
Material Safety Data Sheet 
According to EU Regulation No. 1907/2006 
Issued on: 14 October 2015 
1. Identification of the substance/preparation and of the company 
1.1 Trade name: 
1.2 Chemical name: 
1.3 Typical use of the material: 
1.4 Identification of the company: 
MagicFil™ Thermo PLA 
PolyLactic Acid based polymer blend 
Monofilament for FFF/FDM technology based 3D printing 
Formfutura VOF 
Groenestraat 215 
6531 HH Nijmegen 
The Netherlands 
Phone: +31 (0)85 002 0881 
Emergency phone number: +31 (0)30 274 8888 
2. Identification of the substance/preparation and of the company 
2.1 Risk advise to man and the environment: 
2.2 Classification of the substance or mixture: 
2.3 Special advice on hazards: 
No risk exists to the health of users if the product is 
handled and processed properly. 
Not classified as dangerous according to Directive 
67/548/EEC 
Danger of burns while handling the heated or molten 
product. 
3. Composition / information on ingredients 
3.1 Chemical nature: 
3.2 CAS number: 
3.3 Additional information: 
Blend of PLA based polymers enhanced for 3D printing 
9051-89-2 
No harmful substances used. 
4.1 If inhaled: 
4.2 On skin contact: 
4.3 On contact with eyes: 
4.4 On ingestion: 
4.5 Note to the physician: 
After inhalation of decomposition products, gases or dust, bring the affected 
person to a source of fresh air and keep calm. Contact a physician in case of 
discomfort. 
In case of contact with melted material, immediately cool the skin with plenty of 
cold running water. Removal of adhering to skin polymer, or burns caused by 
molten material require hospital treatment. 
In case of contact with eyes, rinse open eyes thoroughly with water. If irritation 
develops, seek immediate medical attention. 
No effects known. Rinse mouth with water and then drink plenty of water. Seek 
medical attention if difficulties or discomfort occur. 
Treat symptomatically 
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Material Safety Data Sheet 
According to EU Regulation No. 1907/2006 
Issued on: 14 October 2015 
5.1 Suitable extinguishing media: 
5.2 Specific hazards: 
5.3 Special protective equipment: 
5.4 Further information: 
Dry extinguishing media, water, or CO2,. 
Carbon monoxide (CO), carbon dioxide (CO2), and hydrocarbons 
during incomplete combustion. The substances mentioned can be 
releases at highly elevated temperatures and in case of fire. 
Full protective clothing and self-contained breathing apparatus. 
Fine dust dispersed in air may ignite. Risk of ignition followed by flame 
propagation or secondary explosions shall be prevented by avoiding 
accumulation of dust. 
Dispose of fire debris and contaminated extinguishing water in 
accordance with official regulations. 
6. Accidental Release Measures 
6.1 Personal precautions: 
6.2 Environmental precautions: 
6.3 Methods for cleaning up: 
Use personal protective equipment/clothing (see Section 8). Avoid eye 
contact and dust formation and remove all sources of ignition. Sweep up 
to prevent slipping hazard. 
Prevent entry into drainage systems, or surface water. 
Sweep/shovel into suitable container for disposal. 
Avoid raising dust and ensure adequate ventilation. 
7.1 Handling: 
7.2 Storage: 
7.3 Precautions: 
7.4 Specific end use(s): 
Handle in a well ventilated area. Install local exhaust at 3D printers area is 
recommended when many printers are operated at once. Avoid contact with 
heated or molten product. Use personal protective equipment (see Section 8). 
Avoid dust formation and electrostatic charge. Keep away from fire ignition 
sources. 
Protect from water, moisture and direct sunlight. Store material in dry rooms and 
keep material in closed packaging/container with desiccant when not in use. 
Store at ambient temperatures. Avoid all sources of ignition. 
No special precautions required. 
Primarily used for 3D printing. 
8. Exposure controls / personal protection 
8.1 Occupational exposure limits: 
8.2 Exposure controls: 
8.3 Personal protective equipment 
8.3.1  Hand protection: 
8.3.2  Eye protection: 
8.3.3  Skin and body protection: 
Given suitable ventilation it can be that the threshold limits will not 
be reached. 
Provide appropriate exhaust ventilation at places where dust is 
formed. Avoid electrostatic charge by use of grounding cables. 
Wear heat protection gloves, preferably cotton or leather, when 
handling hot molten product. 
Wear protective glasses, preferable with side-shields. 
Wear (protective) clothing to avoid direct exposure of skin to hot 
molten product when handling. 
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Material Safety Data Sheet 
According to EU Regulation No. 1907/2006 
Issued on: 14 October 2015 
8.3.4  Safety and hygiene measures: 
8.4 Environmental exposure controls: 
Avoid contact of hot molten material to skin. Avoid inhalation of 
dust, mists and vapours. Eye wash fountains and safety showers 
must be easily accessible. Handle in accordance with good 
industrial hygiene and safety practice. No eating or drinking 
during working. 
Prevent entry into drainage systems, or surface water. 
9. Physical and chemical properties 
9.1 Form: 
9.2 Colour: 
9.3 Odour: 
9.4 Melting point/range: 
9.5 Auto-ignition temperature: 
9.6 Explosions limit: 
9.7 Density: 
9.8 Solubility in water: 
Granules 
Natural 
Almost odourless 
150 °C - 170 °C  
Not self-igniting / Not highly flammable 
Not specified 
1.24 g/cc 
Insoluble 
10. Stability and reactivity 
10.1 Stability: 
10.2 Conditions to avoid: 
10.3 Substances to avoid: 
10.4 Hazardous reactions: 
10.4.1 Hazardous decomposition products: 
Product is stable at recommended storage conditions. 
Avoid extreme heat and all sources of ignition. Thermal 
decomposition > 240°C. 
Strong oxidizing agents. 
The product is chemically stable. 
Carbon monoxide (CO), carbon dioxide (CO2), and 
hydrocarbons. 
11. Toxicological information 
11.1 Information on toxicological effects: 
11.1.1 Acute toxicity 
Inhalation: 
Ingestion: 
Skin contact: 
Eye contact: 
11.1.2 Irritation 
Skin: 
Eye: 
11.1.3 Sensitization: 
11.1.4 Repeated dose toxicity: 
11.1.5 Carcinogenicity: 
11.1.6 Mutagenicity: 
11.1.7 Toxicity for reproduction: 
11.2 Other information: 
Toxicological data has not been determined for this product. 
Information is based on similar products. 
No data available, but not expected. 
After ingestion stomach pain or nausea are possible. 
No data available, but not expected. 
No data available, but not expected. 
Dust can cause irritation of eyes, respiratory organs and skin. 
Dust can cause irritation of eyes, respiratory organs and skin. 
Not expected to be a skin sensitizer. 
Not expected to cause toxic effects. 
No data available, but not expected. 
No data available, but not expected. 
No data available, but not expected. 
Based on our state of knowledge and experience no injurious 
health effects are expected if product is properly handled for the 
designated use. 
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Material Safety Data Sheet 
According to EU Regulation No. 1907/2006 
Issued on: 14 October 2015 
12. Ecological information 
12.1 Information on eco-toxicity: 
12.1.1 Ecological toxicity effects: 
12.2 Mobility in soil: 
12.3 Persistence and degradability: 
12.4 Bioaccumulation potential: 
No ecological toxicity data has been generated for this product. There 
are no test results available and information is based on similar 
products. 
No negative ecological effects are known at the present state of 
knowledge. 
The product is essentially insoluble in water.  
The product has low mobility in soil. 
Product is biodegradable. 
The product will not be readily bioavailable due to its consistency and 
insolubility in water. 
13. Disposal considerations 
13.1 Product: 
13.2 Packaging: 
Generation of waste should be minimized, check possibility for recycling. Waste product 
can be incinerated or dumped together with domestic waste in compliance with local 
authority requirements. 
Packaging material has to be emptied completely and disposed in accordance with the 
regulations. Packaging can be recycled if not contaminated. 
14. Transport information 
14.1 International Air Transportation Association Classification (IATA): 
14.2 International Maritime Organization (IMDG): 
14.3 14.3 UN, IMO, ADR/RID, ICAO Code: 
This product is not classified as 
hazardous. 
This product is not classified as 
hazardous. 
This product is not classified as 
hazardous. 
15. Regulatory information 
15.1 EU / National regulations: 
This product does not require a hazard warning label in accordance with 
EC Directives. 
Company name: 
Additional data: 
Disclaimer: 
Formfutura VOF 
In addition to the information given in this Material Safety Data Sheet (MSDS) we refer to 
the products specific Technical Data Sheet (TDS). 
The information given in the Material Safety Data Sheet only applies to the described 
product in connection with its appropriate use. All information is based on the latest state 
of our knowledge. In particular, it describes our product under the aspect of possible 
hazards and pertaining safety measures. The information does not constitute any 
guarantee of specific product and/or quality properties. The information given in this 
Material Safety Data Sheet is not required according to article 31 and Annex II of 
Regulation (EC) No.1907/2006. It merely serves the purpose of providing sufficient 
information on a voluntary basis to ensure safe use of the compound/product. There is no 
obligation on the part of Formfutura to revise this document. 
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