product:
Components:
Laureth-6:
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SAFETY DATA SHEET
GOJO® MULTI GREEN® Hand Cleaner
GOJO® MULTI GREEN® Eco Hand Cleaner
Version 1.4
SDS Number: 400000005228
Revision Date: 10/18/2018
Acute inhalation toxicity
:
LC50 (Rat): > 1.6 mg/l
Remarks: Based on data from similar materials
Acute dermal toxicity
:
LD50 (Rat): > 2,000 mg/kg
Remarks: Based on data from similar materials
Acute oral toxicity
:
LD50 (Rat): > 2,000 mg/kg
Remarks: Based on data from similar materials
Acute oral toxicity
:
LD50 (Rat): 1,050 mg/kg
Remarks: Based on data from similar materials
Exposure time: 4 h
Test atmosphere: dust/mist
Limonene:
Assessment: The substance or mixture has no acute oral
toxicity
Sodium Hydroxymethylglycinate:
Skin corrosion/irritation
Not classified based on available information.
Product:
Result: No skin irritation
Components:
Laureth-6:
Species: Rabbit
Result: No skin irritation
Remarks: Based on data from similar materials
Limonene:
Species: Rabbit
Result: Skin irritation
Sodium Hydroxymethylglycinate:
Species: Rabbit
Result: Skin irritation
Serious eye damage/eye irritation
Causes eye irritation.
Product:
Result: Mild eye irritation
Components:
Laureth-6:
Species: Rabbit
Result: Irreversible effects on the eye
Remarks: Based on data from similar materials
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SAFETY DATA SHEET
GOJO® MULTI GREEN® Hand Cleaner
GOJO® MULTI GREEN® Eco Hand Cleaner
Version 1.4
SDS Number: 400000005228
Revision Date: 10/18/2018
Test Type: Local lymph node assay (LLNA)
Assessment: Probability or evidence of skin sensitisation in humans
Test Type: Maximisation Test (GPMT)
Assessment: Probability or evidence of skin sensitisation in humans
Genotoxicity in vitro
:
Test Type: Bacterial reverse mutation assay (AMES)
Remarks: Based on data from similar materials
Limonene:
Species: Rabbit
Result: No eye irritation
Sodium Hydroxymethylglycinate:
Species: Rabbit
Result: Irritation to eyes, reversing within 21 days
Respiratory or skin sensitisation
Skin sensitisation: Not classified based on available information.
Respiratory sensitisation: Not classified based on available information.
Product:
Result: Does not cause skin sensitisation.
Remarks: Patch test on human volunteers did not demonstrate sensitisation properties.
Components:
Laureth-6:
Test Type: Maximisation Test (GPMT)
Exposure routes: Skin contact
Species: Guinea pig
Method: OECD Test Guideline 406
Result: negative
Remarks: Based on data from similar materials
Limonene:
Exposure routes: Skin contact
Species: Mouse
Result: positive
Sodium Hydroxymethylglycinate:
Exposure routes: Skin contact
Species: Guinea pig
Result: positive
Germ cell mutagenicity
Not classified based on available information.
Components:
Laureth-6:
Limonene:
Method: OECD Test Guideline 471
Result: negative
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SAFETY DATA SHEET
GOJO® MULTI GREEN® Hand Cleaner
GOJO® MULTI GREEN® Eco Hand Cleaner
Version 1.4
SDS Number: 400000005228
Revision Date: 10/18/2018
Result: negative
Genotoxicity in vivo
:
Test Type: Transgenic rodent somatic cell gene mutation
Result: negative
Genotoxicity in vitro
:
Test Type: Bacterial reverse mutation assay (AMES)
Result: negative
Genotoxicity in vivo
:
Test Type: Unscheduled DNA synthesis (UDS) test with
Result: negative
IARC
No component of this product present at levels greater than or
human carcinogen by IARC.
OSHA
No component of this product present at levels greater than or
carcinogen by OSHA.
NTP
No component of this product present at levels greater than or
by NTP.
Effects on foetal
:
Species: Rat
Result: negative
Genotoxicity in vitro
Sodium Hydroxymethylglycinate:
Carcinogenicity
Not classified based on available information.
Components:
Limonene:
Species: Mouse
Application Route: Ingestion
Exposure time: 103 weeks
Result: negative
:
Test Type: In vitro mammalian cell gene mutation test
assay
Test species: Rat
Application Route: Ingestion
mammali an liver cells in vivo
Test species: Rat
equal to 0.1% is identified as probable, possible or confirmed
equal to 0.1% is identified as a carcinogen or potential
equal to 0.1% is identified as a known or anticipated carcinogen
Reproductive toxicity
Not classified based on available information.
Components:
Sodium Hydroxymethylglycinate:
development
Application Route: Ingestion
STOT - single exposure
Not classified based on available information.
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SAFETY DATA SHEET
GOJO® MULTI GREEN® Hand Cleaner
GOJO® MULTI GREEN® Eco Hand Cleaner
Version 1.4
SDS Number: 400000005228
Revision Date: 10/18/2018
Toxicity to daphnia and other
:
EC50 (Daphnia magna (Water flea)): > 1 - 10 mg/l
Remarks: Based on data from similar materials
Toxicity to daphnia and other
(Chronic toxicity)
:
NOEC (Daphnia magna (Water flea)): > 0.1 - 1 mg/l
Remarks: Based on data from similar materials
Toxicity to fish
:
LC50 (Pimephales promelas (fathead minnow)): 0.72 mg/l
Exposure time: 96 h
Toxicity to daphnia and other
:
EC50 (Daphnia magna (Water flea)): 0.36 mg/l
Remarks: Based on data from similar materials
M-Factor (Acute aquatic
toxicity)
: 1
Toxicity to fish
:
LC50 (Danio rerio (zebra fish)): > 1 - 10 mg/l
Remarks: Based on data from similar materials
STOT - repeated exposure
Not classified based on available information.
Repeated dose toxicity
Components:
Limonene:
Species: Rat
NOAEL: 600 mg/kg
Application Route: Ingestion
Exposure time: 13 w
Aspiration toxicity
Not classified based on available information.
Components:
Limonene:
The substance or mixture is known to cause human aspiration toxicity hazards or has to be
regarded as if it causes a human aspiration toxicity hazard.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Components:
Laureth-6:
aquatic invertebrates
aquatic invertebrates
Limonene:
Exposure time: 96 h
Exposure time: 48 h
Exposure time: 21 d
aquatic invertebrates
Toxicity to algae
Exposure time: 48 h
:
ErC50 (Desmodesmus subspicatus (green algae)): 150 mg/l
Exposure time: 72 h
Test substance: Water Accommodated Fraction
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SAFETY DATA SHEET
GOJO® MULTI GREEN® Hand Cleaner
GOJO® MULTI GREEN® Eco Hand Cleaner
Version 1.4
SDS Number: 400000005228
Revision Date: 10/18/2018
Toxicity to fish
:
LC50: > 10 - 100 mg/l
Exposure time: 96 h
Toxicity to daphnia and other
:
EC50 (Daphnia pulex (Water flea)): > 10 - 100 mg/l
Exposure time: 72 h
Toxicity to bacteria
:
EC50: > 100 mg/l
Exposure time: 120 h
Biodegradability
:
Result: rapidly degradable
Remarks: Based on data from similar materials
Biodegradability
:
Result: Readily biodegradable.
Remarks: Based on data from similar materials
Biodegradability
:
Result: Readily biodegradable.
Bioaccumulation
:
Species: Fish
Remarks: Based on data from similar materials
Partition coefficient: noctanol/water
:
log Pow: 4.38
Partition coefficient: noctanol/water
:
log Pow: < 3
Regulation
40 CFR Protection of Environment; Part 82 Protection of
Sodium Hydroxymethylglycinate:
aquatic invertebrates
Toxicity to algae
Persistence and degradability
Components:
Laureth-6:
Limonene:
Sodium Hydroxymethylglycinate:
Exposure time: 48 h
:
ErC50 (Desmodesmus subspicatus (Scenedesmus
subspicatus)): > 10 - 100 mg/l
Biodegradation: 80 %
Exposure time: 28 d
Bioaccumulative potential
Components:
Laureth-6:
Limonene:
Sodium Hydroxymethylglycinate:
Mobility in soil
No data available
Other adverse effects
No data available
Product:
Bioconcentration factor (BCF): < 500
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SAFETY DATA SHEET
GOJO® MULTI GREEN® Hand Cleaner
GOJO® MULTI GREEN® Eco Hand Cleaner
Version 1.4
SDS Number: 400000005228
Revision Date: 10/18/2018
Waste from residues
: Dispose of in accordance with local regulations.
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
49 CFR
Not regulated as a dangerous good
SARA 311/312 Hazards
: Acute Health Hazard
SARA 302 :
No chemicals in this material are subject to the reporting
reporting levels established by SARA Title III, Section 313.
Stratospheric Ozone - CAA Section 602 Class I Substances
Remarks This product neither contains, nor was manufactured with a
Class I or Class II ODS as defined by the U.S. Clean Air Act
Section 602 (40 CFR 82, Subpt. A, App.A + B).
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Contaminated packaging
Dispose of as unused product.
:
Empty containers should be taken to an approved waste
handling site for recycling or disposal.
SECTION 14. TRANSPORT INFORMATION
International Regulation
National Regulations
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Kn ow Act
CERCLA Reportable Quantity
This material does not contain an y com ponents with a CERCL A RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain an y com ponents with a sec tion 304 EH S RQ.
requirements of SARA Title III, Section 302.
SARA 313
:
This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
Clean Air Act
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean
Air Act Section 12 (40 CFR 61).
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SAFETY DATA SHEET
GOJO® MULTI GREEN® Hand Cleaner
GOJO® MULTI GREEN® Eco Hand Cleaner
Version 1.4
SDS Number: 400000005228
Revision Date: 10/18/2018
California Prop 65
This product does not require a warning label under California
Proposition 65.
TSCA
:
On TSCA Inventory
CH INV :
On the inventory, or in compliance with the inventory
AICS
:
On the inventory, or in compliance with the inventory
DSL
:
On the inventory, or in compliance with the inventory
ISHL
:
On the inventory, or in compliance with the inventory
KECI
:
On the inventory, or in compliance with the inventory
PICCS :
On the inventory, or in compliance with the inventory
ENCS :
On the inventory, or in compliance with the inventory
IECSC :
On the inventory, or in compliance with the inventory
NZIoC :
On the inventory, or in compliance with the inventory
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for
Accidental Release Prevention (40 CFR 68.130, Subpart F).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111
SOCMI Intermediate or Final VOC's (40 CFR 60.489).
This product does not contain any VOC exemptions listed under the U.S. Clean Air Act Section
450.
Clean Water Act
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section
307
The components of this product are reported in the following inventories:
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)
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SAFETY DATA SHEET
GOJO® MULTI GREEN® Hand Cleaner
GOJO® MULTI GREEN® Eco Hand Cleaner
Instability
Health
NFPA:
HMIS III:
Flammability
4 = Extreme, * = Chronic
Revision Date
:
10/18/2018
Version 1.4 SDS Number: 400000005228 Revision Date: 10/18/2018
SECTION 16. OTHER INFORMATION
Further information
1
1
Special hazard.
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as
a guidance for safe handling, use, processing, storage, transportation, disposal and release
and is not to be considered a warranty or quality specification. The information relates only to
the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.
0
HEALTH
FLAMMABILITY
PHYSICAL HAZARD
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
1
1
0
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