SAFETY DATA SHEET
Issue Date 01-Feb-2016 Revision Date 08-Jan-2015 Version 1
1. PRODUCT AND COMPANY IDENTIFICATION
Product identifier
Product Name
Other means of identification
Product Code
Synonyms
Details of the supplier of the safety data sheet
Company Name
Emergency telephone number
Emergency Telephone
Classification
Liquid Hand Soap
640412
None
Global Industrial
2505 Mill Center Parkway, Buford, GA 30518
(888) 978-7759
Chemtrec (US &Canada) 800-424-9300
Chemtrec (outside US & Canada) 703-527-3887
2. HAZARDS IDENTIFICATION
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Acute toxicity - Oral Not classified
Acute toxicity - Dermal Not classified
Label elements
Emergency Overview
Appearance White Emulsion Physical state Liquid Odor Fresh Orchard
Precautionary Statements - Response
Immediately call a POISON CENTER or doctor/physician
Specific Treatment (See Section 4 on the SDS)
Hazards not otherwise classified (HNOC)
Other Information
• Harmful to aquatic life with long lasting effects
• Harmful to aquatic life
Unknown Acute Toxicity 0.02313883% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Weight-% Trade Secret
Cocamide DEA 68603-42-9 .1-1 *
Cocamidopropyl Betaine 61789-40-0 .1-1 *
*The exact percentage (concentration) of composition has been withheld as a trade secret.
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4. FIRST AID MEASURES
First aid measures
Skin Contact
Eye contact
Inhalation
Ingestion
Most important symptoms and effects, both acute and delayed
Symptoms
Indication of any immediate medical attention and special treatment needed
Note to physicians
Wash off immediately with plenty of water. Wash skin with soap and water.
Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.
Consult a physician.
Remove to fresh air.
Clean mouth with water and drink afterwards plenty of water.
Any additional important symptoms and effects are described in Section 11: Toxicology
Information.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media
Specific hazards arising from the chemical
No Information available.
Caution: Use of water spray when fighting fire may be inefficient.
Explosion data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
None.
None.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Environmental precautions
Environmental precautions
Methods and material for containment and cleaning up
Methods for containment
Methods for cleaning up
Ensure adequate ventilation, especially in confined areas.
See Section 12 for additional ecological information.
Prevent further leakage or spillage if safe to do so.
Pick up and transfer to properly labeled containers.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Conditions for safe storage, including any incompatibilities
Handle in accordance with good industrial hygiene and safety practice.
640412 Liquid Hand Soap Revision Date 08-Jan-2015
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Storage Conditions
Incompatible materials
Keep containers tightly closed in a dry, cool and well-ventilated place.
None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Ethylene Glycol Stearate
111-60-4
Glycerin
56-81-5
Ethanol
64-17-5
Diethanolamine
111-42-2
Formaldehyde
50-00-0
NIOSH IDLH Immediately Dangerous to Life or Health
.
TWA: 10 mg/m3 except stearates
of toxic metals
- TWA: 15 mg/m3 mist, total
STEL: 1000 ppm TWA: 1000 ppm
TWA: 1 mg/m3 inhalable fraction
and vapor
S*
Ceiling: 0.3 ppm TWA: 0.75 ppm
- -
TWA: 5 mg/m3 mist, respirable
(vacated) TWA: 10 mg/m3 mist,
(vacated) TWA: 5 mg/m3 mist,
(vacated) TWA: 1900 mg/m
(vacated) TWA: 3 ppm unless
(vacated) STEL: 10 ppm 30 min
unless specified in 1910.1048
(vacated) Ceiling: 5 ppm unless
particulate
fraction
total particulate
respirable fraction
TWA: 1900 mg/m
(vacated) TWA: 1000 ppm
(vacated) TWA: 3 ppm
(vacated) TWA: 15 mg/m
specified in 1910.1048
specified in 1910.1048
STEL: 2 ppm see 29 CFR
1910.1048
3
3
3
-
IDLH: 3300 ppm
TWA: 1000 ppm
TWA: 1900 mg/m
TWA: 3 ppm
TWA: 15 mg/m
IDLH: 20 ppm
Ceiling: 0.1 ppm 15 min
TWA: 0.016 ppm
3
3
Other Information
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).
Appropriate engineering controls
Engineering Controls
Showers, Eyewash stations & Ventilation systems.
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin and body protection
Respiratory protection
Wear safety glasses if handling large volume.
No special technical protective measures are necessary.
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Positive-pressure supplied air respirators may be
required for high airborne contaminant concentrations. Respiratory protection must be
provided in accordance with current local regulations.
General Hygiene
Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state
Appearance
Color
Liquid
White Emulsion
White
640412 Liquid Hand Soap Revision Date 08-Jan-2015
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Odor
Odor threshold
Fresh Orchard
No Information available
Property Values Remarks • Method
pH
Specific Gravity
Viscosity
Melting point/freezing point
Flash point
Boiling point / boiling range
Evaporation rate
Flammability (solid, gas)
Flammability Limits in Air
Upper flammability limit:
Lower flammability limit:
Vapor pressure
Vapor density
Water solubility
Partition coefficient
Autoignition temperature
Decomposition temperature
7.0 - 8.0
1.03
> 1000 cP @ 25°C
No Information available
None
100 °C / 212 ° F Degrees
No Information available
No data available
No Information available
No Information available
No Information available
No Information available
Complete
No Information available
No Information available
No Information available
Other Information
Density Lbs/Gal
VOC Content (%)
8.56
0.05899
10. STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
Extremes of temperature and direct sunlight.
Incompatible materials
None known based on information supplied.
Hazardous Decomposition Products
None known based on information supplied.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Inhalation
Eye contact
Skin Contact
May cause eye irritation. May be harmful if swallowed
Avoid breathing vapors or mists. May cause irritation of respiratory tract.
Avoid contact with eyes. May cause irritation.
Prolonged or repeated contact may dry skin and cause irritation. Repeated or prolonged
skin contact may cause allergic reactions with susceptible persons.
Ingestion
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Cocamide DEA
68603-42-9
Cocamidopropyl Betaine
61789-40-0
May cause gastro intestinal irritation.
= 12400 µL/kg ( Rat ) - -
= 4900 mg/kg ( Rat ) - -
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Information on toxicological effects
Symptoms
No Information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
Germ cell mutagenicity
Carcinogenicity
No Information available.
No Information available.
The table below indicates whether each agency has listed any ingredient as a carcinogen.
Ethanol has been shown to be carcinogenic in long-term studies only when consumed as
alcoholic beverage.
Chemical Name ACGIH IARC NTP OSHA
Cocamide DEA
68603-42-9
IARC (International Agency for Research on Cancer)
Group 2B - Possibly Carcinogenic to Humans
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
Reproductive toxicity
STOT - single exposure
STOT - repeated exposure
Chronic toxicity
- Group 2B - X
No Information available.
No Information available.
No Information available.
Ethanol has been shown to be a reproductive toxin only when consumed as an alcoholic
beverage. Ethanol has been shown to be carcinogenic in long-term studies only when
consumed as alcoholic beverage.
Aspiration hazard
No Information available.
Numerical measures of toxicity - Product Information
Unknown Acute Toxicity
0.02313883% of the mixture consists of ingredient(s) of unknown toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral)
29,681.00
12. ECOLOGICAL INFORMATION
Ecotoxicity
4.62964% of the mixture consists of components(s) of unknown hazards to the aquatic environment
Chemical Name Algae/aquatic plants Fish Crustacea
Sodium Chloride
7647-14-5
Cocamide DEA
68603-42-9
Cocamidopropyl Betaine
61789-40-0
Glycerin
56-81-5
Ethanol
64-17-5
Diethanolamine 7.8: 72 h Desmodesmus 4460 - 4980: 96 h Pimephales 55: 48 h Daphnia magna mg/L
0.55: 96 h Desmodesmus
subspicatus mg/L EC50 1.0 - 10.0:
72 h Desmodesmus subspicatus
- 5560 - 6080: 96 h Lepomis
macrochirus mg/L LC50
flow-through 6420 - 6700: 96 h
Pimephales promelas mg/L LC50
static 4747 - 7824: 96 h
Oncorhynchus mykiss mg/L LC50
flow-through 12946: 96 h Lepomis
macrochirus mg/L LC50 static 6020
- 7070: 96 h Pimephales promelas
mg/L LC50 static 7050: 96 h
Pimephales promelas mg/L LC50
semi-static
- 3.6: 96 h Brachydanio rerio mg/L
LC50 semi-static
1.0 - 10.0: 96 h Brachydanio rerio
mg/L LC50 2: 96 h Brachydanio
rerio mg/L LC50 semi-static
mg/L EC50
- 51 - 57: 96 h Oncorhynchus mykiss
mL/L LC50 static
- 12.0 - 16.0: 96 h Oncorhynchus
mykiss mL/L LC50 static 100: 96 h
Pimephales promelas mg/L LC50
static 13400 - 15100: 96 h
Pimephales promelas mg/L LC50
flow-through
340.7 - 469.2: 48 h Daphnia magna
mg/L EC50 Static 1000: 48 h
Daphnia magna mg/L EC50
4.2: 24 h Daphnia magna mg/L
EC50
6.5: 48 h Daphnia magna mg/L
EC50
500: 24 h Daphnia magna mg/L
EC50
10800: 24 h Daphnia magna mg/L
EC50 9268 - 14221: 48 h Daphnia
magna mg/L LC50 2: 48 h Daphnia
magna mg/L EC50 Static
640412 Liquid Hand Soap Revision Date 08-Jan-2015
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111-42-2 subspicatus mg/L EC50 2.1 - 2.3:
Formaldehyde
50-00-0
Persistence and degradability
No Information available.
Bioaccumulation
No Information available.
Other adverse effects
Waste treatment methods
96 h Pseudokirchneriella
subcapitata mg/L EC50
- 41: 96 h Brachydanio rerio mg/L
promelas mg/L LC50 flow-through
600 - 1000: 96 h Lepomis
macrochirus mg/L LC50 static 1200
- 1580: 96 h Pimephales promelas
mg/L LC50 static
LC50 static 100 - 136: 96 h
Oncorhynchus mykiss mg/L LC50
static 1510: 96 h Lepomis
macrochirus µg/L LC50 static 22.6 -
25.7: 96 h Pimephales promelas
mg/L LC50 flow-through 23.2 - 29.7:
96 h Pimephales promelas mg/L
LC50 static 0.032 - 0.226: 96 h
Oncorhynchus mykiss mL/L LC50
No Information available
13. DISPOSAL CONSIDERATIONS
EC50
2: 48 h Daphnia magna mg/L LC50
11.3 - 18: 48 h Daphnia magna
mg/L EC50 Static
flow-through
Disposal of wastes
Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated packaging
Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes
Formaldehyde
50-00-0
Do not reuse container.
U122 Included in waste streams:
K009, K010, K038, K040,
K156, K157
- U122
This product contains one or more substances that are listed with the State of California as a hazardous waste.
14. TRANSPORT INFORMATION
The basic description below is specific to the container size. This information is provided for at a glance DOT information. Please
refer to the container and/or shipping papers for the appropriate shipping description before tendering this material for shipment.
For additional information, please contact the distributor listed in section 1 of this SDS.
DOT
TDG
Not regulated
Not regulated
15. REGULATORY INFORMATION
International Inventories
TSCA
DSL/NDSL
Complies
Complies
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
US Federal Regulations
640412 Liquid Hand Soap Revision Date 08-Jan-2015
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SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
Acute health hazard
Chronic Health Hazard
Fire hazard
Sudden release of pressure hazard
Reactive Hazard
No
No
No
No
No
CWA (Clean Water Act)
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42)
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals
Chemical Name California Proposition 65
Cocamide DEA - 68603-42-9 Carcinogen
Ethanol - 64-17-5 Carcinogen
Diethanolamine - 111-42-2 Carcinogen
Formaldehyde - 50-00-0 Carcinogen
Developmental
WARNING: This product contains a chemical known to the state of California to cause cancer. WARNING: This
product contains a chemical known in the State of California to cause birth defects or other reproduction harm.
Chemical Name(s):
Acetic acid, 2,2,-dichloro- , Methanol
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
Glycerin
56-81-5
Ethanol
64-17-5
Diethanolamine
111-42-2
Formaldehyde
50-00-0
X X X
X X X
X X X
X X X
U.S. EPA Label Information
EPA Pesticide Registration Number
Not Applicable
16. OTHER INFORMATION
NFPA Health hazards 0 Flammability 0 Instability 0 Physical and Chemical
Properties Yes
HMIS Health hazards 0 Flammability 0 Physical hazards 0 Personal protection A
Issue Date
Revision Date
Revision Note
No Information available
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
01-Feb-2016
08-Jan-2015
640412 Liquid Hand Soap Revision Date 08-Jan-2015
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transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
End of Safety Data Sheet
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