Global Industrial 695803 User Manual

Page 1/10

Safety Data Sheet

29 CFR 1910.1200

Printing date 10/29/2020 Reviewed on 10/26/2020Version number 1

1 Identification

· Product identifier

· Trade name: 12V8AV Li-Battery

· Recommended use of the chemical and restrictions on use:

· Application of the substance / the preparation:

· Details of the supplier of the safety data sheet

· Manufacturer/Supplier:

· Full address:

· Phone number:

· Email:

ROOM 201 NO.6TH BUILDING NO.2500, XIUPU ROAD, SHANGHAI

13764542869

[e-mail]

SHANGHAI ILIFE INDUSTRIAL CO.,LTD

electric sprayer power

· Other U.S. contact point:

· Further information obtainable from:

Not available

SHANGHAI ILIFE INDUSTRIAL CO.,LTD

· Emergency telephone number:

Poison Center
Tel: [phone]

· Reference Number:

CANML2018433101,GZIN2010058397PC

· Remark:

* This sample is likely to be classified as article product and is out of scope of a SDS as set out in 29 CFR
Part 1910.1200. This SDS is generated for client’s reference only.

2 Hazard(s) identification

· Classification of the substance or mixture

Classification according to OSHA Hazard Communication Standard (29 CFR 1910.1200)

GHS02 Flame

Flam. Sol. 1 H228 Flammable solid.

GHS08 Health hazard

Carc. 1A H350 May cause cancer.

STOT RE 1 H372 Causes damage to through prolonged or repeated exposure.

GHS05 Corrosion

Eye Dam. 1 H318 Causes serious eye damage.

GHS07

Acute Tox. 4 H302 Harmful if swallowed.

Skin Irrit. 2 H315 Causes skin irritation.

Skin Sens. 1 H317 May cause an allergic skin reaction.

· Information concerning particular hazards for human and environment:

The product has to be labeled due to the calculation procedure of OSHA Hazard Communication Standard
(29 CFR 1910.1200).

(Contd. on page 2)

USA

49.4.20

Safety Data Sheet

29 CFR 1910.1200

Printing date 10/29/2020 Reviewed on 10/26/2020Version number 1

Trade name: 12V8AV Li-Battery

(Contd. of page 1)

· Classification system:

The classification is according to the latest edition of OSHA Hazard Communication Standard (29 CFR

1910.1200), and extended by company and literature data.

· Label elements

· Labelling according to OSHA Hazard Communication Standard (29 CFR 1910.1200)

· Hazard pictograms

GHS02 GHS05 GHS07 GHS08

Page 2/10

· Signal word

Danger

· Hazard-determining components of labeling:

Lithium manganese oxide
Lithium nickel manganese cobalt oxide
lithium hexafluorophosphate(1-)

· Hazard statements

H228 Flammable solid.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H317 May cause an allergic skin reaction.
H350 May cause cancer.
H372 Causes damage to through prolonged or repeated exposure.

· Precautionary statements

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing must not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 If swallowed: Call a poison center/doctor if you feel unwell.
P302+P352 If on skin: Wash with plenty of water.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing.
P310 Immediately call a poison center/doctor.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P321 Specific treatment (see on this label).
P314 Get medical advice/attention if you feel unwell.
P330 Rinse mouth.
P362+P364 Take off contaminated clothing and wash it before reuse.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P363 Wash contaminated clothing before reuse.
P370+P378 In case of fire: Use for extinction: CO2, powder or water spray.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international

regulations.

· Hazards not otherwise classified (HNOC)

49.4.20

No further relevant information available.

USA

(Contd. on page 3)

Safety Data Sheet

29 CFR 1910.1200

Printing date 10/29/2020 Reviewed on 10/26/2020Version number 1

Trade name: 12V8AV Li-Battery

3 Composition/information on ingredients

· Chemical characterization: Mixtures

· Description:

Mixture of the substances listed below with nonhazardous additions.
For the wording of the listed hazard statements refer to Section 16.

· Composition:

12057-17-9 Lithium manganese oxide

Acute Tox. 4, H302; Acute Tox. 4, H332

7782-42-5 Graphite 21%

346417-97-8 Lithium nickel manganese cobalt oxide

Carc. 1A, H350; Skin Sens. 1, H317

7440-50-8 copper 11%

108481-44-3 Dimethyl-d6 carbonate

Flam. Liq. 2, H225

7429-90-5 Aluminum 10%

9003-55-8 1,3-Butadiene/styrene copolymers 4%

24937-79-9 Poly(vinylidene fluoride) 3%

21324-40-3 lithium hexafluorophosphate(1-)

Acute Tox. 3, H301; STOT RE 1, H372; Skin Corr. 1A, H314

Page 3/10

(Contd. of page 2)

24%

13%

11%

3%

4 First-aid measures

· Description of first aid measures

· General description:

Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
hours after the accident.

· After inhalation:

Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.

· After skin contact:

· After eye contact:

· After swallowing:

· Most important symptoms and effects, both acute and delayed

Immediately wash with water and soap and rinse thoroughly.
Rinse opened eye for several minutes under running water. Then consult a doctor.
Immediately call a doctor.

No further relevant information available.

· Indication of any immediate medical attention and special treatment needed

No further relevant information available.

5 Fire-fighting measures

· Suitable extinguishing agents:

· Special hazards arising from the substance or mixture:

During heating or in case of fire poisonous gases are produced.

· Special protective equipment and precautions for firefighters

· Protective equipment:

Mouth respiratory protective device.

Use fire fighting measures that suit the environment.

6 Accidental release measures

· Personal precautions, protective equipment and emergency procedures:

Mount respiratory protective device.

49.4.20

(Contd. on page 4)

USA

Safety Data Sheet

29 CFR 1910.1200

Printing date 10/29/2020 Reviewed on 10/26/2020Version number 1

Trade name: 12V8AV Li-Battery

Wear protective equipment. Keep unprotected persons away.

Page 4/10

(Contd. of page 3)

· Environmental precautions:

Do not allow to enter sewers/ surface or ground water.

· Methods and material for containment and cleaning up:

Use neutralizing agent.
Dispose contaminated material as waste according to section 13.
Ensure adequate ventilation.

7 Handling and storage

· Precautions for safe handling:

Thorough dedusting.
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
For the general occupational hygienic measures refer to Section 8.

· Information about protection against explosions and fires:

Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Keep respiratory protective device available.

· Conditions for safe storage, including any incompatibilities

· Requirements to be met by storerooms and receptacles:

No special requirements.

· Information about storage in one common storage facility:

· Further information about storage conditions:

Keep receptacle tightly sealed.

8 Exposure controls/personal protection

Not required.

· Components with limit values that require monitoring at the workplace:

7782-42-5 Graphite (21%)

PEL (USA) Long-term value: 15 mppcf* mg/m³

*impinger samples counted by light field techn.

REL (USA) Long-term value: 2.5* mg/m³

*respirable dust

TLV (USA) Long-term value: 2* mg/m³

all forms except graphite fibers;*resp. fraction

7440-50-8 copper (11%)

PEL (USA) Long-term value: 1* 0.1** mg/m³

as Cu *dusts and mists **fume

REL (USA) Long-term value: 1* 0.1** mg/m³

as Cu *dusts and mists **fume

TLV (USA) Long-term value: 1* 0.2** mg/m³

*dusts and mists; **fume; as Cu

7429-90-5 Aluminum (10%)

PEL (USA) Long-term value: 15*; 5** mg/m³

*Total dust; ** Respirable fraction

REL (USA) Long-term value: 10* 5** mg/m³

as Al*Total dust**Respirable/pyro powd./welding f.

TLV (USA) Long-term value: 1* mg/m³

as Al; *as respirable fraction

· Regulatory information

PEL (USA): Guide to Occupational Exposure Values (OSHA PELs)
REL (USA): Guide to Occupational Exposure Values (NIOSH RELs)
TLV (USA): Guide to Occupational Exposure Values (ACGIH)

(Contd. on page 5)

USA

49.4.20

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Safety Data Sheet

29 CFR 1910.1200

Printing date 10/29/2020 Reviewed on 10/26/2020Version number 1

Trade name: 12V8AV Li-Battery

(Contd. of page 4)

· Additional information:

· Based on the composition shown in Section 3, the following measures are suggested for occupational

safety measure.

· Appropriate engineering controls:

Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the skin.
Avoid contact with the eyes and skin.
See Section 7 for information about design of technical facilities.

· Personal protective equipment:

· Breathing equipment:

In case of brief exposure or low pollu tion use respiratory filter device. In case of intensive or longer
exposure use respiratory protective device that is independent of circulating air.

· Protection of hands:

The lists that were valid during the creation were used as basis.

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and t he
degradation

· Material of gloves

The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manuf acturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.

· Penetration time of glove material:

The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.

· Eye protection:

Tightly sealed goggles

9 Physical and chemical properties

· General Information

· Appearance:

Form:
Color:

· Odor:

· Odor threshold:

Solid
Orange
Smell at the time of leakage
Not available

· pH-value:

Not available

· Change in condition

Melting point/Freezing point:
Initial boiling point and boiling range:

49.4.20

Not available
Not available

(Contd. on page 6)

USA

Safety Data Sheet

29 CFR 1910.1200

Printing date 10/29/2020 Reviewed on 10/26/2020Version number 1

Trade name: 12V8AV Li-Battery

· Flash point:

Not available

Page 6/10

(Contd. of page 5)

· Flammability (solid, gaseous):

· Auto-Ignition temperature:

· Decomposition temperature:

· Explosion limits:

Lower:
Upper:

· Vapor pressure:

· Density:

· Relative density:

· Vapor density:

· Evaporation rate:

· Solubility in / Miscibility with

Water:

· Partition coefficient (n-octanol/water):

· Viscosity:

Dynamic:
Kinematic:

· Other information

10 Stability and reactivity

Not available

Not available

Not available

Not available
Not available

Not available

Not available
Not available
Not available
Not available

Not available

Not available

Not available
Not available

No further relevant information available.

· Reactivity:

· Chemical stability:

· Possibility of hazardous reactions:

· Conditions to avoid:

· Incompatible materials:

· Hazardous decomposition products:

Data not available

Data not available

No dangerous reactions known.

No further relevant information available.

No further relevant information available.

No dangerous decomposition products known.

11 Toxicological information

· Acute toxicity:

· LD/LC50 values that are relevant for classification:

· Skin corrosion/irritation:

· Serious eye damage/irritation:

Irritant to skin and mucous membranes.

Strong irritant with the danger of severe eye injury.

· Respiratory or skin sensitization:

Sensitization possible through skin contact.

· Additional toxicological information:

The product shows the following dangers according to internally approv ed calcul ation methods for
preparations:
Harmful
Irritant

· Carcinogenic categories

· IARC (International Agency for Research on Cancer)

346417-97-8 Lithium nickel manganese cobalt oxide 1

Not available

(Contd. on page 7)

USA

49.4.20

Safety Data Sheet

29 CFR 1910.1200

Printing date 10/29/2020 Reviewed on 10/26/2020Version number 1

Trade name: 12V8AV Li-Battery

(Contd. of page 6)

9003-55-8 1,3-Butadiene/styrene copolymers 3

· NTP (National Toxicology Program)

346417-97-8 Lithium nickel manganese cobalt oxide K

· OSHA-Ca (Occupational Safety & Health Administration)

None of the ingredients is listed.

12 Ecological information

· Toxicity

· Aquatic toxicity:

No further relevant information available.

Page 7/10

· Persistence and degradability:

· Bioaccumulative potential:

· Mobility in soil:

· Other adverse effects

No further relevant information available.

No further relevant information available.

No further relevant information available.

No further relevant information available.

13 Disposal considerations

· Waste treatment methods

· Recommendation:

Must not be disposed of together with household garbage. Do not allow product to reach sewage system.

· Uncleaned packagings:

· Recommendation:

Disposal must be made according to official regulations.

14 Transport information

· UN-Number

· DOT, IMDG, IATA

· UN proper shipping name

· DOT

· IMDG, IATA

· Transport hazard class(es)

UN3481

Lithium ion batteries contained in equipment
LITHIUM ION BATTERIES CONTAINED IN EQUIPMENT

· DOT, IMDG, IATA

· Class

· Label

9 Miscellaneous dangerous substances and articles
9A

· Packing group

· DOT, IMDG, IATA

· Environmental hazards:

· Special precautions for user

· EMS Number:

· Stowage Category

49.4.20

₋

Not applicable

Warning: Miscellaneous dangerous substances and articles
F-A,S-I
A

(Contd. on page 8)

USA

Safety Data Sheet

29 CFR 1910.1200

Printing date 10/29/2020 Reviewed on 10/26/2020Version number 1

Trade name: 12V8AV Li-Battery

· Stowage Code

· Transport in bulk according to Annex II of

MARPOL73/78 and the IBC Code

· Transport/Additional information:

· IMDG

· Limited quantities (LQ)

· Excepted quantities (EQ)

SW19 For batteries transported in accordance with SP 376 or
SP 3 77 C a t e g ory C, un l es s tr a n spo rt ed on a s h ort
international voyage.

Not applicable

0
Code: E0
Not permitted as Excepted Quantity

Page 8/10

(Contd. of page 7)

· UN "Model Regulation":

UN 34 8 1 LITHIUM IO N BA T TERIES CONT A I N E D IN
EQUIPMENT

15 Regulatory information

· Safety, health and environmental regulations/legislation specific for the substance or mixture

· Sara

· Section 355 (extremely hazardous substances):

None of the ingredients is listed.

· Section 313 (Specific toxic chemical listings):

346417-97-8 Lithium nickel manganese cobalt oxide

7440-50-8 copper

7429-90-5 Aluminum

· TSCA (Toxic Substances Control Act):

12057-17-9 Lithium manganese oxide ACTIVE

7782-42-5 Graphite ACTIVE

7440-50-8 copper ACTIVE

7429-90-5 Aluminum ACTIVE

9003-55-8 1,3-Butadiene/styrene copolymers ACTIVE

21324-40-3 lithium hexafluorophosphate(1-) ACTIVE

24937-79-9 Poly(vinylidene fluoride) ACTIVE

· Proposition 65

· Chemicals known to cause cancer:

346417-97-8 Lithium nickel manganese cobalt oxide

· Chemicals known to cause reproductive toxicity for females:

None of the ingredients is listed.

· Chemicals known to cause reproductive toxicity for males:

None of the ingredients is listed.

· Chemicals known to cause developmental toxicity:

None of the ingredients is listed.

· New Jersey Right-to-Know List:

7782-42-5 Graphite

7440-50-8 copper

7429-90-5 Aluminum

(Contd. on page 9)

USA

49.4.20

Safety Data Sheet

29 CFR 1910.1200

Printing date 10/29/2020 Reviewed on 10/26/2020Version number 1

Trade name: 12V8AV Li-Battery

(Contd. of page 8)

· New Jersey Special Hazardous Substance List:

7429-90-5 Aluminum F3, R1

· Pennsylvania Right-to-Know List:

7782-42-5 Graphite

7440-50-8 copper

7429-90-5 Aluminum

· Pennsylvania Special Hazardous Substance List:

7440-50-8 copper E

7429-90-5 Aluminum E

· Cancerogenity categories

· EPA (Environmental Protection Agency)

7440-50-8 copper D

Page 9/10

· TLV (Threshold Limit Value established by ACGIH)

7429-90-5 Aluminum A4

· NIOSH-Ca (National Institute for Occupational Safety and Health)

346417-97-8 Lithium nickel manganese cobalt oxide

16 Other information

· Relevant hazard statements

H225 Highly flammable liquid and vapor.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H332 Harmful if inhaled.
H350 May cause cancer.
H372 Causes damage to through prolonged or repeated exposure.

· ***************************************************************************************

The contents and format of this SDS are in accordance with 29 CFR 1910.1200.

DISCLAIMER OF LIABILITY
The information in this SDS was obtained from source s which we believe are reliable. However, the
information is provided without any warranty, express or implied, regarding its correctness. The conditions
or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond
our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability
for loss, damage or expense arising out of or in any way connected with the handling, storage, use or
disposal of the product. This SDS was prepared and is to be used only for this product. If the product is used
as a component in another product, this SDS information may not be applicable.
Remark:
* This sample is likely to be classified as article product and is out of scope of a SDS as set out in 29 CFR
Part 1910.1200. This SDS is generated for client’s reference only.

· Date of preparation / last revision

10/29/2020 / -

· Abbreviations and acronyms:

IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent

49.4.20

(Contd. on page 10)

USA

Safety Data Sheet

29 CFR 1910.1200

Printing date 10/29/2020 Reviewed on 10/26/2020Version number 1

Trade name: 12V8AV Li-Battery

Page 10/10

NIOSH: National Institute for Occupational Safety

(Contd. of page 9)

OSHA: Occupational Safety & Health
Flam. Liq. 2: Flammable liquids – Category 2
Flam. Sol. 1: Flammable solids – Category 1
Acute Tox. 3: Acute toxicity – Category 3
Acute Tox. 4: Acute toxicity – Category 4
Skin Corr. 1A: Skin corrosion/irritation – Category 1A
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Dam. 1: Serious eye damage/eye irritation – Category 1
Skin Sens. 1: Skin sensitisation – Category 1
Carc. 1A: Carcinogenicity – Category 1A
STOT RE 1: Specific target organ toxicity (repeated exposure) – Category 1

· ***************************************************************************************

End of document

USA

49.4.20