Global Industrial 641190 User Manual

Page 1
Global™ Graffiti Wipes
Safety Data Sheet
Date of issue: 12/9/2016
Revision date: 07/13/2015
P GHS SDS
Page 1 of 5
SECTION 1: Product and company identification
Product name
:
Global™ Graffiti Wipes
Use of the substance/mixture
:
Premoistened wipe
Product code
:
641190 SDS Number: 1447
Company
:
Global Industrial 2505 Mill Center Parkway Buford, GA 30518 - USA T 800-645-1232
Emergency number
:
Chemtrec 800-424-9300
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification (GHS-US)
Eye Irrit. 2A
H319
Full text of H-phrases: see section 16
2.2. Label elements
GHS-US labeling
Hazard pictograms (GHS-US)
:
GHS07
Signal word (GHS-US)
:
Warning
Hazard statements (GHS-US)
:
Causes serious eye irritation
Precautionary statements (GHS-US)
:
Wash thoroughly after handling Wear eye protection, protective clothing, protective gloves If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention
2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
Full text of H-phrases: see section 16
3.2. Mixture
Name
Product identifier
%
Classification (GHS-US)
Dimethyl Adipate
(CAS No) 627-93-0
10 - 30
Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Inhalation), H332
UNDECETH-5
(CAS No) 34398-01-1
1 - 5
Acute Tox. 4 (Oral), H302 Eye Dam. 1, H318
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general
:
If you feel unwell, seek medical advice (show the label where possible).
First-aid measures after inhalation
:
If you feel unwell, seek medical advice.
First-aid measures after skin contact
:
Gently wash with plenty of soap and water.
First-aid measures after eye contact
:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Page 2
Global™ Graffiti Wipes
Safety Data Sheet
Date of issue: 12/9/2016
Revision date: 07/13/2015
P GHS SDS
Page 2 of 5
First-aid measures after ingestion
:
Rinse mouth with water. Do not induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries
:
Not expected to present a significant hazard under anticipated conditions of normal use.
Symptoms/injuries after inhalation
:
None under normal use.
Symptoms/injuries after skin contact
:
Contact during a long period may cause light irritation. Repeated exposure may cause skin dryness or cracking.
Symptoms/injuries after eye contact
:
Causes serious eye irritation.
Symptoms/injuries after ingestion
:
Gastrointestinal complaints.
Chronic symptoms
:
No data available.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
:
Foam. Carbon dioxide. Dry chemical powder.
Unsuitable extinguishing media
:
Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard
:
Combustible liquid.
Reactivity
:
Upon combustion: CO and CO2 are formed.
5.3. Advice for firefighters
Firefighting instructions
:
Exercise caution when fighting any chemical fire. Use water spray or fog for cooling exposed containers. Take account of environmentally hazardous firefighting water.
Protection during firefighting
:
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures
:
Isolate from fire, if possible, without unnecessary risk.
6.1.1. For non-emergency personnel
Protective equipment
:
Protective goggles. Gloves. Protective clothing.
Emergency procedures
:
Evacuate unnecessary personnel. NO open flames, NO sparks, and NO smoking. Avoid contact with skin, eyes and clothing. Ventilate spillage area.
6.1.2. For emergency responders
Protective equipment
:
Equip cleanup crew with proper protection.
Emergency procedures
:
Stop leak if safe to do so. Stop release. Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters.
6.3. Methods and material for containment and cleaning up
For containment
:
Contain released substance, pump into suitable containers.
Methods for cleaning up
:
This material and its container must be disposed of in a safe way, and as per local legislation.
6.4. Reference to other sections
No additional information available
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling
:
Comply with the legal requirements. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Do not eat, drink or smoke when using this product. Do not get in eyes, on skin, or on clothing. Handle and open the container with care. Keep away from sources of ignition - No smoking.
Hygiene measures
:
Wash thoroughly after handling. Wash contaminated clothing before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures
:
Comply with applicable regulations.
Storage conditions
:
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Incompatible products
:
Oxidizing agent. strong acids. Strong bases.
Page 3
Global™ Graffiti Wipes
Safety Data Sheet
Date of issue: 12/9/2016
Revision date: 07/13/2015
P GHS SDS
Page 3 of 5
Incompatible materials
:
Sources of ignition. Heat sources.
Heat-ignition
:
KEEP SUBSTANCE AWAY FROM: heat sources. ignition sources.
Prohibitions on mixed storage
:
KEEP SUBSTANCE AWAY FROM: (strong) acids. (strong) bases. oxidizing agents.
Storage area
:
Meet the legal requirements. Store in a cool area. Store in a well-ventilated place.
Special rules on packaging
:
meet the legal requirements.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
No additional information available
8.2. Exposure controls
Personal protective equipment
:
Use appropriate personal protective equipment when risk assessment indicates this is necessary. Safety glasses. Gloves. Protective clothing.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
:
Solid
Appearance
:
Premoistened wipe.
Odor
:
Mild odor
Odor threshold
:
No data available
pH:No data available
Melting point
:
No data available
Freezing point
:
No data available
Boiling point
:
No data available
Flash point
:
163 °F Closed cup - Tested using the liquid component of the towelette
Relative evaporation rate (butyl acetate=1)
:
No data available
Flammability (solid, gas)
:
No data available
Explosion limits
:
No data available
Explosive properties
:
No data available
Oxidizing properties
:
No data available
Vapor pressure
:
No data available
Relative density
:
No data available
Relative vapor density at 20 °C
:
No data available
Specific gravity / density
:
1.03 g/ml - Tested using the liquid component of the towelette
Solubility
:
Liquid component is soluble in water.
Log Pow
:
No data available
Log Kow
:
No data available
Auto-ignition temperature
:
No data available
Decomposition temperature
:
No data available
Viscosity
:
No data available
Viscosity, kinematic
:
No data available
Viscosity, dynamic
:
No data available
VOC content
:
< 20 % - Tested using the liquid component of the towelette
SECTION 10: Stability and reactivity
10.1. Reactivity
Upon combustion: CO and CO2 are formed.
10.2. Chemical stability
No additional information available
Page 4
Global™ Graffiti Wipes
Safety Data Sheet
Date of issue: 12/9/2016
Revision date: 07/13/2015
P GHS SDS
Page 4 of 5
10.3. Possibility of hazardous reactions
Refer to section 10.1 on Reactivity.
10.4. Conditions to avoid
No additional information available
10.5. Incompatible materials
strong acids. Strong bases. Oxidizing agents.
10.6. Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity
:
Not classified
UNDECETH-5 (34398-01-1)
LD50 oral rat
> 1400 mg/kg
Skin corrosion/irritation
:
Not classified
Serious eye damage/irritation
:
Causes serious eye irritation.
Respiratory or skin sensitization
:
Not classified
Germ cell mutagenicity
:
Not classified
Carcinogenicity
:
Not classified
Reproductive toxicity
:
Not classified
Specific target organ toxicity (single exposure)
:
Not classified
Specific target organ toxicity (repeated exposure)
:
Not classified
Aspiration hazard
:
Not classified
Symptoms/injuries after inhalation
:
None under normal use.
Symptoms/injuries after skin contact
:
Contact during a long period may cause light irritation. Repeated exposure may cause skin dryness or cracking.
Symptoms/injuries after eye contact
:
Causes serious eye irritation.
Symptoms/injuries after ingestion
:
Gastrointestinal complaints.
Chronic symptoms
:
No data available.
Likely routes of exposure
:
Dermal
SECTION 12: Ecological information
12.1. Toxicity
Ecology - general
:
Not classified due to lack of data.
UNDECETH-5 (34398-01-1) LC50 fish 1
< 10 mg/l
EC50 Daphnia 1
< 10 mg/l
ErC50 (algae)
< 10 mg/l
12.2. Persistence and degradability
Graffiti Wipes Persistence and degradability
Not established.
12.3. Bioaccumulative potential
No additional information available
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste treatment methods
:
Do not flush wipes.
Waste disposal recommendations
:
Dispose in a safe manner in accordance with local/national regulations.
Page 5
Global™ Graffiti Wipes
Safety Data Sheet
Date of issue: 12/9/2016
Revision date: 07/13/2015
P GHS SDS
Page 5 of 5
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT : Not regulated for transport
Additional information
Other information
:
No supplementary information available.
ADR
No additional information available
Transport by sea
No additional information available
Air transport
No additional information available
SECTION 15: Regulatory information
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory.
This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR §372.38(a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
UNDECETH-5 (34398-01-1)
SARA Section 311/312 Hazard Classes
Immediate (acute) health hazard
California Proposition 65 - This product does not contain substances known to the state of California to cause cancer and/or reproductive toxicity.
SECTION 16: Other information
Training advice
:
Normal use of this product shall imply use in accordance with the instructions on the packaging.
Full text of H-phrases:
------
Acute Tox. 4 (Inhalation)
Acute toxicity (inhalation) Category 4
------
Acute Tox. 4 (Oral)
Acute toxicity (oral) Category 4
------
Eye Dam. 1
Serious eye damage/eye irritation Category 1
------
Eye Irrit. 2A
Serious eye damage/eye irritation Category 2A
------
H302
Harmful if swallowed
------
H318
Causes serious eye damage
------
H319
Causes serious eye irritation
------
H332
Harmful if inhaled
NFPA health hazard
:
1 - Exposure could cause irritation but only minor residual injury even if no treatment is given.
NFPA fire hazard
:
2 - Must be moderately heated or exposed to relatively high temperature before ignition can occur.
NFPA reactivity
:
0 - Normally stable, even under fire exposure conditions, and are not reactive with water.
Prepared by: Technical Department
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety an d environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. No w arranty is expressed or implied regarding the accuracy of this data or the results obtained from the use thereof. Our compan y assumes no responsibility for personal injury or property damage to the vendee, users or third parties caused by the material. Su ch vendees or users assume all risks associated with the use of this material.
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