Page 1
SAFETY DATA SHEET
GOJO® Antibacterial Plum Foam Handwash
Version
2.0
Revision Date:
04/17/2015
MSDS Number:
31854-00003
Date of last issue: 02/16/2015
Date of first issue: 11/24/2014
Product name
:
GOJO® Antibacterial Plum Foam Handwash
Company name of supplier
:
GOJO Industries, Inc.
Address
:
One GOJO Plaza, Suite 500
Akron OH 44311
Telephone
:
1 (330) 255-6000
Emergency telephone
:
1-800-424-9300 CHEMTREC
Recommended use
:
Antibacterial Soap
Restrictions on use
:
This is a personal care or cosmetic product that is safe for
consumers and other users under normal and reasonably
foreseeable use. Cosmetics and consumer products,
specifically defined by regulations around the world, are
exempt from the requirement of an SDS for the consumer.
While this material is not considered hazardous, this SDS
contains valuable information critical to the safe handling and
proper use of the product for industrial workplace conditions
as well as unusual and unintended exposures such as large
spills. This SDS should be retained and available for
employees and other users of this product. For specific
intended-use guidance, please refer to the information
provided on the package or instruction sheet.
Flammable liquids
:
Category 3
Serious eye damage
:
Category 1
Hazard pictograms
:
Signal Word
:
Danger
Hazard Statements
:
H226 Flammable liquid and vapor.
H318 Causes serious eye damage.
SECTION 1. IDENTIFICATION
Manufacturer or supplier's details
Recommended use of the chemical and restrictions on use
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
GHS Label element
1 / 21
Page 2
SAFETY DATA SHEET
GOJO® Antibacterial Plum Foam Handwash
Version
2.0
Revision Date:
04/17/2015
MSDS Number:
31854-00003
Date of last issue: 02/16/2015
Date of first issue: 11/24/2014
Precautionary Statements
:
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
P233 Keep container tightly closed.
P241 Use explosion-proof electrical/ ventilating/ lighting/
equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/shower.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER or doctor/ physician.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.
Substance / Mixture
:
Mixture
Chemical Name
CAS-No.
Concentration (%)
Ethanol
64-17-5
>= 10
- < 20
Dodecanoic acid
143-07-7
>= 5
- < 10
Propylene glycol
57-55-6
>= 5
- < 10
Ethanolamine
141-43-5
>= 1
- < 5
Imidazolium compounds, 1-[2(carboxymethoxy)ethyl]-1-(carboxymethyl)-4,5dihydro-2-norcoco alkyl, hydroxides, sodium
salts
68650-39-5
>= 1
- < 5
General advice
:
In the case of accident or if you feel unwell, seek medical
advice immediately.
When symptoms persist or in all cases of doubt seek medical
advice.
If inhaled
:
If inhaled, remove to fresh air.
Get medical attention if symptoms occur.
In case of skin contact
:
Wash with water and soap as a precaution.
Get medical attention if symptoms occur.
Other hazards
Vapors may form explosive mixture with air.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ingredients
SECTION 4. FIRST AID MEASURES
2 / 21
Page 3
SAFETY DATA SHEET
GOJO® Antibacterial Plum Foam Handwash
Version
2.0
Revision Date:
04/17/2015
MSDS Number:
31854-00003
Date of last issue: 02/16/2015
Date of first issue: 11/24/2014
In case of eye contact
:
In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
If easy to do, remove contact lens, if worn.
Get medical attention immediately.
If swallowed
:
If swallowed, DO NOT induce vomiting.
Get medical attention if symptoms occur.
Rinse mouth thoroughly with water.
Most important symptoms
and effects, both acute and
delayed
:
Causes serious eye damage.
Protection of first-aiders
:
First Aid responders should pay attention to self-protection,
and use the recommended personal protective equipment
when the potential for exposure exists.
Notes to physician
:
Treat symptomatically and supportively.
Suitable extinguishing media
:
Water spray
Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing
media
:
High volume water jet
Specific hazards during fire
fighting
:
Do not use a solid water stream as it may scatter and spread
fire.
Flash back possible over considerable distance.
Vapors may form explosive mixtures with air.
Exposure to combustion products may be a hazard to health.
Hazardous combustion products
:
Carbon oxides
Nitrogen oxides (NOx)
Metal oxides
Specific extinguishing
methods
:
Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Use water spray to cool unopened containers.
Remove undamaged containers from fire area if it is safe to do
so.
Evacuate area.
Special protective equipment
for fire-fighters
:
In the event of fire, wear self-contained breathing apparatus.
Use personal protective equipment.
Personal precautions,
:
Remove all sources of ignition.
SECTION 5. FIRE-FIGHTING MEASURES
SECTION 6. ACCIDENTAL RELEASE MEASURES
3 / 21
Page 4
SAFETY DATA SHEET
GOJO® Antibacterial Plum Foam Handwash
Version
2.0
Revision Date:
04/17/2015
MSDS Number:
31854-00003
Date of last issue: 02/16/2015
Date of first issue: 11/24/2014
protective equipment and
emergency procedures
Use personal protective equipment.
Follow safe handling advice and personal protective
equipment recommendations.
Environmental precautions
:
Discharge into the environment must be avoided.
Prevent further leakage or spillage if safe to do so.
Prevent spreading over a wide area (e.g. by containment or oil
barriers).
Retain and dispose of contaminated wash water.
Local authorities should be advised if significant spillages
cannot be contained.
Methods and materials for
containment and cleaning up
:
Non-sparking tools should be used.
Soak up with inert absorbent material.
Suppress (knock down) gases/vapors/mists with a water spray
jet.
For large spills, provide diking or other appropriate
containment to keep material from spreading. If diked material
can be pumped, store recovered material in appropriate
container.
Clean up remaining materials from spill with suitable
absorbent.
Local or national regulations may apply to releases and
disposal of this material, as well as those materials and items
employed in the cleanup of releases. You will need to
determine which regulations are applicable.
Sections 13 and 15 of this SDS provide information regarding
certain local or national requirements.
Technical measures
:
See Engineering measures under EXPOSURE
CONTROLS/PERSONAL PROTECTION section.
Local/Total ventilation
:
Use with local exhaust ventilation.
Use only in an area equipped with explosion proof exhaust
ventilation.
Advice on safe handling
:
Avoid inhalation of vapor or mist.
Do not swallow.
Do not get in eyes.
Avoid prolonged or repeated contact with skin.
Handle in accordance with good industrial hygiene and safety
practice.
Non-sparking tools should be used.
Keep container tightly closed.
Keep away from heat and sources of ignition.
Take precautionary measures against static discharges.
Take care to prevent spills, waste and minimize release to the
environment.
Conditions for safe storage
:
Keep in properly labeled containers.
Keep tightly closed.
Keep in a cool, well-ventilated place.
SECTION 7. HANDLING AND STORAGE
4 / 21
Page 5
SAFETY DATA SHEET
GOJO® Antibacterial Plum Foam Handwash
Version
2.0
Revision Date:
04/17/2015
MSDS Number:
31854-00003
Date of last issue: 02/16/2015
Date of first issue: 11/24/2014
Store in accordance with the particular national regulations.
Keep away from heat and sources of ignition.
Materials to avoid
:
Do not store with the following product types:
Strong oxidizing agents
Organic peroxides
Flammable solids
Pyrophoric liquids
Pyrophoric solids
Self-heating substances and mixtures
Substances and mixtures which in contact with water emit
flammable gases
Explosives
Gases
Ingredients
CAS-No.
Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
Ethanol
64-17-5
TWA
1,000 ppm
1,900 mg/m3
NIOSH REL
TWA
1,000 ppm
1,900 mg/m3
OSHA Z-1
STEL
1,000 ppm
ACGIH
Propylene glycol
57-55-6
TWA
10 mg/m3
US WEEL
Ethanolamine
141-43-5
TWA
3 ppm
ACGIH
STEL
6 ppm
ACGIH
TWA
3 ppm
8 mg/m3
NIOSH REL
ST
6 ppm
15 mg/m3
NIOSH REL
TWA
3 ppm
6 mg/m3
OSHA Z-1
Ingredients
CAS-No.
Dodecanoic acid
143-07-7
Imidazolium compounds, 1-[2(carboxymethoxy)ethyl]-1(carboxymethyl)-4,5-dihydro-2norcoco alkyl, hydroxides,
sodium salts
68650-39-5
Engineering measures
:
Minimize workplace exposure concentrations.
Use only in an area equipped with explosion proof exhaust
ventilation.
Use with local exhaust ventilation.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Hazardous components without workplace control parameters
Personal protective equipment
5 / 21
Page 6
SAFETY DATA SHEET
GOJO® Antibacterial Plum Foam Handwash
Version
2.0
Revision Date:
04/17/2015
MSDS Number:
31854-00003
Date of last issue: 02/16/2015
Date of first issue: 11/24/2014
Respiratory protection
:
General and local exhaust ventilation is recommended to
maintain vapor exposures below recommended limits. Where
concentrations are above recommended limits or are
unknown, appropriate respiratory protection should be worn.
Follow OSHA respirator regulations (29 CFR 1910.134) and
use NIOSH/MSHA approved respirators. Protection provided
by air purifying respirators against exposure to any
hazardous chemical is limited. Use a positive pressure air
supplied respirator if there is any potential for uncontrolled
release, exposure levels are unknown, or any other
circumstance where air purifying respirators may not provide
adequate protection.
Material
:
Impervious gloves
Material
:
Flame retardant gloves
Remarks
:
Choose gloves to protect hands against chemicals depending
on the concentration specific to place of work. Breakthrough
time is not determined for the product. Change gloves often!
For special applications, we recommend clarifying the
resistance to chemicals of the aforementioned protective
gloves with the glove manufacturer. Wash hands before
breaks and at the end of workday.
Eye protection
:
Wear the following personal protective equipment:
Chemical resistant goggles must be worn.
If splashes are likely to occur, wear:
Face-shield
Skin and body protection
:
Select appropriate protective clothing based on chemical
resistance data and an assessment of the local exposure
potential.
Wear the following personal protective equipment:
Flame retardant antistatic protective clothing.
Skin contact must be avoided by using impervious protective
clothing (gloves, aprons, boots, etc).
Hygiene measures
:
Ensure that eye flushing systems and safety showers are
located close to the working place.
When using do not eat, drink or smoke.
Wash contaminated clothing before re-use.
Appearance
:
liquid
Color
:
clear, purple
Odor
:
citrus
Odor Threshold
:
No data available
Hand protection
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
6 / 21
Page 7
SAFETY DATA SHEET
GOJO® Antibacterial Plum Foam Handwash
Version
2.0
Revision Date:
04/17/2015
MSDS Number:
31854-00003
Date of last issue: 02/16/2015
Date of first issue: 11/24/2014
pH :
7.8 - 9.7
Melting point/freezing point
:
No data available
Initial boiling point and boiling
range
:
97.00 °C
Flash point
:
56.00 °C
Evaporation rate
:
No data available
Flammability (solid, gas)
:
Not applicable
Upper explosion limit
:
No data available
Lower explosion limit
:
No data available
Vapor pressure
:
No data available
Relative vapor density
:
No data available
Density
:
1.00 g/cm3
Water solubility
:
soluble
Partition coefficient: noctanol/water
:
Not applicable
Autoignition temperature
:
No data available
Decomposition temperature
:
The substance or mixture is not classified self-reactive.
Viscosity, kinematic
:
10 - 20 mm2/s (20 °C)
Explosive properties
:
Not explosive
Oxidizing properties
:
The substance or mixture is not classified as oxidizing.
Reactivity
:
Not classified as a reactivity hazard.
Chemical stability
:
Stable under normal conditions.
Possibility of hazardous reactions
:
Flammable liquid and vapor.
Vapors may form explosive mixture with air.
Can react with strong oxidizing agents.
Conditions to avoid
:
Heat, flames and sparks.
Solubility(ies)
Viscosity
SECTION 10. STABILITY AND REACTIVITY
7 / 21
Page 8
SAFETY DATA SHEET
GOJO® Antibacterial Plum Foam Handwash
Version
2.0
Revision Date:
04/17/2015
MSDS Number:
31854-00003
Date of last issue: 02/16/2015
Date of first issue: 11/24/2014
Incompatible materials
:
Oxidizing agents
Hazardous decomposition
products
:
No hazardous decomposition products are known.
Acute oral toxicity
:
Acute toxicity estimate: > 5,000 mg/kg
Method: Calculation method
Acute inhalation toxicity
:
Acute toxicity estimate: > 40 mg/l
Exposure time: 4 h
Test atmosphere: vapor
Method: Calculation method
Acute dermal toxicity
:
Acute toxicity estimate: > 5,000 mg/kg
Method: Calculation method
Acute oral toxicity
:
LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity
:
LC50 (Rat): 124.7 mg/l
Exposure time: 4 h
Test atmosphere: vapor
Acute oral toxicity
:
LD50 (Rat): > 5,000 mg/kg
Method: OECD Test Guideline 401
Acute inhalation toxicity
:
LC50 (Rat): > 0.162 mg/l
Exposure time: 4 h
Test atmosphere: vapor
Remarks: Based on data from similar materials
Acute dermal toxicity
:
LD50 (Rabbit): > 2,000 mg/kg
Assessment: The substance or mixture has no acute dermal
toxicity
Remarks: Based on data from similar materials
Acute oral toxicity
:
LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity
:
LC50 (Rabbit): > 159 mg/l, > 51091 ppm
Exposure time: 4 h
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation
Skin contact
Ingestion
Eye contact
Acute toxicity
Not classified based on available information.
Product:
Ingredients:
Ethanol:
Dodecanoic acid:
Propylene glycol:
8 / 21
Page 9
SAFETY DATA SHEET
GOJO® Antibacterial Plum Foam Handwash
Version
2.0
Revision Date:
04/17/2015
MSDS Number:
31854-00003
Date of last issue: 02/16/2015
Date of first issue: 11/24/2014
Test atmosphere: dust/mist
Assessment: The substance or mixture has no acute
inhalation toxicity
Acute dermal toxicity
:
LD50 (Rabbit): > 2,000 mg/kg
Assessment: The substance or mixture has no acute dermal
toxicity
Acute oral toxicity
:
LD50 (Rat): 1,515 mg/kg
Acute inhalation toxicity
:
Acute toxicity estimate: 11 mg/l
Test atmosphere: vapor
Method: Expert judgment
Remarks: Based on harmonised classification in EU regulation
1272/2008, Annex VI
Acute dermal toxicity
:
LD50 (Rabbit): 1,025 mg/kg
Acute oral toxicity
:
LD50 (Rat, male): > 5,000 mg/kg
Remarks: Based on data from similar materials
Acute dermal toxicity
:
LD50 (Rat): > 5,000 mg/kg
Method: OECD Test Guideline 402
Remarks: Based on data from similar materials
Result: No skin irritation
Species: Rabbit
Method: OECD Test Guideline 404
Result: No skin irritation
Species: Rabbit
Method: OECD Test Guideline 404
Result: No skin irritation
Species: Rabbit
Method: OECD Test Guideline 404
Result: No skin irritation
Species: Rabbit
Result: Corrosive after 3 minutes to 1 hour of exposure
Ethanolamine:
Imidazolium compounds, 1-[2-(carboxymethoxy)ethyl]-1-(carboxymethyl)-4,5-dihydro-2norcoco alkyl, hydroxides, sodium salts:
Skin corrosion/irritation
Not classified based on available information.
Product:
Ingredients:
Ethanol:
Dodecanoic acid:
Propylene glycol:
Ethanolamine:
9 / 21
Page 10
SAFETY DATA SHEET
GOJO® Antibacterial Plum Foam Handwash
Version
2.0
Revision Date:
04/17/2015
MSDS Number:
31854-00003
Date of last issue: 02/16/2015
Date of first issue: 11/24/2014
Species: Rabbit
Method: OECD Test Guideline 404
Result: No skin irritation
Remarks: Based on data from similar materials
Species: Rabbit
Result: Irritation to eyes, reversing within 21 days
Method: OECD Test Guideline 405
Species: Rabbit
Result: Irreversible effects on the eye
Method: OECD Test Guideline 405
Species: Rabbit
Result: No eye irritation
Method: OECD Test Guideline 405
Species: Rabbit
Result: Irreversible effects on the eye
Species: Rabbit
Result: Irreversible effects on the eye
Method: OECD Test Guideline 405
Remarks: Based on data from similar materials
Assessment: Does not cause skin sensitization.
Test Type: Local lymph node assay (LLNA)
Routes of exposure: Skin contact
Species: Mouse
Result: negative
Test Type: Maximization Test (GPMT)
Imidazolium compounds, 1-[2-(carboxymethoxy)ethyl]-1-(carboxymethyl)-4,5-dihydro-2norcoco alkyl, hydroxides, sodium salts:
Serious eye damage/eye irritation
Causes serious eye damage.
Ingredients:
Ethanol:
Dodecanoic acid:
Propylene glycol:
Ethanolamine:
Imidazolium compounds, 1-[2-(carboxymethoxy)ethyl]-1-(carboxymethyl)-4,5-dihydro-2norcoco alkyl, hydroxides, sodium salts:
Respiratory or skin sensitization
Skin sensitization: Not classified based on available information.
Respiratory sensitization: Not classified based on available information.
Product:
Ingredients:
Ethanol:
Dodecanoic acid:
10 / 21
Page 11
SAFETY DATA SHEET
GOJO® Antibacterial Plum Foam Handwash
Version
2.0
Revision Date:
04/17/2015
MSDS Number:
31854-00003
Date of last issue: 02/16/2015
Date of first issue: 11/24/2014
Routes of exposure: Skin contact
Species: Guinea pig
Result: negative
Test Type: Maximization Test (GPMT)
Routes of exposure: Skin contact
Species: Guinea pig
Result: negative
Test Type: Maximization Test (GPMT)
Routes of exposure: Skin contact
Species: Guinea pig
Result: negative
Test Type: Maximization Test (GPMT)
Routes of exposure: Skin contact
Species: Guinea pig
Method: OECD Test Guideline 406
Result: negative
Remarks: Based on data from similar materials
Genotoxicity in vitro
:
Test Type: In vitro mammalian cell gene mutation test
Result: negative
Genotoxicity in vivo
:
Test Type: Rodent dominant lethal test (germ cell) (in vivo)
Species: Mouse
Application Route: Ingestion
Result: negative
Genotoxicity in vitro
:
Test Type: In vitro mammalian cell gene mutation test
Method: OECD Test Guideline 476
Result: negative
Remarks: Based on data from similar materials
Genotoxicity in vitro
:
Test Type: Bacterial reverse mutation assay (AMES)
Result: negative
Genotoxicity in vivo
:
Test Type: In vivo micronucleus test
Species: Mouse
Application Route: Intraperitoneal injection
Result: negative
Genotoxicity in vitro
:
Test Type: In vitro mammalian cell gene mutation test
Propylene glycol:
Ethanolamine:
Imidazolium compounds, 1-[2-(carboxymethoxy)ethyl]-1-(carboxymethyl)-4,5-dihydro-2norcoco alkyl, hydroxides, sodium salts:
Germ cell mutagenicity
Not classified based on available information.
Ingredients:
Ethanol:
Dodecanoic acid:
Propylene glycol:
Ethanolamine:
11 / 21
Page 12
SAFETY DATA SHEET
GOJO® Antibacterial Plum Foam Handwash
Version
2.0
Revision Date:
04/17/2015
MSDS Number:
31854-00003
Date of last issue: 02/16/2015
Date of first issue: 11/24/2014
Method: OECD Test Guideline 476
Result: negative
Genotoxicity in vivo
:
Test Type: Mammalian erythrocyte micronucleus test (in vivo
cytogenetic assay)
Species: Mouse
Application Route: Ingestion
Method: OECD Test Guideline 474
Result: negative
Genotoxicity in vitro
:
Test Type: Chromosome aberration test in vitro
Method: OECD Test Guideline 473
Result: negative
Remarks: Based on data from similar materials
:
Test Type: Bacterial reverse mutation assay (AMES)
Result: negative
Remarks: Based on data from similar materials
:
Test Type: In vitro mammalian cell gene mutation test
Method: OECD Test Guideline 476
Result: negative
Remarks: Based on data from similar materials
Species: Rat
Application Route: Ingestion
Exposure time: 2 Years
Result: negative
IARC
No ingredient of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
OSHA
No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
NTP
No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
Effects on fertility
:
Test Type: Two-generation reproduction toxicity study
Imidazolium compounds, 1-[2-(carboxymethoxy)ethyl]-1-(carboxymethyl)-4,5-dihydro-2norcoco alkyl, hydroxides, sodium salts:
Carcinogenicity
Not classified based on available information.
Ingredients:
Propylene glycol:
Reproductive toxicity
Not classified based on available information.
Ingredients:
Ethanol:
12 / 21
Page 13
SAFETY DATA SHEET
GOJO® Antibacterial Plum Foam Handwash
Version
2.0
Revision Date:
04/17/2015
MSDS Number:
31854-00003
Date of last issue: 02/16/2015
Date of first issue: 11/24/2014
Species: Mouse
Application Route: Ingestion
Method: OECD Test Guideline 416
Result: negative
Effects on fertility
:
Test Type: Combined repeated dose toxicity study with the
reproduction/developmental toxicity screening test
Species: Rat
Application Route: Ingestion
Method: OECD Test Guideline 422
Result: negative
Remarks: Based on data from similar materials
Effects on fetal development
:
Test Type: Combined repeated dose toxicity study with the
reproduction/developmental toxicity screening test
Species: Rat
Application Route: Ingestion
Method: OECD Test Guideline 422
Result: negative
Remarks: Based on data from similar materials
Effects on fertility
:
Species: Mouse
Application Route: Ingestion
Result: negative
Effects on fetal development
:
Test Type: Embryo-fetal development
Species: Mouse
Application Route: Ingestion
Result: negative
Effects on fertility
:
Test Type: Two-generation reproduction toxicity study
Species: Rat
Application Route: Ingestion
Result: negative
Effects on fetal development
:
Test Type: Embryo-fetal development
Species: Rat
Application Route: Ingestion
Method: OECD Test Guideline 414
Result: negative
Assessment: May cause respiratory irritation.
Dodecanoic acid:
Propylene glycol:
Ethanolamine:
STOT-single exposure
Not classified based on available information.
Ingredients:
Ethanolamine:
STOT-repeated exposure
Not classified based on available information.
13 / 21
Page 14
SAFETY DATA SHEET
GOJO® Antibacterial Plum Foam Handwash
Version
2.0
Revision Date:
04/17/2015
MSDS Number:
31854-00003
Date of last issue: 02/16/2015
Date of first issue: 11/24/2014
Routes of exposure: inhalation (dust/mist/fume)
Assessment: No significant health effects observed in animals at concentrations of 0.2 mg/l/6h/d
or less.
Species: Rat
NOAEL: 2,400 mg/kg
Application Route: Ingestion
Exposure time: 2 y
Species: Rat
NOAEL: 10,000 mg/kg
Application Route: Ingestion
Exposure time: 18 w
Species: Rat
NOAEL: 1,700 mg/kg
Application Route: Ingestion
Exposure time: 2 y
Species: Rat
NOAEL: 150 mg/m3
Application Route: inhalation (dust/mist/fume)
Exposure time: 28 d
Species: Rat, female
NOAEL: 250 mg/kg
LOAEL: 500 mg/kg
Application Route: Ingestion
Exposure time: 28 d
Remarks: Based on data from similar materials
Toxicity to fish
:
LC50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l
Exposure time: 96 h
Ingredients:
Ethanolamine:
Repeated dose toxicity
Ingredients:
Ethanol:
Dodecanoic acid:
Propylene glycol:
Ethanolamine:
Imidazolium compounds, 1-[2-(carboxymethoxy)ethyl]-1-(carboxymethyl)-4,5-dihydro-2norcoco alkyl, hydroxides, sodium salts:
Aspiration toxicity
Not classified based on available information.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Ingredients:
Ethanol:
14 / 21
Page 15
SAFETY DATA SHEET
GOJO® Antibacterial Plum Foam Handwash
Version
2.0
Revision Date:
04/17/2015
MSDS Number:
31854-00003
Date of last issue: 02/16/2015
Date of first issue: 11/24/2014
Toxicity to daphnia and other
aquatic invertebrates
:
EC50 (Daphnia magna (Water flea)): > 1,000 mg/l
Exposure time: 48 h
Toxicity to algae
:
EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201
Toxicity to daphnia and other
aquatic invertebrates
(Chronic toxicity)
:
NOEC (Daphnia magna (Water flea)): 9.6 mg/l
Exposure time: 9 d
Toxicity to bacteria
:
EC50 (Photobacterium phosphoreum): 32.1 mg/l
Exposure time: 0.25 h
Toxicity to fish
:
LC50 (Oryzias latipes (Japanese medaka)): 5 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203
Toxicity to daphnia and other
aquatic invertebrates
:
EC50 (Daphnia magna (Water flea)): 3.6 mg/l
Exposure time: 48 h
Method: OECD Test Guideline 202
Toxicity to algae
:
EC50 (Selenastrum capricornutum (green algae)): > 7.6 mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201
Remarks: No toxicity at the limit of solubility.
NOEC (Selenastrum capricornutum (green algae)): > 7.6 mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201
Remarks: No toxicity at the limit of solubility.
Toxicity to fish (Chronic
toxicity)
:
NOEC (Danio rerio (zebra fish)): 2 mg/l
Exposure time: 28 d
Remarks: Based on data from similar materials
Toxicity to daphnia and other
aquatic invertebrates
(Chronic toxicity)
:
NOEC (Daphnia magna (Water flea)): 0.47 mg/l
Exposure time: 21 d
Method: OECD Test Guideline 211
Toxicity to bacteria
:
EC10 (Pseudomonas putida): > 1,000 mg/l
Exposure time: 30 min
Method: OECD Test Guideline 209
Toxicity to fish
:
LC50 (Oncorhynchus mykiss (rainbow trout)): 40,613 mg/l
Exposure time: 96 h
Toxicity to daphnia and other
aquatic invertebrates
:
EC50 (Ceriodaphnia dubia (water flea)): 18,340 mg/l
Exposure time: 48 h
Toxicity to algae
:
EC50 (Skeletonema costatum (marine diatom)): 19,000 mg/l
Exposure time: 48 h
Dodecanoic acid:
Propylene glycol:
15 / 21
Page 16
SAFETY DATA SHEET
GOJO® Antibacterial Plum Foam Handwash
Version
2.0
Revision Date:
04/17/2015
MSDS Number:
31854-00003
Date of last issue: 02/16/2015
Date of first issue: 11/24/2014
Method: OECD Test Guideline 201
Toxicity to fish (Chronic
toxicity)
:
Chronic Toxicity Value: 2,500 mg/l
Exposure time: 30 d
Toxicity to daphnia and other
aquatic invertebrates
(Chronic toxicity)
:
NOEC (Ceriodaphnia dubia (water flea)): 29,000 mg/l
Exposure time: 7 d
Toxicity to bacteria
:
NOEC (Pseudomonas putida): > 20,000 mg/l
Exposure time: 18 h
Toxicity to fish
:
LC50 (Cyprinus carpio (Carp)): 349 mg/l
Exposure time: 96 h
Toxicity to daphnia and other
aquatic invertebrates
:
EC50 (Daphnia magna (Water flea)): 65 mg/l
Exposure time: 48 h
Toxicity to algae
:
ErC50 (Selenastrum capricornutum (green algae)): 2.8 mg/l
Exposure time: 72 h
NOEC (Scenedesmus capricornutum (fresh water algae)): 1
mg/l
Exposure time: 72 h
Toxicity to fish (Chronic
toxicity)
:
NOEC (Oryzias latipes (Orange-red killifish)): 1.24 mg/l
Exposure time: 41 d
Toxicity to daphnia and other
aquatic invertebrates
(Chronic toxicity)
:
NOEC (Daphnia magna (Water flea)): 0.85 mg/l
Exposure time: 21 d
Toxicity to bacteria
:
EC50 (Pseudomonas putida): 110 mg/l
Exposure time: 17 h
Toxicity to fish
:
LC50 (Oncorhynchus mykiss (rainbow trout)): 4.2 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203
Remarks: Based on data from similar materials
Toxicity to daphnia and other
aquatic invertebrates
:
EC50 (Daphnia magna (Water flea)): 17.9 mg/l
Exposure time: 48 h
Method: OECD Test Guideline 202
Remarks: Based on data from similar materials
Toxicity to algae
:
NOEC (Pseudokirchneriella subcapitata (green algae)): 3.2
mg/l
Exposure time: 72 h
Method: Directive 67/548/EEC, Annex V, C.3.
Remarks: Based on data from similar materials
ErC50 (Pseudokirchneriella subcapitata (green algae)): 10
Ethanolamine:
Imidazolium compounds, 1-[2-(carboxymethoxy)ethyl]-1-(carboxymethyl)-4,5-dihydro-2norcoco alkyl, hydroxides, sodium salts:
16 / 21
Page 17
SAFETY DATA SHEET
GOJO® Antibacterial Plum Foam Handwash
Version
2.0
Revision Date:
04/17/2015
MSDS Number:
31854-00003
Date of last issue: 02/16/2015
Date of first issue: 11/24/2014
mg/l
Exposure time: 72 h
Method: Directive 67/548/EEC, Annex V, C.3.
Remarks: Based on data from similar materials
Biodegradability
:
Result: Biodegradable
Biodegradability
:
Result: Readily biodegradable.
Biodegradation: 84 %
Exposure time: 20 d
Biodegradability
:
Result: Readily biodegradable.
Biodegradation: 86 %
Exposure time: 30 d
Method: OECD Test Guideline 301D
Biodegradability
:
Result: Readily biodegradable.
Biodegradation: 98.3 %
Exposure time: 28 d
Method: OECD Test Guideline 301F
Biodegradability
:
Result: Readily biodegradable.
Biodegradation: > 90 %
Exposure time: 21 d
Biodegradability
:
Result: Readily biodegradable.
Biodegradation: 79 %
Exposure time: 28 d
Method: OECD Test Guideline 301F
Remarks: Based on data from similar materials
Partition coefficient: noctanol/water
:
log Pow: -0.35
Bioaccumulation
:
Species: Fish
Bioconcentration factor (BCF): 234 - 288
Remarks: Based on data from similar materials
Persistence and degradability
Product:
Ingredients:
Ethanol:
Dodecanoic acid:
Propylene glycol:
Ethanolamine:
Imidazolium compounds, 1-[2-(carboxymethoxy)ethyl]-1-(carboxymethyl)-4,5-dihydro-2norcoco alkyl, hydroxides, sodium salts:
Bioaccumulative potential
Ingredients:
Ethanol:
Dodecanoic acid:
17 / 21
Page 18
SAFETY DATA SHEET
GOJO® Antibacterial Plum Foam Handwash
Version
2.0
Revision Date:
04/17/2015
MSDS Number:
31854-00003
Date of last issue: 02/16/2015
Date of first issue: 11/24/2014
Partition coefficient: noctanol/water
:
Pow: 4.6
Partition coefficient: noctanol/water
:
log Pow: -1.07
Partition coefficient: noctanol/water
:
log Pow: -1.91
Waste from residues
:
Dispose of in accordance with local regulations.
Contaminated packaging
:
Dispose of as unused product.
Empty containers should be taken to an approved waste
handling site for recycling or disposal.
Do not burn, or use a cutting torch on, the empty drum.
UNRTDG
UN number
:
UN 1170
Proper shipping name
:
ETHYL ALCOHOL SOLUTION
Class
:
3
Packing group
:
III
Labels
:
3
IATA-DGR
UN/ID No.
:
UN 1170
Proper shipping name
:
Ethanol solution
Class
:
3
Packing group
:
III
Labels
:
Flammable Liquids
Packing instruction (cargo
aircraft)
:
366
Packing instruction
(passenger aircraft)
:
355
IMDG-Code
UN number
:
UN 1170
Propylene glycol:
Ethanolamine:
Mobility in soil
No data available
Other adverse effects
No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
SECTION 14. TRANSPORT INFORMATION
International Regulation
18 / 21
Page 19
SAFETY DATA SHEET
GOJO® Antibacterial Plum Foam Handwash
Version
2.0
Revision Date:
04/17/2015
MSDS Number:
31854-00003
Date of last issue: 02/16/2015
Date of first issue: 11/24/2014
Proper shipping name
:
ETHYL ALCOHOL SOLUTION
(Triclosan)
Class
:
3
Packing group
:
III
Labels
:
3
EmS Code
:
F-E, S-D
Marine pollutant
:
yes
49 CFR
UN/ID/NA number
:
UN 1170
Proper shipping name
:
ETHYL ALCOHOL SOLUTIONS
Class
:
3
Packing group
:
III
Labels
:
FLAMMABLE LIQUID
ERG Code
:
127
Marine pollutant
:
yes (Triclosan)
SARA 311/312 Hazards
:
Fire Hazard
Acute Health Hazard
SARA 302
:
No chemicals in this material are subject to the reporting
requirements of SARA Title III, Section 302.
SARA 313
:
This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
Water
7732-18-5
70 - 90 %
Ethanol
64-17-5
10 - 20 %
Propylene glycol
57-55-6
5 - 10 %
Dodecanoic acid
143-07-7
5 - 10 %
Ethanolamine
141-43-5
1 - 5 %
Propan-2-ol
67-63-0
0.1 - 1 %
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know
CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
US State Regulations
Pennsylvania Right To Know
19 / 21
Page 20
SAFETY DATA SHEET
GOJO® Antibacterial Plum Foam Handwash
Version
2.0
Revision Date:
04/17/2015
MSDS Number:
31854-00003
Date of last issue: 02/16/2015
Date of first issue: 11/24/2014
Water
7732-18-5
70 - 90 %
Ethanol
64-17-5
10 - 20 %
Propylene glycol
57-55-6
5 - 10 %
Dodecanoic acid
143-07-7
5 - 10 %
Ethanolamine
141-43-5
1 - 5 %
California Prop 65
This product does not contain any chemicals known to the
State of California to cause cancer, birth, or any other
reproductive defects.
AICS
:
All ingredients listed or exempt.
NFPA:
HMIS III:
ACGIH
:
USA. ACGIH Threshold Limit Values (TLV)
NIOSH REL
:
USA. NIOSH Recommended Exposure Limits
OSHA Z-1
:
USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants
US WEEL
:
USA. Workplace Environmental Exposure Levels (WEEL)
ACGIH / TWA
:
8-hour, time-weighted average
ACGIH / STEL
:
Short-term exposure limit
NIOSH REL / TWA
:
Time-weighted average concentration for up to a 10-hour
workday during a 40-hour workweek
NIOSH REL / ST
:
STEL - 15-minute TWA exposure that should not be exceeded
at any time during a workday
Flammability
Health
Instability
3
2
0
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
2
0
3
Special hazard.
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
New Jersey Right To Know
The ingredients of this product are reported in the following inventories:
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan),
ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA
(USA)
SECTION 16. OTHER INFORMATION
Further information
Full text of other abbreviations
20 / 21
Page 21
SAFETY DATA SHEET
GOJO® Antibacterial Plum Foam Handwash
Version
2.0
Revision Date:
04/17/2015
MSDS Number:
31854-00003
Date of last issue: 02/16/2015
Date of first issue: 11/24/2014
OSHA Z-1 / TWA
:
8-hour time weighted average
US WEEL / TWA
:
8-hr TWA
Sources of key data used to
compile the Material Safety
Data Sheet
:
Internal technical data, data from raw material SDSs, OECD
eChem Portal search results and European Chemicals Agency, http://echa.europa.eu/
Revision Date
:
04/17/2015
Items where changes have been made to the previous version are highlighted in the body of
this document by two vertical lines.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and
shall not be considered a warranty or quality specification of any type. The information provided relates only to the specific material identified at the top of this SDS and may not be valid
when the SDS material is used in combination with any other materials or in any process, unless specified in the text. Material users should review the information and recommendations
in the specific context of their intended manner of handling, use, processing and storage, including an assessment of the appropriateness of the SDS material in the user’s end product, if
applicable.
US / Z8
21 / 21
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