GoJo 1911-02, 8811-03 User Manual

Page 1
SAFETY DATA SHEET
GOJO® Clear & Mild Foam Handwash
Version 1.0
Revision Date: 09/20/2016
Company name of supplier
:
GOJO Industries, Inc.
Address
:
One GOJO Plaza, Suite 500
Emergency telephone
:
1-800-424-9300 CHEMTREC Recommended use
:
Skin-care
Restrictions on use
:
This is a personal care or cosmetic product that is safe for
Eye irritation
:
Category 2B
Signal word
:
Warning
Hazard statements
:
H320 Causes eye irritation.
Precautionary statements
:
Response:
SECTION 1. IDENTIFICATION
Product name
Manufacturer or supplier's details
Telephone
number
Recommended use of the chemical and restrictions on use
: GOJO® Clear & Mild Foam Handwash
Akron, Ohio 44311
: 1 (330) 255-6000
consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifi­cally defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this mate­rial is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures suc h as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet.
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
GHS label elements
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ atten­tion.
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SAFETY DATA SHEET
GOJO® Clear & Mild Foam Handwash
Version 1.0
Revision Date: 09/20/2016
Chemical name
CAS-No.
Concentration (%)
Sodium Laureth Sulfate
68585-34-2
>= 1
- < 5
Glycerin
56-81-5
>= 1
- < 5
General advice
:
In the case of accident or if you feel unwell, seek medical ad­In case of skin contact
:
Wash with water and soap as a precaution.
If swallowed
:
If swallowed, DO NOT induce vomiting.
Most important symptoms
:
Causes eye irritation. Protection of first-aiders
:
First Aid responders should pay attention to self-protection
Suitable extinguishing media
:
Use water spray, alcohol-resistant foam, dry chemical or car-
Unsuitable extinguishing
:
None known.
Hazardous combustion prod-
:
Sulphur oxides
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
SECTION 4. FIRST AID MEASURES
If inhaled
In case of eye contact
and effects, both acute and delayed
vice immediately. When symptoms persist or in all cases of doubt seek medical advice.
: If inhaled, remove to fresh air.
If symptoms persist, call a physician.
Get medical attention if irritation develops and persists.
: In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes. If easy to do, remove contact lens, if worn. Seek medical advice.
Rinse mouth with water. Obtain medical attention.
and use the recommended protective clothing
SECTION 5. FIREFIGHTING MEASURES
media
ucts
bon dioxide.
Carbon oxides Nitrogen oxides (NOx) Metal oxides
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SAFETY DATA SHEET
GOJO® Clear & Mild Foam Handwash
Version 1.0
Revision Date: 09/20/2016
Specific extinguishing meth-
:
Use extinguishing measures that are appropriate to local cir-
Further information
:
Collect contaminated fire extinguishing water separately. This
Personal precautions, protec-
:
Use personal protective equipment.
Environmental precautions
:
Discharge into the environment must be avoided.
Methods and materials for
:
Contain spillage, and then collect wit h non -combustible ab-
Advice on safe handling
:
For personal protection see section 8.
(Form of
ters / Permissible
ods
Special protective equipment for firefighters
SECTION 6. ACCIDENTAL RELEASE MEASURES
tive equipment and emer­gency procedures
cumstances and the surrounding environment. Use a water spray to cool fully closed containers.
must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
: In the event of fire, wear self-contained breathing apparatus.
Use personal protective equipment.
Ensure adequate ventilatio n. Evacuate personnel to safe areas. Material can create slippery conditions.
Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.
containment and cleaning up
SECTION 7. HANDLING AND STORAGE
Conditions for safe storage : Keep in properly labelled containers.
SECTION 8. EXPOSURE CONT RO L S/PERSONAL PROT ECTION
Components with workplace control parameters
Components CAS-No. Value type
sorbent material, (e.g. sand, earth, diatomaceous earth, ver­miculite) and place in container for disposal according to local / national regulations (see section 13). Keep in suitable, closed containers for disposal. Clean contaminated floors and objects thoroughly while ob­serving environmental regulations.
Do not swallow. Avoid contact with eyes. Keep container closed when not in use.
Keep container tightly closed in a dry and well-ventilated place. Store in accordance with the particular nat ion al regu lat ions .
Control parame-
Basis
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SAFETY DATA SHEET
GOJO® Clear & Mild Foam Handwash
Version 1.0
Revision Date: 09/20/2016
exposure)
concentration
Glycerin
56-81-5
TWA (mist, fraction)
5 mg/m3
OSHA Z-1 TWA (mist, total dust)
15 mg/m3
OSHA Z-1
Skin and body protection
:
No special measures necessary provided product is used
Appearance
:
liquid
Colour
:
clear, colourless, light yellow
Odour
:
like soap
Odour Threshold
:
No data available
pH :
5.3 - 6.7, (20 °C)
Solidification / Setting point
:
1.4 °C
Initial boiling point and boiling
:
98 °C Flash point
:
> 100 °C
Evaporation rate
:
No data available
Flammability (solid, gas)
:
Not applicable
Upper explosion limit
:
No data available
respirable
Personal protective equipment
Respiratory protection
Eye protection
: No personal respiratory protective equipment normally re-
quired.
: No special measures necessary provided product is used
correctly. Wear face-shield and protective suit for abnormal processing problems.
Protective measures
Hygiene measures
SECTION 9. PHYSI CAL AND CHEMIC AL PRO PER TIES
correctly.
: Choose body protection in relation to its type, to the concen-
tration and amount of dangerous substances, and to the spe­cific work-place. Ensure that eye flushing systems and safety showers are located close to the working place.
: Handle in accordance with good industrial hygiene and safety
practice. Avoid contact with eyes.
range
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SAFETY DATA SHEET
GOJO® Clear & Mild Foam Handwash
Version 1.0
Revision Date: 09/20/2016
Lower explosion limit
:
No data available
Vapour pressure
:
No data available
Relative vapour density
:
No data available
Density
:
1.012 g/cm3
Auto-ignition temper ature
:
not determined
Thermal decomposition
:
The substance or mixture is not classified self-reactive.
Explosive properties
:
Not explosive
Oxidizing properties
:
The substance or mixture is not classified as oxidizing.
Reactivity
:
Not classified as a reactivity hazard.
Chemical stability
:
Stable under normal conditions.
Possibility of hazardous reac-
:
No dangerous reaction known under conditions of normal use. Incompatible materials
:
Strong oxidizing agents
Hazardous decomposition
:
No hazardous decomposition products are known.
Acute oral toxicity
:
Acute toxicity estimate : > 5,000 mg/kg
Solubility(ies)
Water solubility
: soluble
Partition coefficient: n­octanol/water
Viscosity
Viscosity, kinematic
SECTION 10. STABILITY AND REACTIVITY
tions
: Not applicable
: 10 - 20 mm2/s (20 °C)
products
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Skin contact Eye contact Inhalation
Acute toxicity
Not classified based on available information.
Product:
Method: Calculation method
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SAFETY DATA SHEET
GOJO® Clear & Mild Foam Handwash
Version 1.0
Revision Date: 09/20/2016
Acute oral toxicity
:
LD50 (Rat): > 2,000 mg/kg
Assessment: Not irritating when applied to human skin. Result: Skin irritation
Result: Mild eye irritation
Genotoxicity in vitro
:
Test Type: In vitro mammalian cell gene mutation test
Components: Sodium Laureth Sulfate:
Glycerin:
Acute oral toxicity
Skin corrosion/irritation
Not classified based on available information.
Product:
Result: No skin irritation
Components: Sodium Laureth Sulfate:
Glycerin:
Result: No skin irritation
Serious eye damage/eye irritation
Causes eye irritation.
Assessment: The substance or mixture has no acute oral tox­icity
: LD50 (Rat): > 5,000 mg/kg
Product:
Components: Sodium Laureth Sulfate:
Result: Eye irritation Remarks: Severe eye irritation
Glycerin:
Result: No eye irritation
Respiratory or skin sensitisation
Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information.
Germ cell mutagenicity
Not classified based on available information.
Components: Glycerin:
Method: OECD Test Guideline 476 Result: negative
Carcinogenicity
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SAFETY DATA SHEET
GOJO® Clear & Mild Foam Handwash
Version 1.0
Revision Date: 09/20/2016
Species: Rat
IARC
ACGIH
OSHA
NTP
Effects on foetal develop-
:
Test Type: Embryo-foetal development Repeated dose toxicity -
:
Causes serious eye irritation. Species: Rat
Not classified based on available information.
Components: Glycerin:
Application Route: Ingestion Exposure time: 2 Years Result: negative
Reproductive toxicity
Not classified based on available information.
Components: Glycerin:
Effects on fertility
No component of this product present at levels greate r than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential car c ino­gen by ACGIH.
No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino­gen by OSHA.
No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
: Test Type: Two-generatio n r eproduc t ion tox icity study
Species: Rat Application Route: Ingestion Result: negative
ment
STOT - single exposure
Not classified based on available information.
STOT - repeated exposure
Not classified based on available information.
Repeated dose toxicity Components:
Sodium Laureth Sulfate:
Assessment
Glycerin:
Species: Rabbit Application Route: Ingestion Result: negative
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Page 8
SAFETY DATA SHEET
GOJO® Clear & Mild Foam Handwash
Version 1.0
Revision Date: 09/20/2016
NOAEL: 167 mg/m3
Toxicity to fish
:
LC50 (Oncorhynchus mykiss (rainbow trout)): 54,000 mg/l
Toxicity to daphnia and other
:
EC50 (Daphnia magna (Water flea)): 1,955 mg/l
Toxicity to bacteria
:
NOEC (Pseudomonas putida): > 10,000 mg/l Biodegradability
:
Result: Readily biodegradable.
Biodegradability
:
Result: Readily biodegradable. Partition coefficient: n-
:
log Pow: -1.76
Regulation
40 CFR Protection of Environment; Part 82 Protection of
Remarks
This product neither contains, nor was manufactured with a
LOAEL: 660 mg/m3 Application Route: inhalation (dust/mist/fume) Exposure time: 13 w Symptoms: Local irritation
Aspiration toxicity
Not classified based on available information.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity Components:
Glycerin:
aquatic invertebrates
Persistence and degradability Components:
Sodium Laureth Sulfate:
Glycerin:
Bioaccumulative potential Components:
Glycerin:
octanol/water
Exposure time: 96 h
Exposure time: 48 h
Exposure time: 16 h
Biodegradation: 94 % Exposure time: 1 d
Mobility in soil
No data available
Other adverse effects
No data available
Product:
Stratospheric Ozone - CAA Section 602 Class I Substances
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SAFETY DATA SHEET
GOJO® Clear & Mild Foam Handwash
Version 1.0
Revision Date: 09/20/2016
Class I or Class II ODS as defined by the U.S. Clean Air Act Waste from residues
:
Dispose of in accordance with local regulations.
Contaminated packaging
:
Dispose of as unused product.
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
49 CFR
Not regulated as a dangerous good
SARA 311/312 Hazards
:
Acute Health Hazard
SARA 302
:
No chemicals in this material are subject to the reporting re-
SARA 313
:
This material does not contain any chemical components with
Glycerin
56-81-5
1.75 %
Section 602 (40 CFR 82, Subpt. A, App.A + B).
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Empty containers should be taken to an approved waste han­dling site for recycling or disposal.
SECTION 14. TRANSPORT INFORMATION
International Regulation
Not regulated as a dangerous good
National Regulations
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Kn ow Act CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Su bst ance s Reportable Quantity
This material does not contain any component s w ith a sec tion 304 EH S RQ.
quirements of SARA Title III, Section 302.
known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Clean Air Act
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermedi­ate or Final VOC's (40 CFR 60.489):
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SAFETY DATA SHEET
GOJO® Clear & Mild Foam Handwash
Version 1.0
Revision Date: 09/20/2016
Glycerin
56-81-5
1 - 5 %
Water (Aqua)
7732-18-5
90 - 100 %
Glycerin
56-81-5
1 - 5 %
Water (Aqua)
7732-18-5
90 - 100 %
Sodium Laureth Sulfate
68585-34-2
1 - 5 %
Glycerin
56-81-5
1 - 5 %
California Prop 65
This product does not contain any chemicals known to State productive harm.
TSCA
:
On the inventory, or in compliance with the inventory
DSL :
All components of this product are on the Canadian DSL.
NZIoC
:
On the inventory, or in compliance with the inventory
ENCS
:
On the inventory, or in compliance with the inventory
KECI
:
On the inventory, or in compliance with the inventory
PICCS
:
On the inventory, or in compliance with the inventory
This product does not contain any VOC exemptions listed under the U.S. Clean Air Act Section
450.
Clean Water Act
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307
Massachusetts Right To Know
Pennsylvania Right To Know
New Jersey Right To Know
of California to cause cancer, birth defects, or any other re-
The components of this product are reported in the following inventories:
CH INV
AICS
ISHL
IECSC
: On the inventory, or in compliance with the inventory
: On the inventory, or in compliance with the inventory
: On the inventory, or in compliance with the inventory
: On the inventory, or in compliance with the inventory
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)
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SAFETY DATA SHEET
GOJO® Clear & Mild Foam Handwash
Version 1.0
Revision Date: 09/20/2016
NFPA:
HMIS III:
Revision Date
:
09/20/2016
Flammability
Health
1
0
0
FLAMMABILITY
HEALTH
0
0
1
Special hazard.
0 = not significant, 1 =Slight,
SECTION 16. OTHER INFORMATION
Further information
The information provided in this Safety Data Sheet is correct to the best of our knowledge, in­formation and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
Instability
PHYSICAL HAZARD
2 = Moderate, 3 = High 4 = Extreme, * = Chronic
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