SAFETY DATA SHEET
Compliant with GB/T16483 and GB/T17519
Section 1 - Chemical and Enterprise Identification
Chinese name
Product name in English
PD-05
PD-05
Recommended use of the chemical and restrictions on use
Coating powder for professional use
Powder application by electrostatic spraying
Information on the Manufacturer/Supplier/Distributor
Producer/Supplier
Producer/Supplier
Huangshan Huajia Surface Technology Co.,Ltd.
Street/Box No 109,Yongjia Avenue,Huizhou District,Huangshan,Anhui,PRC
Telephone
Telefax
+86 559 3513678
+86 559 3512643
Emergency Information
Emergency telephone number +86 559 3516967
Section 2 - Hazard Identification
This preparation is hazardous per the following GHS criteria
GHS Hazard Category
Acute oral toxicity Category 4
Acute inhalation toxicity Category 4
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 1
Skin sensitization Category 1
Germ cell mutagenicity Category 1B
Specific target organ toxicity - repeated exposure Category 2
Endpoints which are “”not classified“”, “”cannot classified“” and “”not applicable“” are not shown
GHS-Labelling
Hazard symbols
Signal word Danger
Hazard statements Harmful if inhaled.
Harmful if swallowed.
Causes skin irritation.
Causes serious eye damage.
May cause damage to organs through prolonged or repeated exposure.
May cause an allergic skin reaction.
May cause genetic defects.
Precautionary statements Contaminated work clothing should not be allowed out of the workplace.
Wear eye/face protection.
Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
Do not eat, drink or smoke when using this product.
Obtain special instructions before use.
Use only outdoors or in a well-ventilated area.
Wash hands after handling.
Wear protective gloves.
IF exposed or concerned: Get medical advice/ attention.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
IF ON SKIN: Wash with plenty of soap and water.
Huangshan Huajia Surface Technology Co.,Ltd
Copies may be made only for those using products.
and all affiliates. All rights reserved.
Huajia Surface Techology
Revision Date: 2 019-06-01
en/CNPage1-8
SAFETY DATA SHEET
Compliant with GB/T16483 and GB/T17519
If skin irritation or rash occurs: Get medical advice/ attention.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician.
Specific treatment (see supplemental first aid instructions on this label).
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local regulation.
Other hazards which do not result in classification
Contains isocyanates. See information supplied by the manufacturer.
Main Symptom and Emergency Summary After Contact
Refer to section 4 of this SDS for information on symptoms, hazards and treatment after contact.
Section 3 - Ingredients/Composition Information
Chemical nature
√
Mixture
Substance
Components
CAS-No. Chemical Name Concentration GHS Hazardous
2451-62-9
-
31570-04-4
14059-33-7
1317-80-2
1309-37-1
7429-90-5
1314-23-4
5567-15-7
147-14-8
25036-25-3
8002-74-2
8002-74-2
471-34-1
1860-26-0
1,3,5-TRIGLYCIDYL ISOCYANURATE
Additive 1
Zinc Salt
TRIS(2,4-DI-TERT-BUTYLPENYL) PHOSPHITE
Additive 2
BISMUTH VANADIUM OXIDE
TITANIUM DIOXIDE (RUTILE)
IRON OXIDE
ALUMINUM
ZIRCONIUM OXIDE
C.I. PIGMENT YELLOW 83
PHTHALOCYANINE BLUE PIGMENT
BISPHENOL A/EPICHLOROHYDRIN POLYMER
HYDROCARBON WAX
HYDROCARBON WAX
CALCIUM CARBONATE
2-ETHYL-N,N-BIS(2-ETHYLHEXYL)HEXYLAMINE
Section 4 - First-aid Measures
1.0-30%
<10%
<10%
<10%
<10%
<10%
<25%
<10%
<10%
<10%
<10%
<10%
<10%
<10%
<10%
<50%
<10%
√
√
√
√
√
√
√
√
√
√
√
√
√
√
√
√
√
Inhalation
Avoid breathing dust. Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat and cough. Move to
fresh air. If breathing is irregular or stopped, administer artificial respiration. If symptoms persist, call a physician.
Skin contact
Do NOT use solvents or thinners. Take off contaminated clothing and shoes immediately. Wash skin thoroughly with soap and
water or use recognized skin cleanser. If skin irritation persists, call a physician.
Eye contact
Remove contact lenses. Irrigate copiously with clean, fresh water for at least 15 minutes, holding the eyelids apart. Seek
medical advice.
Ingestion
If swallowed, seek medical advice immediately and show this container or label.
Most important symptoms/effects, acute and delayed
Inhalation
Exposure to isocyanates may cause respiratory sensitization. This effect may be permanent. Symptoms include an asthma-like
reaction with shortness of breath, wheezing, cough or permanent lung sensitization. This effect may be delayed for several
hours after exposure. Repeated overexposure to isocyanates may cause a decrease in lung function, which may be permanent.
Individuals with lung or breathing problems or prior reactions to isocyanates must not be exposed to vapors or spray mist of this
product.
Ingestion
May result in gastrointestinal distress.
Huangshan Huajia Surface Technology Co.,Ltd
Copies may be made only for those using products.
and all affiliates. All rights reserved.
Huajia Surface Techology
Revision Date: 2 019-06-01
en/CNPage2-8
SAFETY DATA SHEET
Compliant with GB/T16483 and GB/T17519
Skin or eye contact
Dust generated from this product may cause irritation of the eyes. Repeated or prolonged contact may cause skin irritation with
discomfort and dermatitis. Skin contact my cause skin sensitization.
Protection of first-aiders
No information available.
Notes to physician
No data available on the product. See section 3 and 11 for hazardous ingredients found in the product.
Section 5 - Fire-fighting Measures
Suitable extinguishing media
Water sprayDry chemical
Extinguishing media which shall not be used for safety reasons
High volume water jet
Specific hazards
Do not allow run-off from fire fighting to enter drains or water courses. Always keep in containers of same material as the
original one.
Specific fire fighting methods and special protective equipment for fire fighters
Wear as appropriate: Full protective flameproof clothing. Wear self contained breathing apparatus for fire fighting if necessary.
Section 6 - Leak Emergency Treatment
Protective measures, devices and emergency treatment procedure for workers
Keep away from sources of ignition. Air out the room. Do not breathe dust. Comply with safety directives (see chapters 7 and 8).
Environmental protection measures
Do not let product enter drains. Notify the respective authorities in accordance with local law in the case of contamination of
rivers, lakes or waste water systems.
Collection of leaking materials, removal method and materials used for disposal
Contain and collect spillage with a electrically protected vacuum cleaner or by wet brushing and place in container for disposal
according to local regulations. Do not use a dry brush as dust clouds or static can be created! The contaminated area should
be cleaned up immediately with a suitable decontaminant. One possible (flammable) decontaminant comprises (by volume):
water (45 parts), ethanol or isopropyl alcohol (50 parts), concentrated (d : 0,880) ammonia solution (5 parts). A non-flammable
alternative is sodium carbonate (5 parts), water (95 parts). Add the same decontaminant to the remnants and let stand for
several days until no further reaction in non-sealed container. Once this stage is reached, close container and dispose according
to local regulations (see section 13).
Prevention of secondary hazards
No information available.
Section 7 - Operation Handling and Storage
Operation Handling
Persons with a histor y of skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be
employed in any process in which this mixture is being used. It is recommended that advice is taken from a competent
occupational health practitioner on the assessment of employees with skin or respiratory complaints before the individual is
exposed to the uncured product.
Technical measures/Precautions
Operators should wear antistatic footwear and clothing. Keep away from open flames, hot surfaces and sources of ignition.
Precautions for safe handling
Precautions should be taken to prevent the formation of dusts in concentrations above flammable, explosive or occupational
exposure limits. Preparation may charge electrostatically: always use grounded leads when transferring from one container to
another. Electrical equipment and lighting should be protected to appropriate standards to prevent dust coming into contact with
hot surfaces, sparks or other ignition sources.
Huangshan Huajia Surface Technology Co.,Ltd
Copies may be made only for those using products.
and all affiliates. All rights reserved.
Huajia Surface Techology
Revision Date: 2 019-06-01
en/CNPage3-8
SAFETY DATA SHEET
Compliant with GB/T16483 and GB/T17519
Hygiene measures
Smoking, eating and drinking should be prohibited in the application area.
Storage
Suitable storage conditions
Observe label precautions. Store between 20 and 35◦C in a dry, well ventilated place away from sources of heat, ignition and
direct sunlight. No smoking. Prevent unauthorized access. Containers which are opened must be carefully resealed and kept
upright to prevent leakage.
Suitable container and packaging materials for safe storage
Always keep in containers made of the same material as the supply container.
Section 8 - Exposure Control and Personal Protection
Persons with a histor y of skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be
employed in any process in which this mixture is being used.
Engineering controls
Provide adequate ventilation. Air-fed protective respiratory equipment must be worn by spray operator even when good
ventilation is provided.
Occupational Exposure Limits
Chemical
Name
TITANIUM DIOXIDE
PARAFFIN WAX
BARIUM SULFATE
ALUMINUM OXIDE
CARBON BLACK
AMORPHOUS SILICA
HYDROCARBON WAX
POLYETHYLENE
MICA
ALUMINUM
QUARTZ-CRYSTALLINE SILICA
Occupational Exposure
Limits
8 mg/m3 TWA
2 mg/m3 TWA
5 mg/m3 TWA
4 mg/m3 TWA
4 mg/m3 TWA
5 mg/m3 TWA
2 mg/m3 TWA
5 mg/m3 TWA
1.5 mg/m3 TWA
3 mg/m3 TWA
0.7 mg/m3 TWA
Regulation
GBZ2.1 Occupational Exposure Limits for Hazardous Agents in the Workplace:Chemical Hazardous Agents
GBZ2.1 Occupational Exposure Limits for Hazardous Agents in the Workplace:Chemical Hazardous Agents
GBZ2.1 Occupational Exposure Limits for Hazardous Agents in the Workplace:Chemical Hazardous Agents
GBZ2.1 Occupational Exposure Limits for Hazardous Agents in the Workplace:Chemical Hazardous Agents
GBZ2.1 Occupational Exposure Limits for Hazardous Agents in the Workplace:Chemical Hazardous Agents
GBZ2.1 Occupational Exposure Limits for Hazardous Agents in the Workplace:Chemical Hazardous Agents
GBZ2.1 Occupational Exposure Limits for Hazardous Agents in the Workplace:Chemical Hazardous Agents
GBZ2.1 Occupational Exposure Limits for Hazardous Agents in the Workplace:Chemical Hazardous Agents
GBZ2.1 Occupational Exposure Limits for Hazardous Agents in the Workplace:Chemical Hazardous Agents
GBZ2.1 Occupational Exposure Limits for Hazardous Agents in the Workplace:Chemical Hazardous Agents
GBZ2.1 Occupational Exposure Limits for Hazardous Agents in the Workplace:Chemical Hazardous Agents
Biological occupational exposure limits
No information available.
Personal protective equipment
Personal protective equipment should be worn to prevent contact with eyes, skin or clothing.
Respiratory protection
If dust formation exceeds the air concentration limits, then a respiratory protection device approved for this purpose must be
worn.
Hand protection
The breakthrough time of gloves is unknown for the product itself. The glove material given is recommended on basis of the
substances in the preparation.
Glove material Glove thickness Break through time
Nitrile rubber 0.33 mm > 240 min
The protective glove should be checked in each case for their work specific suitability (e.g. mechanical stability, product
compatibility, and anti-static properties). After contamination, the glove has to be changed. Care should be taken when
working with sharp edged articles as these can easily damage the gloves and make them ineffective. The instructions and
information provided by the glove supplier on use, storage, maintenance and replacement must be followed. Damaged gloves or
those showing signs of wear should be replaced immediately. Preventive skin protection such as skin protective cream is
recommended. Work tasks should be arranged in such a way that gloves do not have to be worn continuously.
Huangshan Huajia Surface Technology Co.,Ltd
Copies may be made only for those using products.
and all affiliates. All rights reserved.
Huajia Surface Techology
Revision Date: 2 019-06-01
en/CNPage4-8
SAFETY DATA SHEET
Compliant with GB/T16483 and GB/T17519
Eye protection
Eye protection (to EN 166/170) designed to protect against exposure to dusts should be worn when there is a likelihood of
exposure.
Skin protection
Wear suitable protective clothing. Care should be taken in the selection of protective clothing.
Hygiene measures
Wash skin thoroughly with soap and water or use recognized skin cleanser. Do not use organic solvents!
Section 9 - Physical and Chemical Properties
Appearance (Physical state, form, colour, etc.)
Physical state solid
Form
Colour
Odour
Odour Threshold no data available
pH (specifed concentration)
Melting point/freezing point
Solidification point Not applicable.
Boiling point, initial boiling point and boiling range
Boiling point/boiling range Not applicable.
solid
Diverse
not applicable
Flash point Not applicable.
Decomposition temperature
Autoignition temperature Not applicable. DIN 51794
Explosion limits
Lower explosion limit
20-70 g/m
3
Vapour pressure 0.0 hPa
Vapour density
Density
no data available
1.0-2.0
g/cm
3
DIN 53217/ISO 2811
Solubility(ies)
Water solubility partly miscible
Partition coefficient: n-octanol/water
Evaporation rate
no data available
not applicable
Does not sustain combustion.
Section 10 - Stability and Reactivity
Stability
Stable
Possible hazardous reactions under specific conditions
As stated above, the product is stable. No fur ther reactions are known.
Conditions to avoid
Stable under recommended storage and handling conditions (see section 7).
Materials to avoid
Keep away from oxidising agents and strongly acid or alkaline materials. Amines and alcohols cause exothermic reactions.
Mixture reacts slowly with water resulting in evolution of CO2. Evolution of CO2 in closed containers causes overpressure and
produces a risk of bursting.
Hazardous decomposition products
When exposed to high temperatures may produce hazardous decomposition products such as carbon monoxide and dioxide,
smoke, oxides of nitrogen as well as hydrogen cyanide, amines, alcohols and water.
Section 11 - Toxicological Information
Huangshan Huajia Surface Technology Co.,Ltd
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Huajia Surface Techology
Revision Date: 2 019-06-01
en/CNPage5-8
SAFETY DATA SHEET
Compliant with GB/T16483 and GB/T17519
Information on likely routes of exposure
Inhalation
Exposure to isocyanates may cause respiratory sensitization. This effect may be permanent. Symptoms include an asthma-like
reaction with shortness of breath, wheezing, cough or permanent lung sensitization. This effect may be delayed for several
hours after exposure. Repeated overexposure to isocyanates may cause a decrease in lung function, which may be permanent.
Individuals with lung or breathing problems or prior reactions to isocyanates must not be exposed to vapors or spray mist of this
product.
Ingestion
May result in gastrointestinal distress.
Skin or eye contact
Dust generated from this product may cause irritation of the eyes. Repeated or prolonged contact may cause skin irritation with
discomfort and dermatitis.
Delayed and immediate effects and also chronic effects from short and long term exposure:
Acute oral toxicity
Acute inhalation toxicity
Skin corrosion/irritation
BISMUTH VANADIUM OXIDE
IRON OXIDE
PHTHALOCYANINE BLUE PIGMENT
BISPHENOL A/EPICHLOROHYDRIN POLYMER
CALCIUM CARBONATE
Serious eye damage/eye irritation
1,3,5-TRIGLYCIDYL ISOCYANURATE
BISMUTH VANADIUM OXIDE
TITANIUM DIOXIDE (RUTILE)
IRON OXIDE
ZIRCONIUM OXIDE
C.I. PIGMENT YELLOW 83
BISPHENOL A/EPICHLOROHYDRIN POLYMER
HYDROCARBON WAX
CALCIUM CARBONATE
Skin sensitization
BISPHENOL A/EPICHLOROHYDRIN POLYMER
Germ cell mutagenicity
1,3,5- triglycidyl isocyanurate Category 3
Additive1
Category 4
1,3,5- triglycidyl isocyanurate Category 3
Category 2
Category 2
Category 3
Category 2
Category 2
Category 1
Category 2B
Category 2B
Category 1
Category 2A
Category 2A
Category 2
Category 2B
Category 2A
1,3,5- triglycidyl isocyanurate Category 1
Category 1
1,3,5- triglycidyl isocyanurate Category 1B
Specific target organ toxicity - repeated exposure
No data available.
Numerical measures of toxicity (acute toxicity estimation (ATE),etc. )
No information available.
Symptoms related to the physical, chemical and toxicological characteristics
Based on the properties of the isocyanate components and considering toxicological data on similar products, the following
applies: This formulation may cause acute irritation and/or sensitization of the respiratory system leading to an asthmatic
condition, wheeziness and a tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms when
exposed to atmospheric concentrations well below the OEL. Repeated exposure may lead to permanent respiratory disability.
Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of
consciousness. Through skin resorbtion, solvents can cause some of the effects described here. Repeated or prolonged contact
with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption
through the skin. The liquid splashed in the eyes may cause irritation and reversible damage.
Huangshan Huajia Surface Technology Co.,Ltd
Copies may be made only for those using products.
and all affiliates. All rights reserved.
Huajia Surface Techology
Revision Date: 2 019-06-01
en/CNPage6-8
SAFETY DATA SHEET
Compliant with GB/T16483 and GB/T17519
Section 12 - Ecological Information
Product does not contain any environmentally hazardous substances and product is not classified per GHS
Ecotoxicity effects
There are no data available on the product itself. The product should not be allowed to enter drains or watercourses. The data in
this section is consistent with data from chemical safety reports available at the date of revision.
Persistence and degradation
No information available.
Bioaccumulation
No information available.
Mobility in soil
No information available.
Other adverse effects
No information available.
Section 13 - Waste Disposal
Waste disposal methods
Dispose of in accordance with local regulations.
Disposal considerations
A disposal process that converts the waste into energy is recommended. Can be landfilled or incinerated, when in compliance
with local regulations.
Used package
Empty containers should be taken to an approved waste handling site for recycling or disposal. If recycling is not practicable,
dispose of in compliance with local regulations.
Section 14 - Transport Information
Not classified as dangerous in the meaning of transport regulations.
Matters needing attention for transportation
Confirm that there is no breakage, corrosion, or leakage from the container before shipping. Be sure to prevent damage to
cargo by loading so as to avoid falling, dropping, or collapse. Ship in appropriate containers with denotation of the content in
accordance with the relevant statutes and rules.
Section 15 - Regulatory Information
Regulations on the Control over the Safety of Dangerous Chemicals
Production Safety Law of the People’s Republic of China
Law of the People’s Republic of China on Prevention and Treatment of Occupational Disease
Environmental Protection Law of the People’s Republic of China
Law of the People’s Republic of China on the Prevention and Control of Atmospheric Pollution
Marine Environment Protection Law of the People’s Republic of China
Fire Protection Law of the People’s Republic of China
Law of the People’s Republic of China on the Prevention and Control of Environmental Pollution by Solid Wastes
Occupational exposure limits for hazardous agents in the workplace Part 1 Chemical hazardous agents (GBZ2.1)
Occupational exposure limits for hazardous agents in the workplace Part 2 Physical agents (GBZ2.2)
General rule for classification and hazard communication of chemicals (GB13690)
National waste list
Section 16 - Other Information
Huangshan Huajia Surface Technology Co.,Ltd
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Huajia Surface Techology
Revision Date: 2 019-06-01
en/CNPage7-8
SAFETY DATA SHEET
Compliant with GB/T16483 and GB/T17519
Sources of key data used to compile the Safety Data Sheet
Department
Data Review Department
Huangshan Huajia Surface Technology Co.,Ltd.
No 109,Yongjia Avenue,Huizhou District,Huangshan,Anhui,PRC
Product Safety
Revision Note
Version Changes
3.0
Revision Date: 2019-06-01
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of
its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The above information relates only to the
specific material(s) designated herein and may not be valid for such material(s) used in combination with any other materials or
in any process or if the material is altered or processed, unless specified in the text.
Huangshan Huajia Surface Technology Co.,Ltd
Copies may be made only for those using products.
and all affiliates. All rights reserved.
Huajia Surface Techology
Revision Date: 2 019-06-01
en/CNPage8-8
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