SAFETY DATA SHEET
GOJO® NATURAL* ORANGE™ Pumice Hand
Cleaner
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
28583-00002
Date of last issue: 11/05/2014
Date of first issue: 11/05/2014
Product name
:
GOJO® NATURAL* ORANGE™ Pumice Hand Cleaner
Company name of supplier
:
GOJO Industries, Inc.
Address
:
One GOJO Plaza, Suite 500
Akron OH 44311
Telephone
:
1 (330) 255-6000
Emergency telephone
:
1-800-424-9300 CHEMTREC
Recommended use
:
Skin-care
Restrictions on use
:
This is a personal care or cosmetic product that is safe for
consumers and other users under normal and reasonably
foreseeable use. Cosmetics and consumer products,
specifically defined by regulations around the world, are
exempt from the requirement of an SDS for the consumer.
While this material is not considered hazardous, this SDS
contains valuable information critical to the safe handling and
proper use of the product for industrial workplace conditions
as well as unusual and unintended exposures such as large
spills. This SDS should be retained and available for
employees and other users of this product. For specific
intended-use guidance, please refer to the information
provided on the package or instruction sheet.
Substance / Mixture
:
Mixture
Chemical Name
CAS-No.
Concentration (%)
SECTION 1. IDENTIFICATION
Manufacturer or supplier's details
Recommended use of the chemical and restrictions on use
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
Not a hazardous substance or mixture.
GHS Label element
Not a hazardous substance or mixture.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ingredients
1 / 13
SAFETY DATA SHEET
GOJO® NATURAL* ORANGE™ Pumice Hand
Cleaner
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
28583-00002
Date of last issue: 11/05/2014
Date of first issue: 11/05/2014
Distillates (petroleum), hydrotreated light
64742-47-8
>= 5
- < 10
1-Methyl 4-(1-Methylethenyl) Cyclohexene
5989-27-5
>= 0.1
- < 1
If inhaled
:
If inhaled, remove to fresh air.
Get medical attention if symptoms occur.
In case of skin contact
:
Wash with water and soap as a precaution.
Get medical attention if symptoms occur.
In case of eye contact
:
Flush eyes with water as a precaution.
Get medical attention if irritation develops and persists.
If swallowed
:
If swallowed, DO NOT induce vomiting.
Get medical attention if symptoms occur.
Rinse mouth thoroughly with water.
Most important symptoms
and effects, both acute and
delayed
:
None known.
Protection of first-aiders
:
No special precautions are necessary for first aid responders.
Notes to physician
:
Treat symptomatically and supportively.
Suitable extinguishing media
:
Water spray
Alcohol-resistant foam
Dry chemical
Carbon dioxide (CO2)
Unsuitable extinguishing
media
:
None known.
Specific hazards during fire
fighting
:
Exposure to combustion products may be a hazard to health.
Hazardous combustion products
:
Carbon oxides
Specific extinguishing
methods
:
Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Use water spray to cool unopened containers.
Remove undamaged containers from fire area if it is safe to do
so.
Evacuate area.
Special protective equipment
for fire-fighters
:
Wear self-contained breathing apparatus for firefighting if
necessary.
SECTION 4. FIRST AID MEASURES
SECTION 5. FIRE-FIGHTING MEASURES
2 / 13
SAFETY DATA SHEET
GOJO® NATURAL* ORANGE™ Pumice Hand
Cleaner
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
28583-00002
Date of last issue: 11/05/2014
Date of first issue: 11/05/2014
Use personal protective equipment.
Personal precautions,
protective equipment and
emergency procedures
:
Follow safe handling advice and personal protective
equipment recommendations.
Environmental precautions
:
Discharge into the environment must be avoided.
Prevent further leakage or spillage if safe to do so.
Prevent spreading over a wide area (e.g. by containment or oil
barriers).
Retain and dispose of contaminated wash water.
Local authorities should be advised if significant spillages
cannot be contained.
Methods and materials for
containment and cleaning up
:
Soak up with inert absorbent material.
For large spills, provide diking or other appropriate
containment to keep material from spreading. If diked material
can be pumped, store recovered material in appropriate
container.
Clean up remaining materials from spill with suitable
absorbent.
Local or national regulations may apply to releases and
disposal of this material, as well as those materials and items
employed in the cleanup of releases. You will need to
determine which regulations are applicable.
Sections 13 and 15 of this SDS provide information regarding
certain local or national requirements.
Technical measures
:
See Engineering measures under EXPOSURE
CONTROLS/PERSONAL PROTECTION section.
Local/Total ventilation
:
Use only with adequate ventilation.
Advice on safe handling
:
Avoid prolonged or repeated contact with skin.
Handle in accordance with good industrial hygiene and safety
practice.
Take care to prevent spills, waste and minimize release to the
environment.
Conditions for safe storage
:
Keep in properly labeled containers.
Store in accordance with the particular national regulations.
Materials to avoid
:
Do not store with the following product types:
Strong oxidizing agents
SECTION 6. ACCIDENTAL RELEASE MEASURES
SECTION 7. HANDLING AND STORAGE
3 / 13
SAFETY DATA SHEET
GOJO® NATURAL* ORANGE™ Pumice Hand
Cleaner
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
28583-00002
Date of last issue: 11/05/2014
Date of first issue: 11/05/2014
Ingredients
CAS-No.
Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
Distillates (petroleum),
hydrotreated light
64742-47-8
TWA (Mist)
5 mg/m3
OSHA Z-1
TWA (Mist)
5 mg/m3
NIOSH REL
ST (Mist)
10 mg/m3
NIOSH REL
Ingredients
CAS-No.
1-Methyl 4-(1-Methylethenyl)
Cyclohexene
5989-27-5
Engineering measures
:
Ensure adequate ventilation, especially in confined areas.
Minimize workplace exposure concentrations.
Dust formation may be relevant in the processing of this
product. In addition to substance-specific OELs, general
limitations of concentrations of particulates in the air at
workplaces have to be considered in workplace risk
assessment. Relevant limits include: OSHA PEL for
Particulates Not Otherwise Regulated of 15 mg/m3 - total
dust, 5 mg/m3 - respirable fraction; and ACGIH TWA for
Particles (insoluble or poorly soluble) Not Otherwise
Specified of 3 mg/m3 - respirable particles, 10 mg/m3 inhalable particles.
Respiratory protection
:
General and local exhaust ventilation is recommended to
maintain vapor exposures below recommended limits. Where
concentrations are above recommended limits or are
unknown, appropriate respiratory protection should be worn.
Follow OSHA respirator regulations (29 CFR 1910.134) and
use NIOSH/MSHA approved respirators. Protection provided
by air purifying respirators against exposure to any
hazardous chemical is limited. Use a positive pressure air
supplied respirator if there is any potential for uncontrolled
release, exposure levels are unknown, or any other
circumstance where air purifying respirators may not provide
adequate protection.
Remarks
:
For prolonged or repeated contact use protective gloves.
Wash hands before breaks and at the end of workday.
Eye protection
:
Wear the following personal protective equipment:
Safety glasses
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Hazardous components without workplace control parameters
Personal protective equipment
Hand protection
4 / 13
SAFETY DATA SHEET
GOJO® NATURAL* ORANGE™ Pumice Hand
Cleaner
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
28583-00002
Date of last issue: 11/05/2014
Date of first issue: 11/05/2014
Skin and body protection
:
Skin should be washed after contact.
Hygiene measures
:
Ensure that eye flushing systems and safety showers are
located close to the working place.
When using do not eat, drink or smoke.
Wash contaminated clothing before re-use.
Appearance
:
liquid
Color
:
gray, opaque
Odor
:
fruity
Odor Threshold
:
No data available
pH :
6 - 8
Melting point/freezing point
:
No data available
Solidification / Setting point
11.40 °C
Initial boiling point and boiling
range
:
98.00 °C
Flash point
:
> 100 °C
Evaporation rate
:
No data available
Flammability (solid, gas)
:
Not applicable
Upper explosion limit
:
No data available
Lower explosion limit
:
No data available
Vapor pressure
:
No data available
Relative vapor density
:
No data available
Density
:
1.0000 g/cm3
Water solubility
:
soluble
Partition coefficient: noctanol/water
:
Not applicable
Autoignition temperature
:
No data available
Decomposition temperature
:
The substance or mixture is not classified self-reactive.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Solubility(ies)
5 / 13
SAFETY DATA SHEET
GOJO® NATURAL* ORANGE™ Pumice Hand
Cleaner
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
28583-00002
Date of last issue: 11/05/2014
Date of first issue: 11/05/2014
Viscosity, kinematic
:
10,000 - 45,000 mm2/s (20 °C)
Explosive properties
:
Not explosive
Oxidizing properties
:
The substance or mixture is not classified as oxidizing.
Reactivity
:
Not classified as a reactivity hazard.
Chemical stability
:
Stable under normal conditions.
Possibility of hazardous reactions
:
Can react with strong oxidizing agents.
Conditions to avoid
:
None known.
Incompatible materials
:
Oxidizing agents
Hazardous decomposition
products
:
No hazardous decomposition products are known.
Acute oral toxicity
:
LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity
:
LC50 (Rat): > 5.3 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Assessment: The substance or mixture has no acute
inhalation toxicity
Remarks: Based on data from similar materials
Acute dermal toxicity
:
LD50 (Rabbit): > 3,160 mg/kg
Assessment: The substance or mixture has no acute dermal
toxicity
Acute oral toxicity
:
LD50 (Rat): > 2,000 mg/kg
Assessment: The substance or mixture has no acute oral
Viscosity
SECTION 10. STABILITY AND REACTIVITY
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation
Skin contact
Ingestion
Eye contact
Acute toxicity
Not classified based on available information.
Ingredients:
Distillates (petroleum), hydrotreated light:
1-Methyl 4-(1-Methylethenyl) Cyclohexene:
6 / 13
SAFETY DATA SHEET
GOJO® NATURAL* ORANGE™ Pumice Hand
Cleaner
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
28583-00002
Date of last issue: 11/05/2014
Date of first issue: 11/05/2014
toxicity
Remarks: Based on data from similar materials
Result: No skin irritation
Assessment: Repeated exposure may cause skin dryness or cracking.
Species: Rabbit
Result: Skin irritation
Species: Rabbit
Result: No eye irritation
Species: Rabbit
Result: No eye irritation
Assessment: Does not cause skin sensitization.
Test Type: Maximization Test (GPMT)
Routes of exposure: Skin contact
Species: Guinea pig
Result: negative
Remarks: Based on data from similar materials
Test Type: Local lymph node assay (LLNA)
Routes of exposure: Skin contact
Species: Mouse
Result: positive
Assessment: Probability or evidence of skin sensitization in humans
Skin corrosion/irritation
Not classified based on available information.
Product:
Ingredients:
Distillates (petroleum), hydrotreated light:
1-Methyl 4-(1-Methylethenyl) Cyclohexene:
Serious eye damage/eye irritation
Not classified based on available information.
Ingredients:
Distillates (petroleum), hydrotreated light:
1-Methyl 4-(1-Methylethenyl) Cyclohexene:
Respiratory or skin sensitization
Skin sensitization: Not classified based on available information.
Respiratory sensitization: Not classified based on available information.
Product:
Ingredients:
Distillates (petroleum), hydrotreated light:
1-Methyl 4-(1-Methylethenyl) Cyclohexene:
7 / 13
SAFETY DATA SHEET
GOJO® NATURAL* ORANGE™ Pumice Hand
Cleaner
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
28583-00002
Date of last issue: 11/05/2014
Date of first issue: 11/05/2014
Genotoxicity in vitro
:
Test Type: Bacterial reverse mutation assay (AMES)
Result: negative
Genotoxicity in vivo
:
Test Type: Chromosomal aberration
Species: Rat
Application Route: Intraperitoneal injection
Result: negative
Remarks: Based on data from similar materials
Genotoxicity in vitro
:
Test Type: In vitro mammalian cell gene mutation test
Result: negative
Genotoxicity in vivo
:
Test Type: Transgenic rodent somatic cell gene mutation assay
Species: Rat
Application Route: Ingestion
Result: negative
Species: Mouse
Application Route: Ingestion
Exposure time: 103 weeks
Result: negative
IARC
No ingredient of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
OSHA
No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
NTP
No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
Germ cell mutagenicity
Not classified based on available information.
Ingredients:
Distillates (petroleum), hydrotreated light:
1-Methyl 4-(1-Methylethenyl) Cyclohexene:
Carcinogenicity
Not classified based on available information.
Ingredients:
1-Methyl 4-(1-Methylethenyl) Cyclohexene:
Reproductive toxicity
Not classified based on available information.
Ingredients:
Distillates (petroleum), hydrotreated light:
8 / 13
SAFETY DATA SHEET
GOJO® NATURAL* ORANGE™ Pumice Hand
Cleaner
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
28583-00002
Date of last issue: 11/05/2014
Date of first issue: 11/05/2014
Effects on fertility
:
Test Type: One-generation reproduction toxicity study
Species: Rat
Application Route: Ingestion
Result: negative
Remarks: Based on data from similar materials
Effects on fetal development
:
Test Type: Embryo-fetal development
Species: Rat
Application Route: Ingestion
Result: negative
Species: Rat
NOAEL: > 10.4 mg/l
Application Route: inhalation (vapor)
Exposure time: 90 d
Remarks: Based on data from similar materials
Species: Rat
NOAEL: 600 mg/kg
Application Route: Ingestion
Exposure time: 13 w
The substance or mixture is known to cause human aspiration toxicity hazards or has to be
regarded as if it causes a human aspiration toxicity hazard.
The substance or mixture is known to cause human aspiration toxicity hazards or has to be
regarded as if it causes a human aspiration toxicity hazard.
STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
Not classified based on available information.
Repeated dose toxicity
Ingredients:
Distillates (petroleum), hydrotreated light:
1-Methyl 4-(1-Methylethenyl) Cyclohexene:
Aspiration toxicity
Not classified based on available information.
Ingredients:
Distillates (petroleum), hydrotreated light:
1-Methyl 4-(1-Methylethenyl) Cyclohexene:
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Ingredients:
Distillates (petroleum), hydrotreated light:
9 / 13
SAFETY DATA SHEET
GOJO® NATURAL* ORANGE™ Pumice Hand
Cleaner
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
28583-00002
Date of last issue: 11/05/2014
Date of first issue: 11/05/2014
Toxicity to fish
:
LL50 (Danio rerio (zebra fish)): > 250 mg/l
Exposure time: 96 h
Test substance: Water Accommodated Fraction
Method: OECD Test Guideline 203
Toxicity to daphnia and other
aquatic invertebrates
:
EL50 (Acartia tonsa): > 3,193 mg/l
Exposure time: 48 h
Test substance: Water Accommodated Fraction
Toxicity to algae
:
EL50 (Skeletonema costatum (marine diatom)): > 3,200 mg/l
Exposure time: 72 h
Test substance: Water Accommodated Fraction
NOELR (Skeletonema costatum (marine diatom)): 993 mg/l
Exposure time: 72 h
Test substance: Water Accommodated Fraction
Toxicity to daphnia and other
aquatic invertebrates
(Chronic toxicity)
:
NOELR (Ceriodaphnia dubia (water flea)): > 70 mg/l
Exposure time: 8 d
Test substance: Water Accommodated Fraction
Toxicity to bacteria
:
EC50: > 100 mg/l
Exposure time: 3 h
Toxicity to fish
:
LC50 (Pimephales promelas (fathead minnow)): 0.72 mg/l
Exposure time: 96 h
Toxicity to daphnia and other
aquatic invertebrates
:
EC50 (Daphnia magna (Water flea)): 0.36 mg/l
Exposure time: 48 h
Toxicity to algae
:
ErC50 (Desmodesmus subspicatus (green algae)): 150 mg/l
Exposure time: 72 h
Test substance: Water Accommodated Fraction
Remarks: Based on data from similar materials
M-Factor (Acute aquatic toxicity)
:
1
Biodegradability
:
Result: Readily biodegradable.
Biodegradation: 82 %
Exposure time: 24 d
Method: OECD Test Guideline 301F
Biodegradability
:
Result: Readily biodegradable.
Biodegradation: 80 %
Exposure time: 28 d
Remarks: Based on data from similar materials
1-Methyl 4-(1-Methylethenyl) Cyclohexene:
Persistence and degradability
Ingredients:
Distillates (petroleum), hydrotreated light:
1-Methyl 4-(1-Methylethenyl) Cyclohexene:
10 / 13
SAFETY DATA SHEET
GOJO® NATURAL* ORANGE™ Pumice Hand
Cleaner
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
28583-00002
Date of last issue: 11/05/2014
Date of first issue: 11/05/2014
Partition coefficient: noctanol/water
:
log Pow: 4.38
Waste from residues
:
Dispose of in accordance with local regulations.
Contaminated packaging
:
Dispose of as unused product.
Empty containers should be taken to an approved waste
handling site for recycling or disposal.
UNRTDG
Not regulated as a dangerous good
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
49 CFR
Not regulated as a dangerous good
Bioaccumulative potential
Ingredients:
1-Methyl 4-(1-Methylethenyl) Cyclohexene:
Mobility in soil
No data available
Other adverse effects
No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
SECTION 14. TRANSPORT INFORMATION
International Regulation
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know
CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
11 / 13
SAFETY DATA SHEET
GOJO® NATURAL* ORANGE™ Pumice Hand
Cleaner
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
28583-00002
Date of last issue: 11/05/2014
Date of first issue: 11/05/2014
SARA 311/312 Hazards
:
No SARA Hazards
SARA 302
:
No chemicals in this material are subject to the reporting
requirements of SARA Title III, Section 302.
SARA 313
:
This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
Water
7732-18-5
70 - 90 %
Pumice
1332-09-8
5 - 10 %
Distillates (petroleum), hydrotreated light
64742-47-8
5 - 10 %
Water
7732-18-5
70 - 90 %
Pumice
1332-09-8
5 - 10 %
Distillates (petroleum), hydrotreated light
64742-47-8
5 - 10 %
California Prop 65
This product does not contain any chemicals known to the
State of California to cause cancer, birth, or any other
reproductive defects.
NFPA:
HMIS III:
NIOSH REL
:
USA. NIOSH Recommended Exposure Limits
Flammability
Health
Instability
0
1
0
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
1
0
0
Special hazard.
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
US State Regulations
Pennsylvania Right To Know
New Jersey Right To Know
SECTION 16. OTHER INFORMATION
Further information
Full text of other abbreviations
12 / 13
SAFETY DATA SHEET
GOJO® NATURAL* ORANGE™ Pumice Hand
Cleaner
Version
1.1
Revision Date:
02/10/2015
MSDS Number:
28583-00002
Date of last issue: 11/05/2014
Date of first issue: 11/05/2014
OSHA Z-1
:
USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air Contaminants
NIOSH REL / TWA
:
Time-weighted average concentration for up to a 10-hour
workday during a 40-hour workweek
NIOSH REL / ST
:
STEL - 15-minute TWA exposure that should not be exceeded
at any time during a workday
OSHA Z-1 / TWA
:
8-hour time weighted average
Sources of key data used to
compile the Material Safety
Data Sheet
:
Internal technical data, data from raw material SDSs, OECD
eChem Portal search results and European Chemicals Agency, http://echa.europa.eu/
Revision Date
:
02/10/2015
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and
shall not be considered a warranty or quality specification of any type. The information provided relates only to the specific material identified at the top of this SDS and may not be valid
when the SDS material is used in combination with any other materials or in any process, unless specified in the text. Material users should review the information and recommendations
in the specific context of their intended manner of handling, use, processing and storage, including an assessment of the appropriateness of the SDS material in the user’s end product, if
applicable.
US / Z8
13 / 13
Loading...