FORMLABS FORM KH T1500 1L Datasheet

Generated using Total SDS™ (patent-pending), www.GSMSDS.com

SECTION 1: Identification of the substance/mixture and of the company/undertaking

SECTION 2: Hazard(s) identification

Safety Data Sheet

According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)

Initial preparation date:

Tough 1500 Resin

1.1 Product identifier

Product Name:
Product code:

1.2 Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses:
Uses advised against:
Reasons why uses advised against:

1.3 Details of the manufacturer/supplier of the safety data sheet
Manufacturer:

United States

Formlabs, Inc
35 Medford St
Suite 201 Somerville, MA 02143
[phone]
[e-mail]

1.4 Emergency telephone number:

1-800-424-9300 (24/7)

2020.02.20

Tough 1500 Resin

FLTO1501

For use in Formlabs SLA Printers

Not determined or not applicable.

Not determined or not applicable.

Supplier:
Germany

Formlabs GmbH
Nalepastr. 18
12459 Berlin
[phone]

Page 1 of 14

2.1 Classification of the substance or mixture:

Classification according to Regulation (EC) No. 1272/2008 (CLP):

Skin irritation, category 2
Skin sensitization, category 1
Chronic aquatic hazard, category 2

Hazard-determining components of labeling:

Methacrylate Monomer(s)
Urethane Dimethacrylate
Phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide

Additional Information:

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 (CLP)
Hazard pictograms:

Signal word:
Hazard statements:

Warning

None

Safety Data Sheet

According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)

Initial preparation date:

2020.02.20

Tough 1500 Resin

Page 2 of 14

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SECTION 3: Composition/information on ingredients

SECTION 4: First aid measures

Identification

REACH Registration
No.

Name

Classification according
to Regulation (EC) No.
1272/2008 (CLP)

Weight %

CAS number:
Trade Secret
EC number:
Trade Secret

–

Methacrylate Monomer(s)

Skin Sens. 1; H317
Skin Irrit. 2; H315

20-30

CAS number:
72869-86-4
EC number:
276-957-5

–

Urethane Dimethacrylate

Skin Sens. 1; H317
Aquatic Chronic 2;
H411

55-75

CAS number:
162881-26-7
EC number:
423-340-5

–

Phenyl bis(2,4,6­trimethylbenzoyl)-phosphine
oxide

Skin Sens. 1; H317
Aquatic Chronic 4;
H413

<0.9

H315 Causes skin irritation
H317 May cause an allergic skin reaction
H411 Toxic to aquatic life with long lasting effects

Precautionary statements:

P264 Wash skin thoroughly after handling
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P272 Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P362 Take off contaminated clothing
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P363 Wash contaminated clothing before reuse
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P391 Collect spillage
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P501 Dispose of contents/container in accordance with local/regional/national regulations

2.3 Other hazards:

None known

3.1 Substance:

3.2 Mixture:

Additional information:
Full Text of H and EUH statements:

Not applicable.

None

4.1 Description of first aid measures

General notes:

Show this Safety Data Sheet to the doctor in attendance.

Following inhalation:

Remove source of exposure or move person to fresh air and keep comfortable for breathing. If

See section 16

Safety Data Sheet

According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)

Initial preparation date:

12.18.2019

Revision date:

02.20.2020

Tough 1500 Resin

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SECTION 5: Firefighting measures

SECTION 6: Accidental release measures

experiencing respiratory symptoms: Call a POISON CENTER or doctor.

Following skin contact:

Wash off immediately with soap and plenty of water while removing contaminated clothing and shoes.
Continue rinsing for at least 15 minutes. See a physician if irritation persists.

Following eye contact:

Immediately flush eyes, under eyelids with water for 15 minutes. Remove contact lenses, if present to do
so. Protect unexposed eye. Continue rinsing on the way to hospital.

Following ingestion:

If swallowed, DO NOT induce vomiting unless told to do so by physician or poison control center. Rinse
mouth with water. Never give anything to drink to an unconscious person. Seek medical advice.

Self-Protection of the first aider:

Not determined or not available.

4.2

Most important symptoms and effects, both acute and delayed

Acute symptoms and effects:

Symptoms may include blistering, irritation, burns and pain. Effects are dependent on exposure (dose,
concentration, contact time).

Delayed symptoms and effects:

Symptoms of poisoning may appear several hours later.

4.3 Indication of any immediate medical attention and special treatment needed

Specific treatment:

None known.

Notes for the doctor:

Treat symptomatically.

5.1

Extinguishing media

Suitable extinguishing media:

Alcohol- resistant foam, Dry chemical or Carbon dioxide

Unsuitable extinguishing media:

None known

5.2

Special hazards arising from the substance or mixture:

Evacuate all personnel to a predetermined safe location, no less than 2,500 feet in all directions. Can
explode or detonate under fire conditions. Burning material may produce toxic vapors.

5.3 Advice for firefighters

Personal protection equipment:

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus
(SCBA)

Special precautions:

Avoid inhaling gases, fumes, mist, dust, vapor or aerosols. Avoid contact with eyes, skin, hair or clothing.

6.1 Personal precautions, protective equipment and emergency procedures:

Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate
personnel to safe areas. For personal protection see section 8.

6.2 Environmental precautions:

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the

Safety Data Sheet

According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)

Initial preparation date:

2020.02.20

Tough 1500 Resin

Page 4 of 14

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SECTION 7: Handling and storage

SECTION 8: Exposure controls/personal protection

Workers - Systemic

Effects

Acute - Oral

Not determined or not applicable.

Acute - Inhalation

No hazard identified

Acute - Dermal

No hazard identified

Chronic - Oral

Not determined or not applicable.

Chronic - Inhalation

14.7 mg/m³

Chronic - Dermal

4.2 mg/kg bw/day

environment must be avoided.

6.3 Methods and material for containment and cleaning up:

Contain and soak up spill with absorbent that does not react with spilled product. Place used absorbent
into suitable, covered, labelled containers for disposal.

6.4 Reference to other sections:

For disposal see section 13.

7.1

7.2

7.3

8.1 Control parameters

Precautions for safe handling:

Avoid contact with skin, eyes, and clothing. Follow good hygiene procedures when handling chemical
materials. Refer to Section 8. Follow proper disposal methods. Refer to Section 13. Do not eat, drink,
smoke, or use personal products when handling chemical substances.

Conditions for safe storage, including any incompatibilities:

Store in a cool, dry, well ventilated place. Store away from sources of heat or ignition. Store away from
incompatible materials described in Section 10. Keep containers closed when not in use

Specific end use(s):

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

Only those substances with limit values have been included below.

Occupational Exposure limit values:

No occupational exposure limits noted for the ingredient(s).

Biological limit values:

No biological exposure limits noted for the ingredient(s).

Derived No Effect Level (DNEL):
Ingredient Name: Methacrylat Monomer(s)
CAS #: Trade Secret

Safety Data Sheet

According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)

Initial preparation date:

2020.02.20

Tough 1500 Resin

Page 5 of 14

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Workers - Local

Effects

Acute - Oral

Not determined or not applicable.

Acute - Inhalation

No hazard identified

Acute - Dermal

No hazard identified

Chronic - Oral

Not determined or not applicable.

Chronic - Inhalation

No hazard identified

Chronic - Dermal

Hazard identified but no DNEL available

General Population -

Systemic Effects

Acute - Oral

No hazard identified

Acute - Inhalation

No hazard identified

Acute - Dermal

No hazard identified

Chronic - Oral

2.5 mg/kg bw/day

Chronic - Inhalation

8.8 mg/m³

Chronic - Dermal

2.5 mg/kg bw/day

General Population -

Local Effect

Acute - Oral

Not determined or not applicable.

Acute - Inhalation

No hazard identified

Acute - Dermal

No hazard identified

Chronic - Oral

Not determined or not applicable.

Chronic - Inhalation

No hazard identified

Chronic - Dermal

Hazard identified but no DNEL available

Workers - Systemic

Effects

Acute - Oral

Not determined or not applicable.

Acute - Inhalation

No hazard identified; 7.84 mg/m³; 16.46 mg/m³

Acute - Dermal

No hazard identified; 3.33 mg/kg bw/day; 4.67 mg/kg bw/day

Chronic - Oral

Not determined or not applicable.

Chronic - Inhalation

7.84 mg/m³; 11.75 mg/m³; 16.46 mg/m³; 21 mg/m³

Chronic - Dermal

3 mg/kg bw/day; 3.33 mg/kg bw/day; 4.67 mg/kg bw/day

Workers - Local

Effects

Acute - Oral

Not determined or not applicable.

Acute - Inhalation

No hazard identified; Hazard identified but no DNEL available

Acute - Dermal

Hazard identified but no DNEL available; No hazard identified

Chronic - Oral

Not determined or not applicable.

Chronic - Inhalation

No hazard identified; Hazard identified but no DNEL available

Chronic - Dermal

Hazard identified but no DNEL available; No hazard identified

General Population -

Systemic Effects

Acute - Oral

No hazard identified; 1.67 mg/kg bw/day; Hazard identified but
no DNEL available

Acute - Inhalation

3.92 mg/m³; Hazard identified but no DNEL available; 1.93
mg/m³; 2.92 mg/m³; 3.92 mg/m³

Acute - Dermal

No hazard identified; 1.67 mg/kg bw/day

Chronic - Oral

No hazard identified; 1.5 mg/kg bw/day; 1.67 mg/kg bw/day

Chronic - Inhalation

1.93 mg/m³; 2.9 mg/m³; 2.92 mg/m³; 3.92 mg/m³; 5.2 mg/m³;

1.67 mg/kg bw/day

Chronic - Dermal

1.5 mg/kg bw/day

Ingredient Name:
CAS #:

162881-26-7

Phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide

Safety Data Sheet

According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)

Initial preparation date:

2020.02.20

Tough 1500 Resin

Page 6 of 14

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General Population -

Local Effect

Acute - Oral

Not determined or not applicable.

Acute - Inhalation

Hazard identified but no DNEL available; No hazard identified

Acute - Dermal

Hazard identified but no DNEL available; No hazard identified

Chronic - Oral

Not determined or not applicable.

Chronic - Inhalation

No hazard identified; Hazard identified but no DNEL available

Chronic - Dermal

Hazard identified but no DNEL available; No hazard identified

Environmental Protection Target

PNEC

Fresh water

0.904 mg/L

Freshwater sediments

6.28 mg/kg

Marine water

0.904 mg/L

Marine sediments

6.28 mg/kg

Food chain

Not determined or not available.

Microorganisms in sewage treatment

10 mg/L

Soil (agricultural)

0.727 mg/kg

Air

No hazard identified

Environmental Protection Target

PNEC

Fresh water

0.8 µg/L

Freshwater sediments

0.712 mg/kg

Marine water

0.8 µg/L; 1 µg/L; 1 µg/L

Marine sediments

0.712 mg/kg

Food chain

Not determined or not available.

Microorganisms in sewage treatment

1 mg/L

Soil (agricultural)

Not determined or not available.

Air

No hazard identified

Predicted No Effect Concentration (PNEC):
Ingredient Name: Methacrylate Monomer

CAS #: Trade Secret

Ingredient Name:
CAS #:

162881-26-7

Phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide

Information on monitoring procedures:

Not determined or not applicable.

8.2 Exposure controls

Appropriate engineering controls:

Effective ventilation in all processing areas.

Personal protection equipment

Eye and face protection:

Safety goggles or safety glasses with side shields

Skin and body protection:

Impervious clothing and chemical resistant gloves

Respiratory protection:

In case of insufficient ventilation, wear suitable respiratory protection

General hygienic measures:

Handle in accordance with good industrial hygiene and safety measures. Wash hands and face after
handling chemical products. Wash hands before eating, drinking and smoking. Wash hands at the end of

Safety Data Sheet

According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)

Initial preparation date:

2020.02.20

Tough 1500 Resin

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SECTION 9: Physical and chemical properties

SECTION 10: Stability and reactivity

Product (substance / mixture) related measures to prevent
exposure:

Not determined or not applicable.
Instruction measures to prevent exposure:

Not determined or not applicable.

Organisational measures to prevent exposure:

Not determined or not applicable.

Technical measures to prevent exposure:

Not determined or not applicable.

Appearance

Grey Liquid

Odor

Characteristic acrylate

Odor threshold

Not determined or not available.

pH

Not determined or not available.

Melting point/freezing point

Not determined or not available.

Initial boiling point/range

> 100°C

Flash point (closed cup)

> 93.5°C

Evaporation rate

Not determined or not available.

Flammability (solid, gas)

Not Flammable

Upper flammability/explosive limit

Not determined or not available.

Lower flammability/explosive limit

Not determined or not available.

Vapor pressure

Not determined or not available.

Vapor density

Not determined or not available.

Density

1.07 g/cm3

Relative density

Not determined or not available.

Solubilities

Not determined or not available.

Partition coefficient (n-octanol/water)

Not determined or not available.

Auto/Self-ignition temperature

Not determined or not available.

Decomposition temperature

Not determined or not available.

Dynamic viscosity

1584 @ 25°C (77°F)

Kinematic viscosity

Not determined or not available.

Explosive properties

Not determined or not available.

Oxidizing properties

Not determined or not available.

the workday.

Environmental exposure controls:

Emissions from ventilation or work process equipment should be checked to ensure they comply with the
requirements of environmental protection legislation.

Risk management measures to control exposure:

Not determined or not applicable.

9.1 Information on basic physical and chemical properties

9.2 Other information

10.1 Reactivity:

Safety Data Sheet

According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)

Initial preparation date:

2020.02.20

Tough 1500 Resin

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SECTION 11: Toxicological information

Name

Route

Result

Methacrylate Monomer(s)

oral

LD50 Rat: >2000 mg/kg

dermal

LD50 Rabbit : >5000 mg/kg

Name

Result

Methacrylate Monomer(s)

Causes serious eye irritation.

Does not react under normal conditions of use and storage.

10.2 Chemical stability:

Stable under normal storage and handling conditions.

10.3 Possibility of hazardous reactions:

Under normal conditions of storage and use, hazardous reactions will not occur.

10.4 Conditions to avoid:

Incompatible materials.
Avoid storage >38°C (100°F) and exposure to light/direct sunlight and heat.

10.5 Incompatible materials:

Strong oxidizing agents.
Polymerization initiators, including peroxides, strong oxidizing agents, alcohols, copper, copper alloys,
carbon steel, iron, rust, and strong bases

10.6 Hazardous decomposition products:

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

11.1 Information on toxicological effects

Acute toxicity

Assessment:

Product data:

Substance data:

Based on available data, the classification criteria are not met.

No data available.

Skin corrosion/irritation

Assessment:

Causes skin irritation.

Product data:

No data available.

Substance data:

Serious eye damage/irritation

Assessment:

Product data:

No data available.

Based on available data, the classification criteria are not met.

No data available.

Substance data:

Respiratory or skin sensitization

Assessment:

May cause an allergic skin reaction.

Product data:

No data available.

Substance data:

Safety Data Sheet

According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)

Initial preparation date:

2020.02.20

Tough 1500 Resin

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SECTION 12: Ecological information

Name

Result

Methacrylate Monomer(s)

May cause an allergic skin reaction.

Urethane Dimethacrylate

May cause an allergic skin reaction.

Phenyl bis(2,4,6­trimethylbenzoyl)-phosphine
oxide

May cause an allergic skin reaction.

Carcinogenicity

Assessment:

Product data:

Substance data:

International Agency for Research on Cancer (IARC):

National Toxicology Program (NTP):

Germ cell mutagenicity

Assessment:

Product data:

Substance data:

Reproductive Toxicity

Assessment:

Product data:

No data available.

Substance data:

Specific target organ toxicity (single exposure)

Assessment:

May cause respiratory irritation.

Product data:

No data available.

Substance data:

Specific target organ toxicity (repeated exposure)

Assessment:

Product data:

No data available.

Substance data:

Aspiration toxicity

Assessment:

Product data:

No data available.

Substance data:

Information on likely routes of exposure:

No data available.

Symptoms related to the physical, chemical and toxicological characteristics:

No data available.

Other information:

No data available.

Based on available data, the classification criteria are not met.

No data available.

No data available.

Based on available data, the classification criteria are not met.

No data available.

No data available.

Based on available data, the classification criteria are not met.

No data available.

No data available.

Based on available data, the classification criteria are not met.

No data available.

Based on available data, the classification criteria are not met.

No data available.

None of the ingredients are listed.

None of the ingredients are listed.

Safety Data Sheet

According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)

Initial preparation date:

2020.02.20

Tough 1500 Resin

Page 10 of 14

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Name

Result

Phenyl bis(2,4,6­trimethylbenzoyl)-phosphine
oxide

EC50 Activated sludge : 100 mg/L

Name

Result

Methacrylate Monomer(s)

The substance has a low potential for adsorption to soil.

Urethane Dimethacrylate

This substance is expected to distribute between the water column and
organic soil and sediment particles.

Phenyl bis(2,4,6­trimethylbenzoyl)-phosphine
oxide

Based upon the log Koc of 3.85 an adsorption to the soil is expected.

Name

Result

Methacrylate Monomer(s)

This substance is readily biodegradable.

Urethane Dimethacrylate

This substance is not readily biodegradable.

Phenyl bis(2,4,6­trimethylbenzoyl)-phosphine
oxide

This substance is not readily biodegradable.

Name

Result

Methacrylate Monomer(s)

The substance has low potential to bioaccumulate because of log Kow
value (0.97 at 20 deg C).

Phenyl bis(2,4,6­trimethylbenzoyl)-phosphine
oxide

Bioaccumulation in organisms is not to be expected.

Methacrylate Monomer(s)

This substance is not PBT.

12.1 Toxicity

Acute (short-term) toxicity

Chronic (long-term) toxicity

12.2 Persistence and degradability

Assessment:
Product data:
Substance data:

Assessment:

Toxic to aquatic life with long lasting effects.

Product data:

Substance data:

Product data:

Substance data:

Based on available data, the classification criteria are not met.

No data available.

No data available.

No data available.

No data available.

12.3 Bioaccumulative potential

Product data:

Substance data:

No data available.

12.4 Mobility in soil

Product data:

Substance data:

12.5

Results of PBT and vPvB assessment

PBT assessment:

No data available.

Safety Data Sheet

According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)

Initial preparation date:

2020.02.20

Tough 1500 Resin

Page 11 of 14

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SECTION 13: Disposal considerations

SECTION 14: Transport information

Urethane Dimethacrylate

This substance is not PBT.

Phenyl bis(2,4,6­trimethylbenzoyl)-phosphine
oxide

This substance is not PBT.

Methacrylate Monomer(s)

This substance is not vPvB.

Urethane Dimethacrylate

This substance is not vPvB.

Phenyl bis(2,4,6­trimethylbenzoyl)-phosphine
oxide

This substance is not vPvB.

UN number

UN3082

UN proper shipping name

Environmentally hazardous liquid, N.O.S. Methacrylate Polymer

UN transport hazard class(es)

9

Packing group

III

Environmental hazards

Marine Pollutant

Special precautions for user

None

Additional Information

This product is not regulated as a dangerous good when
transported in sizes of <5L or <5 kg provided the packaging
meets the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to

4.1.1.8

UN number

UN3082

UN proper shipping name

Environmentally hazardous liquid, N.O.S. Methacrylate Polymer

vPvB assessment:

12.6 Other adverse effects:

12.7 Hazard to the ozone layer

13.1

Assessment:
Product data:
Substance data:

Waste treatment methods

13.1.1

Product / Packaging disposal: Not determined or not available.

Based on available data, the classification criteria are not met.

No data available.

No data available.

Waste codes / waste designations according to LoW:

13.1.2 Waste treatment-relevant information:

13.1.3 Sewage disposal-relevant information:

13.1.4 Other disposal recommendations:

characterize all waste materials according to applicable regulatory entities

No data available.

Not determined or not available.

Not determined or not available.

Not determined or not available.

It is the responsibility of the waste generator to properly

International Carriage of Dangerous Goods by Road/Rail (ADR/RID)

International Carriage of Dangerous Goods by Inland Waterways (ADN)

Safety Data Sheet

According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)

Initial preparation date:

2020.02.20

Tough 1500 Resin

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SECTION 15: Regulatory information

UN transport hazard class(es)

9

Packing group

III

Environmental hazards

Marine Pollutant

Special precautions for user

None

Additional Information

This product is not regulated as a dangerous good when
transported in sizes of <5L or <5 kg provided the packaging
meets the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to

4.1.1.8

UN number

UN3082

UN proper shipping name

Environmentally hazardous liquid, N.O.S. Methacrylate Polymer

UN transport hazard class(es)

9

Packing group

III

Environmental hazards

Marine Pollutant

Special precautions for user

None

Additional Information

This product is not regulated as a dangerous good when
transported in sizes of ≤5L or ≤5 kg provided the packaging
meets the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to

4.1.1.8.

UN number

UN3082

UN proper shipping name

Environmentally hazardous liquid, N.O.S. Methacrylate Polymer

UN transport hazard class(es)

9

Packing group

III

Environmental hazards

Marine Pollutant

Special precautions for user

None

Additional Information

This product is not regulated as a dangerous good when
transported in sizes of ≤5L or 5≤ kg provided the packagings
meet the general provisions of 5.0.2.4.1, 5.0.2.6.1 and 5.0.2.8.

Trade Secret

Methacrylate Monomer(s)

Listed

72869-86-4

Urethane Dimethacrylate

Listed

International Maritime Dangerous Goods (IMDG)

International Air Transport Association Dangerous Goods Regulations (IATA-DGR)

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture.

European regulations

Inventory listing (EINECS):

Safety Data Sheet

According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)

Initial preparation date:

2020.02.20

Tough 1500 Resin

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SECTION 16: Other information

162881-26-7

Phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide

Not
Listed

Trade Secret

Methacrylate Monomer(s)

Not
Listed

72869-86-4

Urethane Dimethacrylate

Not
Listed

162881-26-7

Phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide

Not
Listed

Trade Secret

Methacrylate Monomer(s)

Not
Listed

72869-86-4

Urethane Dimethacrylate

Not
Listed

162881-26-7

Phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide

Not
Listed

Trade Secret

Methacrylate Monomer(s)

Not
Listed

72869-86-4

Urethane Dimethacrylate

Not
Listed

162881-26-7

Phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide

Not
Listed

Ingredient Name

CAS Class

Methacrylate Monomer(s)

Trade Secret

Water hazard class 1: slightly hazardous to water

Urethane Dimethacrylate

72869-86-4

Water hazard class 1: slightly hazardous to water

Phenyl bis(2,4,6­trimethylbenzoyl)­phosphine oxide

162881-26-7

Water hazard class 1: slightly hazardous to water

Ingredient Name

CAS Class

Base
Emission Rate

Max Concentration

Methacrylate Monomer(s)

Trade Secret

Not Applicable

Urethane Dimethacrylate

72869-86-4

Not Applicable

Phenyl bis(2,4,6­trimethylbenzoyl)­phosphine oxide

162881-26-7

Not Applicable

REACH SVHC candidate list:

REACH SVHC Authorizations:

REACH Restriction:

Water hazard class (WGK) (Product):

Water hazard class (WGK) (Substance):

Other regulations

15.2

Germany TA Luft:

Chemical Safety Assessment

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

Abbreviations and Acronyms:

None

Safety Data Sheet

According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)

Initial preparation date:

2020.02.20

Tough 1500 Resin

Page 14 of 14

Generated using Total SDS™ (patent-pending), www.GSMSDS.com

Classification according to Regulation (EC) No. 1272/2008 (CLP)

Method Used

Skin irritation, category 2

Calculation method

Skin sensitization, category 1

Calculation method

Chronic aquatic hazard, category 2

Bridging principle substantially
similar mixtures

Skin Sens. 1

Skin sensitization, category 1

Skin Irrit. 2

Skin irritation, category 2

Aquatic Chronic 2

Chronic aquatic hazard, category 2

Aquatic Chronic 4

Chronic aquatic hazard, category 4

H317 May cause an allergic skin reaction

H315

Causes skin irritation

H411

Toxic to aquatic life with long lasting effects

H413 May cause long lasting harmful effects to aquatic life

Classification procedure:

Summary of classification(s) in section 3:

Summary of hazard statements in section 3:

Disclaimer:

This product has been classified in accordance with EC No. 1272/2008 (CLP) and EC No. 1907/2006
(REACH). The information provided in this SDS is correct, to the best of our knowledge, based on
information available. The information given is designed only as a guidance for safe handling, use,
storage, transportation and disposal and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used
in combination with any other materials, unless specified in the text. The responsibility to provide a safe
workplace remains with the user.

Initial preparation date:

2020.02.20

End of Safety Data Sheet