Global Industrial 641527, 641528, 641529 User Manual

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Page 1

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Safety Data Sheet

Printing date :Aug.20th,2019 Revision: Aug.20th,2019

1 Identification of the substance/preparation and of the company/undertaking

Product details

Trade name: Alkaline Battery LR6 LR03 LR20 LR14 6LR61

Registration number:

Application of the substance / the preparation:

To provide power, mainly for remote control, flashlight and so on.

Manufacturer/Supplier:

WUXI NORAN BATTERY CO., LTD. Zhetangbang village, QQqianzhou town,huishan district,wuxi, jiangsu, China. Tel: +86-510-83381858 Fax: +86-510-83399778

Further information obtainable from:

Information in case of emergency:

Andrew MP: 13376218678

Email:

Reference Number:

enquiries@live.cn

Not available.

WUXI NORAN BATTERY CO., LTD.

OGCSH090122-1; SH9000538-1/CHEM

2 Hazards identification

Hazard description:

N Dangerous for the environment

Information concerning particular hazards for human and environment:

The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Classification system:

The classification is according to the latest editions of the EU-lists, and extended by company and literature data.

3 Composition/information on ingredients

Chemical characterization

Description:

Mixture of substances listed below with nonhazardous additions. For the wording of the listed risk phrases refer to section 16.

Dangerous components:

CAS: 1313-13-9 EINECS: 215-202-6 EU Number: 025-001-00-3

CAS: 7440-66-6 EINECS: 231-175-3

CAS: 1310-58-3 EINECS: 215-181-3 EU Number: 019-002-00-8

CAS: 7782-42-5 EINECS: 231-955-3

Non-dangerous component:

CAS: 12597-69-2 Steel

CAS: 7440-50-8 EINECS: 231-159-6

CAS: 32131-17-2 Nylon-66

manganese dioxide Xn; R 20/22 35-40 %

Zinc powder - zinc dust (pyrophoric) F, N; R 15-17-50/53 10-22 %

potassium hydroxide C, Xn; R 22-35 5-9 %

Graphite Xi; R 36/37 2.5- 3 %

copper

15-20%

2-4 %

1- Q2 %

(Contd. on page 2)

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Safety Data Sheet

Trade name:Alkaline Battery LR6 LR03 LR20 LR14 6LR61

Remark :

manganese dioxide (CAS No. 1313-13-9) Synonym: MnO

Zinc (CAS No. 7440-66-6) Synonym: Zn

potassium hydroxide (CAS No. 1310-58-3) Synonym: KOH

copper (CAS No. 7440-50-8) Synonym: Cu

4 First aid measures

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Revision:Aug.20th,2019Printing date: Aug.20th,2019

(Contd. of page 1)

General information:

After inhalation:

After skin contact:

After eye contact:

After swallowing:

Immediately remove any clothing soiled by the product.

Supply fresh air; consult doctor in case of complaints.

Immediately rinse with water. Rinse opened eye for several minutes under running water. Then consult a doctor. If symptoms persist consult doctor.

5 Fire-fighting measures

, sand, extinguishing powder. Do not use water.

Suitable extinguishing agents:

Protective equipment:

₂

Wear fully protective suit. Wear self-contained respiratory protective device. Do not inhale explosion gases or combustion gases.

6 Accidental release measures

Person-related safety precautions:

Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation. Use respiratory protective device against the effects of fumes/dust/aerosol. Keep away from ignition sources.

Measures for environmental protection:

Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water.

Measures for cleaning/collecting:

Do not flush with water or aqueous cleansing agents

7 Handling and storage

Handling

Information for safe handling:

Ensure good ventilation/exhaustion at the workplace. Keep away from heat and direct sunlight. Open and handle receptacle with care.

Information about fire - and explosion protection:

Protect against electrostatic charges. Keep ignition sources away - Do not smoke. Keep respiratory protective device available.

Storage

Requirements to be met by storerooms and receptacles:

Store in a cool location. Store only in the original receptacle.

(Contd. on page 3)

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Safety Data Sheet

Printing date:Aug.20th,2019 Revision: Aug.20th,2019

Trade name:Alkaline Battery LR6 LR03 LR20 LR14 6LR61

(Contd. of page 2)

Information about storage in one common storage facility:

Store away from foodstuffs. Store away from flammable substances.

Further information about storage conditions:

Keep container tightly sealed. Store in cool, dry conditions in well sealed receptacles.

8 Exposure controls/personal protection

Additional information about design of technical facilities:

Ingredients with limit values that require monitoring at the workplace:

No further data; see item 7.

1313-13-9manganese dioxide (35-40%)

WEL (Great Britain)

5 mg/m³ as Mn

PEL (USA)

Short-term value:: C 5 mg/m³ as Mn

REL (USA)

Short-term value:: 3 mg/m³ Long-term value:: 1 mg/m³ as Mn

TLV (USA)

0,2 mg/m³ as Mn

1310-58-3potassium hydroxide (5-9%)

WEL (Great Britain) REL (USA) TLV (USA)

Short-term value:: 2 mg/m³ 2 mg/m³ Short-term value:: C 2 mg/m³

7440-50-8copper (2-4,0%)

WEL (Great Britain)

Short-term value:: 2** mg/m³ Long-term value:: 0,2* 1** mg/m³ *fume **dusts and mists (as Cu)

PEL (USA)

1* 0,1** mg/m³ as Cu *dusts and mists **fume

REL (USA)

Short-term value:: II (2)** mg/m³ Long-term value:: 1* 0,1 R** mg/m³ as Cu *dusts and mists **fume

TLV (USA)

Short-term value:: (0,1)** mg/m³ Long-term value:: (1)* (02)** mg/m³ *dusts and mists; **fume; as Cu

7782-42-5Graphite (2,5-3%)

PEL (USA) REL (USA)

15 mppcf mg/m³ 2,5* mg/m³ *respirable dust

TLV (USA)

2 R mg/m³ all forms except graphite fibers

DNELs:

PNECs:

Additional information:

Personal protective equipment

General protective and hygienic measures:

Not available. Not available.

The lists valid during the making were used as basis.

Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work.

Respiratory protection:

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.

(Contd. on page 4)

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Safety Data Sheet

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Trade name:Alkaline Battery LR6 LR03 LR20 LR14 6LR61

(Contd. of page 3)

Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.

Material of gloves:

The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.

Penetration time of glove material:

The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.

Eye protection:

Safety glasses.

9 Physical and chemical properties

General Information:

Form: Colour: Odour:

Change in condition:

Melting point/Melting range: Boiling point/Boiling range:

Flash point:

Flammability (solid, gaseous):

Ignition temperature:

Self-igniting:

Danger of explosion:

Explosion limits:

Lower: Upper:

Oxidizing properties:

Vapour pressure:

Density:

Relative density:

Vapour density:

Evaporation rate:

Solubility in / Miscibility with

water:

pH-value:

Segregation coefficient (n-octanol/water):

Viscosity:

Dynamic:

Solid Silvery Odourless

Not available. Not available.

Not available.

Product is not selfigniting.

Product does not present an explosion hazard.

Not available. Not available. Not available.

Not available.

Not available. Not available. Not available. Not available.

Not available.

(Contd. on page 5)

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Safety Data Sheet

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Trade name:Alkaline Battery LR6 LR03 LR20 LR14 6LR61

(Contd. of page 4)

10 Stability and reactivity

Thermal decomposition / conditions to be avoided:

Dangerous reactions:

Dangerous decomposition products:

No dangerous reactions known.

Heavy metal pollution: manganese, Zinc and copper.

No decomposition if used according to specifications.

11 Toxicological information

Acute toxicity

LD/LC50 values relevant for classification: 1310-58-3 potassium hydroxide

Oral LD50 273 mg/kg (rat)

Primary irritant effect

on the skin:

on the eye:

Sensitization:

Toxicokinetics, metabolism and distribution:

Acute effects (acute toxicity, irritation and corrosivity):

Repeated dose toxicity:

CMR effects (carcinogenity, mutagenicity and toxicity for reproduction):

Irritating effect possible.

Sensitization possible.

Not available.

12 Ecological information

Information about elimination (persistence and degradability):

Behaviour in environmental systems

Mobility and bioaccumulation potential:

Ecotoxical effects

Acquatic toxicity:

Remark:

General notes:

Very toxic for fish

Not available.

Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water. Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. Also poisonous for fish and plankton in water bodies. Very toxic for aquatic organisms

PBT assessments:

Not available.

13 Disposal considerations

Product

Recommendation:

Must not be disposed together with household garbage. Do not allow product to reach sewage system.

Uncleaned packaging

Recommendation:

Disposal must be made according to official regulations.

14 Transport information

Manganese dioxide battery is considered as "dry cell" battery and not to subject to hazardous materials and dangerous materials regulations for the transportation by U.S.Department of Transportation (US-DOT),the International Civil Organization?(ICAO),the International Air Transport Assosiation (IATA)or International

Maritime Organization(IMO) and also is not classified as dangerous under the current dition of the IATA DANGEROUS GOODS REGULATIONS(Edition 60th),with complying to the Special Provision A123,and all

applicable carrier and government regulations.During the transportation of battereis by ship,trailer or railway, do not leave them in the palces of high temperature and do not allow densation. During transportation,do not allow packages to be fallen down or damaged.

(Contd. on page 6)

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Safety Data Sheet

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Trade name:Alkaline Battery LR6 LR03 LR20 LR14 6LR61

(Contd. of page 5)

Tunnel restriction code:

Maritime transport IMDG

IMDG Class:

UN Number:

Label:

Packaging group:

EMS Number:

Marine pollutant:

Proper shipping name:

Remarks:

Air transport ICAO-TI and IATA-DGR

ICAO/IATA Class:

UN/ID Number:

Label:

Packaging group:

Proper shipping name:

Remarks:

The product is not subject to IMO IMDG Code. The goods are packaged according to the packaging requirement of ordinary goods.

The product is not subject to IATA-DGR. The goods are packaged according to the packaging requirement of ordinary goods.

15 Regulatory information

Sara

Section 355(extremely hazardous substances):

None of the ingredients is listed.

Section 313(Specific toxic chemical listings):

7440-50-8 copper

TSCA(Toxic Substances Control Act):

1313-13-9 manganese dioxide

1310-58-3 potassium hydroxide

7782-42-5 Graphite

7440-50-8 copper

Proposition 65

Chemicals known to cause cancer:

None of the ingredients is listed.

Chemicals known to cause reproductive toxicity for females:

None of the ingredients is listed.

Chemicals known to cause reproductive toxicity for males:

None of the ingredients is listed.

Chemicals known to cause developmental toxicity:

None of the ingredients is listed.

Cancerogenity categories

EPA(Environmental Protection Agency):

1313-13-9 manganese dioxide D

7440-50-8 copper D

IARC(International Agency for Research on Cancer):

None of the ingredients is listed.

NTP(National Toxicology Program):

None of the ingredients is listed.

(Contd. on page 7)

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Safety Data Sheet

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Trade name:Alkaline Battery LR6 LR03 LR20 LR14 6LR61

(Contd. of page 6)

TLV(Threshold Limit Value established by ACGIH):

None of the ingredients is listed.

NIOSH-Ca(National Institute for Occupational Safety and Health):

None of the ingredients is listed.

OSHA-Ca(Occupational Safety & Health Administration):

None of the ingredients is listed.

Labelling according to EU guidelines:

The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous

Materials.

Code letter and hazard designation of product:

N Dangerous for the environment

Hazard-determining components of labelling:

manganese dioxide

potassium hydroxide

Risk phrases:

50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Safety phrases:

1/2 Keep locked up and out of the reach of children.

26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

29/56 Do not empty into drains, dispose of this material and its container at hazardous or special waste

collection point. 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. 43 In case of fire, use sand, carbon dioxide or powdered extinguishing agent. Never use water. 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where

possible).

National regulations:

Waterhazard class:

Water hazard class 2 (Self-assessment): hazardous for water.

16 Other information

Relevant R-phrases

15 Contact with water liberates extremely flammable gases. 17 Spontaneously flammable in air. 20/22 Harmful by inhalation and if swallowed. 22 Harmful if swallowed. 35 Causes severe burns. 36/37 Irritating to eyes and respiratory system. 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

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The contents and format of this MSDS/SDS are in accordance with REGULATION (EC) No 1907/2006, EU Commission Directive 1999/45/EC, 67/548/EEC.

DISCLAIMER OF LIABILITY : The information in this MSDS/SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS/SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS/SDS information may not be applicable.

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