Energizer L91 User Manual

Lithium L91 Batteries

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10/17/01

The information contained within is provided for your information only. This battery is an article pursuant to 29 CFR 1910.1200 and, as such, is
not subject to the OSHA Hazard Communication Standard requirement for preparation of a material safety data sheet. The information and
recommendations set forth herein are made in good faith and are believed to be accurate as of the date of preparation. However, EVEREADY
BATTERY COMPANY, INC., MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED, WITH RESPECT TO THIS INFORMATION
AND DISCLAIMS ALL LIABILITY FROM RELIANCE ON IT.

PRODUCT SAFETY DATA SHEET

PRODUCT NAME: EVEREADY Battery Type No.: L91 Volts: 1.5
TRADE NAME: ENERGIZER, Lithium-Iron Disulfide Battery Approximate Weight: 14.5 grams
CHEMICAL SYSTEM: Lithium-Iron Disulfide Designed for Recharge: No

SECTION I - MANUFACTURER INFORMATION

Eveready Battery Company, Inc. Telephone Numbers for Information:
25225 Detroit Road
Westlake, OH 44145

[phone]
[phone] (USA)

Date Prepared: October 17, 2001

SECTION II - HAZARDOUS INGREDIENTS

IMPORTANT NOTE: The battery should not be opened or burned. Exposure to the ingredients contained within or their combustion

products could be harmful.

MATERIAL OR INGREDIENT PEL (OSHA) TLV (ACGIH) %/wt.

Carbon Black

3.5 mg/m

3

TWA 3.5 mg/m3 TWA 0-4

(CAS# 1333-86-4)
1,2-Dimethoxyethane

None established None established 5-8

(CAS# 110-71-4)
1,3-Dioxolane

(CAS# 646-06-0)
Graphite

(CAS# 7782-42-5)

None established None established 2-5

15 mg/m3 TWA (total dust)
5 mg/m3 TWA (respirable

2 mg/m
fraction)

3

TWA (respirable

0-4

fraction)

Iron Disulfide

None established None established 24-27

(CAS# 1309-36-0)
Lithium or Lithium Alloy

None established None established 6-7

(CAS# 7439-93-2)
Lithium Iodide

None established None established 0-3

(CAS# 10377-51-2)

SECTION III - FIRE AND EXPLOSION HAZARD DATA

In case of fire where lithium batteries are present, apply a smothering agent such as METL-X, sand, dry ground dolomite, or soda
ash, or flood the area with water. A smothering agent will extinguish burning lithium batteries. Water may not extinguish burning
batteries but will cool the adjacent batteries and control the spread of fire. Burning batteries will burn themselves out. Virtually all
fires involving lithium batteries can be controlled with water. When water is used, however, hydrogen gas may evolve. In a confined
space, hydrogen gas can form an explosive mixture. In this situation, smothering agents are recommended.
Fire fighters should wear self-contained breathing apparatus. Burning lithium-iron disulfide batteries produce hydrogen sulfide gas,
sulfur dioxide gas, toxic and corrosive lithium hydroxide fumes.

 2001 EVEREADY BATTERY COMPANY, INC.

SECTION IV - HEALTH HAZARD DATA

Under normal conditions of use, the battery is hermetically sealed.

Ingestion: Swallowing a battery can be harmful.
Contents of an open battery can cause serious chemical burns of mouth, esophagus, and gastrointestinal tract.
If battery or open battery is ingested, do not induce vomiting or give food or drink. Seek medical attention

immediately. CALL NATIONAL BATTERY INGESTION HOTLINE for advice and follow-up (202-625-3333)
collect, day or night.

Inhalation: Contents of an open battery can cause respiratory irritation. Provide fresh air and seek medical
attention.

Skin Absorption: Dimethoxyethane and dioxolane may be absorbed through the skin, causing localized
inflammation.

Skin Contact: Contents of an open battery can cause skin irritation and/or chemical burns. Remove
contaminated clothing and wash skin with soap and water. If a chemical burn occurs or if irritation persists, seek

medical attention.
Eye Contact: Contents of an open battery can cause severe irritation and chemical burns. Immediately flush

eyes thoroughly with water for at least 15 minutes, lifting upper and lower lids, until no evidence of the chemical
remains. Seek medical attention.

Note: Carbon black is listed as a possible carcinogen by International Agency for Research on Cancer (IARC).

Lithium L91 Batteries

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10/17/01

SECTION V - PRECAUTIONS FOR SAFE HANDLING AND USE

Storage: Store in a cool, well ventilated area. Elevated temperatures can result in shortened battery life.

Mechanical Containment: Containment of this battery in a manner that obstructs or defeats the safety vent or

electrical disconnect mechanisms designed into this battery can result in fire and/or explosion and cause
personal injury and device damage. This battery is not designed to be potted, enclosed in hermetic

overpackaging, or sealed by any means that prevents free operation of the designed safety mechanisms.
Handling: Accidental short circuit for a few seconds will not seriously affect the battery. Prolonged short circuit

will cause the battery to lose energy, and can cause the safety release vent to open. Sources of short circuits
include jumbled batteries in bulk containers, metal jewelry, metal covered tables or metal belts used for
assembly of batteries into devices.

If soldering or welding to the battery is required, consult your Eveready Battery Company representative for
proper precautions to prevent seal damage or short circuit.

Charging: This battery is manufactured in a charged state. It is not designed for recharging. Recharging can
cause battery leakage or, in some cases, high pressure rupture. Inadvertent charging can occur if a battery is

installed backwards.
Labeling: If the Eveready label or package warnings are not visible, it is important to provide a package and/or

device label stating:

WARNING: FIRE, EXPLOSION, and BURN HAZARD. DO NOT OPEN BATTERY, DISPOSE OF IN
FIRE, HEAT ABOVE 100° C (212° F), EXPOSE CONTENTS TO WATER, RECHARGE, PUT IN
BACKWARDS, MIX WITH USED OR OTHER BATTERY TYPES - MAY EXPLODE OR LEAK AND

CAUSE PERSONAL INJURY.

Where accidental ingestion of small batteries is possible, the label should include:

WARNING: (1) KEEP AWAY FROM SMALL CHILDREN. IF SWALLOWED, PROMPTLY SEE
DOCTOR; HAVE DOCTOR PHONE [phone] COLLECT. (2) FIRE, EXPLOSION, BURN
HAZARD. DO NOT OPEN BATTERY, DISPOSE OF IN FIRE, HEAT ABOVE 100° C (212° F),
EXPOSE CONTENTS TO WATER, RECHARGE, PUT IN BACKWARDS, MIX WITH USED OR

OTHER BATTERY TYPES - MAY EXPLODE OR LEAK AND CAUSE PERSONAL INJURY.

Disposal: Dispose in accordance with all applicable federal, state and local regulations.

 2001 EVEREADY BATTERY COMPANY, INC.