Global Industrial 640414 User Manual

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SAFETY DATA SHEET
Issue Date 09-Jan-2015 Revision Date 09-Jan-2015 Version 1
1. PRODUCT AND COMPANY IDENTIFICATION
Product identifier Product Name
Other means of identification Product Code Synonyms
Details of the supplier of the safety data sheet Company Name
Emergency telephone number Emergency Telephone
Classification
Glass & Mirror Cleaner
Global Industrial 2505 Mill Center Parkway, Buford, GA 30518 (888) 978-7759
Chemtrec (US &Canada) 800-424-9300 Chemtrec (outside US & Canada) 703-527-3887
2. HAZARDS IDENTIFICATION
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Acute toxicity - Oral Not classified Acute toxicity - Dermal Not classified Flammable liquids Category 3
Label elements
Emergency Overview
Warning
Flammable liquid and vapor
Appearance Clear Blue Physical state Liquid Odor Lilac Precautionary Statements - Prevention
Keep away from heat/sparks/open flames/hot surfaces. — No smoking
Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools Take precautionary measures against static discharge Wear protective gloves/protective clothing/eye protection/face protection
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Precautionary Statements - Response
Specific Treatment (See Section 4 on the SDS) IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower In case of fire: Use CO2, dry chemical, or foam for extinction
Precautionary Statements - Storage
Store in a well-ventilated place. Keep cool
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC) Other Information
Unknown Acute Toxicity 0.015% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Weight-% Trade Secret
2-Propanol 67-63-0 1-5 *
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
First aid measures General advice Skin Contact
Eye contact
Inhalation
Ingestion
Self-protection of the first aider Most important symptoms and effects, both acute and delayed Symptoms
Indication of any immediate medical attention and special treatment needed
If symptoms persist, call a physician. Immediate medical attention is not required. Wash off immediately with soap and plenty of
water while removing all contaminated clothes and shoes. If skin irritation persists, call a physician.
Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Keep eye wide open while rinsing. If symptoms persist, call a physician.
Immediate medical attention is not required. If symptoms persist, call a physician. Move to fresh air in case of accidental inhalation of vapors or decomposition products.
Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Call a physician. Do NOT induce vomiting.
Use personal protective equipment as required.
Any additional important symptoms and effects are described in Section 11: Toxicology Information.
Note to physicians
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use. Dry chemical. Carbon dioxide (CO2). Water spray (fog). Alcohol resistant foam.
Unsuitable extinguishing media
Caution: Use of water spray when fighting fire may be inefficient.
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Specific hazards arising from the chemical
Keep product and empty container away from heat and sources of ignition. Risk of ignition.
Explosion data Sensitivity to Mechanical Impact Sensitivity to Static Discharge
None. None.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures Personal precautions
Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Remove all sources of ignition. Pay attention to flashback. Take precautionary measures against static discharges. Use personal protective equipment as required.
Environmental precautions Environmental precautions
Prevent further leakage or spillage if safe to do so. Prevent product from entering drains.
Methods and material for containment and cleaning up Methods for containment Methods for cleaning up
Prevent further leakage or spillage if safe to do so. Dam up. Soak up with inert absorbent material. Pick up and transfer to properly labeled
containers. Take precautionary measures against static discharges.
7. HANDLING AND STORAGE
Precautions for safe handling Advice on safe handling
Conditions for safe storage, including any incompatibilities Storage Conditions
Use with local exhaust ventilation. All equipment used when handling the product must be
grounded. Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Use
personal protective equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors).
Keep containers tightly closed in a cool, well-ventilated place. Keep away from heat. Keep in properly labeled containers.
Incompatible materials
None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
2-Propanol
67-63-0
NIOSH IDLH Immediately Dangerous to Life or Health
Other Information
.
STEL: 400 ppm
TWA: 200 ppm
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).
TWA: 400 ppm
TWA: 980 mg/m
(vacated) TWA: 400 ppm
(vacated) TWA: 980 mg/m
(vacated) STEL: 500 ppm
(vacated) STEL: 1225 mg/m
3
IDLH: 2000 ppm
TWA: 400 ppm
3
3
TWA: 980 mg/m
STEL: 500 ppm
STEL: 1225 mg/m
3
3
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Appropriate engineering controls Engineering Controls Individual protection measures, such as personal protective equipment
Eye/face protection Skin and body protection
Respiratory protection
General Hygiene
Showers, Eyewash stations & Ventilation systems.
Tight sealing safety goggles. No special technical protective measures are necessary. Wear protective gloves and
protective clothing. Prolonged contact may cause redness and irritation. Wear protective gloves and protective clothing if needed.
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.
When using do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties Physical state
Appearance Color Odor Odor threshold
Liquid Clear Blue Blue Lilac No Information available
Property Values Remarks • Method
pH Specific Gravity Viscosity
Melting point/freezing point
Flash point Boiling point / boiling range Evaporation rate Flammability (solid, gas) Flammability Limits in Air Upper flammability limit: Lower flammability limit: Vapor pressure Vapor density Water solubility Partition coefficient Autoignition temperature Decomposition temperature
6.5 - 8.5
0.99 < 25 cP @ 25°C No Information available 42 °C 107 °F < 212 °F / No Information available
Not Applicable Not Applicable No Information available No Information available Complete No Information available No Information available No Information available
Other Information
Density Lbs/Gal VOC Content (%)
8.25
3.5
10. STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
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Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
Heat, flames and sparks.
Incompatible materials
None known based on information supplied.
Hazardous Decomposition Products
None known based on information supplied.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure Product Information
Inhalation
Harmful by inhalation, ingestion, in contact with eyes and skin. Breathing of vapors may cause dizziness and shortness of breath. Inhalation of vapors in
high concentration may cause irritation of respiratory system.
Eye contact Skin Contact Ingestion
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
2-Propanol 67-63-0
Contact with eyes may cause irritation. Prolonged or repeated contact may dry skin and cause irritation. May cause gastro intestinal irritation.
= 1870 mg/kg ( Rat ) = 4059 mg/kg ( Rabbit ) = 72600 mg/m3 ( Rat ) 4 h
Information on toxicological effects Symptoms
No Information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization
Germ cell mutagenicity Carcinogenicity
Chemical Name ACGIH IARC NTP OSHA
2-Propanol 67-63-0
IARC (International Agency for Research on Cancer)
Not classifiable as a human carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
Reproductive toxicity STOT - single exposure STOT - repeated exposure
Target organ effects
Aspiration hazard
No Information available. No Information available. The table below indicates whether each agency has listed any ingredient as a carcinogen.
Yes Group 3 Yes X
No Information available. No Information available. No Information available. EYES, Respiratory system, Skin. No Information available.
Numerical measures of toxicity - Product Information Unknown Acute Toxicity
0.015% of the mixture consists of ingredient(s) of unknown toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
12. ECOLOGICAL INFORMATION
Ecotoxicity
0.05% of the mixture consists of components(s) of unknown hazards to the aquatic environment
Chemical Name Algae/aquatic plants Fish Crustacea
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2-Propanol
67-63-0
Persistence and degradability
No Information available.
Bioaccumulation
Bioaccumulative potential.
Chemical Name Partition coefficient
2-Propanol
67-63-0
Other adverse effects
Waste treatment methods Disposal of wastes
Contaminated packaging
1000: 96 h Desmodesmus
subspicatus mg/L EC50 1000: 72 h
Desmodesmus subspicatus mg/L
EC50
9640: 96 h Pimephales promelas
mg/L LC50 flow-through 11130: 96
h Pimephales promelas mg/L LC50
static 1400000: 96 h Lepomis
macrochirus µg/L LC50
13299: 48 h Daphnia magna mg/L
0.05
No Information available
13. DISPOSAL CONSIDERATIONS
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Do not reuse container.
EC50
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste Status
2-Propanol
67-63-0
Toxic
Ignitable
14. TRANSPORT INFORMATION
The shipping classification information in this section (Section 14) is meant as a guide to the overall classification of the product. However, transportation classifications may be subject to change with changes in package size. Consult shipper requirements under 49 CFR, IATA and IMDG to assure regulatory compliance. According to Exceptions for Class 3 (flammable and combustible liquids), this product maybe reclassed as combustible liquid, see 49CFR173.150(e)(1) and (2).
DOT
UN/ID No. Proper shipping name Hazard Class Packing Group Special Provisions Description Emergency Response Guide Number
TDG
UN/ID No. Proper shipping name Hazard Class Packing Group Description
Regulated UN1993 Flammable liquids, n.o.s. 3 III B1, B52, IB3, T4, TP1, TP29 UN1993, Flammable liquids, n.o.s. (Isopropanol), 3, III 129
UN1993 Flammable liquid, n.o.s. 3 III UN1993, Flammable liquids, n.o.s. (Isopropanol), 3, III
International Inventories
TSCA DSL/NDSL
15. REGULATORY INFORMATION
Complies Complies
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Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical Name SARA 313 - Threshold Values %
2-Propanol - 67-63-0 1.0
SARA 311/312 Hazard Categories
Acute health hazard Chronic Health Hazard Fire hazard Sudden release of pressure hazard Reactive Hazard
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material
Yes No Yes No No
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
2-Propanol
67-63-0
X X X
U.S. EPA Label Information EPA Pesticide Registration Number
Not Applicable
16. OTHER INFORMATION
NFPA Health hazards 1 Flammability 2 Instability 0 Physical and Chemical
Properties Yes
HMIS Health hazards 1 Flammability 2 Physical hazards 0 Personal protection B Issue Date
Revision Date Revision Note
No Information available
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
09-Jan-2015 09-Jan-2015
End of Safety Data Sheet
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