SAFETY DATA SHEET
Enforcer(R) Instant Knockdown Wasp & Hornet Killer
Version 2.0
Revision Date 07/18/2016
Print Date 08/08/2016
Material name
:
Enforcer(R) Instant Knockdown Wasp & Hornet Killer
EPA ID Number:
40849-77
Material number
:
000000000001045839
Company
:
Zep Commercial Sales & Service, a unit of Zep, Inc.
Address
:
1310 Seaboard Industrial Blvd., NW
Atlanta, GA 30318
Telephone
:
404-352-1680
Emergency telephone numbers
For SDS Information
:
Compliance Services 1-877-428-9937
For a Medical Emergency
:
877-541-2016 Toll Free - All Calls Recorded
For a Transportation
Emergency
:
CHEMTREC: 800-424-9300 - All Calls Recorded.
In the District of Columbia 202-483-7616
Recommended use
:
Pesticide
Appearance
Aerosol containing a compressed gas
Colour
clear, white
Odour
slight, characteristic
Flammable aerosols
:
Category 1
Gases under pressure
:
Compressed gas
Hazard pictograms
:
Signal word
:
Danger
Hazard statements
:
H222 Extremely flammable aerosol.
H280 Contains gas under pressure; may explode if heated.
Precautionary statements
:
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
P211 Do not spray on an open flame or other ignition source.
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Manufacturer or supplier's details
Recommended use of the chemical and restrictions on use
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
GHS Classification
GHS label elements
1 / 11
SAFETY DATA SHEET
Enforcer(R) Instant Knockdown Wasp & Hornet Killer
Version 2.0
Revision Date 07/18/2016
Print Date 08/08/2016
P251 Pressurized container: Do not pierce or burn, even after
use.
Storage:
P410 + P412 Protect from sunlight. Do not expose to
temperatures exceeding 50 °C/ 122 °F.
Substance / Mixture
:
Mixture
Chemical name
CAS-No.
Concentration [%]
Distillates (petroleum), hydrotreated light
64742-47-8
>= 70 - < 90
Solvent naphtha (petroleum), heavy aliph.
64742-96-7
>= 5 - < 10
carbon dioxide
124-38-9
>= 1 - < 5
m-phenoxybenzyl 3-(2,2-dichlorovinyl)-2,2dimethylcyclopropanecarboxylate
52645-53-1
>= 0.1 - < 1
General advice
:
Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled
:
If unconscious place in recovery position and seek medical
advice.
If symptoms persist, call a physician.
Move to fresh air.
In case of skin contact
:
Take off contaminated clothing and shoes immediately.
Wash contaminated clothing before re-use.
If symptoms persist, call a physician.
Wash off immediately with plenty of water for at least 15
minutes.
In case of eye contact
:
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If in eyes, rinse with water for 15 minutes.
If swallowed
:
Keep respiratory tract clear.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
DO NOT induce vomiting unless directed to do so by a
physician or poison control center.
Suitable extinguishing media
:
Alcohol-resistant foam
Carbon dioxide (CO2)
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
The exact percentages of disclosed substances are withheld as trade secrets.
SECTION 4. FIRST AID MEASURES
SECTION 5. FIREFIGHTING MEASURES
2 / 11
SAFETY DATA SHEET
Enforcer(R) Instant Knockdown Wasp & Hornet Killer
Version 2.0
Revision Date 07/18/2016
Print Date 08/08/2016
Dry chemical
Water spray jet
Unsuitable extinguishing
media
:
High volume water jet
Specific hazards during
firefighting
:
Do not allow run-off from fire fighting to enter drains or water
courses.
Hazardous combustion
products
:
Carbon dioxide (CO2)
Carbon monoxide
Smoke
Specific extinguishing
methods
:
Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Further information
:
For safety reasons in case of fire, cans should be stored
separately in closed containments.
Use a water spray to cool fully closed containers.
Special protective equipment
for firefighters
:
Wear self-contained breathing apparatus for firefighting if
necessary.
Personal precautions,
protective equipment and
emergency procedures
:
Ensure adequate ventilation.
Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Environmental precautions
:
Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for
containment and cleaning up
:
Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Sweep up or vacuum up spillage and collect in suitable
container for disposal.
Advice on safe handling
:
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Take precautionary measures against static discharges.
Provide sufficient air exchange and/or exhaust in work rooms.
Open drum carefully as content may be under pressure.
Dispose of rinse water in accordance with local and national
regulations.
Do not breathe vapours or spray mist.
Always replace cap after use.
SECTION 6. ACCIDENTAL RELEASE MEASURES
SECTION 7. HANDLING AND STORAGE
3 / 11
SAFETY DATA SHEET
Enforcer(R) Instant Knockdown Wasp & Hornet Killer
Version 2.0
Revision Date 07/18/2016
Print Date 08/08/2016
Conditions for safe storage
:
BEWARE: Aerosol is pressurized. Keep away from direct sun
exposure and temperatures over 50 °C. Do not open by force
or throw into fire even after use. Do not spray on flames or
red-hot objects.
No smoking.
Observe label precautions.
Keep in a dry, cool and well-ventilated place.
Electrical installations / working materials must comply with
the technological safety standards.
Materials to avoid
:
Oxidizing agents
Components
CAS-No.
Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
Distillates (petroleum),
hydrotreated light
64742-47-8
TWA
500 ppm
2,000 mg/m3
OSHA Z-1
TWA
400 ppm
1,600 mg/m3
OSHA P0
carbon dioxide
124-38-9
TWA
5,000 ppm
ACGIH
STEL
30,000 ppm
ACGIH
TWA
5,000 ppm
9,000 mg/m3
NIOSH REL
ST
30,000 ppm
54,000 mg/m3
NIOSH REL
TWA
5,000 ppm
9,000 mg/m3
OSHA Z-1
TWA
10,000 ppm
18,000 mg/m3
OSHA P0
STEL
30,000 ppm
54,000 mg/m3
OSHA P0
Engineering measures
:
effective ventilation in all processing areas
Respiratory protection
:
In case of insufficient ventilation, wear suitable respiratory
equipment.
Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
Remarks
:
The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection
:
Safety glasses
Ensure that eyewash stations and safety showers are close to
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Hazardous components without workplace control parameters
Personal protective equipment
Hand protection
4 / 11
SAFETY DATA SHEET
Enforcer(R) Instant Knockdown Wasp & Hornet Killer
Version 2.0
Revision Date 07/18/2016
Print Date 08/08/2016
the workstation location.
Skin and body protection
:
Impervious clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Hygiene measures
:
Wash hands before breaks and at the end of workday.
When using do not eat or drink.
When using do not smoke.
Appearance
:
Aerosol containing a compressed gas
Colour
:
clear, white
Odour
:
slight, characteristic
Odour Threshold
:
No data available
pH : Not applicable
Melting point/freezing point
:
No data available
Boiling point
:
217.77 °C
Flash point
:
Not applicable
Evaporation rate
:
< 1
n-Butyl Acetate = 1.0
Flammability (solid, gas)
:
Extremely flammable aerosol.
Upper explosion limit
:
No data available
Lower explosion limit
:
No data available
Vapour pressure
:
0.093 hPa
Relative vapour density
:
No data available
Density
:
0.8 g/cm3
Water solubility
:
insoluble
Partition coefficient: noctanol/water
:
No data available
Auto-ignition temperature
:
not determined
Thermal decomposition
:
No data available
Viscosity, kinematic
:
No data available
Heat of combustion
:
45.79 kJ/g
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Solubility(ies)
Viscosity
5 / 11
SAFETY DATA SHEET
Enforcer(R) Instant Knockdown Wasp & Hornet Killer
Version 2.0
Revision Date 07/18/2016
Print Date 08/08/2016
Reactivity
:
Stable
Chemical stability
:
Stable under normal conditions.
Possibility of hazardous
reactions
:
No decomposition if stored and applied as directed.
Vapours may form explosive mixture with air.
Conditions to avoid
:
Heat, flames and sparks.
Extremes of temperature and direct sunlight.
Incompatible materials
:
Oxidizing agents
Hazardous decomposition
products
:
Carbon oxides
IARC
No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
OSHA
No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by OSHA.
NTP
No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
Acute oral toxicity
:
LD50 Rat: > 5,000 mg/kg
Acute inhalation toxicity
:
LC50 Rat: > 4.6 mg/l
Exposure time: 6 h
Acute dermal toxicity
:
LD50 Rat: > 2,000 mg/kg
SECTION 10. STABILITY AND REACTIVITY
SECTION 11. TOXICOLOGICAL INFORMATION
Potential Health Effects
Carcinogenicity:
Acute toxicity
Components:
Distillates (petroleum), hydrotreated light:
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
6 / 11
SAFETY DATA SHEET
Enforcer(R) Instant Knockdown Wasp & Hornet Killer
Version 2.0
Revision Date 07/18/2016
Print Date 08/08/2016
Remarks: No data available
Remarks: No data available
Partition coefficient: noctanol/water
:
Remarks: No data available
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
No data available
Reproductive toxicity
No data available
Distillates (petroleum), hydrotreated light:
Solvent naphtha (petroleum), heavy aliph.:
carbon dioxide:
m-phenoxybenzyl 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate:
STOT - single exposure
No data available
STOT - repeated exposure
No data available
Aspiration toxicity
No data available
Further information
Product:
Components:
Distillates (petroleum), hydrotreated light:
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
Product:
Mobility in soil
No data available
Other adverse effects
7 / 11
SAFETY DATA SHEET
Enforcer(R) Instant Knockdown Wasp & Hornet Killer
Version 2.0
Revision Date 07/18/2016
Print Date 08/08/2016
Regulation
40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks
Warning: Manufactured with /$/, a substance which
harms public health and environment by destroying
ozone in the upper atmosphere.
Additional ecological
information
:
No data available
Additional ecological
information
:
No data available
Waste from residues
:
Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Dispose of in accordance with local regulations.
Contaminated packaging
:
Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.
Transportation Regulation: 49 CFR (USA):
ORM-D, CONSUMER COMMODITY
Transportation Regulation: IMDG (Vessel):
UN1950, AEROSOLS, 2.1, - Limited quantity
Transportation Regulation: IATA (Cargo Air):
UN1950, Aerosols, flammable, 2.1, - Limited quantity
Transportation Regulation: IATA (Passenger Air):
UN1950, Aerosols, flammable, 2.1, - Limited quantity
Transportation Regulation: TDG (Canada):
UN1950, AEROSOLS, 2.1, - Limited quantity
No data available
Product:
Components:
Distillates (petroleum), hydrotreated light :
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
SECTION 14. TRANSPORT INFORMATION
The product as delivered to the customer conforms to packaging requirements for shipment by road
under US Department of Transportation (DOT) regulations. Additional transportation classifications
8 / 11
SAFETY DATA SHEET
Enforcer(R) Instant Knockdown Wasp & Hornet Killer
Version 2.0
Revision Date 07/18/2016
Print Date 08/08/2016
SARA 311/312 Hazards
:
Fire Hazard
Sudden Release of Pressure Hazard
SARA 302
:
No chemicals in this material are subject to the reporting
requirements of SARA Title III, Section 302.
SARA 313
:
This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
California Prop 65
This product does not contain any chemicals known to State of
California to cause cancer, birth defects, or any other
reproductive harm.
TSCA
On TSCA Inventory
DSL
All components of this product are on the Canadian DSL
noted above are for reference only, and not a certification or warranty of the suitability of the packaging
for shipment under these alternative transport regulations.
SECTION 15. REGULATORY INFORMATION
This product is regulated under the United States Federal Insecticide, Fungicide and Rodenticide Act
(FIFRA).
Pesticide Labeling Information Required Under U.S. FIFRA Regulations
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject
to certain labeling requirements under federal pesticide law. These requirements differ from the
classification criteria and hazard information required for safety data sheets, and for workplace labels
of non-pesticide chemicals. Following is the hazard information as required on the pesticide label:
CAUTION
Causes moderate eye irritation.
Harmful if swallowed.
Harmful if inhaled.
Harmful if absorbed through skin.
Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.
This pesticide is extremely toxic to fish and aquatic invertebrates.
This product is highly toxic to bees and other pollinating insects exposed to direct treatment or
residues on blooming crops or weeds.
Observe label precautions.
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
The components of this product are reported in the following inventories:
For information on the country notification status for other regions please contact the
manufacturer’s regulatory group.
9 / 11
SAFETY DATA SHEET
Enforcer(R) Instant Knockdown Wasp & Hornet Killer
Version 2.0
Revision Date 07/18/2016
Print Date 08/08/2016
NFPA:
HMIS III:
Hazard pictograms
:
Signal word
:
Danger:
Hazard statements
:
Extremely flammable aerosol. Contains gas under pressure; may explode if heated.
Precautionary statements
:
Prevention: Keep away from heat/sparks/open flames/hot surfaces. No smoking. Do
not spray on an open flame or other ignition source. Pressurized container: Do not
pierce or burn, even after use.
Storage: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122
°F.
Version:
2.0
Revision Date:
07/18/2016
Print Date:
08/08/2016
Flammability
Health
Instability
1
4
0
Special hazard.
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
4
2
1
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
Inventory Acronym and Validity Area Legend:
TSCA (USA), DSL (Canada), NDSL (Canada)
SECTION 16. OTHER INFORMATION
Further information
OSHA - GHS Label Information:
We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.
Zep Inc. markets products under well recognized and established brand names such as Zep®,
Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Mis ty®, Next
10 / 11
SAFETY DATA SHEET
Enforcer(R) Instant Knockdown Wasp & Hornet Killer
Version 2.0
Revision Date 07/18/2016
Print Date 08/08/2016
Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®,
Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC
Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.
11 / 11
Loading...