GoJo 6396-06 User Manual

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SAFETY DATA SHEET
GOJO® Scrubbing Towels
Version 1.0
Revision Date: 03/29/2018
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SECTION 1. IDENTIFICATION
Product name
:
GOJO® Scrubbing Towels
Manufacturer or supplier's details
Company name of supplier
:
GOJO Industries, Inc.
Address
:
One GOJO Plaza, Suite 500 Akron, Ohio 44311
Telephone
:
1 (330) 255-6000
Emergency telephone number
:
CHEMTREC 1-800-424-9300 CHEMTREC +1-703-527-3887: Outside USA & CANADA
Recommended use of the chemical and restrictions on use
Recommended use
:
Skin-care
Restrictions on use
:
This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet.
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
Eye irritation
:
Category 2A
GHS label elements
Hazard pictograms
:
Signal word
:
Warning
Hazard statements
:
H319 Causes serious eye irritation.
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Precautionary statements
:
Prevention: P280 Wear eye protection/ face protection.
Response:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
Chemical name
CAS-No.
Concentration (%)
Laureth-7
9002-92-0
>= 1
- < 5
Limonene
5989-27-5
>= 0.1
- < 1
SECTION 4. FIRST AID MEASURES
General advice
:
In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice.
If inhaled
:
If inhaled, remove to fresh air. If symptoms persist, call a physician.
In case of skin contact
:
Wash with water and soap as a precaution. Get medical attention if irritation develops and persists.
In case of eye contact
:
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Seek medical advice.
If swallowed
:
If swallowed, DO NOT induce vomiting. Rinse mouth with water. Obtain medical attention.
Most important symptoms and effects, both acute and delayed
:
Causes serious eye irritation. Protection of first-aiders
:
First Aid responders should pay attention to self-protection and use the recommended protective clothing
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media
:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
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Revision Date: 03/29/2018
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:
None known.
Specific hazards during firefighting
:
Exposure to decomposition products may be a hazard to health. Carbon oxides
Hazardous combustion products
:
Carbon oxides
Specific extinguishing methods
:
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers.
Further information
:
Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Special protective equipment for firefighters
:
In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
:
Use personal protective equipment. Ensure adequate ventilation. Material can create slippery conditions.
Environmental precautions
:
Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.
Methods and materials for containment and cleaning up
:
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Keep in suitable, closed containers for disposal. Clean contaminated floors and objects thoroughly while observing environmental regulations.
SECTION 7. HANDLING AND STORAGE
Advice on safe handling
:
For personal protection see section 8. Do not swallow. Avoid contact with eyes. Keep container closed when not in use.
Conditions for safe storage
:
Keep in properly labelled containers. Keep containers tightly closed in a dry, cool and well-
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SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components
CAS-No.
Value type (Form of exposure)
Control parameters / Permissible concentration
Basis
Limonene
5989-27-5
TWA
20 ppm
ACGIH
Personal protective equipment
Respiratory protection
:
No personal respiratory protective equipment normally required.
Eye protection
:
No special measures necessary provided product is used correctly. Wear face-shield and protective suit for abnormal processing problems.
Skin and body protection
:
No special measures necessary provided product is used correctly.
Protective measures
:
Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place.
Hygiene measures
:
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
:
sheets
Colour
:
clear, colourless, light yellow
Odour
:
citrus
Odour Threshold
:
No data available
pH :
6.0 - 8.5
Melting point/freezing point
:
No data available
Initial boiling point and boiling range
:
No data available Flash point
:
> 100.00 °C Evaporation rate
:
No data available
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:
Not applicable
Flammability (liquids)
:
No data available
Upper explosion limit
:
No data available
Lower explosion limit
:
No data available
Vapour pressure
:
No data available
Relative vapour density
:
No data available
Density
:
1.0012 g/cm3
Solubility(ies)
Water solubility
:
soluble
Partition coefficient: n­octanol/water
:
Not applicable Auto-ignition temperature
:
No data available
Thermal decomposition
:
The substance or mixture is not classified self-reactive.
Viscosity
Viscosity, dynamic
:
No data available
Explosive properties
:
Not explosive
Oxidizing properties
:
The substance or mixture is not classified as oxidizing.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
:
Not classified as a reactivity hazard.
Chemical stability
:
Stable under normal conditions.
Conditions to avoid
:
None known.
Incompatible materials
:
Oxidizing agents
Hazardous decomposition products
:
No hazardous decomposition products are known.
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation Eye contact Skin contact
Acute toxicity
Not classified based on available information.
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Product:
Acute oral toxicity
:
Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method
Components:
Laureth-7:
Acute oral toxicity
:
LD50 (Rat): > 500 - 2,000 mg/kg Remarks: Based on data from similar materials
Acute inhalation toxicity
:
LC50 (Rat): > 1.6 mg/l Exposure time: 4 h Test atmosphere: dust/mist Remarks: Based on data from similar materials
Acute dermal toxicity
:
LD50 (Rat): > 2,000 mg/kg Remarks: Based on data from similar materials
Limonene:
Acute oral toxicity
:
LD50 (Rat): > 2,000 mg/kg Assessment: The substance or mixture has no acute oral toxicity Remarks: Based on data from similar materials
Skin corrosion/irritation
Not classified based on available information.
Components:
Laureth-7:
Species: Rabbit Result: No skin irritation Remarks: Based on data from similar materials
Limonene:
Species: Rabbit Result: Skin irritation
Serious eye damage/eye irritation
Causes serious eye irritation.
Product:
Result: Irritating to eyes.
Components:
Laureth-7:
Species: Rabbit Result: Irreversible effects on the eye Remarks: Based on data from similar materials
Limonene:
Species: Rabbit Result: No eye irritation
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Respiratory or skin sensitisation
Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information.
Product:
Result: Does not cause skin sensitisation. Remarks: Patch test on human volunteers did not demonstrate sensitisation properties.
Components:
Laureth-7:
Test Type: Maximisation Test (GPMT) Exposure routes: Skin contact Species: Guinea pig Method: OECD Test Guideline 406 Result: negative Remarks: Based on data from similar materials
Limonene:
Test Type: Local lymph node assay (LLNA) Exposure routes: Skin contact Species: Mouse Result: positive
Assessment: Probability or evidence of skin sensitisation in humans
Germ cell mutagenicity
Not classified based on available information.
Components:
Laureth-7:
Genotoxicity in vitro
:
Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative Remarks: Based on data from similar materials
Limonene:
Genotoxicity in vitro
:
Test Type: In vitro mammalian cell gene mutation test Result: negative
Genotoxicity in vivo
:
Test Type: Transgenic rodent somatic cell gene mutation assay Test species: Rat Application Route: Ingestion Result: negative
Carcinogenicity
Not classified based on available information.
Components:
Limonene:
Species: Mouse Application Route: Ingestion Exposure time: 103 weeks Result: negative
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IARC
No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
OSHA
No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
NTP
No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
Reproductive toxicity
Not classified based on available information.
STOT - single exposure
Not classified based on available information.
STOT - repeated exposure
Not classified based on available information.
Repeated dose toxicity
Components:
Limonene:
Species: Rat NOAEL: 600 mg/kg Application Route: Ingestion Exposure time: 13 w
Aspiration toxicity
Not classified based on available information.
Components:
Limonene:
The substance or mixture is known to cause human aspiration toxicity hazards or has to be regarded as if it causes a human aspiration toxicity hazard.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity Components:
Laureth-7:
Toxicity to fish
:
LC50 (Danio rerio (zebra fish)): > 1 - 10 mg/l Exposure time: 96 h Remarks: Based on data from similar materials
Toxicity to daphnia and other aquatic invertebrates
:
EC50 (Daphnia magna (Water flea)): > 1 - 10 mg/l Exposure time: 48 h Remarks: Based on data from similar materials Toxicity to daphnia and other
:
NOEC (Daphnia magna (Water flea)): > 0.1 - 1 mg/l
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Exposure time: 21 d Remarks: Based on data from similar materials
Limonene:
Toxicity to fish
:
LC50 (Pimephales promelas (fathead minnow)): 0.72 mg/l Exposure time: 96 h
Toxicity to daphnia and other aquatic invertebrates
:
EC50 (Daphnia magna (Water flea)): 0.36 mg/l Exposure time: 48 h
Toxicity to algae
:
ErC50 (Desmodesmus subspicatus (green algae)): 150 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction Remarks: Based on data from similar materials
M-Factor (Acute aquatic toxicity)
:
1
Persistence and degradability Components:
Laureth-7:
Biodegradability
:
Result: rapidly degradable Remarks: Based on data from similar materials
Limonene:
Biodegradability
:
Result: Readily biodegradable. Biodegradation: 80 % Exposure time: 28 d Remarks: Based on data from similar materials
Bioaccumulative potential Components:
Laureth-7:
Bioaccumulation
:
Species: Fish Bioconcentration factor (BCF): < 500 Remarks: Based on data from similar materials
Limonene:
Partition coefficient: n­octanol/water
:
log Pow: 4.38
Mobility in soil
No data available
Other adverse effects
No data available
Product:
Regulation
40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances
Remarks
This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act
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Section 602 (40 CFR 82, Subpt. A, App.A + B).
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues
:
Dispose of in accordance with local regulations.
Contaminated packaging
:
Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal.
SECTION 14. TRANSPORT INFORMATION
International Regulation
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
National Regulations
49 CFR
Not regulated as a dangerous good
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards
:
Acute Health Hazard
SARA 302
:
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313
:
This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Clean Air Act
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). This product does not contain any VOC exemptions listed under the U.S. Clean Air Act Section
450.
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Clean Water Act
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307
US State Regulations Pennsylvania Right To Know
Water (Aqua)
7732-18-5
90 - 100 %
Laureth-7
9002-92-0
1 - 5 %
New Jersey Right To Know
Water (Aqua)
7732-18-5
90 - 100 %
Laureth-7
9002-92-0
1 - 5 %
Polysorbate 20
9005-64-5
1 - 5 %
California Prop 65
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
The components of this product are reported in the following inventories:
TSCA
:
On TSCA Inventory
AICS
:
On the inventory, or in compliance with the inventory
DSL :
All components of this product are on the Canadian DSL.
ENCS
:
On the inventory, or in compliance with the inventory
ISHL
:
On the inventory, or in compliance with the inventory
KECI
:
On the inventory, or in compliance with the inventory
PICCS
:
On the inventory, or in compliance with the inventory
IECSC
:
On the inventory, or in compliance with the inventory
NZIoC
:
On the inventory, or in compliance with the inventory
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)
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SECTION 16. OTHER INFORMATION
Further information
NFPA:
HMIS III:
Revision Date
:
03/29/2018
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
Flammability
Health
Instability
2
1
0
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
1
0
2
Special hazard.
0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
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