GoJo 0945-04 User Manual

SAFETY DATA SHEET

GOJO® NATURAL* ORANGE™ Smooth Hand Cle a ne r

Version 0.0

SDS Number: 400000000196

Revision Date: 10/19/2016

Company name of supplier

:

GOJO Industries, Inc.

Address

:

One GOJO Plaza, Suite 500

Emergency telephone

:

1-800-424-9300 CHEMTREC
Recommended use

:

Skin-care

Restrictions on use

:

This is a personal care or cosmetic product that is safe for

Chemical name

CAS-No.

Concentration (%)

Petroleum Distillates

64742-47-8

>= 5

- < 10

Limonene

5989-27-5

>= 0.1

- < 1

SECTION 1. IDENTIFICATION

Product name

Manufacturer or supplier's details

Telephone

number

Recommended use of the chemical and restrictions on use

: GOJO® NATURAL* ORANGE™ Smooth Hand Cleaner

Akron, Ohio 44311

: 1 [phone]

consumers and other users under normal and reasonably
foreseeable use. Cosmetics and consumer products, specifi­cally defined by regulations around the world, are exempt from
the requirement of an SDS for the consumer. While this mate­rial is not considered hazardous, this SDS contains valuable
information critical to the safe handling and proper use of the
product for industrial workplace conditions as well as unusual
and unintended exposures suc h as large spills. This SDS
should be retained and available for employees and other
users of this product. For specific intended-use guidance,
please refer to the information provided on the package or
instruction sheet.

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification

Not a hazardous substance or mixture.

GHS label elements

Not a hazardous substance or mixture.

Other hazards

None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous components

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SAFETY DATA SHEET

GOJO® NATURAL* ORANGE™ Smooth Hand Cle a ne r

Version 0.0

SDS Number: 400000000196

Revision Date: 10/19/2016

General advice

:

In the case of accident or if you feel unwell, seek medical ad­If inhaled

:

If inhaled, remove to fresh air.

In case of skin contact

:

Wash with water and soap as a precaution.

In case of eye contact

:

In case of contact, immediately flush eyes with plenty of water
If swallowed

:

If swallowed, DO NOT induce vomiting.

Most important symptoms

:

None known.
Protection of first-aiders

:

First Aid responders should pay attention to self-protection

Suitable extinguishing media

:

Use water spray, alcohol-resistant foam, dry chemical or car-

Hazardous combustion prod-

:

Carbon oxides

Special protective equipment

:

In the event of fire, wear self-contained breathing apparatus.

SECTION 4. FIRST AID MEASURES

and effects, both acute and
delayed

vice immediately.
When symptoms persist or in all cases of doubt seek medical
advice.

If symptoms persist, call a physician.

Get medical attention immediately if irritation develops and
persists.

for at least 15 minutes.
If easy to do, remove contact lens, if worn.
Seek medical advice.

Rinse mouth with water.
Obtain medical attention.

and use the recommended protective clothing

SECTION 5. FIREFIGHTING MEASURES

Unsuitable extinguishing
media

ucts
Specific extinguishing meth-

ods

Further information : Collect contaminated fire extinguishing water separately. This

for firefighters

bon dioxide.

: None known.

: Use extinguishing measures that are appropriate to local cir-

cumstances and the surrounding environment.
Use water spray to cool unopened containers.

must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.

Use personal protective equipment.

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SAFETY DATA SHEET

GOJO® NATURAL* ORANGE™ Smooth Hand Cle a ne r

Version 0.0

SDS Number: 400000000196

Revision Date: 10/19/2016

Personal precautions, protec-

:

Use personal protective equipment.

Environmental precautions

:

Discharge into the environment must be avoided.
Methods and materials for

:

Keep in suitable, closed containers for disposal.

Advice on safe handling

:

For personal protection see section 8.

exposure)

concentration

Petroleum Distillates

64742-47-8

TWA (Mist)

5 mg/m3

OSHA Z-1

TWA

200 mg/m3
carbon vapor)

ACGIH
TWA (Mist)

5 mg/m3

NIOSH REL

ST (Mist)

10 mg/m3

NIOSH REL

Limonene

5989-27-5

TWA

20 ppm

ACGIH

SECTION 6. ACCIDENTAL RELEASE MEASURES

tive equipment and emer­gency procedures

containment and cleaning up

SECTION 7. HANDLING AND STORAGE

Conditions for safe storage : Keep in properly labelled containers.

Ensure adequate ventilatio n.
Evacuate personnel to safe areas.
Material can create slippery conditions.

Prevent further leakage or spillage if safe to do so.
Retain and dispose of contaminated wash water.
Local authorities should be advised if significant spillages
cannot be contained.

Clean contaminated floors and objects thoroughly while ob­serving environmental regulations.

Do not swallow.
Avoid contact with eyes.
Keep container closed when not in use.

Keep container tightly closed in a dry and well-ventilated
place.
Store in accordance with the particular nat ion al regu lat ions .

SECTION 8. EXPOSURE CONT RO L S/PERSONAL PROT ECTION

Components with workplace control parameters

Components CAS-No. Value type

Personal protective equipment

Respiratory protection

Eye protection

Control parame-

(Form of

: No personal respiratory protective equipment normally re-

quired.

: No special protective equipment required.

Wear face-shield and protective suit for abnormal processing
problems.

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ters / Permissible

(as total hydro-

Basis

SAFETY DATA SHEET

GOJO® NATURAL* ORANGE™ Smooth Hand Cle a ne r

Version 0.0

SDS Number: 400000000196

Revision Date: 10/19/2016

Skin and body protection

:

No special protective equipment required.

Protective measures

:

Choose body protection in relation to its type, to the concen-

Hygiene measures

:

Handle in accordance with good industrial hygiene and safety

Appearance

:

liquid

Colour

:

opaque, white, grey

Odour

:

citrus

Odour Threshold

:

No data available

pH :

6 - 8, (20 °C)

Melting point/range

:

11.4 °C

Initial boiling point and boiling

:

95 °C
Flash point

:

> 100 °C

Evaporation rate

:

No data available

Flammability (solid, gas)

:

Not applicable

Upper explosion limit

:

No data available

Lower explosion limit

:

No data available

Vapour pressure

:

No data available

Relative vapour density

:

No data available

Density

:

0.9758 g/cm3

Water solubility

:

soluble

Partition coefficient: n-

:

Not applicable
Auto-ignition temper ature

:

No data available

Thermal decomposition

:

The substance or mixture is not classified self-reactive.

Viscosity, kinematic

:

10000 - 45000 mm2/s (20 °C)

SECTION 9. PHYSI CAL AND CHEMIC AL PRO PER TIES

range

tration and amount of dangerous substances, and to the spe­cific work-place.

practice.
Avoid contact with eyes.

Solubility(ies)

octanol/water

Viscosity

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SAFETY DATA SHEET

GOJO® NATURAL* ORANGE™ Smooth Hand Cle a ne r

Version 0.0

SDS Number: 400000000196

Revision Date: 10/19/2016

Explosive properties

:

Not explosive

Oxidizing properties

:

The substance or mixture is not classified as oxidizing.

Reactivity

:

Not classified as a reactivity hazard.

Chemical stability

:

Stable under normal conditions.

Possibility of hazardous reac-

:

No dangerous reaction known under conditions of normal use.
Incompatible materials

:

Oxidizing agents

Hazardous decomposition

:

No hazardous decomposition products are known.

Acute dermal toxicity

:

LD50 (Rabbit): > 3,160 mg/kg

SECTION 10. STABILITY AND REACTIVITY

tions

products

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Inhalation
Eye contact
Skin contact

Acute toxicity

Not classified based on available information.

Components:
Petroleum Distillates:

Acute oral toxicity
Acute inhalation toxicity

: LD50 (Rat): > 5,000 mg/kg
: LC50 (Rat): > 5.3 mg/l

Exposure time: 4 h
Test atmosphere: dust/mist
Assessment: The substance or mixture has no acute inhala­tion toxicity
Remarks: Based on data from similar materials

Limonene:

Acute oral toxicity

Skin corrosion/irritation

Not classified based on available information.

Assessment: The substance or mixture has no acute dermal
toxicity

: LD50 (Rat): > 2,000 mg/kg

Assessment: The substance or mixture has no acute oral tox­icity
Remarks: Based on data from similar materials

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SAFETY DATA SHEET

GOJO® NATURAL* ORANGE™ Smooth Hand Cle a ne r

Version 0.0

SDS Number: 400000000196

Revision Date: 10/19/2016

Assessment: Repeated exposure may cause skin dryness or cracking.

Species: Rabbit

Species: Rabbit

Test Type: Local lymph node assay (LLNA)
Genotoxicity in vivo

:

Test Type: Chromosomal aberration
Application Route: Intr a peri tone al inj ect ion

Components:
Petroleum Distillates:

Limonene:

Species: Rabbit
Result: Skin irritation

Serious eye damage/eye irritation

Not classified based on available information.

Components:
Petroleum Distillates:

Result: No eye irritation

Limonene:

Result: No eye irritation

Respiratory or skin sensitisation

Skin sensitisation: Not classified based on available information.
Respiratory sensitisation: Not classified based on available information.

Product:

Assessment: Does not cause skin sensitisation.

Components:
Petroleum Distillates:

Test Type: Maximisation Test (GPMT)
Exposure routes: Skin contact
Species: Guinea pig
Result: negative
Remarks: Based on data from similar materials

Limonene:

Exposure routes: Skin contact
Species: Mouse
Result: positive

Assessment: Probability or evidence of skin sensitisation in humans

Germ cell mutagenicity

Not classified based on available information.

Components:
Petroleum Distillates:

Genotoxicity in vitro

: Test Type: Bacterial reverse mutation assay (AMES)

Result: negative

Test species: Rat

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SAFETY DATA SHEET

GOJO® NATURAL* ORANGE™ Smooth Hand Cle a ne r

Version 0.0

SDS Number: 400000000196

Revision Date: 10/19/2016

Result: negative

Genotoxicity in vitro

:

Test Type: In vitro mammalian cell gene mutation test

Species: Mouse

IARC

OSHA

NTP

Remarks: Based on data from similar materials

Limonene:

Genotoxicity in vivo

Carcinogenicity

Not classified based on available information.

Components:
Limonene:

Application Route: Ingestion
Exposure time: 103 weeks
Result: negative

Result: negative

: Test Type: Transgenic rodent somatic cell gene mutation as-

say
Test species: Rat
Application Route: Ingestion
Result: negative

No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.

No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential carcino­gen by OSHA.

Reproductive toxicity

Not classified based on available information.

Components:
Petroleum Distillates:

Effects on fertility

Effects on foetal develop­ment

STOT - single exposure

Not classified based on available information.

No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

: Test Type: One-generation reproduct ion tox icity study

Species: Rat
Application Route: Ingestion
Result: negative
Remarks: Based on data from similar materials

: Test Type: Embryo-foetal development

Species: Rat
Application Route: Ingestion
Result: negative

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SAFETY DATA SHEET

GOJO® NATURAL* ORANGE™ Smooth Hand Cle a ne r

Version 0.0

SDS Number: 400000000196

Revision Date: 10/19/2016

Species: Rat

Toxicity to fish

:

LL50 (Danio rerio (zebra fish)): > 250 mg/l
Toxicity to daphnia and other

:

EL50 (Acartia tonsa): > 3,193 mg/l

Toxicity to algae

:

EL50 (Skeletonema costatum (marine diatom)): > 3,200 mg/l

NOELR (Skeletonema costatum (marine diatom)): 993 mg/l

STOT - repeated exposure

Not classified based on available information.

Repeated dose toxicity
Components:

Petroleum Distillates:

Species: Rat
NOAEL: > 10.4 mg/l
Application Route: inhalation (vapour)
Exposure time: 90 d
Remarks: Based on data from similar materials

Limonene:

NOAEL: 600 mg/kg
Application Route: Ingestion
Exposure time: 13 w

Aspiration toxicity

Not classified based on available information.

Components:
Petroleum Distillates:

The substance or mixture is known to cause human aspiration toxicity hazards or has to be re­garded as if it causes a human aspiration toxicity hazard.

Limonene:

The substance or mixture is known to cause human aspiration toxicity hazards or has to be re­garded as if it causes a human aspiration toxicity hazard.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Components:

Petroleum Distillates:

aquatic invertebrates

Exposure time: 96 h
Test substance: Water Accommodated Fraction
Method: OECD Test Guideline 203

Exposure time: 48 h
Test substance: Water Accommodated Fraction

Exposure time: 72 h
Test substance: Water Accommodated Fraction

Exposure time: 72 h
Test substance: Water Accommodated Fraction

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SAFETY DATA SHEET

GOJO® NATURAL* ORANGE™ Smooth Hand Cle a ne r

Version 0.0

SDS Number: 400000000196

Revision Date: 10/19/2016

Toxicity to daphnia and other

:

NOELR (Ceriodaphnia Dubia (water flea)): > 70 mg/l
Toxicity to bacteria

:

EC50: > 100 mg/l

Toxicity to fish

:

LC50 (Pimephales promelas (fathead minnow)): 0.72 mg/l

Toxicity to algae

:

ErC50 (Desmodesmus subspicatus (green algae)): 150 mg/l

Remarks

This product neither contains, nor was manufact ured with a

aquatic invertebrates (Chron­ic toxicity)

Limonene:

Toxicity to daphnia and other
aquatic invertebrates

M-Factor (Acute aquatic tox­icity)

Persistence and degradability
Components:

Petroleum Distillates:

Biodegradability

Exposure time: 8 d
Test substance: Water Accommodated Fraction

Exposure time: 3 h

Exposure time: 96 h

: EC50 (Daphnia magna (Water flea)): 0.36 mg/l

Exposure time: 48 h

Exposure time: 72 h
Test substance: Water Accommodated Fraction
Remarks: Based on data from similar materials

: 1

: Result: Readily biodegradable.

Biodegradation: 82 %
Exposure time: 24 d
Method: OECD Test Guideline 301F

Limonene:

Biodegradability

Bioaccumulative potential
Components:

Limonene:

Partition coefficient: n­octanol/water

Mobility in soil

No data available

Other adverse effects

No data available

Product:

Regulation

: Result: Readily biodegradable.

Biodegradation: 80 %
Exposure time: 28 d
Remarks: Based on data from similar materials

: log Pow: 4.38

40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I Substances

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SAFETY DATA SHEET

GOJO® NATURAL* ORANGE™ Smooth Hand Cle a ne r

Version 0.0

SDS Number: 400000000196

Revision Date: 10/19/2016

Class I or Class II ODS as defined by the U.S. Clean Air Act
Waste from residues

:

Dispose of in accordance with local regulations.

Contaminated packaging

:

Dispose of as unused product.

IATA-DGR

Not regulated as a dangerous good

IMDG-Code

49 CFR

Not regulated as a dangerous good

SARA 311/312 Hazards

:

No SARA Hazards

SARA 302

:

No chemicals in this material are subject to the reporting re-

SARA 313

:

This material does not contain any chemical components with

Section 602 (40 CFR 82, Subpt. A, App.A + B).

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods

Empty containers should be taken to an approved waste han­dling site for recycling or disposal.

SECTION 14. TRANSPORT INFORMATION

International Regulation

Not regulated as a dangerous good

National Regulations

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Kn ow Act
CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.

SARA 304 Extremely Hazardous Substances Reportable Quantity

This material does not contain any component s w ith a sec tion 304 EH S RQ.

quirements of SARA Title III, Section 302.

known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

Clean Air Act

This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean
Air Act Section 12 (40 CFR 61).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for
Accidental Release Prevention (40 CFR 68.130, Subpart F).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111
SOCMI Intermediate or Final VOC's (40 CFR 60.489).

10 / 12

SAFETY DATA SHEET

GOJO® NATURAL* ORANGE™ Smooth Hand Cle a ne r

Version 0.0

SDS Number: 400000000196

Revision Date: 10/19/2016

Water (Aqua)

7732-18-5

90 - 100 %

Water (Aqua)

7732-18-5

90 - 100 %

California Prop 65

This product does not contain any chemicals known to State
TSCA

:

On TSCA Inventory

CH INV

:

On the inventory, or in compliance with the inventory

DSL :

All components of this product are on the Canadian DSL.

ENCS

:

On the inventory, or in compliance with the inventory

PICCS

:

On the inventory, or in compliance with the inventory

IECSC

:

On the inventory, or in compliance with the inventory

ISHL

:

On the inventory, or in compliance with the inventory

NZIoC

:

On the inventory, or in compliance with the inventory

KECI

:

On the inventory, or in compliance with the inventory

This product does not contain any VOC exemptions listed under the U.S. Clean Air Act Section

450.

Clean Water Act

This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section
307

US State Regulations
Massachusetts Right To Know

Pennsylvania Right To Know

Petroleum Distillates 64742-47-8 5 - 10 %

New Jersey Right To Know

The components of this product are reported in the following inventories:

AICS

Petroleum Distillates 64742-47-8 5 - 10 %

Petroleum Distillates 64742-47-8 5 - 10 %

of California to cause cancer, birth defects, or any other re­productive harm.

: On the inventory, or in compliance with the inventory

Inventories

AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)

11 / 12

SAFETY DATA SHEET

GOJO® NATURAL* ORANGE™ Smooth Hand Cle a ne r

Version 0.0

SDS Number: 400000000196

Revision Date: 10/19/2016

NFPA:

HMIS III:

Revision Date

:

10/19/2016

Flammability

Health

0

1

0

FLAMMABILITY

HEALTH

1

0

0

Special hazard.

0 = not significant, 1 =Slight,

SECTION 16. OTHER INFORMATION

Further information

The information provided in this Safety Data Sheet is correct to the best of our knowledge, in­formation and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and
is not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with
any other materials or in any process, unless specified in the text.

Instability

PHYSICAL HAZARD

2 = Moderate, 3 = High
4 = Extreme, * = Chronic

12 / 12