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Safety Data Sheet
acc. to according to GHS Rev. 8 2019 and OSHA HCS
Printing date 12/14/2022 Reviewed on 12/14/2022
1 Identification
Product identifier
Trade name:
Article number:
Application of the substance / the mixture
Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Fronius International GmbH
Fronius Straße 5
A-4642 Sattledt
T: +43 7242 241 0
Information department:
welding.techsupport@fronius.com
msds.techsupport@fronius.com
Emergency telephone number:
+43 7242 241 0
Available:
Mo - Th: 08:00 - 16:00 h (CET)
Fr: 08:00 - 12:00 h (CET)
Please contact your regional poison center or emergency call!
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42,0510,0390
Auxiliary for electrolytic cleaning and polishing.
2 Hazard(s) identification
Classification of the substance or mixture
Skin Irritation 2 H315 Causes skin irritation.
Eye Irritation 2A H319 Causes serious eye irritation.
Label elements
GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS07
Signal word
Hazard statements
Causes skin irritation.
Causes serious eye irritation.
Precautionary statements
Wash thoroughly after handling.
Warning
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Safety Data Sheet
acc. to according to GHS Rev. 8 2019 and OSHA HCS
Printing date 12/14/2022 Reviewed on 12/14/2022
Trade name:
Wear eye protection / face protection.
If on skin: Wash with plenty of water.
Specific treatment (see on this label).
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
If skin irritation occurs: Get medical advice/attention.
Take off contaminated clothing and wash it before reuse.
If eye irritation persists: Get medical advice/attention.
Classification system:
NFPA ratings (scale 0 - 4)
2
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
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1
0
2
1
0
(Contd. of page 1)
Health = 2
Fire = 1
Reactivity = 0
Health = 2
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:
The mixture does not contain PBT substances ≥ 0,1 %.
vPvB:
* 3
Composition/information on ingredients
Chemical characterization: Mixtures
Description:
Dangerous components:
[% (w/w)]
CAS: 77-92-9 Citric acid
CAS: 1341-49-7 ammonium bifluoride
The mixture does not contain vPvB substances ≥ 0,1 %.
Mixture of the substances listed below with nonhazardous additions.
Eye Irritation 2A, H319; Specific Target Organ Toxicity - Single Exposure
3, H335
Acute Toxicity - Oral 3, H301
Skin Corrosion 1B, H314
Specific concentration limits: Skin Corr. 1B; H314: C ≥ 1 %
10 - < 20%
< 0.25%
Skin Irrit. 2; H315: 0.1 % ≤ C < 1 %
Eye Irrit. 2; H319: 0.1 % ≤ C < 1 %
(Contd. on page 3)
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Safety Data Sheet
acc. to according to GHS Rev. 8 2019 and OSHA HCS
Printing date 12/14/2022 Reviewed on 12/14/2022
Trade name:
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(Contd. of page 2)
4 First-aid measures
Description of first aid measures
General information:
In case of discomfort or doubt, seek medical advice.
If unconscious, use a stable lateral position and do not administer anything through mouth.
After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms
persist.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Take off contaminated clothing and wash it before reuse.
Seek medical treatment.
After eye contact:
Rinse opened eye for several minutes under running water.
Remove contact lenses, if present and easy to do. Continue rinsing.
Seek medical treatment.
After swallowing:
Rinse mouth.
Do NOT induce vomiting.
Call a doctor immediately.
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Indication of any immediate medical attention and special treatment needed
Depending on the condition of the patients, the doctor must assess the symptoms and the overall general
condition.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
For safety reasons unsuitable extinguishing agents:
Water with full jet
Special hazards arising from the substance or mixture
In case of fire, the following can be released:
COx, NO
x
Hydrogen fluoride (HF)
Ammonia
Advice for firefighters
Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
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Safety Data Sheet
acc. to according to GHS Rev. 8 2019 and OSHA HCS
Printing date 12/14/2022 Reviewed on 12/14/2022
Trade name:
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(Contd. of page 3)
Additional information
Collect contaminated fire fighting water separately. It must not enter the sewage system.
6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Restricted access to the affected area until cleaning work is completed.
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Avoid contact with skin and eyes.
Do not breathe vapour/spray.
Environmental precautions:
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
Dispose of the collected material according to regulations.
Protective Action Criteria for Chemicals
PAC-1:
CAS: 1341-49-7 ammonium bifluoride 11 mg/m³
PAC-2:
CAS: 1341-49-7 ammonium bifluoride 130 mg/m³
PAC-3:
CAS: 1341-49-7 ammonium bifluoride 750 mg/m³
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Keep receptacles tightly sealed.
Avoid contact with skin and eyes.
Prevent formation of aerosols.
Avoid breathing mist/vapours/spray.
Use personal protective equipment as required.
Observe protective measures and safety instructions.
Information about protection against explosions and fires:
No special measures required.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:
Store in dry conditions.
Store in a cool location.
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