Eutech Instruments WATERPROOF C401 User Manual

Instruction Manual

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C401/301/201/102/101

Portable Colorimeter

68X357704 Rev. 0 08/04

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Preface

This manual functions in two ways: first as a step by step guide to help you operate the waterproof C401/301/201/102/101 Colorimeter; second, it serves as a handy reference guide.

It contains basic instructions that you must follow during the operation, care and maintenance of the instrument. The safety protection provided by this equipment may be impaired if it is used in a manner not described in this manual. It is recommended that all operators should read this manual prior to working with this instrument.

Eutech Instruments/ Oakton Instruments cannot accept any responsibility for damage or malfunction to the meter caused by improper use of the instrument.

The information presented in this manual is subject to change without notice as improvements are made, and does not represent a commitment on the part of Eutech Instruments Pte Ltd/ Oakton Instruments.

Note: Eutech Instruments Pte Ltd/ Oakton Instruments reserves the right to make improvements in design, construction, and appearance of our products without notice.

Eutech Instruments Pte Ltd

Oakton Instruments

Rev. 0 08/04

TABLE OF CONTENTS

1 INTRODUCTION ..................................................................................................................1

1.1 UNPACKING C401/301/201/102/101 COLORIMETER AND ACCESSORIES ...........................2

1.2 DISPLAY ............................................................................................................................3

1.3 KEYS AND FUNCTIONS....................................................................................................... 4

1.4 BATTERY INSTALLATION...................................................................................................5

2 MEASUREMENT ..................................................................................................................6

2.1 GENERAL INFORMATION.................................................................................................... 6

2.2 PREPARATION OF SAMPLE VIAL ........................................................................................ 7

2.3 MEASUREMENT PROCEDURE .............................................................................................7

2.4 CHLORINE, FREE & TOTAL (0 – 6PPM CL2)........................................................................ 9

2.4.1 Sample Collection...................................................................................................11

2.4.2 Sample Measurement..............................................................................................11

2.4.3 Interferences ...........................................................................................................12

2.4.4 Correcting for dilution............................................................................................13

2.4.5 Accuracy Check / User Calibration........................................................................13

2.4.6 Chemistry................................................................................................................14

2.5 CYANURIC ACID (5-90 PPM)............................................................................................ 15

2.5.1 Sample Collection...................................................................................................17

2.5.2 Sample Measurement..............................................................................................17

2.5.3 Interferences ...........................................................................................................17

2.5.4 Accuracy Check / User Calibration........................................................................17

2.5.5 Chemistry................................................................................................................18

2.6 PH (5.9-8.2 PH UNITS) .....................................................................................................19

2.6.1 Sample Collection...................................................................................................21

2.6.2 Sample Measurement..............................................................................................21

2.6.3 Interferences ...........................................................................................................21

2.6.4 Accuracy Check / User Calibration........................................................................21

2.6.5 Chemistry................................................................................................................22

3 CALIBRATION.................................................................................................................... 23

3.1 CALIBRATION PROCEDURE .............................................................................................. 23

3.2 CHLORINE, FREE & TOTAL .............................................................................................. 24

3.3 CYANURIC ACID..............................................................................................................27

3.4 PH.................................................................................................................................... 30

3.5 RESTORING FACTORY CALIBRATION ...............................................................................33

4 TROUBLESHOOTING GUIDE.........................................................................................35

5 ROUTINE MAINTENANCE.............................................................................................. 36

5.1 VIALS – HANDLING, CLEANING AND CARE ..................................................................... 36

6 ACCESSORIES....................................................................................................................37

7 SPECIFICATIONS ..............................................................................................................38

8 WARRANTY ........................................................................................................................39

9 RETURN OF ITEMS...........................................................................................................39

Introduction C401/301/201/102/101

1 INTRODUCTION

Thank you for selecting the waterproof portable C401/301/201/102/101 Colorimeter. Depending on the model selected, the C401/301/201/102/101 Colorimeter allows you to measure up to four parameters - namely the pH, Cyanuric acid, Free Chlorine and Total Chlorine of an aqueous sample in the field. You have one of the following models:

• C101: pH measurement

• C102: Cyanuric Acid measurement

• C201: Free Chlorine and Total Chlorine measurement

• C301: Free Chlorine, Total Chlorine and pH measurement

• C401: Free Chlorine, Total Chlorine, Cyanuric Acid and pH

measurement

Introduction C401/301/201/102/101

1.1 Unpacking C401/301/201/102/101 Colorimeter and

Accessories

The table below indicates the items that you should find in your Colorimeter shipment.

Item Quantity

1. Field Portable C401/301/202/102/101Colorimeter with 4 “AAA” batteries

2. Instruction Manual 1

3. Instrument Carrying Case 1

4. Empty Vial 4

5. pH Indicator (Phenol Red) Reagent Kit (Only for C101, C301, C401) 1

6. Cyanuric Acid Reagent Kit (Only for C102, C401) 1

7. Free Chlorine DPD Reagent Kit (Only for C201, C301, C401) 1

8. Total Chlorine DPD reagent Kit (Only for C201, C301, C401) 1

Remove C401/301/201/102/101 Colorimeter from the packing carton. Carefully inspect all items to ensure that no visible damage has occurred during shipment. If the items you received do not match your order, please contact your nearest distributor immediately.

WARNING: Extra care should be taken when unpacking, opening, and handling the sample vials. Surface scratches or finger smudges on the vial surface may cause meas urement errors. Handle these items by their caps only.

Batteries provided with the meter package are to be installed prior to use. See Section 1.4 Battery Installation on page 5.

In the next page, Figure 1 depicts the meter. The three main components of the instrument are the sample well, the display, and the keypad. The following sections will describe the functionality of the display and the keypad. The proper use of the instrument will be discussed in later sections.

Introduction C401/301/201/102/101

Sample Vial

Sample Well

Liquid Crystal

Marking

Display

Keypad

Meter Index

Figure 1: Parts of C401/301/201/102/101Colorimeter

1.2 Display

All the LCD segments and annunciators that can appear on the display are shown in Figure 2. The display is used for reporting the colorimeter reading, communicate error messages and provide guidance for the operation of the instrument.

Calibration Mode Annunciator

Battery Indicator

CAL

ppm pH

14-segment Liquid Crystal Display

Figure 2: Customized LCD when switched on

Units of Measure

Introduction C401/301/201/102/101

1.3 Keys and Functions

The keypad has four keys: ON/OFF, MODE, ZERO and READ/ENTER.

Keys Functions ON/OFF - Powers on and shuts off the meter. With the auto switch-off feature

the meter automatically shuts off 10 minutes after last key press.

MODE - Selects the test to be performed.

- Selects the calibration point in an incremental circular manner during

calibration.

ZERO - Blanks the instrument (sets the meter to zero) before chemical

reagent is added.

- Initiates the calibration mode when used with the ON/OFF key.

- Aborts the calibration process without saving.

- Exits the calibration mode.

READ / ENTER

- Initiates the measurement of the sample after the chemical reagent

has been added.

- Confirms the test selection.

WATERPROOF

READ

ENTER

ZERO

OFF

MODE

Figure 3: C401/301/201/102/101 Keypad

Introduction C401/301/201/102/101

1.4 Battery Installation

Four AAA-sized batteries are included in your meter’s packaging:

1. Use a Philips screwdriver to remove the two screws holding the battery cover. See Figure 4 : Battery Installation.

2. Remove the battery cover.

3. Insert the batteries. Follow the diagram inside the cover for correct polarity.

4. Replace the battery cover onto its original position using the two screws removed earlier.

5. The meter is now ready to operate.

Philips Screws

Battery cover

Four 'AAA'-sized batteries

Figure 4 : Battery Installation

NOTE: Dispose used batteries in accordance with your local regulations.

Measurement C401/301/201/102/101

2 MEASUREMENT

2.1 General Information

The waterproof C401/301/202/102/101Colorimeter allows you to measure up to four parameters - namely the pH, Cyanuric acid, Free Chlorine and Total Chlorine of a sample and reports the results in appropriate units (ppm or pH). Each specific measurement has its own range as listed in the specifications.

The meter will go through a power sequence as shown below.

Meter’s Model Number

Meter’s Revision Number

Figure 5: Power Up Sequence

Measurement Mode Selection

An accurate colorimeter measurement depends on good measurement techniques. Factors such as clean sample vials, positioning of vial in the sample well, covering the vial with the light shield cap, meter calibration, handling of meter, and others, have to be taken into consideration.

NOTE: Do not pour liquid directly into the sample well of the instrument. Always use a vial. The instrument will only accurately measure the sample when vials sealed with the black caps are used. The black cap serves as both seal and a light shield.

NOTE: Do not attempt to clean the sample well. The optics may be damaged.

NOTE: This instrument is designed to measure solutions contained in the custom made glass vials and therefore the use of other type of sample vials or sample cells may result in inaccurate measurements.

Measurement C401/301/201/102/101

2.2 Preparation of Sample Vial

1. Obtain a clean and dry sample vial (Figure 6).

2. Take care to handle the sample vial by the top.

3. Rinse the vial with approximately 10 ml of the sample water, capping the vial with the black screw cap and gently inverting it several times. Discard the used sample and repeat the rinsing procedure two more times.

Figure 6: Sam

4. Fill the rinsed vial with the remaining portion (approximately

le Vial

10 ml) of the grab sample up to the mark indicated in the vial. Cap the vial with the supplied black screw cap.

5. Wipe the vial with a soft, lint-free cloth. Ensure that the outside of the vial is dry, clean and free from smudges.

6. You are now ready to place the vial into the meter for measurement.

2.3 Measurement Procedure

1. Place C401/301/202/102/101Colorimeter on a flat and level surface.

2. Place the sample vial inside the sample well and align the vial’s mark with the meter’s index mark. See Figure 8.

Align index mark on the sample vial with the index mark on the colorimeter and push till it is fully snapped in

IMPORTANT

Place me t er on a flat and leve l s ur face. DO NOT hold it on hands while operating the meter. It may lead to inaccurate readings

Figure 8: Sample vial index alignment to the meter's index mark

3. Push the vial until it is fully snapped in.

4. Turn on the meter by pressing the ON/OFF key. The display will

Measurement C401/301/201/102/101

indicate the last test performed

5. Select the desired test to be performed by pressing the MODE key.

6. Press the READ/ENTER key to confirm your selection. The meter will display [STbY] indicating it is ready to accept a measurement or a blanking.

7. Press the ZERO key to perform the blanking of the meter. If the user chooses to skip this step, the meter will use the last value of the blank for the next calculation.

8. Remove the sample vial used for blanking from the instrument and add the appropriate reagent to it. Cap the vial and follow the appropriate instructions (including the time required to develop the color) for each type of reagents.

9. Place the vial with the developed color into the sample well and align the ▼ mark on the vial with the ▲ mark on the instrument, and press it down until it snaps fully into the optical holder.

10. Press the READ/ENTER key. The meter will display the reading in appropriate units within 3 seconds.

11. To repeat the measurement of the same sample, repeat steps 7-11. Ideally, step 7 should not be skipped, but the user may do so if testing the same sample.

Measurement: Chlorine, Free & Total C401/301/201/102/101

2.4 Chlorine, Free & Total (0 – 6ppm Cl

• DPD method

for Free Chlorine - applicable to water, treated water,

)

estuary water and seawater.

• DPD method

for Total Chlorine - applicable to water, treated

water, wastewater, estuary water and seawater.

The DPD Method is USEPA accepted for reporting drinking water analyses (Free and Total Chlorine) and wastewater analyses2 (Total Chlorine only).

Note: 1Adapted from “Standard methods for the Examination of Water and Wastewater.”

Note: 2Procedure is equivalent to USEPA method 330.5 for wastewater and Standard Method 4500-Cl G for drinking water.

1. Switch the meter on by pressing the ON/OFF key.

2. Press the MODE key repeatedly until [CL – F] is displayed (for Free Chlorine determination) or [CL – T] is displayed (for Total Chlorine determination).

3. Press the READ/ENTER key to confirm the desired test parameter. The meter will read [STbY] indicating it is in stand-by mode, waiting for either blanking or measurement.

READ

ENTER

4. Select a clean and dry vial, un-screw the cap and fill with sample water to the line on the vial. Replace the cap, ensuring it is screwed on finger tight to the vial.

5. Ensure the outside of the vial is clean, dry and absent of any marks or finger-prints. Gently push the vial fully into the sample well of the instrument, whilst aligning the ▼ mark on the vial with the ▲ mark on the meter.

6. Press the ZERO key to initiate blanking of the meter. The display will show [ZERo] while blanking is taking place.

Note: The meter will store and use the last blanking (or zero) value, even if it is turned off, or if the batteries are removed.

ZERO

Blanking Sample

ppm

Measurement: Chlorine, Free & Total C401/301/201/102/101

7. Remove the vial from the meter and add into it the content of one DPD Free sachet (for Free Chlorine determination) or the content of one DPD Total sachet (for Total Chlorine determination).

8. Replace the cap, ensuring it is screwed on finger tight to the vial. Invert the vial repeatedly for approximately 20 seconds, until the powder has dissolved.

Note: A small amount of the powder may remain un-dissolved in the vial, but this will not affect the measurement.

Add content of one DPD Free sachet (for Free Chlorine determination) or one DPD Total sachet (for Total Chlorine determination).

Invert vial approximately 20 seconds until powder dissolves

9. Gently push the vial back fully into the sample well of the meter, whilst again aligning the ▼ mark on the vial with the ▲ mark on the meter.

10. For Free Chlorine determination, press the READ/ENTER key within two minutes from the time the DPD Free reagent was added to the vial.

11. For Total Chlorine determination, wait for two minutes and then press the READ/ENTER key within four minutes from the time the DPD Total reagent was added to the vial.

12. The meter will flash either [CL-F] or [CL-T], depending on which test is being performed, whilst the measurement is taken. It will then display the Chlorine concentration in parts per million (ppm) Cl2.

READ

Free Chlorine Sample

ENTER

ppm

Measurement: Chlorine, Free & Total C401/301/201/102/101

Chlorine, Free & Total

Measuring Hints & Tips

2.4.1 Sample Collection

Chlorine determination must take place as soon as possible after the sample is taken or else low results may be obtained.

Plastic containers should not be used to collect the sample because these may have a high chlorine demand which will lead to low reading results. It is advisable to wash the container with sample water before the sample is collected.

Avoid agitating the sample excessively as this may also result in low results.

2.4.2 Sample Measurement

If the pink color forms and then rapidly fades, this is an indication that the chlorine concentration may be very high. If this is the case, dilute the sample with de-ionized water and retest. Multiply the result by the dilution factor used.

Example: if the sample was diluted 2:1 with de-ionized water (i.e. 1 part sample water to 1 part de-ionized water), the result is multiplied by 2 to give the true concentration of the original sample.

Note: Results obtained by this method will not be as accurate as stated in this manual because some chlorine will be lost in the dilution process.

After use, the vial should be cleaned thoroughly to avoid contaminating the next sample. Do not use household cleaners as these may have a chlorine demand which will lead to low results on subsequent tests.

After testing Total Chlorine give extra attention to cleaning the vial as any residual reagent will affect any subsequent Free Chlorine tests. It is advisable to use separate vials for Free and Total Chlorine.

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