FORMLABS FORM KH WA 1L F2 Datasheet

Castable Wax Resin

Photoreactive Resin for Form 2

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SAFETY DATA SHEET

Prepared: 07/05/2018

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GHS Format

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Castable wax

Not available.

Liquid.

GHS product identifier

Other means of identification

Product type

Emergency telephone
number (with hours of
operation)

Section 1. Identification

:::

:

Supplier's details

:

Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Not available.

:

Product code

:

Not available.

North America call [phone]
Worldwide Intl. call +01 813 248 0585
(24/7)

Formlabs, Inc.
35 Medford Street, Suite #201
Somerville, MA
USA
Email: [e-mail]

Section 2. Hazards identification

SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B
SKIN SENSITIZATION - Category 1

Classification of the
substance or mixture

:

Signal word

:

Warning

Hazard statements

:

H320 - Causes eye irritation.
H317 - May cause an allergic skin reaction.

Hazard pictograms

:

Precautionary statements

Prevention

:

P280 - Wear protective gloves.
P261 - Avoid breathing vapor.
P264 - Wash hands thoroughly after handling.
P272 (OSHA) - Contaminated work clothing must not be allowed out of the workplace.

Response

:

P302 + P352 + P363 - IF ON SKIN: Wash with plenty of soap and water. Wash
contaminated clothing before reuse.
P333 + P313 - If skin irritation or rash occurs: Get medical attention.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical attention.

Storage

:

Not applicable.

Disposal

:

P501 - Dispose of contents and container in accordance with all local, regional, national
and international regulations.

GHS label elements

Hazards not otherwise
classified

:

None known.

OSHA/HCS status

:

This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).

1/10

Conforms to HCS 2012- United States

Section 3. Composition/information on ingredients

Trade secret 1

Proprietary

-

Trade secret 3

Proprietary

-

Trade secret 2

Proprietary

-

Ingredient name

CAS number
%

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as
hazardous to health or the environment and hence require reporting in this section.

Other means of identification

:

Not available.

Substance/mixture

:

Occupational exposure limits, if available, are listed in Section 8.

Mixture

The exact percentage (concentration) in the composition has been withheld as a trade secret in accordance with
paragraph (i) of §1910.1200.

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention if adverse health
effects persist or are severe. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20
minutes. If irritation persists, get medical attention.

Wash with plenty of soap and water. Wash contaminated clothing thoroughly with
water before removing it, or wear gloves. Continue to rinse for at least 20 minutes. Get
medical attention. In the event of any complaints or symptoms, avoid further exposure.
Wash clothing before reuse. Clean shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse
health effects persist or are severe. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen tight clothing such as
a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to be kept under medical
surveillance for 48 hours.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

:

:

:

:

Description of necessary first aid measures

Most important symptoms/effects, acute and delayed

Inhalation

:

No known significant effects or critical hazards.

No known significant effects or critical hazards.

:

Ingestion

Skin contact

:

May cause an allergic skin reaction.

Causes eye irritation.

:

Eye contact

Over-exposure signs/symptoms

Potential acute health effects

2/10

Conforms to HCS 2012- United States

Section 4. First aid measures

Protection of first-aiders

:

No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.

Notes to physician

:

In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.

Specific treatments

:

No specific treatment.

Skin contact

Ingestion

Inhalation

No known significant effects or critical hazards.

No known significant effects or critical hazards.

Adverse symptoms may include the following:
irritation
redness

:

:

:

Eye contact

:

Adverse symptoms may include the following:
pain or irritation
watering
redness

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.

Hazardous thermal
decomposition products

Specific hazards arising from
the chemical

Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
phosphorus oxides

In a fire or if heated, a pressure increase will occur and the container may burst.

Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment
for fire-fighters

Use an extinguishing agent suitable for the surrounding fire.

Extinguishing media

:::

None known.
Suitable extinguishing media

:

Unsuitable extinguishing
media

:

Special protective actions for
fire-fighters

:

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

:

No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.

For non-emergency
personnel

3/10

Conforms to HCS 2012- United States

Section 6. Accidental release measures

Environmental precautions

:

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

For emergency responders

:

If specialized clothing is required to deal with the spillage, take note of any information
in Section 8 on suitable and unsuitable materials. See also the information in "For non­emergency personnel".

Small spill

Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see Section
1 for emergency contact information and Section 13 for waste disposal.

Large spill

:

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material
and place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.

:

Section 7. Handling and storage

Advice on general
occupational hygiene

Conditions for safe storage,
including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. See also Section 8 for additional information on hygiene
measures.

Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Keep container tightly closed and sealed until
ready for use. Containers that have been opened must be carefully resealed and kept
upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. See Section 10 for incompatible
materials before handling or use.

:

:

Protective measures

Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid
breathing vapor or mist. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Empty containers retain
product residue and can be hazardous. Do not reuse container.

:

Precautions for safe handling

4/10

Conforms to HCS 2012- United States

Section 8. Exposure controls/personal protection

Trade secret 1

None.

Trade secret 3

AIHA WEEL (United States, 10/2011).
TWA: 10 mg/m³ 8 hours. Form: Aerosol.

Trade secret 2

None.

Ingredient name

Exposure limits

Hand protection

Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.

Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.

Eye/face protection

Respiratory protection

:

:

:

Body protection

Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.

:

Environmental exposure
controls

:

Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation.

Appropriate engineering
controls

:

Good general ventilation should be sufficient to control worker exposure to airborne
contaminants.

Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.

Hygiene measures

:

Individual protection measures

Skin protection

Other skin protection

:

Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.

Section 9. Physical and chemical properties

Physical state

Melting point

Liquid.

Not available.

Light / Characteristic / Acrylate.

Odor

pH

Burgundy.

Color

Not available.

Not available.

Odor threshold

:

:

:

:

:

:

Appearance

5/10

Conforms to HCS 2012- United States

Control parameters

Occupational exposure limits

Section 9. Physical and chemical properties

Vapor pressure

Relative density

Vapor density

Solubility

1.11 g/cm

3

Not available.

Not available.

Very slightly soluble in the following materials: cold water and hot water. Soluble in
organic solvents.

Evaporation rate

Not available.

Auto-ignition temperature

Flash point

Not available.

Closed cup: >100°C (>212°F)

Not available.
Viscosity

Dynamic (room temperature): 1580 mPa·s (1580 cP) @ 25°C

Partition coefficient: n-octanol/
water

:

:::

:

:
:

:

:

Boiling point

:

>100°C (>212°F)

Flammability (solid, gas)

:

Not available.

Lower and upper explosive
(flammable) limits

:

Not available.
Decomposition temperature

:

Not available.

Flow time (ISO 2431)

:

Not available.

Section 10. Stability and reactivity

Hazardous decomposition
products

Conditions to avoid

No specific data.

Under normal conditions of storage and use, hazardous decomposition products should
not be produced.

The product is stable.

Chemical stability

Reactive or incompatible with the following materials: oxidizing materials.

:

:

:

Incompatible materials

:

Possibility of hazardous
reactions

:

Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity

:

No specific test data related to reactivity available for this product or its ingredients.

Section 11. Toxicological information

Acute toxicity

Mutagenicity

Irritation/Corrosion

Product/ingredient name

Result

Score

Exposure

Observation

Sensitization

Species

Information on toxicological effects

There is no data available.

Trade secret 3

Eyes - Mild irritant

Rabbit

-

24 hours 500 mg

-

Eyes - Mild irritant

Rabbit

-

500 mg

-

Skin - Mild irritant

Rabbit

-

24 hours 500 mg

-

Skin - Mild irritant

Rabbit

-

500 mg

-

There is no data available.

6/10

Conforms to HCS 2012- United States

Section 11. Toxicological information

Carcinogenicity

Teratogenicity

Reproductive toxicity

Information on the likely
routes of exposure

Inhalation

:

No known significant effects or critical hazards.

No known significant effects or critical hazards.

:

Ingestion

Skin contact

:

May cause an allergic skin reaction.

Causes eye irritation.

:

Eye contact

Once sensitized, a severe allergic reaction may occur when subsequently exposed to
very low levels.

General

:

No known significant effects or critical hazards.

Carcinogenicity

:

No known significant effects or critical hazards.

Mutagenicity

:

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation

No known significant effects or critical hazards.

No known significant effects or critical hazards.

Adverse symptoms may include the following:
irritation
redness

:

:

:

Eye contact

:

Adverse symptoms may include the following:
pain or irritation
watering
redness

Potential chronic health effects

Delayed and immediate effects and also chronic effects from short and long term exposure

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Aspiration hazard

:

Dermal contact. Eye contact. Inhalation. Ingestion.
Potential acute health effects

Potential immediate effects

:

No known significant effects or critical hazards.

Short term exposure

Potential delayed effects

:

No known significant effects or critical hazards.

Potential immediate effects

:

No known significant effects or critical hazards.

Long term exposure

Potential delayed effects

:

No known significant effects or critical hazards.

There is no data available.

There is no data available.

There is no data available.

There is no data available.

There is no data available.

There is no data available.

There is no data available.

7/10

Conforms to HCS 2012- United States

Section 11. Toxicological information

No known significant effects or critical hazards.

Teratogenicity

:

Developmental effects

:

No known significant effects or critical hazards.

Fertility effects

:

No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates

There is no data available.

Section 12. Ecological information

LogP

ow

BCF

Potential

Bioaccumulative potential

Other adverse effects

:

No known significant effects or critical hazards.

Product/ingredient name

Toxicity

Product/ingredient name

Species

Result

Exposure

Persistence and degradability

Soil/water partition
coefficient (KOC)

:

Not available.
Mobility in soil

Trade secret 3

Acute LC50 >1000000 µg/L Fresh water

Fish - Salmo salar - Parr

96 hours

There is no data available.

Trade secret 1

3-low

Trade secret 3

-

3.2

low

Section 13. Disposal considerations

The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority
requirements. Dispose of surplus and non-recyclable products via a licensed waste
disposal contractor. Waste should not be disposed of untreated to the sewer unless
fully compliant with the requirements of all authorities with jurisdiction. Waste
packaging should be recycled. Incineration or landfill should only be considered when
recycling is not feasible. This material and its container must be disposed of in a safe
way. Care should be taken when handling empty containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.

:

Disposal methods

8/10

Conforms to HCS 2012- United States

Section 14. Transport information

-

-

-

-

-

-

-

Not regulated.

-

-

Not regulated.

Not regulated.

DOT Classification

IMDG

IATA

UN number

UN proper
shipping name

Transport hazard
class(es)

Packing group

Environmental
hazards

Special precautions for user
No.

No.

No.

Transport within user’s premises: always transport in closed containers that are upright
and secure. Ensure that persons transporting the product know what to do in the event
of an accident or spillage.

:

AERG

:

Not applicable

Section 15. Regulatory information

U.S. Federal regulations

:

Clean Air Act Section 112(b)
Hazardous Air Pollutants
(HAPs)

:

Not listed
Clean Air Act Section 602

Class I Substances

:

Not listed

Clean Air Act Section 602
Class II Substances

:

Not listed

DEA List I Chemicals
(Precursor Chemicals)

:

Not listed

DEA List II Chemicals
(Essential Chemicals)

:

Not listed
TSCA 8(a) CDR Exempt/Partial exemption: Not determined

SARA 302/304

SARA 304 RQ

:

Not applicable.

Composition/information on ingredients

SARA 311/312

Classification

:

SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B
SKIN SENSITIZATION - Category 1

Trade secret 1

SKIN SENSITIZATION - Category 1

Trade secret 3

SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A

Trade secret 2

SKIN SENSITIZATION - Category 1B

Name

Classification

Composition/information on ingredients

No products were found.

United States inventory (TSCA 8b): Not determined.

9/10

Conforms to HCS 2012- United States

Section 15. Regulatory information

None of the components are listed.

No products were found.
Massachusetts

:

SARA 313

California Prop. 65

New York

:

None of the components are listed.

New Jersey

:

None of the components are listed.

Pennsylvania

:

None of the components are listed.

State regulations

There is no data available.

Section 16. Other information

Procedure used to derive the classification

Classification

Justification

SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B

Calculation method

SKIN SENSITIZATION - Category 1

Calculation method

History

Date of issue mm/dd/yyyy

Prepared by

:

Date of previous issue

Version

:

:

:

1

05/30/2018

Not applicable

Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries,
assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with
caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

KMK Regulatory Services Inc.

10/10

Conforms to HCS 2012- United States